A kind of surface modification test was introduced, by which plasma spray in argon atmosphere with CNC4500 system was applied for TA7 titanium alloy to be coated with molybdenum, and technology to produce metallurgica...A kind of surface modification test was introduced, by which plasma spray in argon atmosphere with CNC4500 system was applied for TA7 titanium alloy to be coated with molybdenum, and technology to produce metallurgical bonding at interface of coating and base meal was tested by heating in vacuum condition for diffusion after hot spray. With the help of scan electron microscope analysis （SEM）, the effect of argon inlet pressure and heating temperature on coating structure as well as product of diffusion layer were studied. The glued tensile test method was used to measure bonding strength of base metal to coating. The result has shown that both argon inlet pressure and heating temperature exert some effect on coating structure and the width of diffusion layer. A bonding strength of base metal to coating which is greater than molybdenum coating itself may be attained and can be controlled in more than 50 MPa level with tested hot spray technology.展开更多
We report the fabrication and photocarrier dynamics in graphene–MoSe2 heterostructures. The samples were fabricated by mechanical exfoliation and manual stacking techniques. Ultrafast laser measurements were performe...We report the fabrication and photocarrier dynamics in graphene–MoSe2 heterostructures. The samples were fabricated by mechanical exfoliation and manual stacking techniques. Ultrafast laser measurements were performed on the heterostructure and MoSe2 monolayer samples. By comparing the results, we conclude that photocarriers injected in MoSe2 of the heterostructure transfer to graphene on an ultrafast time scale. The carriers in graphene alter the optical absorption coefficient of MoSe2. These results illustrate the potential applications of this material in optoelectronic devices.展开更多
Mo-modified Pd/Al2O3catalysts were prepared by an impregnation method and tested for the catalytic combustion of benzene. The catalysts were characterized by N2 isothermal adsorption, X-ray diffraction（XRD）, X-ray p...Mo-modified Pd/Al2O3catalysts were prepared by an impregnation method and tested for the catalytic combustion of benzene. The catalysts were characterized by N2 isothermal adsorption, X-ray diffraction（XRD）, X-ray photoelectron spectroscopy（XPS）, temperatureprogrammed desorption of NH3（NH3-TPD）, H2temperature-programmed reduction（H2-TPR）, and high-angle annular dark-field scanning transmission electron microscopy（HAADF-STEM）. The results showed that the addition of Mo effectively improved the activity and stability of the Pd/Al2O3catalyst by increasing the dispersion of Pd active components, changing the partial oxidation state of palladium and increasing the oxygen species concentration on the surface of catalyst. In the case of the Pd-Mo/Al2O3catalyst,benzene conversion of 90% was obtained at temperatures as low as 190°C, which was 45°C lower than that for similar performance with the Pd/Al2O3catalyst. Moreover, the 1.0% Pd-5% Mo/Al2O3catalyst was more active than the 2.0% Pd/Al2O3catalyst. It was concluded that Pd and Mo have a synergistic effect in benzene catalytic combustion.展开更多
文摘A kind of surface modification test was introduced, by which plasma spray in argon atmosphere with CNC4500 system was applied for TA7 titanium alloy to be coated with molybdenum, and technology to produce metallurgical bonding at interface of coating and base meal was tested by heating in vacuum condition for diffusion after hot spray. With the help of scan electron microscope analysis （SEM）, the effect of argon inlet pressure and heating temperature on coating structure as well as product of diffusion layer were studied. The glued tensile test method was used to measure bonding strength of base metal to coating. The result has shown that both argon inlet pressure and heating temperature exert some effect on coating structure and the width of diffusion layer. A bonding strength of base metal to coating which is greater than molybdenum coating itself may be attained and can be controlled in more than 50 MPa level with tested hot spray technology.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.61275058,61527817,61335006,and 61378073)the National Science Foundation,China(Grant No.DMR-1505852)+1 种基金the National Basic Research Program of China(Grant Nos.2016YFA0202300 and 2016YFA0202302)Beijing Science and Technology Committee,China(Grant No.Z151100003315006)
文摘We report the fabrication and photocarrier dynamics in graphene–MoSe2 heterostructures. The samples were fabricated by mechanical exfoliation and manual stacking techniques. Ultrafast laser measurements were performed on the heterostructure and MoSe2 monolayer samples. By comparing the results, we conclude that photocarriers injected in MoSe2 of the heterostructure transfer to graphene on an ultrafast time scale. The carriers in graphene alter the optical absorption coefficient of MoSe2. These results illustrate the potential applications of this material in optoelectronic devices.
基金supported by the National High-Tech Research and Development Program (863) of China (No. 2008AA06XK1480855)
文摘Mo-modified Pd/Al2O3catalysts were prepared by an impregnation method and tested for the catalytic combustion of benzene. The catalysts were characterized by N2 isothermal adsorption, X-ray diffraction（XRD）, X-ray photoelectron spectroscopy（XPS）, temperatureprogrammed desorption of NH3（NH3-TPD）, H2temperature-programmed reduction（H2-TPR）, and high-angle annular dark-field scanning transmission electron microscopy（HAADF-STEM）. The results showed that the addition of Mo effectively improved the activity and stability of the Pd/Al2O3catalyst by increasing the dispersion of Pd active components, changing the partial oxidation state of palladium and increasing the oxygen species concentration on the surface of catalyst. In the case of the Pd-Mo/Al2O3catalyst,benzene conversion of 90% was obtained at temperatures as low as 190°C, which was 45°C lower than that for similar performance with the Pd/Al2O3catalyst. Moreover, the 1.0% Pd-5% Mo/Al2O3catalyst was more active than the 2.0% Pd/Al2O3catalyst. It was concluded that Pd and Mo have a synergistic effect in benzene catalytic combustion.
