Characteristics of Pegmatite-Related Fluids and Significance to Ore-Forming Processes in the Zhaxikang Pb-Zn-Sb Polymetallic Deposit,Tibet,China

The Zhaxikang Pb-Zn-Sb polymetallic deposit is one of the most important deposits in the newly recognized southern Tibet antimony-gold metallogenic belt.Compared to the porphyry deposits in the Gangdese belt,much less researches have addressed these deposits,and the genesis of the Zhaxikang deposit is still controversial.Based on field investigation,petrographic,microthermometric,Laser Raman Microprobe（LRM） and SEM/EDS analyses of fluid,melt-fluid,melt and solid inclusions in quartz and beryl from pegmatite,this paper documents the characteristics and the evolution of primary magmatic fluid which was genetically related to greisenization,pegmatitization,and silification in the area.The results show that the primary magmatic fluids were derived from unmixing between melt and fluid and underwent a phase separation process soon after the exsolution.The primary magmatic fluids are of low salinity,high temperature,and can be approximated by the H_2O-NaCl-CO_2 system.The presence of Mn-Fe carbonate in melt-fluid inclusions and a Zn-bearing mineral（gahnite） trapped in beryl and in inclusions from pegmatite indicates high Mn,Fe,and Zn concentrations in the parent magma and magmatic fluids,and implies a genetic link between pegmatite and Pb-Zn-Sb mineralization.High B and F concentrations in the parent magma largely lower the solidus of the magma and lead to late fluid exsolution,thus the primary magmatic fluids related to pegmatite have much lower temperature than those in most porphyry systems.Boiling of the primary magmatic fluids leads to high-salinity and high-temperature fluids which have high capacity to transport Pb,Zn and Sb.The decrease in temperature and mixing with fluids from other sources may have caused the precipitation of Pb-Zn-Sn（Au） minerals in the distal fault systems surrounding the causative intrusion.

REE Geochemistry of Sulfides from the Huize Zn-Pb Ore Field, Yunnan Province: Implication for the Sources of Ore-forming Metals

REE abundances in sulfides from the Huize Zn-Pb ore field were determined with the ICPMS after preconcentration. The REE abundances in 26 sulfide samples （including pyrite, galena and sphalerite） are very low, with the ~REE ranging from 1.6×10^-9 to 166.8×10^-9. Their LREE/HREE ratios range from 7.6 to 98, showing LREE enrichment relatively. The JEu values are below 1, indicating that they were deposited from an Eu-depleted and reducing fluid-system. Similar to the ore-hosting carbonate strata, calcite separates from carbonate veinlets filling in the fractures or faults crosscutting the carbonate strata also show clear Eu-depletion. This indicates that the carbonate veinlets and their parent fluid was possibly sourced from the strata and inherited the REE geochemical features of the strata. Therefore, REE-geochemical characteristics of both the sulfides and calcites, which were deposited from an ore-forming hydrothermal system, are similar to those of carbonate strata, and strongly suggest that the ore metals were mainly sourced from carbonate strata.

Geochemical Mobility Associated to Gold and Base Metal Occurrences of Mangodara Sector, in Southern Burkina Faso, Banfora Greenstone Belts (West African Craton)

In the Mangodara area within the Banfora greenstone belts (Baoulé-Mossi domain of the West African Craton), our study focused on geochemical assessment of the mobility of major and trace elements. Gold and base metal occurrences are hosted in highly metamorphic felsic (metarhyolite) and intermediate (metadacite and metaandesite) formations. Common mineral assemblages made up of staurolite - kyanite - pyrophyllite are interpreted to represent the metamorphosed equivalent of aluminous hydrothermal alteration. Associated felsic and intermediate volcanic rocks are enriched in Fe2O3, K2O (metaandesite, metarhyolite) and depleted in MgO, Al2O3, CaO, P2O5, Na2O (metarhyolite) and Fe2O3, MgO, CaO (metaandesite). Al2O3 depletion in mineralized kyanite-staurotide bearing metarhyolites suggests corroded minerals. Mineralized metarhyolites show enrichment in Au, Ag, Ba, Bi, Cr, Cu, Eu, La, Mo, Ni, Pb, S, Sc, V and depletion in As Sb Co, Sn, Zn while mineralized metaandesites show enrichment in Au, Ag, As, Mo, S, Sb and depletion in Co, Sn, Zn, Bi, Cr, Cu, Eu, Ni, Pb, Sc. Ba, La, V are immobile in metaandesites. Finally, Ag, As, Sn appear as geochemical vectors for gold exploration in the study area since gold mineralization is characterized by Au + Ba + Cu + Eu + La + Mo + Ni + S association in metarhyolites and Au + S + Sb + As + Ag + Bi in metaandesites.

Characteristics and evolution of ore-forming fluids of the Chongjiang copper deposit in the Gangdise porphyry copper belt, Tibet

Petrography, microthermometry, and scanning electron microscope/energy dispersive spectrometer （SEM/EDS） studies were performed on the fluid inclusions in the ore-beating quartz veins and quartz phenocrysts in the porphyry of the Chongjiang porphyry copper deposit. The analyses of the fluid inclusions indicate that the ore-forming fluids were exsolved from magma. They are near-saturated, supercritical, rich in volatile constituents, and have the capture temperature of 362-389℃ and salinities of 17.7wt%- 18.9wt% NaC1 eq. With the decreasing of temperature and pressure, the supercritical fluids were separated into a low salinity vapor phase and a high salinity liquid phase. During quartz-sericitization, the high salinity fluid boiled and separated into a low salinity vapor phase and a high salinity liquid phase. The high salinity inclusions that formed in the boiling process had daughter mineral melting temperatures higher than the homogenization temperatures of the vapor and liquid phases. The late fluids that are responsible for argillization are of lower temperature and salinity.

A Metallogenic Model of Gold Deposits of the Jiaodong Granite-Greenstone Belt

An analysis of trace elements and isotopic geochemistry suggest that the ore-forming materials of gold deposits in the Jiaodong granite-greenstone belt have multiple sources, especially the mantle source. Seismic wave, magnetic and gravity fields show that the crust-mantle structure and its coupling mechanism are the fundamental dynamic causes for the exchange and accumulation of materials and energy in the metallogenic system. Considering the evolution history of the structural setting, the tectono-metallogenic dynamics model of the area can be summarized as follows: (1) occurrence of the greenstone belt during the Archean-Proterozoic-the embryonic form of Au-source system; (2) stable tectonic setting in the Paleozoic-an intermittence in gold mineralization; (3) intensive activation and reformation of the greenstone belt in the Mesozoic-tectono-mineralization and tectono-diagensis; (4) posthumous structural activity in the Cenozoic-destruction of orebodies in the later stage. In the middle and late Indosinian, the Tancheng-Lujiang fault zone cut deeply into the upper mantle so that the ore-bearing fluids migrated to higher layers through the crust-mantle interaction, resulting in alteration and mineralization.

Effects of heavy metal pollution on farmland soils and crops:A case study of the Xiaoqinling Gold Belt,China

This paper focuses on the heavy metal enrichment and heavy metal pollution degree associated with mining activities in some crops and the soils of different parent materials in the Xiaoqinling Gold Belt.According to the geochemical analysis results of the soils observed in the gold belt,the soils are most highly enriched in Pb,followed by Cr,Cu,and Zn.Furthermore,they are relatively poor in Hg,Cd,and As.It is also shown that the heavy metals in all kinds of soils have the same geochemical characteristics in the gold belt.As for the crops(such as corn and wheat)in the gold belt,Zn and Cu are the most abundant elements,followed by Pb and Cr.Meanwhile,Hg,Cd,and As were found to have relatively low concentrations in the crops.The heavy metals in wheat and corn have the same geochemical characteristics in the gold belt in general.Compared to the aeolian loess soils and the crops therein,heavy metals are more enriched in diluvial and alluvial soils and the crops therein.As shown by relevant studies,the Hg,Pb,Cd,Cu,and Zn pollution are mainly caused by mining activities.Corn and wheat in the gold belt have a high tendency of risk exposure to heavy metal pollution since they are mostly affected by mining activities and feature high background values of heavy metal concentrations.Furthermore,wheat is more liable to be enriched in heavy metals than corn is grown in all types of soils.The Hg pollution in soils leads to Hg accumulation,increasing the risk of Hg uptake in crops,and further affecting human health.This study will provide a scientific basis for the control and management of heavy metals in farmland soils of mining areas.

Discussion on the Source of Ore-forming Materials of the Yinan Gold Deposit,Shandong

Based on the main characteristics of the tectonic -magmatic evolution of region and Tanlu fault zone,we have discussed ore-bearing magmatic rocks petrochemistry,strontium and lead isotope,and the source of ore-forming materials in Yinan skarn deposit in this paper.The petrochemical features show that the ore-bearing magmatic rocks are calc-alkaline rocks of sub-alkaline series formed during

Mykert-Sanzheevka Field of Polycomponent Ores (Pb, Zn, Ag, Au, PGE): Geologic-Substance Characteristics and Formation Features of Ore-Forming System

The new results of geologic-structural, petrographic and mineralogic-geochemical researches of Mykert-Sanzheevka ore field—the Uda-Vitim mineragenic zone South-West ending of West Transbaikalia are given. Its main ore-controlling structure, represented by losange, consisting of rhombohedral and tetrahedral blocks-duplexes mosaic clusters, which are separated by narrow tectonic sutures, is specified. It is clarified that polycomponent ores clusters are confined with these small-block sutures, made by subvolcanic dykes of shoshonite-latite volcano-plutonic association (233 - 188 million years), apodyke dynamometamorphites (breccias, cataclasite, mylonites) and also mechanometasomatites. Four stages of the dynamometamorphites formation characterized by different species compositions of ore minerals appeared as a result of mechanochemical reactions are determined. A carbonyl model of mineral microaggregates formation with films containing noble metal nanoparticles is proposed. Ore-forming system features of Mykert-Sanzheevka field are considered.

Investigating the Whole-lithosphere Structure of a Mineral System——Pathways and Source of Ore-forming Fluids Imaged with Magnetotelluric Modeling

Whole-lithosphere structure has direct implications for both the genesis of minerals and the locations of mineral emplacement;thus knowledge of the deep structural framework of the lithosphere can advance understanding of the development and evolution of mineral systems.

Ore Forming Systems (Fe, Ti, Ni, Pb, Zn, Noble Metals) of the Transbaikalia Neoproterozoic Greenstone Belts

It is shown that the ore-forming systems (OFS) of the Vendian-Riphean Greenstone belts (GSB) in the Transbaikalia region were formed in a wide age range: from the Riphean to the Cenozoic. They are grouped into 6 metallogenic types. The noble metal type is divided into 6 metallogenic subtypes differed in time duration intervals of functioning. OFS evolution wore multistage nature inherited from the composition of the GSB primary rocks, with a tendency of the ore generating processes remobilization and regeneration (dynamometamorphism) changing over time by rejuvenation (shoshonite latite and picrobasalt magmatism, mud volcanism).

喜马拉雅琼嘉岗伟晶岩型锂矿成矿地质特征和形成机制

西藏喜马拉雅琼嘉岗伟晶岩型锂矿是喜马拉雅稀有金属成矿带标志性的伟晶岩型矿床。其成矿地质特征、成矿机理-机制和含矿性评价的研究对喜马拉雅稀有金属成矿带的形成机制和找矿勘查工作研究具有重要意义。中国科学院地质与地球物理研究所在2021~2023年期间对喜马拉雅琼嘉岗伟晶岩型锂矿形成机制研究中,获得如下认识:(1)琼嘉岗锂辉石伟晶岩的主矿体主要顺矽卡岩化大理岩和钙质千枚岩面理侵入,中部整体上呈板状近水平(10°~20°),主矿体两侧倾角相对较大(30°~50°);(2)琼嘉岗矿床的富锂矿物主要为锂辉石(包括3个期次),次为透锂长石、锂绿泥石、锂云母等,其他稀有金属矿物包括绿柱石、日光榴石、羟硅铍石、铌锰矿-铌铁矿、锡石等,围岩蚀变主要为矽卡岩化并含有少量锡矿化;(3)琼嘉岗锂矿中花岗岩-伟晶岩的演化和成矿受岩浆结晶分异过程控制,锂辉石伟晶岩矿体的形成与系统大量流体出溶有关,花岗质熔体演化的早期阶段稀有金属可能达到饱和;(4)钾长石Ti温度计和流体包裹体等容线相交法揭示出从电气石白云母花岗岩到锂辉石伟晶岩呈现降温趋势,锂辉石伟晶岩石英形成时流体的捕获温度为410~475℃,捕获压力为180~240MPa,结合含锂矿物相关系揭示出降压是锂辉石伟晶岩形成的重要机制;(5)建立了琼嘉岗锂矿的成矿模式,指出高度结晶分异、流体出溶和降压过程控制了琼嘉岗锂辉石伟晶岩的形成,流体交代作用形成了稀有金属矿化;(6)长石结构和化学成分(Rb、Cs、Sr、Ba、K/Rb和形成温度)、石榴子石组成(高水含量、高Mn/(Mn+Fe)的锰铝榴石)、副矿物组成及其包裹矿物类型是琼嘉岗及周边伟晶岩含矿性评价的有效指标。

宁夏沿黄城市带土壤重金属分布特征及其生态风险评价

宁夏沿黄城市带是黄河中上游重要的产业聚集区,其土壤健康状况对黄河流域生态保护和高质量发展先行区建设具有重要意义。为摸清沿黄城市带土壤重金属现状及生态风险,该研究取样检测了该区域682个样点的土壤重金属元素含量,分析了其生态风险,并进行了溯源。研究结果表明:(1)宁夏沿黄城市带0~20 cm土壤砷(As)、铬(Cr)、铜(Cu)、锰(Mn)、铅(Pb)、锌(Zn)、镍(Ni)和镉(Cd)8种重金属元素平均值分别为(3.11±1.88)、(60.66±15.64)、(17.86±6.10)、(509.92±186.74)、(17.62±11.10)、(57.36±25.33)、(25.23±4.95)和(0.77±0.49) mg/kg。0~20 cm土层重金属元素平均含量均低于土壤背景值,也低于农用地土壤污染风险筛选值。0~5 cm土层重金属元素含量高于0~20 cm土层,且Cr、Mn、Zn和Cd 4种元素含量超过了土壤背景值。(2)沿黄城市带中As、Cr、Cu、Mn、Pb、Zn和Ni这7种元素对环境污染风险极低。大部分区域土壤Cd含量明显高于背景值,污染风险较高。(3)沿黄城市带重金属元素有5种来源,其中母质源对重金属来源贡献率最高,其次为农业和工业复合源、交通运输源,农业源和工业源对重金属元素贡献小。研究结果表明宁夏沿黄城市带土壤重金属有较高等级的Cd生态风险,值得关注。

新疆阿尔泰造山带伟晶岩型稀有金属矿床成矿作用

花岗伟晶岩与稀有金属(Li、Be、Nb、Ta等)矿床关系密切。关于伟晶岩成矿模式、伟晶岩与花岗岩之间的成因关系等,已有大量研究和讨论,但仍然存在争议。新疆阿尔泰是我国著名的伟晶岩及稀有金属矿床集中区,研究资料丰富。本文系统分析了阿尔泰伟晶岩的地质背景与成矿地质特征,阐明阿尔泰造山带伟晶岩与花岗岩存在3种关系:(1)缺乏成因联系,伟晶岩可能为变质脱水熔融形成的独立伟晶岩;(2)可能为“兄弟关系”;(3)可能为“母子关系”,共同构成花岗岩-伟晶岩成岩成矿系统。作者提出一个包含多种成因伟晶岩的成岩成矿构造模式,可能在矿带、矿田、矿床尺度上都适用。阿尔泰造山带稀有金属伟晶岩成矿省的形成受到古生代地层的控制。阿尔泰造山带处于典型的幔坡带,为长期活跃的构造活动带,极易受到外部构造域的干扰,在晚三叠纪受到特提斯构造域的一系列陆块向北漂移并拼贴到欧亚大陆南缘的远程效应影响而发生大规模的稀有金属成矿作用,在侏罗纪,其构造活动及成岩成矿作用则受新特提斯构造域和蒙古-鄂霍茨克洋构造域地质作用的远程效应共同影响。

滇西高黎贡山地区培里伟晶岩型锂矿化的发现及其意义

稀有金属锂矿是我国紧需的战略性矿产资源。滇西地区是我国重要的稀有金属成矿远景区,但目前区内已知的稀有金属资源主要为Be-Nb-Ta-Sn矿,鲜有锂矿的报道。本研究首次在滇西高黎贡山培里地区发现了锂辉石伟晶岩型锂矿,为云南省新增一处有潜力的锂辉石型伟晶岩锂矿床,对区域稀有金属锂矿床的找矿工作具有重要意义。6个样品的全岩主微量元素分析显示培里地区伟晶岩主要发育有Li、Be、Rb、Cs、Nb、Ta矿化。LA-ICP-MS铌钽矿U-Pb年代学结果显示培里地区锂矿伟晶岩形成于18.4±0.3Ma,这一结果与共生的锡石U-Pb年代学(17.5±1.2Ma)结果一致,表明其为新生代成岩成矿作用产物。这一成矿年代与高黎贡山地区变质年代以及淡色花岗岩成岩年代一致,暗示培里伟晶岩可能为变质重熔产物,也可能是淡色花岗岩进一步结晶分异的产物。在大区域尺度上,该成矿事件与藏南稀有金属成矿时代一致,结合区域显著的地球化学背景异常,我们认为滇西地区可能是喜马拉雅稀有金属成矿带的南延部分,具有良好的稀有金属锂矿找矿前景。

川西扎乌龙地区卡吉亚二云母花岗岩、稀有金属伟晶岩的地球化学、年代学特征及二者的成矿关系

锂-铍等稀有金属是中国乃至世界上重要的战略性关键金属矿产,美国、澳大利亚和日本等国早已将其列为禁止出口矿产名录,其战略地位非同一般。中国锂-铍矿产资源丰富,成矿背景优越,但地表第四纪覆盖严重,且分布不均。近年甜水海-松潘-甘孜造山带花岗伟晶岩型锂矿资源逐步被勘探发现,引起国内外学者广泛关注。川西石渠县扎乌龙锂矿作为该造山带中部重要的花岗伟晶岩型锂矿点,厘清该矿床锂资源聚集主控因素及其稀有金属富集规律将为甜水海-松潘-甘孜造山带下一步战略找矿行动提供指导和重要决策依据。本文对扎乌龙地区锂辉石钠长石伟晶岩脉、白云母钠长伟晶岩脉、电气石钠长石伟晶岩脉、卡吉亚二云母花岗岩体以及岩体边部的含电气石细晶岩、十字石黑云母片岩等进行系统采样分析,利用LA-ICP-MS独居石U-Th-Pb同位素定年技术,确定扎乌龙卡吉亚二云母花岗岩形成于晚三叠世213~211 Ma,含电气石细晶岩约形成于210 Ma,白云母钠长石伟晶岩约形成于210~200 Ma,富锂伟晶岩可能在205 Ma集中产出。结合前人年代学资料,综合分析认为扎乌龙矿区由二云母花岗岩、电气石细晶岩到白云母钠长石伟晶岩和锂辉石钠长石伟晶岩形成时代逐步年轻。210 Ma以后,岩浆演化逐步进入岩浆-热液阶段,在约10 Ma时间内发生了持续、多期次的岩浆侵位活动。此外,结合花岗岩向伟晶岩逐步降低的REE、K/Rb、Nb/Ta和Zr/Hf等微量特征值,以及高演化伟晶岩独居石矿物Nd、Eu负异常现象,表明花岗质岩浆的结晶分异作用在扎乌龙伟晶岩稀有金属富集过程中发挥着重要作用。

西藏龙玛拉矽卡岩型铅锌多金属矿床金属矿物特征及地质意义

龙玛拉铅锌多金属矿床是冈底斯成矿带东段北缘念青唐古拉矽卡岩型多金属成矿带一个典型的铅锌矿床,矿床以铅锌银矿化为主,伴生铁铜矿化,具有矿化元素丰富,品位高的特点。矿体在纵向上发育明显的矿化分带,从矿体顶部向下依次发育铅锌银矿化、锌铜矿化、铁铜矿化和铁矿化,表现出从矿体顶部到矿体,从低温到高温的元素和矿物组合的分布规律。镜下鉴定及电子探针分析结果表明,矿床主要金属矿物有方铅矿、闪锌矿、黄铜矿、黄铁矿、磁黄铁矿和磁铁矿,同时存在少量的斜方辉铅铋矿、自然铋等铋矿物以及白铁矿、铜蓝、孔雀石等次生矿物,金属矿物间具有复杂的穿插交代关系,根据详细的野外观察和镜下鉴定厘清了矿物生成顺序。黄铁矿Co/Ni比值集中在1~5之间,显示出岩浆热液成因的特点,其Fe/(S+As)比值和胶状黄铁矿的出现暗示矿床形成于中浅成环境,闪锌矿富Fe、Mn,多为铁闪锌矿,表明其形成于中高温环境,按照Fe元素温度计估算出闪锌矿成矿温度为259~305℃,磁黄铁矿以单斜磁黄铁矿为主,为低温成因,且在浅部围岩和矿体中均大量出现,显示出成矿流体运移至近地表后快速降温,在强还原条件下发生了硫化物沉淀,龙玛拉矿床为远端岩浆热液矽卡岩型矿床。矿床中铋矿物与银具有密切的时空关系,指示铋对银的富集可能具有重要作用,对该带银成矿规律的研究具有一定的指示意义。

全球淡色花岗岩的地球化学特征及其与稀有金属的成矿联系

【研究目的】近年来,淡色花岗岩成为岩石学和稀有金属成矿学研究的热点,但全球淡色花岗岩的时空分布特征尚不明确。本文旨在探讨全球淡色花岗岩的时空分布特征及其成矿专属性,进而指导勘查实践。【研究方法】文章系统梳理了全球115个淡色花岗岩体1155组地球化学数据,并结合项目组在南岭、川西、藏南、阿尔泰等地的工作,对数据开展综合分析研究。【研究结果】在成分上,淡色花岗岩的SiO_(2)含量较全球花岗岩平均值高1%以上,发生稀有金属矿化的岩体稀土含量极低。在空间上,中西欧海西造山带淡色花岗岩的SiO_(2)和ALK(Na_(2)O+K_(2)O)含量低于喜马拉雅淡色花岗岩,也低于中国西部淡色花岗岩,而中国西部淡色花岗岩的SiO_(2)和ALK含量又低于中国东部的淡色花岗岩,中西欧和北美地区的淡色花岗岩富集P_(2)O_(5);样品中Li、Be、Nb、Ta、Ga、Rb和Sn含量的最高平均值均出现在中西欧地区,W含量最高平均值出现在中国东部。在时间上,新生代淡色花岗岩的SiO_(2)和ALK含量高于古生代,低于中生代;古生代淡色花岗岩富集P_(2)O_(5);电气石是新元古代淡色花岗岩的一个重要矿物特征。【结论】成矿的淡色花岗岩一般不含岩浆型石榴子石,A/CNK>1.2,与Sn–W–Nb–Ta成矿有关的淡色花岗岩的Rb/Sr>1,ΣREE>10×10^(−6),与Li–Sn–Nb–Ta–Be成矿有关的淡色花岗岩的Rb/Sr>1,ΣREE<10×10^(−6)。相比之下,中国东部中生代淡色花岗岩演化程度最高,成矿潜力最好。

安徽安庆铜铁矿床钴的赋存状态、分布与富集规律研究

长江中下游成矿带是我国东部最重要的成矿带之一,广泛发育矽卡岩型铜铁矿床且伴生Co资源,而成矿带内的矽卡岩型铜铁矿床中关键金属Co元素的赋存状态、分布以及富集规律研究尚未系统开展。本文以矽卡岩型铜铁矿床——安庆铜矿为研究对象,通过系统采样、显微观察、扫描电子显微镜、全岩化学分析及矿物原位LA-ICP MS微量成分测试手段,初步估算矿床中伴生Co的资源量约为8769t,达到中型规模,查明了伴生Co的平均含量为166×10^(-6),综合利用潜力较大。查明了铜矿石中Co含量(平均含量为166×10^(-6))明显高于铁矿石(平均含量为126×10^(-6)),尤其是含铜磁黄铁矿型矿石中Co元素富集程度最高,且计算得出磁黄铁矿、黄铁矿、磁铁矿和黄铜矿分别赋存矿石Co含量的45.1%、52.8%、0.5%和1.6%。此外,矿床内不同类型矿化蚀变岩中Co含量与磁黄铁矿和黄铁矿总量具有较强的正相关性,Co主要以类质同像的形式赋存于黄铁矿和磁黄铁矿内,黄铁矿中Co的含量变化范围较大,早石英硫化物阶段的黄铁矿(Py1)中Co含量为258×10^(-6)~25920×10^(-6),晚石英硫化物阶段的黄铁矿(Py2)中Co含量为0.3×10^(-6)~594×10^(-6),磁黄铁矿中Co含量变化范围较小,主要集中于311×10^(-6)~1181×10^(-6),Co主要富集于早石英硫化物阶段,晚石英硫化物阶段不富集。含铜磁黄铁矿型矿石中Co元素变化范围大(85×10^(-6)~430×10^(-6))是由于矿石中黄铁矿和磁黄铁矿的含量以及黄铁矿Co含量极不均匀造成的。综合前人研究,本次工作认为大气降水混入引起的成矿流体冷却和稀释可能是导致安庆铜矿中Co元素沉淀富集在黄铁矿和磁黄铁矿内的主要因素。

长江经济带非金属矿采矿权时空变化特征分析

文章基于长江经济带非金属矿产数据,利用地理信息系统(geographic information system,GIS)空间分析方法和脱钩模型研究2007—2018年期间该地区非金属矿采矿权分布的时空变化特征。结果表明:非金属矿开采重心呈现出向西部地区移动的趋势;非金属矿采矿权分布呈现“西南—东北”的空间格局,且非金属矿高开采强度区呈现出收缩趋势;非金属矿采矿权分布具有显著的空间正相关特性,其中,高-高类型区域分布在贵州、江西等省份,低-低类型区域分布在浙江、江苏、安徽等省份;非金属矿采矿权面积与经济增长脱钩状态稳定,脱钩情况理想,经济发展对非金属矿产开发依赖性减小;建筑石料用灰岩采矿权分布的时空规律和非金属矿采矿权分布的时空规律相似,均呈现开采重心向西部偏移的态势。该研究结果反映了在2007—2018年中国经济高速发展期间,长江经济带非金属矿采矿权分布的时空特征变化及其影响因素,为今后非金属矿产资源开发空间布局优化提供空间决策参考。

北淮阳成矿带东段岩浆岩成矿特征研究

安徽北淮阳成矿带中生代岩浆作用强烈,成岩与成矿具有紧密的时空关系和成因联系,广泛发育钼、铅、锌、金等多金属矿化。通过对北淮阳成矿带东段区域基本地质特征、成矿地质作用和成矿规律开展研究,发现该区域上白垩纪早期成矿作用以Au、Ag、Pb、Zn等矿种为主,与之相关的岩浆作用为高钾钙碱和钾玄岩系列的火山岩和侵入岩;而白垩纪晚期的成矿作用以Mo成矿为主,与之相关的岩浆作用主要为碱性深成岩。北淮阳地区进行勘察找矿工作的过程中,应该以白垩纪晚期的(石英)正长岩-花岗斑岩作为重点关注对象。