Two kinds of high strength-damping aluminum alloys (LZ7) were fabricated by rapid solidification and powder metallurgy (RS-PM) process. One material was extruded to profile aluminum directly and the other was extr...Two kinds of high strength-damping aluminum alloys (LZ7) were fabricated by rapid solidification and powder metallurgy (RS-PM) process. One material was extruded to profile aluminum directly and the other was extruded to bar and then rolled to sheet. The damping capacity over a temperature range of 25-300 ℃was studied with damping mechanical thermal analyzer (DMTA) and the microstructures were investigated by optical microscopy (OM), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The experimental results show that the damping capacity increases with the test temperature elevating. Internal friction value of rolled sheet aluminum is up to 11.5×10^-2 and that of profile aluminum is as high as 6.0×10^-2 and 7.5×10^-2 at 300 ℃, respectively. Microstructure analysis shows the shape of precipitation phase of rolled alloy is more regular and the distribution is more homogeneous than that of profile alloy. Meanwhile, the interface between particulate and matrix of rolled sheet alloy is looser than that of profile alloy. Maybe the differences at interface can explain why damping capacity of rolled sheet alloy is higher than that of profile alloys at high temperature (above 120 ℃).展开更多
The potential of powder metallurgy processing for the manufacture of Al?SrB6 composites was explored. Al4Sr particles fractured extensively during the ball milling of Al?15Sr/Al?4B powder mixtures. There was no intera...The potential of powder metallurgy processing for the manufacture of Al?SrB6 composites was explored. Al4Sr particles fractured extensively during the ball milling of Al?15Sr/Al?4B powder mixtures. There was no interaction between the Al4Sr and AlB2 compounds across the section of the aluminium grains in the as-milled state. SrB6 formed, when the ball milled powder blends were subsequently annealed at sufficiently high temperatures. Ball milling for 1 h was sufficient for SrB6 to become the major constituent in powder blends annealed at 700 °C while it took 2 h of ball milling for powder blends annealed at 600 °C. Higher annealing temperatures and longer ball milling time encouraged the formation of the SrB6 compound while the latter made a great impact on the microstructural features of the Al?SrB6 composite. The SrB6 compound particles were much smaller and more uniformly distributed across the aluminium matrix grains in powder grains ball milled for 2 h before the annealing treatments at 600 °C and 700 °C.展开更多
TiAI-based alloys with various compositions (including Ti-48Al, Ti-47Al-2Cr-2Nb, Ti-47Al-2Cr-2Nb-0.2B and Ti-47Al-3Cr, in mole fraction) had been prepared by elemental powder metallurgy (EPM). The results have shown t...TiAI-based alloys with various compositions (including Ti-48Al, Ti-47Al-2Cr-2Nb, Ti-47Al-2Cr-2Nb-0.2B and Ti-47Al-3Cr, in mole fraction) had been prepared by elemental powder metallurgy (EPM). The results have shown that the density of the prepared Ti-48AI alloy increases with increasing hot pressing temperature up to 1300℃. The Ti-48AI alloy microstructure mainly consisted of island-like Ti3Al phase and TiAl matrix at hot pressing temperature below 1300℃, however, coarse α2/γ lamellar colonies and γ grains appeared at 1400℃. It has also indicated that the additions of elemental Cr and B can refine the alloy microstructure. The main microstructural inhomogeneity in EPM TiAI-based alloys was the island-like α2 phase or the aggregate of α2/γ lamellar colony, and such island-like structure will be inherited during subsequent heat treatment in (α+γ) field. Only after heat treatment in a field would this structure be eliminated. The mechanical properties of EPM TiAl-based alloys with various compositions were tested, and the effect of alloy elements on the mechanical properties was closely related to that of alloy elements on the alloy microstructures. Based on the above results, TiAI-based alloy exhaust valves were fabricated by elemental powder metallurgy and diffusion joining. The automobile engine test had demonstrated that the performance of the manufactured valves was very promising for engine service.展开更多
Reducing CO_(2)emissions of the iron and steel industry,a typical heavy CO_(2)-emitting sector is the only way that must be passed to achieve the‘dual-carbon’goal,especially in China.In previous studies,however,it i...Reducing CO_(2)emissions of the iron and steel industry,a typical heavy CO_(2)-emitting sector is the only way that must be passed to achieve the‘dual-carbon’goal,especially in China.In previous studies,however,it is still unknown what is the difference between blast furnace basic oxygen furnace(BF-BOF),scrap-electric furnace(scrap-EF)and hydrogen metallurgy process.The quantitative research on the key factors affecting CO_(2)emissions is insufficient There is also a lack of research on the prediction of CO_(2)emissions by adjusting industria structure.Based on material flow analysis,this study establishes carbon flow diagrams o three processes,and then analyze the key factors affecting CO_(2)emissions.CO_(2)emissions of the iron and steel industry in the future is predicted by adjusting industrial structure The results show that:(1)The CO_(2)emissions of BF-BOF,scrap-EF and hydrogen metallurgy process in a site are 1417.26,542.93 and 1166.52 kg,respectively.(2)By increasing pellet ratio in blast furnace,scrap ratio in electric furnace,etc.,can effectively reduce CO_(2)emissions(3)Reducing the crude steel output is the most effective CO_(2)reduction measure.There is still 5.15×10^(8)-6.17×10^(8) tons of CO_(2)that needs to be reduced by additional measures.展开更多
A new technology was developed to recover V2O5 from Bayer spent liquor by ion exchange.The experimental results show that in the conditions of 105℃ and 0.20-0.25 mass ratios between CaO in lime and Al2O3 in spent liq...A new technology was developed to recover V2O5 from Bayer spent liquor by ion exchange.The experimental results show that in the conditions of 105℃ and 0.20-0.25 mass ratios between CaO in lime and Al2O3 in spent liquor, the precipitation rate of vanadium in Bayer liquor is more than 85%.The vanadium-bearing precipitation is leached by NaHCO3 solution.The leaching rate of vanadium can reach 85% in the conditions of 95℃, 40 g·L-1 of NaHCO3 concentration, and ventilating of CO2.The 201 × 7 type of resin has good adsorption effect on vanadium in the leaching solution.The adsorption rate is more than 94% with the flow rate of 0.09 mL·min-1·g-1 of leaching solution and the temperature of 40-50℃.By using 3 mol·L-1 of NaOH to desorb the saturated resin after adsorption at 40-50℃, a solution with more than 5 g·L-1 of V2O5 can be obtained.After roasting ammonium metavanadate that precipitates from the desorption solution when NH4Cl is added at the temperature of 500-550℃ for 2 h, V2O5 with more than 99% of purity is obtained.展开更多
基金Project (50971012) supported by the National Natural Science Foundation of China
文摘Two kinds of high strength-damping aluminum alloys (LZ7) were fabricated by rapid solidification and powder metallurgy (RS-PM) process. One material was extruded to profile aluminum directly and the other was extruded to bar and then rolled to sheet. The damping capacity over a temperature range of 25-300 ℃was studied with damping mechanical thermal analyzer (DMTA) and the microstructures were investigated by optical microscopy (OM), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The experimental results show that the damping capacity increases with the test temperature elevating. Internal friction value of rolled sheet aluminum is up to 11.5×10^-2 and that of profile aluminum is as high as 6.0×10^-2 and 7.5×10^-2 at 300 ℃, respectively. Microstructure analysis shows the shape of precipitation phase of rolled alloy is more regular and the distribution is more homogeneous than that of profile alloy. Meanwhile, the interface between particulate and matrix of rolled sheet alloy is looser than that of profile alloy. Maybe the differences at interface can explain why damping capacity of rolled sheet alloy is higher than that of profile alloys at high temperature (above 120 ℃).
文摘The potential of powder metallurgy processing for the manufacture of Al?SrB6 composites was explored. Al4Sr particles fractured extensively during the ball milling of Al?15Sr/Al?4B powder mixtures. There was no interaction between the Al4Sr and AlB2 compounds across the section of the aluminium grains in the as-milled state. SrB6 formed, when the ball milled powder blends were subsequently annealed at sufficiently high temperatures. Ball milling for 1 h was sufficient for SrB6 to become the major constituent in powder blends annealed at 700 °C while it took 2 h of ball milling for powder blends annealed at 600 °C. Higher annealing temperatures and longer ball milling time encouraged the formation of the SrB6 compound while the latter made a great impact on the microstructural features of the Al?SrB6 composite. The SrB6 compound particles were much smaller and more uniformly distributed across the aluminium matrix grains in powder grains ball milled for 2 h before the annealing treatments at 600 °C and 700 °C.
基金the National Natural Science Foundation of China (Project 59895150) and the National Advanced Materials Committee (Project 7
文摘TiAI-based alloys with various compositions (including Ti-48Al, Ti-47Al-2Cr-2Nb, Ti-47Al-2Cr-2Nb-0.2B and Ti-47Al-3Cr, in mole fraction) had been prepared by elemental powder metallurgy (EPM). The results have shown that the density of the prepared Ti-48AI alloy increases with increasing hot pressing temperature up to 1300℃. The Ti-48AI alloy microstructure mainly consisted of island-like Ti3Al phase and TiAl matrix at hot pressing temperature below 1300℃, however, coarse α2/γ lamellar colonies and γ grains appeared at 1400℃. It has also indicated that the additions of elemental Cr and B can refine the alloy microstructure. The main microstructural inhomogeneity in EPM TiAI-based alloys was the island-like α2 phase or the aggregate of α2/γ lamellar colony, and such island-like structure will be inherited during subsequent heat treatment in (α+γ) field. Only after heat treatment in a field would this structure be eliminated. The mechanical properties of EPM TiAl-based alloys with various compositions were tested, and the effect of alloy elements on the mechanical properties was closely related to that of alloy elements on the alloy microstructures. Based on the above results, TiAI-based alloy exhaust valves were fabricated by elemental powder metallurgy and diffusion joining. The automobile engine test had demonstrated that the performance of the manufactured valves was very promising for engine service.
基金supported by the National Natural Science Foundation of China(No.52270177)the Young Elite Scientists Sponsorship Program by CAST(No.2022QNRC001)the Key R&D Plan of Liaoning Province(No.2021JH2/10300103)。
文摘Reducing CO_(2)emissions of the iron and steel industry,a typical heavy CO_(2)-emitting sector is the only way that must be passed to achieve the‘dual-carbon’goal,especially in China.In previous studies,however,it is still unknown what is the difference between blast furnace basic oxygen furnace(BF-BOF),scrap-electric furnace(scrap-EF)and hydrogen metallurgy process.The quantitative research on the key factors affecting CO_(2)emissions is insufficient There is also a lack of research on the prediction of CO_(2)emissions by adjusting industria structure.Based on material flow analysis,this study establishes carbon flow diagrams o three processes,and then analyze the key factors affecting CO_(2)emissions.CO_(2)emissions of the iron and steel industry in the future is predicted by adjusting industrial structure The results show that:(1)The CO_(2)emissions of BF-BOF,scrap-EF and hydrogen metallurgy process in a site are 1417.26,542.93 and 1166.52 kg,respectively.(2)By increasing pellet ratio in blast furnace,scrap ratio in electric furnace,etc.,can effectively reduce CO_(2)emissions(3)Reducing the crude steel output is the most effective CO_(2)reduction measure.There is still 5.15×10^(8)-6.17×10^(8) tons of CO_(2)that needs to be reduced by additional measures.
文摘A new technology was developed to recover V2O5 from Bayer spent liquor by ion exchange.The experimental results show that in the conditions of 105℃ and 0.20-0.25 mass ratios between CaO in lime and Al2O3 in spent liquor, the precipitation rate of vanadium in Bayer liquor is more than 85%.The vanadium-bearing precipitation is leached by NaHCO3 solution.The leaching rate of vanadium can reach 85% in the conditions of 95℃, 40 g·L-1 of NaHCO3 concentration, and ventilating of CO2.The 201 × 7 type of resin has good adsorption effect on vanadium in the leaching solution.The adsorption rate is more than 94% with the flow rate of 0.09 mL·min-1·g-1 of leaching solution and the temperature of 40-50℃.By using 3 mol·L-1 of NaOH to desorb the saturated resin after adsorption at 40-50℃, a solution with more than 5 g·L-1 of V2O5 can be obtained.After roasting ammonium metavanadate that precipitates from the desorption solution when NH4Cl is added at the temperature of 500-550℃ for 2 h, V2O5 with more than 99% of purity is obtained.