The methoxycarbonylations of cyclohexene and 1-decene with CO2 can take place under ambient conditions by catalysis of [Co]([Co]=Co(acac)(2), Co(OAc)(2), CoCl2) in the presence of ultraviolet irradiation.
Methoxycarbonylation was performed on 1-heptene, 1-octene and 1-dodecene with Co(acac)(2) catalyst in the presence of UV light under ambient conditions.
基金the Natural Science & Technology Foundation Council of Liaoning ProvinceOpen Laboratory of Carbon Resource Utilization of Da
文摘The methoxycarbonylations of cyclohexene and 1-decene with CO2 can take place under ambient conditions by catalysis of [Co]([Co]=Co(acac)(2), Co(OAc)(2), CoCl2) in the presence of ultraviolet irradiation.
文摘Methoxycarbonylation was performed on 1-heptene, 1-octene and 1-dodecene with Co(acac)(2) catalyst in the presence of UV light under ambient conditions.