A lead-free base glaze suitable for pearlescent pigments was prepared by a low-temperature solid-phase reaction with alkali waste.Tests were performed to evaluate the effects of the sintering conditions and alkali was...A lead-free base glaze suitable for pearlescent pigments was prepared by a low-temperature solid-phase reaction with alkali waste.Tests were performed to evaluate the effects of the sintering conditions and alkali waste composition on the prepared base glaze and pearlescent glaze.The experimental results show that partially replacing SiO_(2) with B_(2)O_(3) effectively reduced the sintering temperature and time to form a glass network,but the network structure becomes disconnected as the B_(2)O_(3) content increases.An amorphous base glaze was obtained when soda ash was replaced with a small amount of alkali waste,but increasing the addition of NaCl further was adverse to base glaze formation by resulting in crystallization of the base glaze and a decrease in the bridging oxygen content.The pearlescent pigment was thermally stable in the glaze at 750℃,while higher temperatures caused the crystalline phase of NaAlSiO_(4) to appear and adhere to the surface of pigment granules,which degraded the pearlescent effect of the glaze.展开更多
The copper complex pearlescent pigment was synthesized by the two steps diazotization and azo coupling. The crystal phases and the microstructure of the copper complex pearlescent pigment powders were characterized th...The copper complex pearlescent pigment was synthesized by the two steps diazotization and azo coupling. The crystal phases and the microstructure of the copper complex pearlescent pigment powders were characterized through a combination of DSC, FT-IR and SEM analysis after purification. The results indicated that the copper complex pearlescent pigment has very good thermal stability and the fine particle size is uniformly distributed, and the average grain size is around 15 μm.展开更多
In this paper, some problems including the preparative principle, lattice transformation, optical property and theory of rutile type titania-mica pearlescent pigments, were studied and inquired into, by determination...In this paper, some problems including the preparative principle, lattice transformation, optical property and theory of rutile type titania-mica pearlescent pigments, were studied and inquired into, by determination and analysis of XRD, SEM, reflectivity.展开更多
Two critical parameters:Glossiness and chromaticity space of pearlescent pigments were evaluated based on crystallinity and grain size.Both the roughness and the vertical distance evolution along the surface of deposi...Two critical parameters:Glossiness and chromaticity space of pearlescent pigments were evaluated based on crystallinity and grain size.Both the roughness and the vertical distance evolution along the surface of deposited TiO_(2)film are affected by the crystallinity.The optimal crystallinity of TiO_(2)was deposited at the temperature of 350℃.The TiCl4 concentration effectively changed the grain size.However,the high flow rate of fluidizing gas and optimal gas–solid ratio(<0.11 m^(3)/(kg h))restricted the change of TiCl_(4)concentrations in fluidized bed reactor.In this case,the grain size of the deposited TiO_(2)film was about 55 nm.Depending on the grain size,the color of pearlescent pigments was adjusted by controlling the film thickness based on TiO_(2)concentration.Finally,the silver pearlescent pigment with high glossiness was prepared by chemical vapor deposition method in a fluidized bed reactor.展开更多
基金by the National Natural Science Foundation of China(No.51402097)the College Students Innovation and Entrepreneurship Training Program of Hubei University of Technology(No.202010500045)。
文摘A lead-free base glaze suitable for pearlescent pigments was prepared by a low-temperature solid-phase reaction with alkali waste.Tests were performed to evaluate the effects of the sintering conditions and alkali waste composition on the prepared base glaze and pearlescent glaze.The experimental results show that partially replacing SiO_(2) with B_(2)O_(3) effectively reduced the sintering temperature and time to form a glass network,but the network structure becomes disconnected as the B_(2)O_(3) content increases.An amorphous base glaze was obtained when soda ash was replaced with a small amount of alkali waste,but increasing the addition of NaCl further was adverse to base glaze formation by resulting in crystallization of the base glaze and a decrease in the bridging oxygen content.The pearlescent pigment was thermally stable in the glaze at 750℃,while higher temperatures caused the crystalline phase of NaAlSiO_(4) to appear and adhere to the surface of pigment granules,which degraded the pearlescent effect of the glaze.
文摘The copper complex pearlescent pigment was synthesized by the two steps diazotization and azo coupling. The crystal phases and the microstructure of the copper complex pearlescent pigment powders were characterized through a combination of DSC, FT-IR and SEM analysis after purification. The results indicated that the copper complex pearlescent pigment has very good thermal stability and the fine particle size is uniformly distributed, and the average grain size is around 15 μm.
文摘In this paper, some problems including the preparative principle, lattice transformation, optical property and theory of rutile type titania-mica pearlescent pigments, were studied and inquired into, by determination and analysis of XRD, SEM, reflectivity.
基金support from National Natural Science Foundation of China(grant Nos.22208355,21978300 and 22178363).
文摘Two critical parameters:Glossiness and chromaticity space of pearlescent pigments were evaluated based on crystallinity and grain size.Both the roughness and the vertical distance evolution along the surface of deposited TiO_(2)film are affected by the crystallinity.The optimal crystallinity of TiO_(2)was deposited at the temperature of 350℃.The TiCl4 concentration effectively changed the grain size.However,the high flow rate of fluidizing gas and optimal gas–solid ratio(<0.11 m^(3)/(kg h))restricted the change of TiCl_(4)concentrations in fluidized bed reactor.In this case,the grain size of the deposited TiO_(2)film was about 55 nm.Depending on the grain size,the color of pearlescent pigments was adjusted by controlling the film thickness based on TiO_(2)concentration.Finally,the silver pearlescent pigment with high glossiness was prepared by chemical vapor deposition method in a fluidized bed reactor.
