The micelle-templated silica （MTS） was firstly chemically modified with 3-glycidoxypropyl-trimethoxysilane （GPTMS） before immobilized with pyoverdin I. The characteristics of pyoverdin I-anchored onto the modified...The micelle-templated silica （MTS） was firstly chemically modified with 3-glycidoxypropyl-trimethoxysilane （GPTMS） before immobilized with pyoverdin I. The characteristics of pyoverdin I-anchored onto the modified MTS were investigated using fluorescence, infrared spectra and scanning electron microscopy. The specific surface area of all materials was calculated by Branauer, Emmett and Teller （BET） method using nitrogen isotherm adsorption data. As the results, the surface area of commercial silica gel decreased from 609.2 to 405.4 m2/g, it indicated that the pyoverdin I could be immobilized onto the surface of silica solid support. This adsorbent was used for extraction of Fe（Ⅲ）, Cu（Ⅱ）, Zn（Ⅱ）, and Pb（Ⅱ） in artificial metals contaminated water. Experimental conditions for effective adsorption of trace levels of metal ions were optimized with respect to different experimental parameters using batch procedure. The optimum pH value for the removal of metal ions simultaneously on this adsorbent was 4.0. Complete desorption of the adsorbed metal ions from the adsorbent was carried out using 0.25 mol/L of EDTA. The effect of different cations and anions on the adsorption of these metals on adsorbent was studied and the results showed that the proposed adsorbent could be applied to the highly saline samples and the sample which contains some transition metals.展开更多
基金supported by the Center of Excellence for Innovation in Chemistry (PERCH-CIC), Commission on Higher Education, Ministry of EducationKhon Kaen University and the National Research Council of Thailand (NRCT) for facilitates both instruments and chemical including research grants
文摘The micelle-templated silica （MTS） was firstly chemically modified with 3-glycidoxypropyl-trimethoxysilane （GPTMS） before immobilized with pyoverdin I. The characteristics of pyoverdin I-anchored onto the modified MTS were investigated using fluorescence, infrared spectra and scanning electron microscopy. The specific surface area of all materials was calculated by Branauer, Emmett and Teller （BET） method using nitrogen isotherm adsorption data. As the results, the surface area of commercial silica gel decreased from 609.2 to 405.4 m2/g, it indicated that the pyoverdin I could be immobilized onto the surface of silica solid support. This adsorbent was used for extraction of Fe（Ⅲ）, Cu（Ⅱ）, Zn（Ⅱ）, and Pb（Ⅱ） in artificial metals contaminated water. Experimental conditions for effective adsorption of trace levels of metal ions were optimized with respect to different experimental parameters using batch procedure. The optimum pH value for the removal of metal ions simultaneously on this adsorbent was 4.0. Complete desorption of the adsorbed metal ions from the adsorbent was carried out using 0.25 mol/L of EDTA. The effect of different cations and anions on the adsorption of these metals on adsorbent was studied and the results showed that the proposed adsorbent could be applied to the highly saline samples and the sample which contains some transition metals.
