Multifunctional Perovskite Photodetectors: From Molecular-Scale Crystal Structure Design to Micro/Nano-scale Morphology Manipulation

Multifunctional photodetectors boost the development of traditional optical communication technology and emerging artificial intelligence fields, such as robotics and autonomous driving. However, the current implementation of multifunctional detectors is based on the physical combination of optical lenses, gratings, and multiple photodetectors, the large size and its complex structure hinder the miniaturization, lightweight, and integration of devices. In contrast, perovskite materials have achieved remarkable progress in the field of multifunctional photodetectors due to their diverse crystal structures, simple morphology manipulation, and excellent optoelectronic properties. In this review, we first overview the crystal structures and morphology manipulation techniques of perovskite materials and then summarize the working mechanism and performance parameters of multifunctional photodetectors. Furthermore, the fabrication strategies of multifunctional perovskite photodetectors and their advancements are highlighted, including polarized light detection, spectral detection, angle-sensing detection, and selfpowered detection. Finally, the existing problems of multifunctional detectors and the perspectives of their future development are presented.

Fluid-Dynamics Analysis and Structural Optimization of a 300 kW MicroGas Turbine Recuperator

Computational Fluid Dynamics(CFD)is used here to reduce pressure loss and improve heat exchange efficiency in the recuperator associated with a gas turbine.First,numerical simulations of the high-temperature and lowtemperature channels are performed and,the calculated results are compared with experimental data(to verify the reliability of the numerical method).Second,the flow field structure of the low-temperature side channel is critically analyzed,leading to the conclusion that the flow velocity distribution in the low-temperature side channel is uneven,and its resistance is significantly higher than that in the high-temperature side.Therefore,five alternate structural schemes are proposed for the optimization of the low-temperature side.In particular,to reduce the flow velocity in the upper channel,the rib length of each channel at the inlet of the low-temperature side region is adjusted.The performances of the 5 schemes are compared,leading to the identification of the configuration able to guarantee a uniform flow rate and minimize the pressure drop.Finally,the heat transfer performance of the optimized recuperator structure is evaluated,and it is shown that the effectiveness of the recuperator is increased by 1.5%.

Generating micro/nanostructures on magnesium alloy surface using ultraprecision diamond surface texturing process

The lightness and high strength-to-weight ratio of the magnesium alloy have attracted more interest in various applications.However,micro/nanostructure generation on their surfaces remains a challenge due to the flammability and ignition.Motivated by this,this study proposed a machining process,named the ultraprecision diamond surface texturing process,to machine the micro/nanostructures on magnesium alloy surfaces.Experimental results showed the various microstructures and sawtooth-shaped nanostructures were successfully generated on the AZ31B magnesium alloy surfaces,demonstrating the effectiveness of this proposed machining process.Furthermore,sawtooth-shaped nanostructures had the function of inducing the optical effect and generating different colors on workpiece surfaces.The colorful letter and colorful flower image were clearly viewed on magnesium alloy surfaces.The corresponding cutting force,chip morphology,and tool wear were systematically investigated to understand the machining mechanism of micro/nanostructures on magnesium alloy surfaces.The proposed machining process can further improve the performances of the magnesium alloy and extend its functions to other fields,such as optics.

Construction and Properties of Structure-and Size-controlled Micro/Nano-energetic Materials

The recent research progress of structure- and size-controlled micro/nano-energetic materials is reviewed, which properties are fundamentally different from those of their corresponding bulk materials. The development of the construction strategies for achieving zero-dimensional (0D), one-dimensional (1D), two-dimensional (2D), and three-dimensional (3D) micro/nanostructures from energetic molecules is introduced. Also, an overview of the unique properties induced by micro/nanostructures and size effects is provided. Special emphasis is focused on the size-dependent properties that are different from those of the conventional micro-sized energetic materials, such as thermal decomposition, sensitivity, combustion and detonation, and compaction behaviors. A conclusion and our view of the future development of micro/nano-energetic materials and devices are given.

REHEATING TEMPERATURE CONTRAST AND MICROSTRUCTURES OF 7075 Al ALLOY CAST BY LIQUIDUS SEMI-CONTINUOUS CASTING

In this study, reheating of liquidus semi-continuous cast billets of 7075 Al alloy was carried out in a resistance furnace, and the temperature contrast of the outer and the center of the reheated billets was investigated, then the reheating microstructures were investigated. Results show that: the difference of temperature between the outer and center is small and the difference of their microstructures are also small. During reheating at 576℃ the spheroidization of grains is significant after 5min and no rosettes are visible after 20min by optical microscopy. Similar observations were madeon materials reheated at 596℃, but the ripening process is faster. The grains growup to 30-60μm, fine enough for thixoforming.

Progress in molecular-simulation-based research on the effects of interface-induced fluid microstructures on flow resistance

In modern chemical engineering processes, solid interface involvement is the most important component of process intensification techniques, such as nanoporous membrane separation and heterogeneous catalysis. The fundamental mechanism underlying interfacial transport remains incompletely understood given the complexity of heterogeneous interfacial molecular interactions and the high nonideality of the fluid involved. Thus, understanding the effects of interface-induced fluid microstructures on flow resistance is the first step in further understanding interfacial transport. Molecular simulation has become an indispensable method for the investigation of fluid microstructure and flow resistance. Here, we reviewed the recent research progress of our group and the latest relevant works to elucidate the contribution of interface-induced fluid microstructures to flow resistance.We specifically focused on water, ionic aqueous solutions, and alcohol–water mixtures given the ubiquity of these fluid systems in modern chemical engineering processes. We discussed the effects of the interfaceinduced hydrogen bond networks of water molecules, the ionic hydration of ionic aqueous solutions, and the spatial distributions of alcohol and alcohol–water mixtures on flow resistance on the basis of the distinctive characteristics of different fluid systems.

Effect of quenching condition on micro inhomogeneous structure of Al-Fe-Ce amorphous alloy

The microstructures of liquid and amorphous Al 90 Fe 5Ce 5 alloys were studied by X ray diffraction (XRD), and the crystalline behavior of the amorphous alloy was also investigated by differential scanning calorimetry (DSC). The distinct pre peaks were found on the structure factors of the liquid and amorphous alloys. The quenching temperature affects the pre peak area, but does not affect its position. The reduction of quenching temperature decreases the crystallization temperature and the activation energy of the Al Fe Ce amorphous alloy. Quenched from 1 050 ℃, a novel structure with a fine dispersion of Al nanophase particles homogeneously distributed in the amorphous matrix was obtained. And the sensitivity of the Al Fe Ce amorphous alloy to the quenching temperature reflects the micro inhomogeneity of the melt.

Encryption/decryption and microtarget capturing by pH-driven Janus microstructures fabricated by the same femtosecond laser printing parameters

Several natural organism can change shape under external stimuli. These natural phenomena have inspired a vast amount of research on exploration and implementation of reconfigurable shape transformation. The Janus structure is a promising approach to achieve shape transformation based on its heterogeneous chemical or physical properties on opposite sides.However, the heterogeneity is generally realized by multi-step processing, different materials,and/or different processing parameters. Here, we present a simple and flexible method of producing p H-sensitive Janus microactuators from a single material, using the same laser printing parameters. These microactuators exhibit reversible structural deformations with large bending angles of ~31°and fast response(~0.2 s) by changing the p H value of the aqueous environment. Benefited from the high flexibility of the laser printing technique and the spatial arrangements, pillar heights, and bending directions of microactuators are readily controlled,enabling a variety of switchable ordered patterns and complex petal-like structures on flat surfaces and inside microchannels. Finally, we explore the potential applications of this method in information encryption/decryption and microtarget capturing.

Flame Structure of a Jet Flame with Penetration of Side Micro-jets

在这份报纸，一口创新喷气与方面提起了火焰微喷气被建议了，它火焰结构上的效果也被调查了。由于起始的燃烧条件的变化，混合并且源于方面的不安的气体动力学微喷气，如此的提起的喷气火焰与普通 premixed 火焰相比有不同火焰结构。结果表明微喷气的罐头控制的那使用，到某个程度，火焰结构包括火焰长度，起飞距离和容易的限制。与一样的燃料和空气流动率，有关于 5%-40% 的微喷气的愿望减少从 58%-76% 作为空气体积比率增加的方面的火焰长度。与普通散开火焰相比，有方面的喷气火焰微喷气示威更容易是动量主导的火焰。火焰长度与 2 微喷气是大约 5% 不到 with 6 在一样的燃料和空气流动率下面微喷气。与一样，控制喷气的更少数字与相对更短的长度导致火焰，不是对更容易开并且更高被吹 NOx 排放。与某些燃料流动率，批评空气体积比率为火焰与是最大的 3 微喷气，它是更困难的与 2， 4 或 6 比盒子被吹掉微喷气。

Numerical Simulation of Macro-and Micro-structures of Intense Convective Clouds with a Spectral Bin Microphysics Model

By use of a three-dimensional compressible non-hydrostatic convective cloud model with detailed microphysics featuring spectral bins of cloud condensation nuclei （CCN）, liquid droplets, ice crystals, snow and graupel particles, the spatial and temporal distributions of hydrometeors in a supercell observed by the （Severe Thunderstorm Electrification and Precipitation Study） STEPS triple-radar network are simulated and analyzed. The bin model is also employed to study the effect of CCN concentration on the evolution characteristics of the supercell. It is found that the CCN concentration not only affects the concentration and spectral distribution of water droplets, but also influences the characteristics of ice crystals and graupel particles. With a larger number of CCN, more water droplets and ice crystals are produced and the growth of graupel is restrained. With a small quantity of CCN the production of large size water droplets are promoted by initially small concentrations of water droplets and ice crystals, leading to earlier formation of small size graupel and restraining the recycling growth of graupel, and thus inhibiting the formation of large size graupel （or small size hail）. It can be concluded that both the macroscopic airflow and microphysical processes influence the formation and growth of large size graupel （or small size hail）. In regions with heavy pollution, a high concentration of CCN may restrain the formation of graupel and hail, and in extremely clean regions, excessively low concentrations of CCN may also limit the formation of large size graupel （hail）.

Osteoblast Behavior on Hierarchical Micro-/Nano-Structured Titanium Surface

In the present work, osteoblast behavior on a hierarchical micro-/nano-structured titanium surface was investigated. A hi- erarchical hybrid micro-/nano-structured titanium surface topography was produced via Electrolytic Etching （EE）. MG-63 cells were cultured on disks for 2 h to 7 days. The osteoblast response to the hierarchical hybrid micro-/nano-structured titanium surface was evaluated through the osteoblast cell morphology, attachment and proliferation. For comparison, MG-63 cells were also cultured on Sandblasted and Acid-etched （SEA） as well as Machined （M） surfaces respectively. The results show signifi- cant differences in the adhesion rates and proliferation levels of MG-63 cells on EE, SLA, and M surfaces. Both adhesion rate and proliferation level on EE surface are higher than those on SLA and M surfaces. Therefore, we may expect that, comparing with SLA and M surfaces, bone growth on EE surface could be accelerated and bone formation could be promoted at an early stage, which could be applied in the clinical practices for immediate and early-stage loadings.

Research on the process of fabricating a multi-layer metal micro-structure based on UV-LIGA overlay technology

In this paper,we report the study of the process of fabricating a multi-layermetal micro-structure using UV-LIGA overlay technology,includingmask fabrication,substrate treatment,and UV-LIGA overlay processes.To solve the process problems in the masking procedure,the swelling problemof the first layer of SU-8 thick photoresist was studied experimentally.The 5μmline-width compensation and closed 20μmand 30μmisolation strips were designed and fabricated around the micro-structure pattern.The pore problemin the Ni micro-electroforming layer was analyzed and the electroforming parameters were improved.The pH value of the electroforming solution should be controlled between 3.8 and 4.4 and the current density should be below 3 A/dm^2.To solve the problems of high inner stress and incomplete development of the micro-cylinder hole array with a diameter of 30μm,the lithography process was optimized.The pre-baking temperature was increased via gradient heating and rose every 5℃ from 65℃ to 85℃ and then remained at 85℃ for 50 min–1 h.In addition,the full contact exposure was used.Finally,a multi-layer metal micro-structure with high precision and good quality of microelectroforming layer was fabricated using UV-LIGA overlay technology.

Simulation of GaN micro-structured neutron detectors for improving electrical properties

Nowadays,the superior detection performance of semiconductor neutron detectors is a challenging task.In this paper,we deal with a novel GaN micro-structured neutron detector(GaN-MSND)and compare three different methods such as the method of modulating the trench depth,the method of introducing dielectric layer and p-type inversion region to improve the width of depletion region(W).It is observed that the intensity of electric field can be modulated by scaling the trench depth.On the other hand,the electron blocking region is formed in the detector enveloped with a dielectric layer.Furthermore,the introducing of p-type inversion region produces new p/n junction,which not only promotes the further expansion of the depletion region but also reduces the intensity of electric field produced by main junction.It can be realized that all these methods can considerably enhance the working voltage as well as W.Of them,the improvement on W of GaN-MSND with the p-type inversion region is the most significant and the value of W could reach 12.8μm when the carrier concentration of p-type inversion region is 10^17 cm^-3.Consequently,the value of W is observed to improve 200%for the designed GaN-MSND as compared with that without additional design.This work ensures to the researchers and scientific community the fabrication of GaN-MSND having superior detection limit in the field of intense radiation.

Seismogenic Structure around the Epicenter of the May 12,2008 Wenchuan Earthquake from Micro-seismic Tomography

A three-dimensional local-scale P-velocity model down to 25 km depth around the main shock epicenter region was constructed using 83821 event-to-receiver seismic rays from 5856 aftershocks recorded by a newly deployed temporary seismic network. Checkerboard tests show that our tomographic model has lateral and vertical resolution of -2 km. The high-resolution P-velocity model revealed interesting structures in the seismogenic layer： （1） The Guanxian-Anxian fault, Yingxiu-Beichuan fault and Wenchuan-Maoxian fault of the Longmen Shan fault zone are well delineated by sharp upper crustal velocity changes; （2） The Pengguan massif has generally higher velocity than its surrounding areas, and may extend down to at least -10 km from the surface; （3） A sharp lateral velocity variation beneath the Wenchuan-Maoxian fault may indicate that the Pengguan massif＇s western boundary and/or the Wenchuan-Maoxian fault is vertical, and the hypocenter of the Wenchuan earthquake possibly located at the conjunction point of the NW dipping Yingxiu-Beichuan and Guanxian-Anxian faults, and vertical Wenchuan-Maoxian fault; （4） Vicinity along the Yingxiu- Beichuan fault is characterized by very low velocity and low seismicity at shallow depths, possibly due to high content of porosity and fractures; （5） Two blocks of low-velocity anomaly are respectively imaged in the hanging wall and foot wall of the Guanxian-Anxian fault with a -7 km offset with -5 km vertical component.

DEVELOPMENT OF MESO-AND MICRO-SCALE STRUCTURES IN THE CHAMBA-BHARMAUR SYNCLINE, WESTERN HIMALAYA, INDIA

The Chamba\|Bharmaur syncline located in between Zanskar range in the north and Dhauladhar\|Pirpanjal range in the south , in the Chamba district of Western Himachal Pradesh. The rocks constituting Chamba\|Bharmaur syncline belong to Precambrian to Lr. Triassic (Rattan, 1973) and represent the southern extension of the Tethyan facies of the Zanskar Tethys Himalayan sequence (Thakur, 1998). The geological and structural mapping in the Chamba\|Bharmaur syncline reveal that the area comprises of various litho\|units which show imprint of various phases of deformation. Three main phases of deformation DF\-1, DF\-2 and DF\-3 have affected the rocks of the Chamba\|Bharmaur syncline. The earliest recognisable deformational structures of the area are tight isoclinal folds appressed with long drawn out limbs and thickened hinges have experienced buckle shortening of 80%. They have been rendered intrafolial folds in many places; only a few of them show disharmony. The folds initiated in the multilayered sequences are generally controlled in their distribution and wave\|length by more competent members of the sequence.

EXPERIMENTAL STUDY ON MACRO AND MICRO-STRUCTURE OF METALLIC PARTS BUILT BY LOW-POWER LASER CLADDING

A low-power CO_2 laser is used to deposit Fe powder and mixture of Fe andcarbon powder on substrates respectively, and the macro and micro-structure of the formed samplesare investigated. It is demonstrated that most grains of these samples are equi-axed. This isderived from the high nucleation velocity in the shallow melt pool besides rapid solidification ofthe liquid-state alloy or metal. Bainitic structure, combination of pearlite and ferrite structureand ferrite structure are seen respectively in the samples involving various amounts of carbon owingto no martensitic transformation in these small samples.

MICROSTRUCTURES AND THE STRUCTURE STABILITY OF INCONEL 725, A NEW AGE-HARDENABLE CORROSION RESISTANT SUPERALLOY

INCONEL725 is a highly corrosion resistant nickel based alloy capable of being age-hardened to high strength levels. The micro structure observations and the phase identification after a standard heat treatment were investigated. The results show that the precipitation phases include the strengthening phasesγ', γ', and 8 phase, primary carbide phase TiC, as well as M6 C carbide and a little extent MC (mainly TiC) precipitates which nucleate mainly at grain boundaries. An isothermal aging study was carried out on this alloy for up to 10 000 hours at 593℃. This additional aging did not affect the tensile strength. However, micro structures show that the thermal exposure has a little additional effect. With increasing the exposure time, the size of γ' phase slightly increases, almost no change for γ' phase, while M6C carbides precipitated at grain boundaries have an increased and complex tendency on a few grain boundaries. The experimental results illustrate the excellent structure stability of the age-hardenable IN725 at 593℃.

Microstructures and properties of Si_3N_4/TiN ceramic nano-multilayer films

The polycrystalline Si3N4/TiN ceramic nano-multilayer films have been synthesized on Si substrates by a reactive magnetron Sputtering technique, aiming at investigating the effects of modulation ratio and modulation period on the microhardness and to elucidate the hardening mechanisms of the synthesized nanomultilayer films. The results showed that the hardness of Si3N4/TiN nano-multilayers is affected not only by modulation period, but also by modulation ratio. The hardness reaches its maximum value when modulation period equa1s a critical value λ0, which is about 12 nm with a modulation ratio of 3: 1. The maximum hardness value is about 40% higher than the value calculated from the rule of mixtures. The hardness of nano-multilayer thin films was found to decrease rapidly with increasing or decreasing modulation period from the Point of λ0. The microstructures of the nano-multilayer films have been investigated using XRD and TEM. Based on experimental results, the mechanism of the superhardness in this system was proposed.

PHASE TRANSFORMATION BEHAVIOR AND MICROSTRUCTURE OBSERVATION OF Nb-Ru HIGH TEMPERATURE SHAPE MEMORY ALLOY

The phase transformation behavior and micro structure of Nb-Ru alloys have been studied by DSC, X-ray diffraction, optical microscopy, transmission electron microscopy (TEM) and high-resolution electron microscopy (HREM). Two-step phase transformation of CsCl (β) →face-centered tetragonal (β)→ monoclinic (β') occurs during cooling from high temperature to room temperature. The lattice parameters of marten-sites of Nb-Ru alloys were found to increase with the increase of Nb content. The martensite variants exhibit triangular self-accommodating morphology, with alternating regular bands inside. The twinning relationship between the sub structural bands was found to be (101) type I mode, and this kind of twinning interface was straight, well-defined and coherent.