Al−Cu−Li−Mg合金纳米相之间溶质配分行为的第一性原理研究

采用一性原理计算考察25种合金化元素在大多数商业牌号Al−Cu−Li−Mg合金中主要纳米相(δʹ-Al3Li、θʹ-Al2Cu、T1-Al6Cu4Li3和S-Al2CuMg)之间的溶质配分能和配分行为。计算结果表明,主合金化元素Li不能直接影响θʹ和S相,Cu不能直接影响δʹ相,Mg不能直接影响θʹ和δʹ相,但可以较弱地固溶于T1相。对于微合金化元素,Si是唯一一种可以固溶于4种纳米相的元素。Au能固溶于δʹ、θʹ和S相,Cd能固溶于δʹ、T1和S相,Zr能固溶于δʹ和T1相,Ni仅有微弱的趋势固溶于θʹ和S相。Ti、V、Zn、Ag和Mo只能固溶于δʹ相,而Cr、Mn、Fe和Co对这4种纳米相均没有直接影响。几乎所有的稀土元素均能强烈固溶于T1、δʹ和S相,但无法固溶于θʹ相。仅Sc略显特殊,对S相没有明显的固溶趋势。计算预测的溶质配分能构成了一个原型数据库,有利于指导和加速Al−Li合金及其他相关Al合金的设计。

微弧氧化后Mg-8Li合金表面MgLiAlY-LDHs@GO膜层的生长及耐蚀性能

目的提高Mg-8Li合金的耐蚀性能。方法首先在Mg-8Li合金表面制备微弧氧化膜(MAO),然后使用原位水热法在微弧氧化膜表面原位生长掺杂氧化石墨烯(GO)的四元(MgLiAlY)层状双羟基金属氧化物(LDHs)智能自修复膜层。采用SEM、XRD、FT-IR、EDS、ICP等手段研究MgLiAlY-LDHs@GO膜层的形貌、结构以及成分。通过EIS、Tafel以及浸泡试验等研究膜层的耐蚀性能,分析膜层的腐蚀行为,阐释其耐蚀机理。结果GO的掺杂可以促使LDHs纳米片生长得更加致密,主体层板中具有缓蚀作用的Y3+可以提高涂层的耐蚀性,四元LDHs的生长所需要的Mg^(2+)、Li^(+)、Al^(3+)等离子来源于镁锂合金基体以及微弧氧化膜的溶解,其中Li+也可以促进LDHs纳米片生长得更为均匀细密。膜层的腐蚀电流密度为6.03×10^(–7)A/cm^(2),比MAO膜层降低了1个数量级,提高了镁锂合金的耐蚀性能。结论GO的负载使LDHs的耐蚀性能和膜层稳定性均有一定程度的提升,引入稀土元素Y会改变LDHs的骨架,造成晶格畸变,使得LDHs微观形貌呈现褶皱状,剩下部分以Y(OH)3形式存在于涂层表面,可进一步提高膜层的耐蚀性能和稳定性。

Mg处理Nb-Ti微合金钢中非金属夹杂物演变机理研究

在工业生产条件下,对Nb-Ti微合金钢进行Mg处理试验,分析了Mg处理条件下,微合金钢中非金属夹杂物的演变规律。结果表明,微合金钢经过铝脱氧产物主要为Al_(2)O_(3)夹杂,进行Ca处理后,Al_(2)O_(3)夹杂减少,转变为CaO-Al_(2)O_(3)夹杂,且部分MnS夹杂转变为CaS夹杂;精炼阶段将Ca处理改为Mg处理后,可将铝脱氧产物Al_(2)O_(3)夹杂变性为MgO-Al_(2)O_(3)夹杂。Mg处理前,夹杂物在LF主要是Al_(2)O_(3)夹杂,进行Mg处理和Ti合金化后,钢中主要夹杂物变为MgO-Al_(2)O_(3)夹杂、MgO夹杂和TiN夹杂,最终在铸坯中的夹杂物为MgO-Al_(2)O_(3)外包裹CaS/MnS和(Nb、Ti)N复合夹杂。对Ca处理和Mg处理的夹杂物尺寸进行对比,夹杂物尺寸主要分布在5μm以内,Mg处理形成的2μm以内的夹杂物占比高于Ca处理工艺,表明镁处理可以较好地细化夹杂物,形成大量弥散分布的细小夹杂,有助于提升钢的综合力学性能。

产教融合下高职动漫设计专业MG动画与Animate软件的课程设计与研究

在产教融合大背景下,高职动漫设计专业中对于信息技术与教育的深度融合追求愈发强烈。在产教融合战略影响下,专业中MG动画教学也与Animate软件课程设计教学融合起来,共同完善课程设计方案。所以本文中就探讨了产教融合背景下高职动漫设计专业中MG动画技术与Animate软件课程的信息化技术设计应用,研究其中的教学设计要点。

TCP/IP Based Intelligent Load Management System in Micro-Grids Network Using MATLAB/Simulink

Computerized power management system with fast and optimal communication network overcomes all major dicrepencies of undue or inadequate load relief that were present in old conventional systems. This paper presents the basic perception and methodology of modern and true intelligent load management scheme in micro grids topology by employing TCP/IP protocol for fast and intelligent switching. The network understudy performs load management and power distribution intelligently in a unified network. Generated power is efficiently distributed among local loads through fast communication system of server in the form of source and clients in the form of loads through TCP/IP. The efficient use of information between server and clients enables to astutely control the load management in a power system of micro grids system. The processing time of above stated system comes out to be 10ms faster than others which ensure very less delay as compared to conventional methods. The Micro Grids system operating through TCP/IP control has been implemented in MATLAB/Simulink and results have been verified.

Study of Micro Grid Safety &Protection Strategies with Control System Infrastructures

Microgrids have been proposed in order to improve reliability and stability of electrical system and to ensure power quality of grid. Microgrid consists of low voltage distribution systems with distributed energy resources, such as wind turbine and photovoltaic power systems, together with storage devices. It is essential to protect a micro grid in both the grid-connected and the islanded mode of operation against all different types of faults. This paper describes micro grid protection and safety concept with central control and monitoring unit where multifunctional intelligent digital relay could be used. This central control & monitoring infrastructure is used for adaptive relay settings strategy for micro grid protection. Also operational safety design concept and fault mitigation technique is proposed to ensure confidence in protection system.

Comparison the Performances of Three Earthing Systems for Micro-Grid Protection during the Grid Connected Mode

This paper presents, tests and compares three earthing systems (TT, TN and IT) for Micro-Grid (MG) protection against various fault types during the connected mode. The main contribution of this work is including the models of all the micro sources which interfaced to the MG by power electronic inverters. Inverters in turns are provided with current limiters and this also included in the inverter models to exactly simulate the real situation in the MG during fault times. Results proved that the most suitable earthing system for MG protection during the connecting mode is the TN earthing system. That system leads to a suitable amount of fault current sufficient to activate over current protection relays. With using TN system, Touch voltages at the faulted bus and all other consumer’s buses are less than the safety limited value if current limiter is included with the transformer of the main grid which connects MG. For the two others earthing systems (TT and IT), fault current is small and nearly equal to the over load current which make over current protection relay can not differentiate between fault current and overload current. All models of micro sources, earthing systems, inverters, main grid and control schemes are built using Matlab?/Simulink? environment.

Design and Testing of Three Earthing Systems for Micro-Grid Protection during the Islanding Mode

This paper presents and tests three earthing systems (TT, TN and IT) for Micro-Grid (MG) protection against various fault types when the MG transferred to the islanding mode. The main contribution of this work is including the models of all micro sources which interfaced to the MG by power electronic inverters. Inverters in turns are provided with current limiters and this also included with the inverter models to exactly simulate the real situation in the MG during fault times. Results proved that the most suitable earthing system for MG protection during the islanding mode is the TN earthing system. That system leads to a suitable amount of fault current sufficient to activate over current pro-tection relays. With using TN earthing system, touch voltages at the faulted bus and all other consumer’s buses are less than the safety limited values during islanding mode. For the two others earthing systems (TT and IT), fault currents are small and nearly equal to the over load currents which make over current protection relay can not differentiate between fault currents and overload currents. All models of micro sources, earthing systems, inverters and control schemes are built using Matlab?/Simulink? environment.

Micro-arc oxidation coatings on Mg-Li alloys

Micro-arc oxidation (MAO) method was used for the surface modification of an Mg-5wt.%Li alloy. Ceramic coatings were in-situ fabricated on the Mg-Li alloy. The morphology feature,phase composition,and corrosion-resistance of the formed ceramic coatings were studied by SEM,XRD,and electrochemical methods,respectively. The results showed that the coatings produced in a sodium silicate solution system were composed of MgO and Mg2SiO4. The ceramic coating became thicker and the content of Mg2SiO4 phase increased as the concentration of Na2SiO3 increased in the solution. The coating was loose at the low concentration of Na2SiO3 and was compact at the high concentration of Na2SiO3. The coated samples had a better corrosion resistance than the Mg-Li substrate in terms of the Tafel polarization curves and the cyclic voltammetry curves (CV).

Effects of Zn content on the microstructure and the mechanical and corrosion properties of as-cast low-alloyed Mg–Zn–Ca alloys

The effects of Zn content on the microstxucture and the mechanical and corrosion properties of as-cast low-alloyed Mg-xZn~.2Ca alloys （x = 0.6wt%, 2.0wt%, 2.5wt%, hereafter denoted as 0.6Zn, 2.0Zn, and 2.5Zn alloys, respectively） axe investigated. The results show that the Zn content not only influences grain refinement but also induces different phase precipitation behaviors. The as-cast microstxucture of the 0.6Zn alloy is composed of ct-Mg, Mg2Ca, and Ca2Mg6Zn3 phases, whereas 2.0Zn and 2.5Zn alloys only contain ct-Mg and Ca2Mg6Zn3 phases, as revealed by X-ray diffraction （XRD） and txonsmission electron microscopy （TEM） analyses. Moreover, with in- creasing Zn content, both the ultimate tensile strength （UTS） and the elongation to fracture first increase and then decrease. Among the three investigated alloys, the largest UTS （178 MPa） and the highest elongation to fracture （6.5%） are obtained for the 2.0Zn alloy. In addition, the corrosion rate increases with increasing Zn content. This paper provides on updated investigation of the alloy composi- tion-microstxucture-property relationships of different Zn-containing Mg-Zn-Ca alloys.

Growth process and corrosion resistance of micro-arc oxidation coating on Mg-Zn-Gd magnesium alloys

A Mg-6Zn-3Gd(mass fraction,%) alloy,noted as ZG63,was coated by different micro-arc oxidation(MAO) processes,and the coating structure and corrosion resistance of the alloy were studied using scanning electron microscopy(SEM),glancing angle X-ray diffractometry(GAXRD) and various electrochemical methods.The micro-arc oxidation process consists of three stages and corresponds with different coating structures.In the initial stage,the coating thickness is linearly increased and is controlled by electrochemical polarization.In the second stage,the coating grows mainly inward and accords with parabolic regularity.In the third stage,the loose coating forms and is controlled by local arc light.The looser coating is mainly composed of MgSiO3 and the compact coating is mainly composed of MgO.From micro-arc oxidation stage to local arc light stage,the corrosion resistance of the coated alloy firstly increases and then decreases.The satisfied corrosion resistance corresponds to the coating time ranging from 6 to10 min.

Optoelectronic characterisation of an individual ZnO nanowire in contact with a micro-grid template

Optoelectronic characterisation of an individual ZnO nanowire in contact with a micro-grid template has been studied. The low-cost micro-grid template made by photolithography is used to fabricate the ohmic contact metal electrodes. The current increases linearly with the bias, indicating good ohmic contacts between the nanowire and the electrodes. The resistivity of the ZnO nanowire is calculated to be 3.8 Ω·cm. We investigate the photoresponses of an individual ZnO nanowire under different light illumination using light emitting diodes （λ= 505 nm, 460 nm, 375 nm） as excitation sources in atmosphere. When individual ZnO nanowire is exposured to different light irradiation, we find that it is extremely sensitive to UV illumination; the conductance is much larger upon UV illumination than that in the dark at room temperature. This phenomenon may be related to the surface oxygen molecule adsorbtion, which indicates their potential application to the optoelectronic switching device.

Micro-source Inverters With Capacitive Equivalent Output Impedance for Improving Micro-grid Voltages

将分布式电源逆变器等效输出阻抗设计成容性可使其体现对系统无功电压调整过程相逆的电源特性,这种特性使得分布式电源逆变器更容易参与公共连接点处的电压调整。对比等效输出阻抗成感性、阻性和容性的3类逆变器下垂控制特性,对容性等效输出阻抗逆变器电压电流控制环进行数学建模;针对容性等效输出阻抗逆变器设计具备下垂调节和克服电压偏离功能的鲁棒功率外环控制器。对比仿真和实验证明,容性输出阻抗分布式电源逆变器控制器能够快速抑制系统功率变化带来的电压波动,能有效地参与系统电压调整。

Dechlorination of Chlorinated Aliphatic Compounds by Micro-scale Al-Zn-Mg/Fe Powders as Advanced Zero-valent Iron

Micro-scale Al-Zn-Mg/Fe composite powders (MAF) with high reactivity and good storage properties were prepared by reducing iron onto the surface of Al-Zn-Mg alloy powders. Experimental results show that MAF as advanced zero-valent iron are highly effective for degradation of chlorinated organic compounds. The efficiency of degradation for carbon tetrachloride and perchloroethylene is higher than 99% within a period of 2 h. The efficiency of degradation for trichloroethylene by MAF after storing for one month is equivalent to that by freshly prepared nano-size zero-valent iron particles.

Ce添加对Mg-Ca挤压合金力学性能与热稳定性影响研究

目的 研究在Mg-0.2Ca挤压合金基础上分别添加质量分数为0.3%的Ce和0.6%的Ca后对合金的组织、力学性能和热稳定性的影响,探究Ce和Ca 2种合金元素对镁合金的强化和中高温条件下的稳定化效果。方法 首先,熔炼制备Mg-0.2Ca、Mg-0.2Ca-0.3Ce和Mg-0.8Ca 3种成分的合金;随后,对3种合金进行挤压变形,并对挤压合金组织和力学性能进行表征和测试;最后,在300℃下对3种合金进行等温退火,研究其组织演变过程和力学性能的衰减情况。结果 在Mg-0.2Ca合金基础上添加质量分数为0.3%的Ce可将挤压态合金再结晶分数由约92%降至约53%,再结晶晶粒尺寸由约1.64μm细化至约0.86μm,Mg-0.2Ca-0.3Ce三元合金的屈服强度可大幅提升至约364 MPa,该屈服强度与Mg-0.8Ca合金相当(约361 MPa),表明单位质量Ce的添加对强度提升的效果优于Ca。退火3 h后,Mg-0.2Ca-0.3Ce三元合金屈服强度的下降幅度约为124 MPa,显著低于Mg-Ca二元合金(约170 MPa)。以Mg-0.2Ca-0.3Ce合金为例进行静态再结晶组织演化分析表明,静态再结晶过程产生了稀土织构,其再结晶机制为不连续静态再结晶。结论 在Mg-0.2Ca挤压合金中添加质量分数为0.3%的Ce后,屈服强度由约307 MPa提升至约364 MPa,其强度与继续添加质量分数0.6%的Ca合金相当,Mg-Ca-Ce三元合金热稳定性优于Mg-Ca二元合金。

Effects of micro-alloying with Sc and Mn on microstructure and mechanical properties of Al-Mg based alloys

An extensive investigation was made on the effects of micro-alloying with small amounts of Sc and Mn on the microstructure and mechanical properties of the Al-Mg based alloys. It is found that the micro-alloying can significantly enhance the tensile strength of the alloys, and eliminate the dendritic cast structure in it. Many fine, spherical and dispersive Al3Sc particles are found in the annealed Al-Mg-Mn-Sc alloys, which can strongly pin up dislocations and subgrain boundaries, thus strongly retarding the recrystallization of the alloys. The strengthening of the micro-alloyed Al-Mg alloys is attributed to the precipitation strengthening by the Al3Sc particles and to the substructure strengthening.

Microstructures and properties of rapidly solidified Mg-Zn-Ca alloys

Ternary alloys based on the Mg-Zn-Ca system were produced by twin-roll rapid solidification.The alloys were characterized by OM,SEM,HRTEM,XRD,EDS and Micro-hardness.The results show that the rapidly solidified flakes are of fine dendritic cell structures with the cell size ranging from 1 to 5μm.The Mg-6Zn-5Ca alloy in RS and annealing(200℃for 1 h) states are mainly composed ofα-Mg,Mg_2Ca,Ca_2Mg_6Zn_3 and a small quantity of Mg_(51)Zn_(20),MgZn_2 and Mg_2Zn_3.Micro-hardness increases with the increment of Ca content and age hardening occurs after aging at 200℃in the flakes probably due to the precipitation strengthening of the fine precipitates Mg_2Ca and Ca_2Mg_6Zn_3.Some phases at the grain boundary in Mg-6Zn-5Ca alloy are identified by means of HRTEM,which may be beneficial to the improvement in thermal stability of the alloy.

Design and testing of a centralized protection scheme for micro-grids

Micro-grids comprise low voltage distribution systems with distributed energy resources(DERs) and controllable loads which can operate connected to the medium voltage grid or islanded in a controlled coordinated way. This concept aims to move from "connect and forget" philosophy towards a full integration of DERs. Micro-grids can provide numerous economic and environmental benefits for end-customers, utilities and society. However, their implementation poses great technical challenges, such as a new philosophy in design of protection systems. In this work, a micro-grid protection scheme is presented based on positive-sequence component using phasor measurement units(PMUs) and a central protection unit(CPU). The salient feature of the proposed scheme in comparison with the previous works is that it has the ability to protect both radial and looped micro-grids against different types of faults with the capability of single-phase tripping. Furthermore, since the CPU is capable of updating its pickup values(upstream and downstream equivalent positive-sequence impedances of each line) after the first change in the micro-grid configuration(such as transferring from grid-connected to islanded mode and or disconnection of a line, bus, or DER either in grid-connected mode or in islanded mode), it can protect micro-grid against subsequent faults. Finally, in order to verify the effectiveness of the suggested scheme and the CPU, several simulations have been undertaken by using DIg SILENT Power Factory and MATLAB software packages.

Voltage Stabilization of Hybrid Micro-Grid Using Super Capacitors

Scarcity of fossil fuel resources has motivated the researchers to develop renewable energy based power projects. Instead of using a single or independent renewable energy source, it is preferable to use the combination of such energy sources in a distributed way to compensate the power fluctuations of the system and this leads to the concept of hybrid micro-grid energy. Voltage stability is an important parameter for the secure operation of the hybrid-micro grid, and IEEE 1547 Standard defines the limit of the voltage for the successful operation of the micro-grid. Although Vanadium Redox Batteries (VRBs) can help the system to stabilize the voltage when voltage sag occurs when a heavy load is suddenly connected to the system, this stabilization process takes some time. This paper discusses the application of super capacitors to the hybrid micro-grid system, as a higher energy density element, to help the system quickly recover its transient voltage.

Compounded Surface Modification of ZK60 Mg Alloy by High Current Pulsed Electron Beam+Micro-plasma Oxidation

In this study, compounded surface modification technology-high current pulsed electron beam （HCPEB） ＋ micro-plasma oxidation （MPO） was applied to treat ZK60 Mg alloys. The characteristics of the microstructure of ZK60 Mg alloy after single MPO and HCPEB＋MPO compounded treatment were investigated by SEM. The results showed that the density of the ceramic layer of HCPEB＋MPO-treated ZK60 Mg alloy was improved and defects were reduced compared to that under MPO treatment alone. Surface modified layer of ZK60 Mg alloys treated by HCPEB＋MPO was divided into three zones, namely the top loose ceramic zone, middle compact zone and inside HCPEB-induced melted zone. Corrosion resistance of ZK60 Mg alloy before and after the compounded surface modification was measured in a solution of 3.5% NaCl by potentiodynamic polarization curves. It was found that the corrosion current density of ZK60 Mg alloys could be reduced by about three orders of magnitude, from 311μA/cm^2 of the original sample to 0.2μA/cm^2 of the HCPEB＋MPO-treated sample. This indicates the great application potential of the HCPEB＋MPO compounded surface modification technology in improving the corrosion resistance of ZK60 Mg alloys in the future.