Micro-emulsion usually consists of water, oil, surfactants and co-surfactants, and each component has an effect on the phase behavior and solubilization of the micro-emulsion. When the surfactant in the micro-emulsion...Micro-emulsion usually consists of water, oil, surfactants and co-surfactants, and each component has an effect on the phase behavior and solubilization of the micro-emulsion. When the surfactant in the micro-emulsion system is quaternary ammonium cationic Gemini surfactant, the surfactant mainly combines with the anions in the salt. With the increase of salt concentration, the phase transformation of Winsor I → Winsor III → Winsor II occurred, but the optimum salinity and salt width are different because of the type of salt. The effects of 5 different kinds of monovalent anions, including C_6H_5SO_3^-, I-, Br-, NO_3^- and Cl-, on the phase behavior and solubilization of quaternary ammonium cationic Gemini micro-emulsion are researched by Winsor phase diagram. It is found that the effects of organic anions C_6H_5SO_3-and I-on the phase behavior and solubilization of quaternary ammonium cationic Gemini micro-emulsion are most significant, and the effects of Br-, NO_3^- and Cl-are less significant. Meanwhile, when the optimum solubilization is achieved, the amount of sodium benzoate is the least, indicating that the organic anion has stronger self-organization behavior with quaternary ammonium cationic Gemini surfactants.展开更多
A silicone acrylate micro-emulsion of multipolymer was prepared by seed emulsion polymerization. The effects of polymerization process, emulsifier rate and amount, initiator rate and amount, polymerization temperature...A silicone acrylate micro-emulsion of multipolymer was prepared by seed emulsion polymerization. The effects of polymerization process, emulsifier rate and amount, initiator rate and amount, polymerization temperature, functional monomers, titration time on performances of emulsion have been discussed in detail.展开更多
The micro crack of aluminum sheet during cold rolling lubricated with emulsions is investigated. Experi-ments show that micro cracks occur after cold rolling process and this is attributed to various parameters, for i...The micro crack of aluminum sheet during cold rolling lubricated with emulsions is investigated. Experi-ments show that micro cracks occur after cold rolling process and this is attributed to various parameters, for instance, the thin oxide film formed at the sheet surface. The micro crack spacing thus becomes an important parameter which deserves more concerns. The aspect ratio of these micro cracks is then analyzed theoreti-cally, which takes into consideration of the oxide fracture process. The good agreement between the obser-vations and the theoretical predictions validates the analysis. The approach can shed some new lights on the mechanical process of aluminium sheet during cold rolling.展开更多
SmOHCO3micro/nano particles were prepared in water/oil （W/O） reverse microemulsion composed of cetyltrimethyl ammonium bromide （CTAB）, n-octane, n-butanol, Sm（NO3）3·6H2O and urea aqueous solution by the cou...SmOHCO3micro/nano particles were prepared in water/oil （W/O） reverse microemulsion composed of cetyltrimethyl ammonium bromide （CTAB）, n-octane, n-butanol, Sm（NO3）3·6H2O and urea aqueous solution by the coupling route of homogeneous precipitation with microemulsion. The nanoparticles were characterized and analyzed by X-ray powder diffraction （XRD）, thermal gravimetric and differential thermal gravimetric analysis （TG-DTG）, Fourier transform infrared absorption spectra （FT-IR） and scan-ning electron microscope （SEM）. The results showed that the phase SmOHCO3 micro/nano particles was in agreement with pure or-thorhombic phase. The different morphologies of SmOHCO3 micro/nano particles with good monodispersity and size were obtained by regulating the reaction temperature and reaction time. Possible formation mechanisms of the morphological structure of SmO-HCO3 were proposed and discussed.展开更多
基金Supported by China Petroleum Science and Technology Innovation Fund(2017D-5007-0601)State Key Laboratory of Heavy Oil Processing and China University of Petroleum(East China)2018 Graduate Engineering Innovation Project Found(SLKZZ-2017002)
文摘Micro-emulsion usually consists of water, oil, surfactants and co-surfactants, and each component has an effect on the phase behavior and solubilization of the micro-emulsion. When the surfactant in the micro-emulsion system is quaternary ammonium cationic Gemini surfactant, the surfactant mainly combines with the anions in the salt. With the increase of salt concentration, the phase transformation of Winsor I → Winsor III → Winsor II occurred, but the optimum salinity and salt width are different because of the type of salt. The effects of 5 different kinds of monovalent anions, including C_6H_5SO_3^-, I-, Br-, NO_3^- and Cl-, on the phase behavior and solubilization of quaternary ammonium cationic Gemini micro-emulsion are researched by Winsor phase diagram. It is found that the effects of organic anions C_6H_5SO_3-and I-on the phase behavior and solubilization of quaternary ammonium cationic Gemini micro-emulsion are most significant, and the effects of Br-, NO_3^- and Cl-are less significant. Meanwhile, when the optimum solubilization is achieved, the amount of sodium benzoate is the least, indicating that the organic anion has stronger self-organization behavior with quaternary ammonium cationic Gemini surfactants.
基金Ministry of Science and Technology of China for Major State Basic Research Projects (2002AA322020)
文摘A silicone acrylate micro-emulsion of multipolymer was prepared by seed emulsion polymerization. The effects of polymerization process, emulsifier rate and amount, initiator rate and amount, polymerization temperature, functional monomers, titration time on performances of emulsion have been discussed in detail.
文摘The micro crack of aluminum sheet during cold rolling lubricated with emulsions is investigated. Experi-ments show that micro cracks occur after cold rolling process and this is attributed to various parameters, for instance, the thin oxide film formed at the sheet surface. The micro crack spacing thus becomes an important parameter which deserves more concerns. The aspect ratio of these micro cracks is then analyzed theoreti-cally, which takes into consideration of the oxide fracture process. The good agreement between the obser-vations and the theoretical predictions validates the analysis. The approach can shed some new lights on the mechanical process of aluminium sheet during cold rolling.
基金Project supported by the grant from Scientific and Technological Projects in Shaanxi Province(2011K07-23)Shaanxi Provincial Department of Education Special Research Projects(11JK0566)
文摘SmOHCO3micro/nano particles were prepared in water/oil （W/O） reverse microemulsion composed of cetyltrimethyl ammonium bromide （CTAB）, n-octane, n-butanol, Sm（NO3）3·6H2O and urea aqueous solution by the coupling route of homogeneous precipitation with microemulsion. The nanoparticles were characterized and analyzed by X-ray powder diffraction （XRD）, thermal gravimetric and differential thermal gravimetric analysis （TG-DTG）, Fourier transform infrared absorption spectra （FT-IR） and scan-ning electron microscope （SEM）. The results showed that the phase SmOHCO3 micro/nano particles was in agreement with pure or-thorhombic phase. The different morphologies of SmOHCO3 micro/nano particles with good monodispersity and size were obtained by regulating the reaction temperature and reaction time. Possible formation mechanisms of the morphological structure of SmO-HCO3 were proposed and discussed.
