Sn_(1−x)Er_(x)O_(2)(x=0%,8%,16%,24%)micro/nanofibers were prepared by electrospinning combined with heat treatment using erbium nitrate,stannous chloride and polyvinylpyrrolidone(PVP)as raw materials.The target produc...Sn_(1−x)Er_(x)O_(2)(x=0%,8%,16%,24%)micro/nanofibers were prepared by electrospinning combined with heat treatment using erbium nitrate,stannous chloride and polyvinylpyrrolidone(PVP)as raw materials.The target products were characterized by thermogravimetric analyzer,X-ray diffrotometer,fourier transform infrared spectrometer,scanning electron microscope,spectrophotometer and infrared emissivity tester,and the effects of Er^(3+)doping on its infrared and laser emissivity were studied.At the same time,the Sn_(1−x)Er_(x)O_(2)(x=0%,16%)doping models were constructed based on the first principles of density functional theory,and the related optoelectronic properties such as their energy band structure,density of states,reflectivity and dielectric constant were analyzed,and further explained the mechanism of Er^(3+)doping on SnO_(2)infrared emissivity and laser absorption from the point of electronic structure.The results showed that after calcination at 600℃,single rutile type SnO_(2)was formed,and the crystal structure was not changed by doping Er^(3+).The calcined products showed good fiber morphology,and the average fiber diameter was 402 nm.The infrared emissivity and resistivity of the samples both decreased first and then increased with the increase of Er^(3+)doping amount.When x=16%,the infrared emis-sivity of the sample was at least 0.71;and Er^(3+)doping can effectively reduce the reflectivity of SnO_(2)at 1.06μm and 1.55μm,when x=16%,its reflectivity at 1.06μm and 1.55μm are 50.5%and 40%,respectively,when x=24%,the reflectivity at 1.06μm and 1.55μm wavelengths are 47.3%and 42.1%,respectively.At the same time,the change of carrier concentration and electron transition before and after Er^(3+)doping were described by first-principle calculation,and the regulation mechanism of infrared emissivity and laser reflectivity was explained.This study provides a certain experimental and theoretical basis for the development of a single-type,light-weight and easily prepared infrared and laser compatible-stealth material.展开更多
We study the spontaneous Raman scattering （RS） in taper-drawn micro/nano-fibers （MNFs） by employing the photon counting technique. The spectra of RS in five MNFs, which are fabricated by using different heating fl...We study the spontaneous Raman scattering （RS） in taper-drawn micro/nano-fibers （MNFs） by employing the photon counting technique. The spectra of RS in five MNFs, which are fabricated by using different heating flames （hydrogen flame or butane flame） and with different diameters, are measured within a frequency shift range of 1435 cm- 1_3200 cm- 1. From the measured spectra, we observe the RS peaks originated from silica and a unique RS peak with a frequency shift of - 2905 cm-1 （- 87.2 THz）. Unlike the former ones, the latter one is not observable in conventional optical fibers. Furthermore, the unique peak becomes obvious and starts to rapidly increase with the decrease of the diameter of MNFs when the diameter is smaller than 2 μm, and the intensity of the unique peak significantly depends on the heating flame used in the fabricating process. Our investigation is useful for the entanglement generation or optical sensing using taper-drawn MNFs.展开更多
To combine the technical functions and advantages of solid-core fiber Bragg gratings(FBGs) and hollow-core optical fibers(HCFs), the hollow and filled FBGs in nano-bore optical fibers(NBFs) with nano-bore in the GeO2-...To combine the technical functions and advantages of solid-core fiber Bragg gratings(FBGs) and hollow-core optical fibers(HCFs), the hollow and filled FBGs in nano-bore optical fibers(NBFs) with nano-bore in the GeO2-doped core are proposed.The fundamental mode field, effective mode index, and confinement loss of NBF with 50 nm–7 μm-diameter hollow and filled nano-bore are numerically investigated by the finite element method.The reflected spectra of FBGs in NBFs are obtained by the transmission matrix method.The hollow FBGs in NBFs can be acheived with ~5% power fraction in the bore and the ~0.9 reflectivity when bore diameter is less than 3 μm.The filled FBGs can be realized with^1% power fraction and 0.98 reflectivity with different fillings including o-xylene, trichloroethylene, and chloroform for 800-nm bore diameter.The feasibility of the index sensing by our proposed NBF FBG is also analyzed and discussed.The experimental fabrication of hollow and filled FBGs are discussed and can be achieved by current techniques.The aim of this work is to establish a principle prototype for investigating the HCFs and solid-core FBGs-based fiber-optic platforms,which are useful for applications such as the simultaneous chemical and physical sensing at the same position.展开更多
Vinyl ester (VE) resin inherently has intrinsic brittleness due to its high cross-link density. To improve mechanical performance, micro/nano fillers are widely used to modify this matrix. In present study, glass fibe...Vinyl ester (VE) resin inherently has intrinsic brittleness due to its high cross-link density. To improve mechanical performance, micro/nano fillers are widely used to modify this matrix. In present study, glass fiber in submicron scale at low contents was added into VE to prepare submicron composite (sMC). The impact resistance of un-notched sMC degraded with the increase of sGF content while that of notched-sMC remained the unchanged. Flexural properties of sMCs also were the same with that of neat resin. The results of Dynamic mechanical analysis (DMA) test showed the slight increase of storage modulus and the decrease of tan delta value in the case of sMC compared to those of un-filled matrix. However, the Mode I fracture toughness of sMC improved up to 26% and 61% corresponding to 0.3 and 0.6 wt% glass fiber used. The compact tension sample test suggests that there is the delay of crack propagation under tensile cyclic load in resin reinforced by submicron glass fiber. The number of failure cycle enlarged proportionally with the increment of sGF content in matrix.展开更多
Nano/micro fibers have evoked much attention of scientists and have been researched as cutting edge and hotspot in the area of fiber science in recent years due to the rapid development of various advanced manufacturi...Nano/micro fibers have evoked much attention of scientists and have been researched as cutting edge and hotspot in the area of fiber science in recent years due to the rapid development of various advanced manufacturing technologies,and the appearance of fascinating and special functions and properties,such as the enhanced mechanical strength,high surface area to volume ratio and special functionalities shown in the surface,triggered by the nano or micro-scale dimensions.In addition,these outstanding and special characteristics of the nano/micro fibers impart fiber-based materials with wide applications,such as environmental engineering,electronic and biomedical fields.This review mainly focuses on the recent development in the various nano/micro fibers fabrication strategies and corresponding applications in the biomedical fields,including tissue engineering scaffolds,drug delivery,wound healing,and biosensors.Moreover,the challenges for the fabrications and applications and future perspectives are presented.展开更多
基金supported by the Key Research and Development Program of Hebei Province(No.21351501D)A Provincial and Ministerial Scientific Research Project(LJ20212C031165)Basic Frontier Science and Technology Innovation Project of Army Engineering University of PLA(KYSZJQZL2210)。
文摘Sn_(1−x)Er_(x)O_(2)(x=0%,8%,16%,24%)micro/nanofibers were prepared by electrospinning combined with heat treatment using erbium nitrate,stannous chloride and polyvinylpyrrolidone(PVP)as raw materials.The target products were characterized by thermogravimetric analyzer,X-ray diffrotometer,fourier transform infrared spectrometer,scanning electron microscope,spectrophotometer and infrared emissivity tester,and the effects of Er^(3+)doping on its infrared and laser emissivity were studied.At the same time,the Sn_(1−x)Er_(x)O_(2)(x=0%,16%)doping models were constructed based on the first principles of density functional theory,and the related optoelectronic properties such as their energy band structure,density of states,reflectivity and dielectric constant were analyzed,and further explained the mechanism of Er^(3+)doping on SnO_(2)infrared emissivity and laser absorption from the point of electronic structure.The results showed that after calcination at 600℃,single rutile type SnO_(2)was formed,and the crystal structure was not changed by doping Er^(3+).The calcined products showed good fiber morphology,and the average fiber diameter was 402 nm.The infrared emissivity and resistivity of the samples both decreased first and then increased with the increase of Er^(3+)doping amount.When x=16%,the infrared emis-sivity of the sample was at least 0.71;and Er^(3+)doping can effectively reduce the reflectivity of SnO_(2)at 1.06μm and 1.55μm,when x=16%,its reflectivity at 1.06μm and 1.55μm are 50.5%and 40%,respectively,when x=24%,the reflectivity at 1.06μm and 1.55μm wavelengths are 47.3%and 42.1%,respectively.At the same time,the change of carrier concentration and electron transition before and after Er^(3+)doping were described by first-principle calculation,and the regulation mechanism of infrared emissivity and laser reflectivity was explained.This study provides a certain experimental and theoretical basis for the development of a single-type,light-weight and easily prepared infrared and laser compatible-stealth material.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11304222 and 11527808)the State Key Development Program for Basic Research of China(Grant No.2014CB340103)
文摘We study the spontaneous Raman scattering （RS） in taper-drawn micro/nano-fibers （MNFs） by employing the photon counting technique. The spectra of RS in five MNFs, which are fabricated by using different heating flames （hydrogen flame or butane flame） and with different diameters, are measured within a frequency shift range of 1435 cm- 1_3200 cm- 1. From the measured spectra, we observe the RS peaks originated from silica and a unique RS peak with a frequency shift of - 2905 cm-1 （- 87.2 THz）. Unlike the former ones, the latter one is not observable in conventional optical fibers. Furthermore, the unique peak becomes obvious and starts to rapidly increase with the decrease of the diameter of MNFs when the diameter is smaller than 2 μm, and the intensity of the unique peak significantly depends on the heating flame used in the fabricating process. Our investigation is useful for the entanglement generation or optical sensing using taper-drawn MNFs.
基金Project supported by the Beijing Natural Science Foundation,China(Grant No.4192047)the Fundamental Research Funds for the Central Universities,China(Grant Nos.2018JBM070 and 2018JBM065)the National Natural Science Foundation of China(Grant No.61675019)
文摘To combine the technical functions and advantages of solid-core fiber Bragg gratings(FBGs) and hollow-core optical fibers(HCFs), the hollow and filled FBGs in nano-bore optical fibers(NBFs) with nano-bore in the GeO2-doped core are proposed.The fundamental mode field, effective mode index, and confinement loss of NBF with 50 nm–7 μm-diameter hollow and filled nano-bore are numerically investigated by the finite element method.The reflected spectra of FBGs in NBFs are obtained by the transmission matrix method.The hollow FBGs in NBFs can be acheived with ~5% power fraction in the bore and the ~0.9 reflectivity when bore diameter is less than 3 μm.The filled FBGs can be realized with^1% power fraction and 0.98 reflectivity with different fillings including o-xylene, trichloroethylene, and chloroform for 800-nm bore diameter.The feasibility of the index sensing by our proposed NBF FBG is also analyzed and discussed.The experimental fabrication of hollow and filled FBGs are discussed and can be achieved by current techniques.The aim of this work is to establish a principle prototype for investigating the HCFs and solid-core FBGs-based fiber-optic platforms,which are useful for applications such as the simultaneous chemical and physical sensing at the same position.
文摘Vinyl ester (VE) resin inherently has intrinsic brittleness due to its high cross-link density. To improve mechanical performance, micro/nano fillers are widely used to modify this matrix. In present study, glass fiber in submicron scale at low contents was added into VE to prepare submicron composite (sMC). The impact resistance of un-notched sMC degraded with the increase of sGF content while that of notched-sMC remained the unchanged. Flexural properties of sMCs also were the same with that of neat resin. The results of Dynamic mechanical analysis (DMA) test showed the slight increase of storage modulus and the decrease of tan delta value in the case of sMC compared to those of un-filled matrix. However, the Mode I fracture toughness of sMC improved up to 26% and 61% corresponding to 0.3 and 0.6 wt% glass fiber used. The compact tension sample test suggests that there is the delay of crack propagation under tensile cyclic load in resin reinforced by submicron glass fiber. The number of failure cycle enlarged proportionally with the increment of sGF content in matrix.
基金supported by the National Key Research and Development Program of China(2020YFA0908200)the Strategic Priority Research Program of the Chinese Academy of Science(XDA16021103)+4 种基金the National Natural Science Foundation of China(61927805,51522302,82101184)Natural Science Foundation of Guangdong Province(2020A1515110780)Shenzhen Fundamental Research Program(JCYJ20210324102809024)Shenzhen PhD Start-up Program(RCB20210609103713045)the China Postdoctoral Science Foundation funded project(2020M680120).
文摘Nano/micro fibers have evoked much attention of scientists and have been researched as cutting edge and hotspot in the area of fiber science in recent years due to the rapid development of various advanced manufacturing technologies,and the appearance of fascinating and special functions and properties,such as the enhanced mechanical strength,high surface area to volume ratio and special functionalities shown in the surface,triggered by the nano or micro-scale dimensions.In addition,these outstanding and special characteristics of the nano/micro fibers impart fiber-based materials with wide applications,such as environmental engineering,electronic and biomedical fields.This review mainly focuses on the recent development in the various nano/micro fibers fabrication strategies and corresponding applications in the biomedical fields,including tissue engineering scaffolds,drug delivery,wound healing,and biosensors.Moreover,the challenges for the fabrications and applications and future perspectives are presented.
