GP Algorithm-Based Fourier Transform Infrared Spectrum Trend Term Removal Model

Trend term removal is a key step in Fourier transform infrared spectroscopy(FTIR)data pre-processing.The most commonly used least squares(LS)method,although satisfying the real-time requirement,has many problems such as highly correlated initial values of the expression parameters,the need to pre-estimate the trend term shape,and poor fitting accuracy at low signal-to-noise ratios.In order to achieve real-time and robust trend term removal,a new trend term removal method using genetic programming(GP)in symbolic regression is constructed in this paper,and the FTIR simulation interference results and experimental measurement data for common volatile organic compounds(VOCs)gases are analyzed.The results show that the genetic programming algorithm can both reduce the initial value requirement and greatly improve the trend term accuracy by 20%-30% in three evaluation indicators,which is suitable for gas FTIR detection in complex scenarios.

利用Transformer的多模态目标跟踪算法

目前目标跟踪方法大多通过融合不同模态信息进行定位决策,存在信息提取不充分、融合方法简单、弱光场景无法准确跟踪目标的问题。为此,提出一种基于Transformer的多模态目标跟踪算法(Trans-RGBT):利用伪孪生网络对可见光图像和红外图像分别进行特征提取,并在特征层面充分融合;将首帧目标信息调制到待跟踪帧的特征向量中,得到一个专用跟踪器;应用Transformer的方法对视野中的目标进行编解码,通过空间位置预测分支预测目标在视野中的空间位置,并结合历史信息滤除干扰目标,得到目标的准确位置;使用矩形框回归网络预测目标的外接矩形框,从而实现目标准确跟踪。在最新的大规模数据集VTUAV、RGBT234上进行了实验,与孪生网络(Siambased)、滤波(filter-based)算法相比,Trans-RGBT精度更高、鲁棒性更好、速度接近实时,达22 FPS。

HRformer:基于多级回归Transformer网络的红外小目标检测

红外小目标检测是指从低信噪比、复杂背景的红外图像中对小目标进行检测,在海上救援、交通管理等应用中具有重要实际意义。然而,由于图像分辨率低、目标尺寸小以及特征不突出等因素,导致红外目标很容易淹没在包含噪声和杂波的背景中,如何精确检测红外小目标的外形信息仍然是一个挑战。针对上述问题,构建了一种基于多级回归Transformer(HRformer)网络的红外小目标检测算法。具体来说,首先为了在获得多尺度信息的同时尽可能避免原始图像信息的损失,采用像素逆重组(PixelUnShuffle)操作对原始图像下采样来获取不同层级网络的输入,同时采用一种可学习的像素重组(PixelShuffle)操作对每一层级的输出特征图进行上采样,提升了网络的灵活性;接着,为实现网络中不同层级特征之间的信息交互,本文设计了一种包含空间注意力计算分支以及通道注意力计算分支在内的交叉注意力融合(cross attention fusion,CAF)模块实现特征高效融合以及信息互补;最后,为进一步提升网络的检测性能,结合普通Transformer结构具有较大感受野以及基于窗口的Transformer结构具有较少计算复杂度的优势,提出了一种局部-全局Transformer(LGT)结构,能够在提取局部上下文信息的同时对全局依赖关系进行建模,计算成本也得到节省。实验结果表明,与目前较为先进的一些红外小目标检测算法相比,本文所提出的算法具有更高的检测精度,同时具有较少的参数量,在解决实际问题中更有意义。

Mathematic Models for Analysis of Quality Components in Sugarcane Juice with Fourier Transform Near Infrared Spectroscopy

With the technique of Fourier transform near infrared (FT-NIR) spectroscopy, the calibration models for quantitative analysis of sucrose and polarization in sugarcane juice were developed by using transmission mode and calibrating with partial least square (PLS) algorithm. The determination coefficients (R2) of the predicted models for sucrose and polarization in juice were 0. 9980 and 0. 9979 respectively; the root mean square errors of cross validation (RMSECV) were 0. 143 and 0. 155% for sucrose and polarization in juice respectively. The predictive errors measured by FT-NIR were close to those by routine laboratory methods. The results demonstrated that the FT-NIR methods had high accuracy and they were able to replace the routine laboratory analysis. It was also demonstrated that as a rapid and accurate measurement, the FT-NIR technique had potential applications in quality control of mill sugarcane, establishment of payment system based on sugarcane quality, and selection of clones in sugarcane breeding.

Retrieval algorithm of quantitative analysis of passive Fourier transform infrared (FTRD) remote sensing measurements of chemical gas cloud from measuring the transmissivity by passive remote Fourier transform infrared

Passive Fourier transform infrared （FTIR） remote sensing measurement of chemical gas cloud is a vital technology. It takes an important part in many fields for the detection of released gases. The principle of concentration measurement is based on the Beer-Lambert law. Unlike the active measurement, for the passive remote sensing, in most cases, the difference between the temperature of the gas cloud and the brightness temperature of the background is usually a few kelvins. The gas cloud emission is almost equal to the background emission, thereby the emission of the gas cloud cannot be ignored. The concentration retrieval algorithm is quite different from the active measurement. In this paper, the concentration retrieval algorithm for the passive FTIR remote measurement of gas cloud is presented in detail, which involves radiative transfer model, radiometric calibration, absorption coefficient calculation, et al. The background spectrum has a broad feature, which is a slowly varying function of frequency. In this paper, the background spectrum is fitted with a polynomial by using the Levenberg-Marquardt method which is a kind of nonlinear least squares fitting algorithm. No background spectra are required. Thus, this method allows mobile, real-time and fast measurements of gas clouds.

Fault diagnosis of electric transformers based on infrared image processing and semi-supervised learning

It is crucial to maintain the safe and stable operation of distribution transformers,which constitute a key part of power systems.In the event of transformer failure,the fault type must be diagnosed in a timely and accurate manner.To this end,a transformer fault diagnosis method based on infrared image processing and semi-supervised learning is proposed herein.First,we perform feature extraction on the collected infrared-image data to extract temperature,texture,and shape features as the model reference vectors.Then,a generative adversarial network(GAN)is constructed to generate synthetic samples for the minority subset of labelled samples.The proposed method can learn information from unlabeled sample data,unlike conventional supervised learning methods.Subsequently,a semi-supervised graph model is trained on the entire dataset,i.e.,both labeled and unlabeled data.Finally,we test the proposed model on an actual dataset collected from a Chinese electricity provider.The experimental results show that the use of feature extraction,sample generation,and semi-supervised learning model can improve the accuracy of transformer fault classification.This verifies the effectiveness of the proposed method.

Infrared Spectroscopy-Based Chemometric Analysis for Lard Differentiation in Meat Samples

One of the most pressing concerns for the consumer market is the detection of adulteration in meat products due to their preciousness.The rapid and accurate identification mechanism for lard adulteration in meat products is highly necessary,for developing a mechanism trusted by consumers and that can be used to make a definitive diagnosis.Fourier Transform Infrared Spectroscopy(FTIR)is used in this work to identify lard adulteration in cow,lamb,and chicken samples.A simplified extraction method was implied to obtain the lipids from pure and adulterated meat.Adulterated samples were obtained by mixing lard with chicken,lamb,and beef with different concentrations(10%–50%v/v).Principal component analysis(PCA)and partial least square(PLS)were used to develop a calibration model at 800–3500 cm^(−1).Three-dimension PCA was successfully used by dividing the spectrum in three regions to classify lard meat adulteration in chicken,lamb,and beef samples.The corresponding FTIR peaks for the lard have been observed at 1159.6,1743.4,2853.1,and 2922.5 cm−1,which differentiate chicken,lamb,and beef samples.The wavenumbers offer the highest determination coefficient R2 value of 0.846 and lowest root mean square error of calibration(RMSEC)and root mean square error prediction(RMSEP)with an accuracy of 84.6%.Even the tiniest fat adulteration up to 10%can be reliably discovered using this methodology.

A simple,sensitive and non-destructive technique for characterizing bovine dental enamel erosion:attenuated total reflection Fourier transform infrared spectroscopy

Although many techniques are available to assess enamel erosion in vitro, a simple, non-destructive method with sufficient sensitivity for quantifying dental erosion is required. This study characterized the bovine dental enamel erosion induced by various acidic beverages in vitro using attenuated total reflection Fourier transform infrared （ATR-FTIR） spectroscopy. Deionized water （control） and 10 acidic beverages were selected to study erosion, and the pH and neutralizable acidity were measured. Bovine anterior teeth （110） were polished with up to 1 200-grit silicon carbide paper to produce flat enamel surfaces, which were then immersed in 20 mL of the beverages for 30 min at 37 ℃. The degree of erosion was evaluated using ATR-FTIR spectroscopy and Vickers＇ microhardness measurements. The spectra obtained were interpreted in two ways that focused on the ~1, ~3 phosphate contour： the ratio of the height amplitude of ~3 P04 to that of/11 P04 （Method 1） and the shift of the v3 P04 peak to a higher wavenumber （Method 2）. The percentage changes in microhardness after the erosion treatments were primarily affected by the pH of the immersion media. Regression analyses revealed highly significant correlations between the surface hardness change and the degree of erosion, as detected by ATR-FTIR spectroscopy （P〈0.001）. Method 1 was the most sensitive to these changes, followed by surface hardness change measurements and Method 2. This study suggests that ATR- FTIR spectroscopy is potentially advantageous over the microhardness test as a simple, non-destructive, sensitive technique for the quantification of enamel erosion.

Fourier Transform Infrared Spectroscopic Studies in Flotation

Fourier transform infrared (FTIR) spectroscopy has beenextensively employed in flotation research. The work done by theauthor and co-workers has been reported. A comparison has been madeamong the different FTIR spectroscopic techniques, e.g., transmissionFTIR spectroscopy, diffuse reflectance infrared Fourier transform(DRIFT) spectroscopy, and attenuated total reflectance (ATR) FTIRspectroscopy.

An infrared and visible image fusion method based upon multi-scale and top-hat transforms

The high-frequency components in the traditional multi-scale transform method are approximately sparse, which can represent different information of the details. But in the low-frequency component, the coefficients around the zero value are very few, so we cannot sparsely represent low-frequency image information. The low-frequency component contains the main energy of the image and depicts the profile of the image. Direct fusion of the low-frequency component will not be conducive to obtain highly accurate fusion result. Therefore, this paper presents an infrared and visible image fusion method combining the multi-scale and top-hat transforms. On one hand, the new top-hat-transform can effectively extract the salient features of the low-frequency component. On the other hand, the multi-scale transform can extract highfrequency detailed information in multiple scales and from diverse directions. The combination of the two methods is conducive to the acquisition of more characteristics and more accurate fusion results. Among them, for the low-frequency component, a new type of top-hat transform is used to extract low-frequency features, and then different fusion rules are applied to fuse the low-frequency features and low-frequency background; for high-frequency components, the product of characteristics method is used to integrate the detailed information in high-frequency. Experimental results show that the proposed algorithm can obtain more detailed information and clearer infrared target fusion results than the traditional multiscale transform methods. Compared with the state-of-the-art fusion methods based on sparse representation, the proposed algorithm is simple and efficacious, and the time consumption is significantly reduced.

The role of fluid polarity in the swelling of sodium-montmorillonite clay:A molecular dynamics and Fourier transform infrared spectroscopy study

Swelling clays are found extensively in various parts of the world, and sodium-montmorillonite(NaMMT) is the main constituent of an expansive clay mineral. In this work, the swelling behavior of NaMMT clay with a wide range of organic fluids, high polar through low polar fluids, is studied using a combination of Fourier transform infrared(FTIR) technique and molecular dynamics(MD) simulations.The construction of the representative clayefluid models is carried out, and the nature of nonbonded interactions between clay and fluids is studied using MD. Our FTIR and MD simulations results suggest the significant nonbonded interactions between Na-MMT clay and polar fluids, such as formamide and water. The nonbonded interactions of Na-MMT with methanol and acetone are significantly less than those in Na-MMT with polar fluids. The interactions of the fluids with various entities of the clay such as Sie O, Fee OH, Mge OH, and Ale OH captured via the spectroscopy experiments and modeling provide a finer understanding of the interactions and their contributions to swelling. The MD simulations are able to capture the band shifts observed in the spectra obtained in the spectroscopy experiments. This work also captures the conformations of interlayer sodium ions with formamide, water, methanol, and acetone during swelling. These nonbonded interactions provide insight into the molecular mechanism that the polarity of fluids plays an important role in the initiation of interlayer swelling, alteration in the orientations, and evolution of microstructure of swelling clays at the molecular scale.

Phase transformation and nanograting structure on TiO2 rutile single crystal induced by infrared femtosecond laser

In this paper, TitaiJum dioxide （TiO2） rutile single crystal was irradiated by infrared femtosecond laser pulses with repetition rate of 250 kHz. For a P-polarized femtosecond laser, the periodic nanograting structure on the ablation crater surface was formed . The periodicity is much less than the laser wavelength. The direction of nanograting alignment depends on the polarization laser beam. Micro-Raman spectra show that the intensity of Eg Raman vibrating mode of rutile phase increases and that of Alg Raman vibrating mode decreases apparently within the ablation crater. With the increase of irradiation time and laser average power, the Raman vibrating modes of anatase phase emerged. Rutile phase of TiO2 single crystal is partly transformed into anatase phase.

Sub-Regional Infrared-Visible Image Fusion Using Multi-Scale Transformation

Infrared-visible image fusion plays an important role in multi-source data fusion,which has the advantage of integrating useful information from multi-source sensors.However,there are still challenges in target enhancement and visual improvement.To deal with these problems,a sub-regional infrared-visible image fusion method(SRF)is proposed.First,morphology and threshold segmentation is applied to extract targets interested in infrared images.Second,the infrared back-ground is reconstructed based on extracted targets and the visible image.Finally,target and back-ground regions are fused using a multi-scale transform.Experimental results are obtained using public data for comparison and evaluation,which demonstrate that the proposed SRF has poten-tial benefits over other methods.

COMP ARISON OF MACROMOLECULAR COMPONENT DISTRIBUTIONS IN OSTEOARTHRITIC AND HEALTHY CARTILAGES BY FOURIER TRANSFORM INFRARED IMAGING

Fourier transform infrared imaging(FTIRI)was used to examine the depth-dependent content variations of macromolcular components,ollagen and protooglycan(PG),in osteoarthritic and healthy cartilages.Dried 6 pmm thick sections of canine knee cartilages were imaged at 6.25 pμrm pixel-size in FTIRI.By analyzing the infrared(IR)images and spectra,the depth dependence of characteristic band(sugar)intensity of PG show obvious difference bet ween the cartilage sections of(OA)and bealth.The result confimns that PG content decreases in the ostcoarthritic cartilage.However,no clear change occurs to collagen,suggesting that the OA influences little on the collagen content at early stage of OA.This observation will be helpful to further understand PG loss associated with pathological conditions in OA,and demonstrates that FIIRI has the po-tential to become an important analytical tool to identify early clinical signs of tissue degna-dation,such as PG loss even collagen disruption.

基于孪生网络和Transformer的红外弱小目标跟踪方法

针对红外弱小目标跟踪准确性较低这一问题,提出一种基于孪生网络和Transformer的红外弱小目标跟踪方法。首先,构建多特征提取级联模块分别提取红外弱小目标模板帧和搜索帧的深度特征,并将二者分别与其对应的HOG特征进行维度层面的串联;其次,引入多头注意力机制Transformer进行模板特征图和搜索特征图的互相关操作,生成响应图;最后,通过响应图上采样网络和边界框预测网络,获得目标在图像的中心位置和回归边界框,完成对红外弱小目标的跟踪。在包含13655张红外图像数据集上的测试结果表明:与KeepTrack跟踪方法相比,成功率提高5.9个百分点,精确率提高1.8个百分点;与TransT(Transformer Tracking)方法相比,成功率提高14.2个百分点,精确率提高14.6个百分点,证明所提方法对复杂背景下的红外弱小目标跟踪准确性更高。

Discrimination of Wild-Grown and Cultivated <i>Ganoderma lucidum</i>by Fourier Transform Infrared Spectroscopy and Chemometric Methods

Wild-grown Ganoderma lucidum (G. lucidum), a traditional Chinese herbal medicine, is highly cherished and expensive for its medicinal efficiency. This study targets the development of an accurate and effective analytical method to distinguish wild-grown G. lucidum from cultivated ones, which are of essential importance for the quality assurance and estimation of its medicinal value. Furthermore, different parts of G. lucidum have been studied to examine the differences between wild-grown and cultivated ones. Fourier transform infrared (FTIR) diffuse reflectance spectroscopy combined with the appropriate chemometric method has been proven to be a rapid and powerful tool for discrimination of wild-grown and cultivated G. lucidum with classification accuracy of 98%. The informative spectral absorption bands for discrimination emphasized by the linear diagnostic rule have provided quantitative interpretations of the chemical constituents of wild-grown G. lucidum regarding its anticancer effects.

Fourier transform infrared spectroscopy analysis of the active components in serum of rats treated with Zuogui Pill

Objective:To investigate the active components Zuogui Pill,a typical recipe for nourishing kidney essence in the traditional Chinese medicine.Methods:Adult male Sprague Dawley rats were treated with the traditional Chinese herbal medicine Zuogui Pill and the active components found in the serum of the animals were analyzed by Fourier transform infrared(FTIR)spectroscopy.FTIR spectra of serum samples of treated and untreated rats were analyzed and the A2960/A2931 and A1540/A1080 ratios were calculated.Results:A2960/A2931 ratios of the serum samples collected following the administration of Zuogui Pill were significantly higher than those of the normal serum samples.FTIR data were then fitted using a Gaussian equation for wave numbers in the range of 1140e1000 cm
1.ARNA/ADNA ratios in the serum of rats treated with Zuogui Pill were higher than those found in normal rat serum.Conclusion:FTIR spectroscopy could be used as an analytical tool to detect the activecomponents in serum of animals treated with Zuogui Pill.

Comparative study on identi¯cation of healthy and osteoarthritic articular cartilages by fourier transform infrared imaging and chemometrics methods

Two discriminant methods,partial least squares-discriminant analysis(PLS-DA)and Fisher's discriminant analysis(FDA),were combined with Fourier transform infrared imaging(FTIRI)to differentiate healthy and osteoarthritic articular cartilage in a canine model.Osteoarthritic cartilage had been developed for up to two years after the anterior cruciate ligament(ACL)transection in one knee.Cartilage specimens were sectioned into 10μm thickness for FTIRI.A PLS-DA model was developed after spectral pre-processing.All IR spectra extracted from FTIR images were calculated by PLS-DA with the discriminant accuracy of 90%.Prior to FDA,principal component analysis(PCA)was performed to decompose the IR spectral matrix into informative princi pal component matrices.Based on the different discriminant mechanism,the discriminant accuracy(96%)of PCA-FDA with high convenience was higher than that of PLS-DA.No healthy cartilage sample was mis assigned by these two methods.The above mentioned suggested that both integrated technologies of FTIRI-PLS-DA and,especially,FTIRI-PCA-FDA could become a promising tool for the discrimination of healthy and osteoarthritic cartilage specimen as well as the diagnosis of cartilage lesion at microscopic level.The results of the study would be helpful for better understanding the pathology of osteoarthritics.

In vivo and in situ detection of colorectal cancer using Fourier transform infrared spectroscopy

AIM: Real-time and rapid identification of the malignant tissue can be performed during or before surgical operation.Here we aimed to detect in vivo and in situ colorectal cancer by using Fourier transform infrared (FTIR) spectroscopy and fiber-optic technology.METHODS: A total of five patients with large intestine cancer were detected in vivo and in situ. Of them, three cases of colon cancer and one case of cecum cancer were detected intraoperatively and in vivo by using a FTIR spectrometer during surgical operation, and one case of rectum cancer was explored non-invasively and in vivo before the surgical operation. Normal and malignant colorectal tissues were detected in vivo and in situ using FTIR spectroscopy on the basis of fundamental studies.RESULTS: There were significant differences between FTIR spectra of normal and malignant colorectal tissues detected in vivo and in situ. Experimental results revealed that the spectral characteristics of normal and malignant tissues found in vivo and in situ were similar to those obtained from in vitro measurement in our previous fundamental research.CONCLUSION: FTIR fiber-optic attenuated total reflectance (ATR) spectroscopy can identify in situ and in vivo colorectal cancer. FTIR spectroscopic method with fiber optics is a non-invasive, rapid, accurate and in vivo cancer detection technique in clinical diagnosis.

Use of Fourier-transform infrared spectroscopy to rapidly diagnose gastric endoscopic biopsies

AIM: To determine if Fourier-transform infrared (FT-IR)spectroscopy of endoscopic biopsies could accurately diagnose gastritis and malignancy.METHODS: A total of 123 gastroscopic samples, including 11 cases of cancerous tissues, 63 cases of chronic atrophic gastritis tissues, 47 cases of chronic superficial gastritis tissues and 2 cases of normal tissues, were obtained from the First Hospital of Xi'an Jiaotong University, China. A modified attenuated total reflectance (ATR) accessory was linked to a WQD-500 FT-IR spectrometer for spectral measurement followed by submission of the samples for pathologic analysis. The spectral characteristics for different types of gastroscopic tissues were summarized and correlated with the corresponding pathologic results.RESULTS: Distinct differences were observed in the FTIR spectra of normal, atrophic gastritis, superficial gastritis and malignant gastric tissues. The sensitivity of FT-IR for detection of gastric cancer, chronic atrophic gastritis and superficial gastritis was 90.9%, 82.5%, 91.5%, and specificity was 97.3%, 91.7%, 89.5% respectively.CONCLUSION: FT-IR spectroscopy can distinguish gastric inflammation from malignancy.