Improved controllability and energy density of ignition agents are of great significance for the devel-opment of energetic composite materials.In this study,droplet microfluidics and emulsification tech-niques were co...Improved controllability and energy density of ignition agents are of great significance for the devel-opment of energetic composite materials.In this study,droplet microfluidics and emulsification tech-niques were combined to prepare HNS/CL-20 composite microspheres with polyglycidyl azide polymer(GAP)as the binder.The influence of binder content on the morphology of microspheres was investi-gated,and the microspheres were characterized and tested for particle size,crystal structure,thermal decomposition,dispersibility,mechanical sensitivity,combustion behavior and detonation performance.The results showed that microspheres prepared with a binder content of 3%had higher sphericity and particle size uniformity.The microspheres retained the crystal structure of both HNS and CL-20(ε-type).Compared with raw HNS,the microspheres had higher apparent activation energy,better safety per-formance,and good dispersibility.The ignition experiments and detonation performance tests show that HNS/CL-20 composite microspheres have excellent ignition performance,obvious combustion flame,and significant energy release effects,which are expected to achieve high energy and high-speed response of the igniter,thus improving the ignition reliability in special environments or systems.展开更多
为了研究底排点火具在弹丸出炮口时瞬态燃烧特性及工作性能,采用半密闭爆发器模拟炮口压力突降过程,借助高速录像系统,开展了高降压速率条件下底排点火具燃烧特性的实验研究。结果表明,在高速降压过程中,底排点火具燃烧受到强烈瞬态扰...为了研究底排点火具在弹丸出炮口时瞬态燃烧特性及工作性能,采用半密闭爆发器模拟炮口压力突降过程,借助高速录像系统,开展了高降压速率条件下底排点火具燃烧特性的实验研究。结果表明,在高速降压过程中,底排点火具燃烧受到强烈瞬态扰动。不同药剂的点火具抗干扰性能不同,其中以硝酸钡为药剂主成分的点火具和以镁粉+PTFE为药剂主成分的点火具燃烧性能稳定,以氢化锆、二氧化铅为药剂主成分的点火具工作稳定性较差,火焰持续时间标准差为523 m s,点火具喷孔堵塞严重。展开更多
基金supported by National Natural Science Foundation of China(grant No.22005275).
文摘Improved controllability and energy density of ignition agents are of great significance for the devel-opment of energetic composite materials.In this study,droplet microfluidics and emulsification tech-niques were combined to prepare HNS/CL-20 composite microspheres with polyglycidyl azide polymer(GAP)as the binder.The influence of binder content on the morphology of microspheres was investi-gated,and the microspheres were characterized and tested for particle size,crystal structure,thermal decomposition,dispersibility,mechanical sensitivity,combustion behavior and detonation performance.The results showed that microspheres prepared with a binder content of 3%had higher sphericity and particle size uniformity.The microspheres retained the crystal structure of both HNS and CL-20(ε-type).Compared with raw HNS,the microspheres had higher apparent activation energy,better safety per-formance,and good dispersibility.The ignition experiments and detonation performance tests show that HNS/CL-20 composite microspheres have excellent ignition performance,obvious combustion flame,and significant energy release effects,which are expected to achieve high energy and high-speed response of the igniter,thus improving the ignition reliability in special environments or systems.
文摘为了研究底排点火具在弹丸出炮口时瞬态燃烧特性及工作性能,采用半密闭爆发器模拟炮口压力突降过程,借助高速录像系统,开展了高降压速率条件下底排点火具燃烧特性的实验研究。结果表明,在高速降压过程中,底排点火具燃烧受到强烈瞬态扰动。不同药剂的点火具抗干扰性能不同,其中以硝酸钡为药剂主成分的点火具和以镁粉+PTFE为药剂主成分的点火具燃烧性能稳定,以氢化锆、二氧化铅为药剂主成分的点火具工作稳定性较差,火焰持续时间标准差为523 m s,点火具喷孔堵塞严重。
