Compared with traditional plastic forming,ultrasonic vibration plastic forming has the advantages of reducing the forming force and improving the surface quality of the workpiece.This technology has a very broad appli...Compared with traditional plastic forming,ultrasonic vibration plastic forming has the advantages of reducing the forming force and improving the surface quality of the workpiece.This technology has a very broad application prospect in industrial manufactur-ing.Researchers have conducted extensive research on the ultrasonic vibration plastic forming of metals and laid a deep foundation for the development of this field.In this review,metals were classified according to their crystal structures.The effects of ultrasonic vibration on the microstructure of face-centered cubic,body-centered cubic,and hexagonal close-packed metals during plastic forming and the mech-anism underlying ultrasonic vibration forming were reviewed.The main challenges and future research direction of the ultrasonic vibra-tion plastic forming of metals were also discussed.展开更多
A new technological process of tube forming was developed, namely solution treatment → granule medium internal high pressure forming → artificial aging. During this process, the mechanical properties of AA6061 tube ...A new technological process of tube forming was developed, namely solution treatment → granule medium internal high pressure forming → artificial aging. During this process, the mechanical properties of AA6061 tube can be adjusted by heat treatment to satisfy the process requirements and the processing method can also be realized by granule medium internal high pressure forming technology with the features of convenient implementation, low requirement to equipment and flexible design in product. Results show that, at a solution temperature of 560 ℃ and time of 120 min, the elongation of AA6061 increases by 313%, but the strength and the hardness dramatically decrease. At an aging temperature of 180 ℃ and time of 360 min, the strength and hardness of AA6061 alloy are recovered to the values of the as-received alloy. The maximum expansion ratio(MER) of AA6061 tube increases by 25.5% and the material properties of formed tube reach the performances of raw material.展开更多
Compared with conventional forming processes,ultrasonic-assisted forming technology with a high frequency and small amplitude can significantly improve the forming quality of materials.Owing to the advantages of reduc...Compared with conventional forming processes,ultrasonic-assisted forming technology with a high frequency and small amplitude can significantly improve the forming quality of materials.Owing to the advantages of reduced forming force,improved surface quality,avoidance of forming defects,and strengthened surface structure,ultrasonic-assisted forming technology has been applied to increasingly advanced forming processes,such as incremental forming,spinning,and micro-forming.However,in the ultrasonic-assisted forming process,there are multiple ultrasonic mechanisms,such as the volume effect and surface effect.The explanation of the effect of ultrasonic vibration(UV)on plastic deformation remains controversial,hindering the development of related technologies.Recently,many researchers have proposed many new theories and technologies for ultrasonic-assisted forming.To summarize these developments,systematic discussions on mechanisms,theoretical models,and forming performances are provided in this review.On this basis,the limitations of the current study are discussed.In addition,an outlook for ultrasonic-assisted forming is proposed:efficient and stable UV systems,difficulty forming components with complex geometry,explanation of the in-depth mechanism,a systematic theoretical prediction model,and multi-field-coupling energy-assisted forming are considered to be hot spots in future studies.The present review enhances existing knowledge of ultrasonic-assisted forming,and facilitates a fast reference for related researchers.展开更多
The discussion on sedimentary macro-structures and their forming mechanics of debris flow is based on thedata of present processes and ancient deposits of Dongchuan in Yunnan Province, Wudu in Gansu Province and Fuxin...The discussion on sedimentary macro-structures and their forming mechanics of debris flow is based on thedata of present processes and ancient deposits of Dongchuan in Yunnan Province, Wudu in Gansu Province and Fuxin inLiaoning Province. Non-cohesive debris flow, which is 1. 3 -1. 7 t/m3 in density, follows hydraulic fluid and flow model. In the hydraulic fluid of flood, electrolytic water combines clay into pulp to transport solid debris. The sedimentary structures show fluid processes as stone-line structure, imbricated structure and stone supporting-sustructure. A part of non-cohesive debris flow with a density of 1. 7 -1. 9t/m3 follows granular model. Debris is in the action of friction, collision and dispersion which forces as debris moving upward to form reverse graded load. The sedimentary structures of granular flow show reverse graded bedding, reverse-normal graded bedding, imbricated verticalstructure and circling linear structure.Cohesive debris flow, which is 1. 9 - 2. 3 t/m3 in density, follows structural two phase flow (viscoplastic) model. The sedimentary structures of cohesive debris flow show reverse graded-chaotic structure,bottom mud-chaotic structure and outwedging structure.展开更多
Laser forraing is a new flexible and dieless forming technique. To achieve the high accuracy forming, the temperature gradient mechanism (TGM) is studied. In the analysis of TGM, the plate bends about x-axis and abo...Laser forraing is a new flexible and dieless forming technique. To achieve the high accuracy forming, the temperature gradient mechanism (TGM) is studied. In the analysis of TGM, the plate bends about x-axis and about y-axis as well. To understand the deformation trend, the numerical simulation of deformation of plate is conducted by choosing different laser powers, laser spot diameters, scanning speeds, lengths, widths and thicknesses. From the results of simulation, it can be seen that the laser spot diameter, the scanning speed, laser power and thickness of plate play dominant roles in the laser forming process. However, the bending angles αx and αy show different trends with the variation of parameters. In addition, in comparison with above four parameters, the effect of length and width of plate on the beading angle may be neglected, but their effects are significant for the bending radius R.展开更多
A method combining theoretical analysis with experiment is adopted and the flowing process of Ti-48A1-2Cr-2Nb alloy melt poured in a permanent mould during the centrifugal casting process has been analyzed. A mathemat...A method combining theoretical analysis with experiment is adopted and the flowing process of Ti-48A1-2Cr-2Nb alloy melt poured in a permanent mould during the centrifugal casting process has been analyzed. A mathematical model of the filling process is established and the forming mechanism of internal gaseous defect is summarized. The results of calculation show that the melt fills the mould with varying cross-section area and inclined angle. The filling speed of the cross-section is a function of filling time. The cross-section area is directly proportional to the filling speed and the inclined angle is inversely proportional to the filling speed at a given rotating speed of the platform. Both of them changes more obvious near the mould entrance. The gaseous defect can be formed in several ways and the centrifugal field has an important influence on the formation of the defect. In addition, the filling process in centrifugal field has been verified by wax experiments and the theoretical analysis are consistent with experimental results.展开更多
This article presents a theory about the growth mechanism of bubble-screw dislocation of nodular graphite. Normally speaking, the crystallizing procedure of most nodular graphite is as follows: firstly, graphite gener...This article presents a theory about the growth mechanism of bubble-screw dislocation of nodular graphite. Normally speaking, the crystallizing procedure of most nodular graphite is as follows: firstly, graphite generates nuclei on bubbles and fills them (mainly in the way of screw dislocation) forming the complete nuclei of nodular graphite-graphite bubble nuclei. Then, graphite grows up in the way of screw dislocation. Two important conditions concerning the production of nodular graphite are: (a) there is a relatively big interfacial energy between ferro liquid and graphite, and the one between ferro liquid and graphite prismatic plane is bigger than that between ferro liquid and graphite basal plane; (b) there are a certain amount of micro-bubbles in the melt.展开更多
As a characteristic sedimentary type,molartooth carbonatites veins(MCV) can be found in almost all the Neoproterozoic carbonatite strata in the North Anhui and Jiangsu Provinces.But their forming mechanism is still an...As a characteristic sedimentary type,molartooth carbonatites veins(MCV) can be found in almost all the Neoproterozoic carbonatite strata in the North Anhui and Jiangsu Provinces.But their forming mechanism is still an enigma,and more than four incompatible forming hypotheses have been put forward according to the structures,mineral components and elements of the MCV.Though all the MCV with the similar shape展开更多
A new thiosemicarbazone compound derived from 1-phenyl-3-methyl-4-(2-thenoyl) pyrazolone-5 (HPMTP) and thiosemicarbazide has been synthesized and characterized by IR, H- NMR, MS, elemental analysis, UV and single-...A new thiosemicarbazone compound derived from 1-phenyl-3-methyl-4-(2-thenoyl) pyrazolone-5 (HPMTP) and thiosemicarbazide has been synthesized and characterized by IR, H- NMR, MS, elemental analysis, UV and single-crystal X-ray diffraction. The compound crystallizes in monoclinic system, Cc space group with a = 7.5925(8), b = 20.263(2), c = 11.4669(13) A, r= 107.825(8)°, V = 1679.5(3) A3, Z = 4, R = 0.0316 and wR = 0.0687. The results of antibacterial activity test against Escherichia coli and Bacillus subtilis indicate that the compound possesses the same antibacterial activity as the contrast (Norfloxacin). Theoretical study of the forming mechanism to the title compound at the RHF/6-31G(d) level shows that there are two steps. The distal amino group of thiosemicarbazide is added to the 4-carbonyl group of HPMTP which forms TM. Then a dehydration reaction occurs in TM and generates a stable product PC.展开更多
Cast molding process has provided a reliable, simple and cost-effective way to fabricate micro structures since decades ago. In order to obtain structures with fine, dense and deep nano-size features by cast molding, ...Cast molding process has provided a reliable, simple and cost-effective way to fabricate micro structures since decades ago. In order to obtain structures with fine, dense and deep nano-size features by cast molding, it is necessary to study the forming mechanism in the process. In this paper, based on major steps of cast molding, filling models of liquid are established and solved; and the forming mechanism of liquid is revealed. Moreover, the scale effect between the liquid and the cavity on the filling velocity of liquid is studied.It is also interesting to find out that the wettability of liquid on the cavity may be changed from wetting to dewetting depends on the pressure difference. Finally, we experimentally verify some of our modeling results on the flowing and filling state of the liquid during the cast molding process.展开更多
Micro-pored CA6 -MA lightweight material with CAM: MA mass ratio of 7:3 was prepared using Al(OH) 3, MgCO3 and CaCO3 as starting materials, and anthracite. sweet potato starch and anthracite + sweet potato starch...Micro-pored CA6 -MA lightweight material with CAM: MA mass ratio of 7:3 was prepared using Al(OH) 3, MgCO3 and CaCO3 as starting materials, and anthracite. sweet potato starch and anthracite + sweet potato starch as pore forming agent (PFA) with an addition of 10 mass%, 20 mass% and 30 mass%, respectively. The starting materials were dry mixed, wet co-milled in a ball mill for 1 h. slip cast into cylindrical specimens with a diameter of 60 ram. and then calcined at 1 450 ℃ for 3 h. With the increase of PFA addition,, apparent porosity increases, and bulk density decreases. The influence of different PFAs on properties of the micro-pored LW CAM -MA aggregate was investigated. The achieved CAM - MA, by adding 30% sweet potato starch, has a porosity of 76. 8%, bulk density of 0. 78 g · cm^ - 3 and median pore size of 1.90 μm.展开更多
The comparative experiments of age forming and artificial aging of 2A12 aluminum alloy were carried out. The effect of the age forming on the microstructure and mechanical properties was investigated. The results demo...The comparative experiments of age forming and artificial aging of 2A12 aluminum alloy were carried out. The effect of the age forming on the microstructure and mechanical properties was investigated. The results demonstrate that the grains are further squashed and elongated compared with artificial aging due to the existence of the applied stress during the age forming. Meanwhile, the precipitated phases change from circle shape with random orientation of age forming to long strip shape with uniform orientation of artificial aging. The dislocation configuration in samples changes from ring dislocation or helical dislocation of the artificial aging to long and straight dislocation of the age forming. Otherwise, age forming slightly reduces the tensile properties and fracture toughness of the alloy and enhances its fatigue crack growth rate.展开更多
The forming condition of coal and coaly organic matter is analyzed. The dynamics of hydrocarbon generation of coal and coaly organic matter is discussed. It has been pointed out that the temperature is the main predom...The forming condition of coal and coaly organic matter is analyzed. The dynamics of hydrocarbon generation of coal and coaly organic matter is discussed. It has been pointed out that the temperature is the main predominant factor for the hydrocarbon generation of coal; chemical effect of structural pressing and shearing force accelerates the evolution of hydrocarbon derived from coal, and is the prerequisite for the hydrocarbons to be expelled from coal. The existence of atoms of N, S, O etc. is the prerequisite for forming the hydrocarbons at early evolution stage. The importance of NSO compounds in the evolution of hydrocarbon generation has been emphasized.展开更多
A series of rod samples with diameter of 3 mm(Zr0.55Al0.10Ni0.05Cu0.30)100-xFex(x=0,1,2,3,4) were prepared by magnetic suspend melting and copper mold suction casting method.The effects of a small amount of Fe on ...A series of rod samples with diameter of 3 mm(Zr0.55Al0.10Ni0.05Cu0.30)100-xFex(x=0,1,2,3,4) were prepared by magnetic suspend melting and copper mold suction casting method.The effects of a small amount of Fe on glass forming ability(GFA) and mechanical properties of Zr55Al10Ni5Cu30 bulk metallic glass(BMG) were investigated.The results show that the addition of an appropriate amount(less than 3%,mole fraction) of Fe enhances GFA,as indicated by the increase in the reduced glass transition temperature Trg(=Tg/Tl) and the parameter γ(=Tx/(Tg+Tl)) with increasing Fe content,and GFA gets deteriorated by further Fe addition(4%).The addition of Fe also effectively improves the compressive plasticity and increases the compressive fracture strength in these Zr-based BMGs.Compressive tests on BMG sample with 3 mm in diameter and 6 mm in length reveal work-hardening and a certain plastic strain in the alloy containing 2% Fe.The BMG composite containing 4% Fe also exhibits a high fracture strength along with significant plasticity.展开更多
Tropic and sub-tropic tidal flats (generalised) are a kind of speific peat-forming environments. Taking the Mangrove tidal flats and mangrove pets in Hainan island as a example, the authors deeply study and discuss th...Tropic and sub-tropic tidal flats (generalised) are a kind of speific peat-forming environments. Taking the Mangrove tidal flats and mangrove pets in Hainan island as a example, the authors deeply study and discuss the peat-forming mechanism of tropic and sub-tropic tidal flats. The conclusions are as follows: intrusion accretiou of plant organic matter is more important ; the organic matter has accumulated witk high productivity, high return rate and high decompeition rate ;anaerobic bacterin play a more important role during early peatification ; sea level change is the fundameutal factor controlling the formation and evolution of tidal flat peat-forming environments; lagoon peat-flat and delta peat-flat are main types of tidal flat peat-forming euvironments ;tidal flat peat-forming environments are remarkably characterized by low-level and rabe properties.展开更多
The effects of heat treatment on the microstructure and mechanical properties of laser solid forming (LSF) Ti-6Al-4V alloy were investigated The influences of the temperature and time of solution treatment and aging...The effects of heat treatment on the microstructure and mechanical properties of laser solid forming (LSF) Ti-6Al-4V alloy were investigated The influences of the temperature and time of solution treatment and aging treatment were analyzed. The results show that the microstructure of LSFed samples consists of Widmanstatten α laths and a little acicular in columnar prior β grains with an average grain width of 300 μm, which grow epitaxiaUy from the substrate along the deposition direction (27). Solution treatment had an important effect on the width, aspect ratio, and volmne fraction of primary and secondary a laths, and aging treatment mainly affects the aspect ratio and volume fraction of primary α laths and the width and volume fraction of secondary a laths. Globular a phase was first observed in LSFed samples when the samples were heat treated with solution treatment (950℃, 8 h/air cooling (AC)) or with solution treatment (950℃, 1 h/AC) and aging treatment (550℃, above 8 h/AC), respectively. The coarsening and globularization mechanisms of a phase in LSFed Ti-6Al-4V alloy during heat treatment were presented. To obtain good integrated mechanical properties for LSFed Ti-6Al-4V alloys, an optimized heat treatment regimen was suggested.展开更多
This study performs single point incremental forming(SPIF)on two aluminum alloys(i.e.AA5754 and AA6061),and analyzes their post forming mechanical properties and microstructure evolution.The forming parameters namely ...This study performs single point incremental forming(SPIF)on two aluminum alloys(i.e.AA5754 and AA6061),and analyzes their post forming mechanical properties and microstructure evolution.The forming parameters namely wall angle(35°-55°),feed rate(1-4 m/min),spindle rotational speed(50-1000 r/min),and lubricant(grease and hydraulic oil)are varied to probe detailed processing effects.The pre-and post-SPIF mechanical properties and microstructures are characterized by conducting tensile tests and optical microscopy,respectively.It is shown that an increase in the wall angle,feed rate and rotational speed causes microscopic variations in the alloys such that the grains of AA5754 and the second phase particles of AA6061 elongate.As a result,the ultimate tensile strength of the formed parts is increased by 10%for AA5754 and by 8%for AA6061.And,the ductility of AA5754 is decreased from 22.9%to 12%and that of AA6061 is decreased from 16%to 10.7%.Regarding the lubricant effect,it is shown that the mechanical properties remain insensitive to the type of lubricant employed.These results indicate that SPIF processing modifies the microstructure of Al alloys in a way to enhance the strength at the cost of ductility.展开更多
Magnesium and its alloys,as a promising class of materials,is popular in lightweight application and biomedical implants due to their low density and good biocompatibility.Additive manufacturing(AM)of Mg and its alloy...Magnesium and its alloys,as a promising class of materials,is popular in lightweight application and biomedical implants due to their low density and good biocompatibility.Additive manufacturing(AM)of Mg and its alloys is of growing interest in academia and industry.The domain-by-domain localized forming characteristics of AM leads to unique microstructures and performances of AM-process Mg and its alloys,which are different from those of traditionally manufactured counterparts.However,the intrinsic mechanisms still remain unclear and need to be in-depth explored.Therefore,this work aims to discuss and analyze the possible underlying mechanisms regarding defect appearance and elimination,microstructure formation and evolution,and performance improvement,based on presenting a comprehensive and systematic review on the relationship between process parameters,forming quality,microstructure characteristics and resultant performances.Lastly,some key perspectives requiring focus for further progression are highlighted to promote development of AM-processed Mg and its alloys and accelerate their industrialization.展开更多
Several argillaceous platforms lie along the Yellow River(YR) of the eastern Guide Basin, northeastern Tibetan Plateau, and their compositions, formation processes, and geomorphic evolution remain debated. Using fie...Several argillaceous platforms lie along the Yellow River(YR) of the eastern Guide Basin, northeastern Tibetan Plateau, and their compositions, formation processes, and geomorphic evolution remain debated. Using field survey data, sample testing, and high-resolution remote sensing images, the evolution of the Erlian mudflow fans are analyzed. The data show significant differences between fans on either side of the YR. On the right bank, fans are dilute debris flows consisting of sand and gravel. On the left bank, fans are viscosity mudflows consisting of red clay. The composition and formation processes of the left bank platforms indicate a rainfall-induced pluvial landscape. Fan evolution can be divided into two stages: early-stage fans pre-date 16 ka B.P., and formed during the last deglaciation; late-stage fans post-date 8 ka B.P.. Both stages were induced by climate change. The data indicate that during the Last Glacial Maximum, the northeastern Tibetan Plateau experienced a cold and humid climate characterized by high rainfall. From 16–8 ka, the YR cut through the Erlian early mudflow fan, resulting in extensive erosion. Since 8 ka, the river channel has migrated south by at least 1.25 km, and late stage mudflow fan formation has occurred.展开更多
基金supported by the National Key R&D Program of China(No.2022YFE0121300)the Introduction Plan for High end Foreign Experts,China(No.G2023105001L)the Young Foreign Talent Program,China(No.QN2023105001L).
文摘Compared with traditional plastic forming,ultrasonic vibration plastic forming has the advantages of reducing the forming force and improving the surface quality of the workpiece.This technology has a very broad application prospect in industrial manufactur-ing.Researchers have conducted extensive research on the ultrasonic vibration plastic forming of metals and laid a deep foundation for the development of this field.In this review,metals were classified according to their crystal structures.The effects of ultrasonic vibration on the microstructure of face-centered cubic,body-centered cubic,and hexagonal close-packed metals during plastic forming and the mech-anism underlying ultrasonic vibration forming were reviewed.The main challenges and future research direction of the ultrasonic vibra-tion plastic forming of metals were also discussed.
基金Project(51775481)supported by the National Natural Science Foundation of ChinaProject(A2016002017)supported by the High-level Talents Program of Heibei Province,China
文摘A new technological process of tube forming was developed, namely solution treatment → granule medium internal high pressure forming → artificial aging. During this process, the mechanical properties of AA6061 tube can be adjusted by heat treatment to satisfy the process requirements and the processing method can also be realized by granule medium internal high pressure forming technology with the features of convenient implementation, low requirement to equipment and flexible design in product. Results show that, at a solution temperature of 560 ℃ and time of 120 min, the elongation of AA6061 increases by 313%, but the strength and the hardness dramatically decrease. At an aging temperature of 180 ℃ and time of 360 min, the strength and hardness of AA6061 alloy are recovered to the values of the as-received alloy. The maximum expansion ratio(MER) of AA6061 tube increases by 25.5% and the material properties of formed tube reach the performances of raw material.
基金Supported by National Natural Science Foundation of China(Grant No.U1737212)National Science and Technology Major Project of China(Grant No.J2019-VII-0014-0154)Shaanxi Provincial Natural Science Foundation for Distinguished Young Scholars of China(Grant No.2019JC-09).
文摘Compared with conventional forming processes,ultrasonic-assisted forming technology with a high frequency and small amplitude can significantly improve the forming quality of materials.Owing to the advantages of reduced forming force,improved surface quality,avoidance of forming defects,and strengthened surface structure,ultrasonic-assisted forming technology has been applied to increasingly advanced forming processes,such as incremental forming,spinning,and micro-forming.However,in the ultrasonic-assisted forming process,there are multiple ultrasonic mechanisms,such as the volume effect and surface effect.The explanation of the effect of ultrasonic vibration(UV)on plastic deformation remains controversial,hindering the development of related technologies.Recently,many researchers have proposed many new theories and technologies for ultrasonic-assisted forming.To summarize these developments,systematic discussions on mechanisms,theoretical models,and forming performances are provided in this review.On this basis,the limitations of the current study are discussed.In addition,an outlook for ultrasonic-assisted forming is proposed:efficient and stable UV systems,difficulty forming components with complex geometry,explanation of the in-depth mechanism,a systematic theoretical prediction model,and multi-field-coupling energy-assisted forming are considered to be hot spots in future studies.The present review enhances existing knowledge of ultrasonic-assisted forming,and facilitates a fast reference for related researchers.
文摘The discussion on sedimentary macro-structures and their forming mechanics of debris flow is based on thedata of present processes and ancient deposits of Dongchuan in Yunnan Province, Wudu in Gansu Province and Fuxin inLiaoning Province. Non-cohesive debris flow, which is 1. 3 -1. 7 t/m3 in density, follows hydraulic fluid and flow model. In the hydraulic fluid of flood, electrolytic water combines clay into pulp to transport solid debris. The sedimentary structures show fluid processes as stone-line structure, imbricated structure and stone supporting-sustructure. A part of non-cohesive debris flow with a density of 1. 7 -1. 9t/m3 follows granular model. Debris is in the action of friction, collision and dispersion which forces as debris moving upward to form reverse graded load. The sedimentary structures of granular flow show reverse graded bedding, reverse-normal graded bedding, imbricated verticalstructure and circling linear structure.Cohesive debris flow, which is 1. 9 - 2. 3 t/m3 in density, follows structural two phase flow (viscoplastic) model. The sedimentary structures of cohesive debris flow show reverse graded-chaotic structure,bottom mud-chaotic structure and outwedging structure.
文摘Laser forraing is a new flexible and dieless forming technique. To achieve the high accuracy forming, the temperature gradient mechanism (TGM) is studied. In the analysis of TGM, the plate bends about x-axis and about y-axis as well. To understand the deformation trend, the numerical simulation of deformation of plate is conducted by choosing different laser powers, laser spot diameters, scanning speeds, lengths, widths and thicknesses. From the results of simulation, it can be seen that the laser spot diameter, the scanning speed, laser power and thickness of plate play dominant roles in the laser forming process. However, the bending angles αx and αy show different trends with the variation of parameters. In addition, in comparison with above four parameters, the effect of length and width of plate on the beading angle may be neglected, but their effects are significant for the bending radius R.
文摘A method combining theoretical analysis with experiment is adopted and the flowing process of Ti-48A1-2Cr-2Nb alloy melt poured in a permanent mould during the centrifugal casting process has been analyzed. A mathematical model of the filling process is established and the forming mechanism of internal gaseous defect is summarized. The results of calculation show that the melt fills the mould with varying cross-section area and inclined angle. The filling speed of the cross-section is a function of filling time. The cross-section area is directly proportional to the filling speed and the inclined angle is inversely proportional to the filling speed at a given rotating speed of the platform. Both of them changes more obvious near the mould entrance. The gaseous defect can be formed in several ways and the centrifugal field has an important influence on the formation of the defect. In addition, the filling process in centrifugal field has been verified by wax experiments and the theoretical analysis are consistent with experimental results.
文摘This article presents a theory about the growth mechanism of bubble-screw dislocation of nodular graphite. Normally speaking, the crystallizing procedure of most nodular graphite is as follows: firstly, graphite generates nuclei on bubbles and fills them (mainly in the way of screw dislocation) forming the complete nuclei of nodular graphite-graphite bubble nuclei. Then, graphite grows up in the way of screw dislocation. Two important conditions concerning the production of nodular graphite are: (a) there is a relatively big interfacial energy between ferro liquid and graphite, and the one between ferro liquid and graphite prismatic plane is bigger than that between ferro liquid and graphite basal plane; (b) there are a certain amount of micro-bubbles in the melt.
文摘As a characteristic sedimentary type,molartooth carbonatites veins(MCV) can be found in almost all the Neoproterozoic carbonatite strata in the North Anhui and Jiangsu Provinces.But their forming mechanism is still an enigma,and more than four incompatible forming hypotheses have been put forward according to the structures,mineral components and elements of the MCV.Though all the MCV with the similar shape
基金supported by the National Natural Science Foundation of China(No.81303306)Natural Science Foundation of Tianjin(No.14JCQNJC06300)Science Development Foundation of Tianjin Agricultural College(No.2011N06)
文摘A new thiosemicarbazone compound derived from 1-phenyl-3-methyl-4-(2-thenoyl) pyrazolone-5 (HPMTP) and thiosemicarbazide has been synthesized and characterized by IR, H- NMR, MS, elemental analysis, UV and single-crystal X-ray diffraction. The compound crystallizes in monoclinic system, Cc space group with a = 7.5925(8), b = 20.263(2), c = 11.4669(13) A, r= 107.825(8)°, V = 1679.5(3) A3, Z = 4, R = 0.0316 and wR = 0.0687. The results of antibacterial activity test against Escherichia coli and Bacillus subtilis indicate that the compound possesses the same antibacterial activity as the contrast (Norfloxacin). Theoretical study of the forming mechanism to the title compound at the RHF/6-31G(d) level shows that there are two steps. The distal amino group of thiosemicarbazide is added to the 4-carbonyl group of HPMTP which forms TM. Then a dehydration reaction occurs in TM and generates a stable product PC.
基金financially supported by NSFC under Grant No. 90923040China’s National "973" Program under Grant No. 2009CB724202
文摘Cast molding process has provided a reliable, simple and cost-effective way to fabricate micro structures since decades ago. In order to obtain structures with fine, dense and deep nano-size features by cast molding, it is necessary to study the forming mechanism in the process. In this paper, based on major steps of cast molding, filling models of liquid are established and solved; and the forming mechanism of liquid is revealed. Moreover, the scale effect between the liquid and the cavity on the filling velocity of liquid is studied.It is also interesting to find out that the wettability of liquid on the cavity may be changed from wetting to dewetting depends on the pressure difference. Finally, we experimentally verify some of our modeling results on the flowing and filling state of the liquid during the cast molding process.
文摘Micro-pored CA6 -MA lightweight material with CAM: MA mass ratio of 7:3 was prepared using Al(OH) 3, MgCO3 and CaCO3 as starting materials, and anthracite. sweet potato starch and anthracite + sweet potato starch as pore forming agent (PFA) with an addition of 10 mass%, 20 mass% and 30 mass%, respectively. The starting materials were dry mixed, wet co-milled in a ball mill for 1 h. slip cast into cylindrical specimens with a diameter of 60 ram. and then calcined at 1 450 ℃ for 3 h. With the increase of PFA addition,, apparent porosity increases, and bulk density decreases. The influence of different PFAs on properties of the micro-pored LW CAM -MA aggregate was investigated. The achieved CAM - MA, by adding 30% sweet potato starch, has a porosity of 76. 8%, bulk density of 0. 78 g · cm^ - 3 and median pore size of 1.90 μm.
基金Project (NCET-10-0278) supported by the Program for New Century Excellent Talents in University, ChinaProject (20102024) supported by the Natural Science Foundation of Liaoning Province, China
文摘The comparative experiments of age forming and artificial aging of 2A12 aluminum alloy were carried out. The effect of the age forming on the microstructure and mechanical properties was investigated. The results demonstrate that the grains are further squashed and elongated compared with artificial aging due to the existence of the applied stress during the age forming. Meanwhile, the precipitated phases change from circle shape with random orientation of age forming to long strip shape with uniform orientation of artificial aging. The dislocation configuration in samples changes from ring dislocation or helical dislocation of the artificial aging to long and straight dislocation of the age forming. Otherwise, age forming slightly reduces the tensile properties and fracture toughness of the alloy and enhances its fatigue crack growth rate.
文摘The forming condition of coal and coaly organic matter is analyzed. The dynamics of hydrocarbon generation of coal and coaly organic matter is discussed. It has been pointed out that the temperature is the main predominant factor for the hydrocarbon generation of coal; chemical effect of structural pressing and shearing force accelerates the evolution of hydrocarbon derived from coal, and is the prerequisite for the hydrocarbons to be expelled from coal. The existence of atoms of N, S, O etc. is the prerequisite for forming the hydrocarbons at early evolution stage. The importance of NSO compounds in the evolution of hydrocarbon generation has been emphasized.
基金Project(50371016) supported by the National Natural Science Foundation of ChinaProject(50611130629) supported by the International Cooperation and Exchange of the National Natural Science Foundation of China
文摘A series of rod samples with diameter of 3 mm(Zr0.55Al0.10Ni0.05Cu0.30)100-xFex(x=0,1,2,3,4) were prepared by magnetic suspend melting and copper mold suction casting method.The effects of a small amount of Fe on glass forming ability(GFA) and mechanical properties of Zr55Al10Ni5Cu30 bulk metallic glass(BMG) were investigated.The results show that the addition of an appropriate amount(less than 3%,mole fraction) of Fe enhances GFA,as indicated by the increase in the reduced glass transition temperature Trg(=Tg/Tl) and the parameter γ(=Tx/(Tg+Tl)) with increasing Fe content,and GFA gets deteriorated by further Fe addition(4%).The addition of Fe also effectively improves the compressive plasticity and increases the compressive fracture strength in these Zr-based BMGs.Compressive tests on BMG sample with 3 mm in diameter and 6 mm in length reveal work-hardening and a certain plastic strain in the alloy containing 2% Fe.The BMG composite containing 4% Fe also exhibits a high fracture strength along with significant plasticity.
文摘Tropic and sub-tropic tidal flats (generalised) are a kind of speific peat-forming environments. Taking the Mangrove tidal flats and mangrove pets in Hainan island as a example, the authors deeply study and discuss the peat-forming mechanism of tropic and sub-tropic tidal flats. The conclusions are as follows: intrusion accretiou of plant organic matter is more important ; the organic matter has accumulated witk high productivity, high return rate and high decompeition rate ;anaerobic bacterin play a more important role during early peatification ; sea level change is the fundameutal factor controlling the formation and evolution of tidal flat peat-forming environments; lagoon peat-flat and delta peat-flat are main types of tidal flat peat-forming euvironments ;tidal flat peat-forming environments are remarkably characterized by low-level and rabe properties.
基金supported by the Program for New Century Excellent Talents in Universities of China (No.NCET-06-0879)the National Natural Science Foundation of China (No.50331010)+2 种基金the Northwestern Polytechnical University Foundation of Fundamental Research (No.NPU-FFR-JC200808)the National Basic Research Program of China (No.2007CB613800)the Program of Introducing Talents of Discipline to Universities,China (No.08040)
文摘The effects of heat treatment on the microstructure and mechanical properties of laser solid forming (LSF) Ti-6Al-4V alloy were investigated The influences of the temperature and time of solution treatment and aging treatment were analyzed. The results show that the microstructure of LSFed samples consists of Widmanstatten α laths and a little acicular in columnar prior β grains with an average grain width of 300 μm, which grow epitaxiaUy from the substrate along the deposition direction (27). Solution treatment had an important effect on the width, aspect ratio, and volmne fraction of primary and secondary a laths, and aging treatment mainly affects the aspect ratio and volume fraction of primary α laths and the width and volume fraction of secondary a laths. Globular a phase was first observed in LSFed samples when the samples were heat treated with solution treatment (950℃, 8 h/air cooling (AC)) or with solution treatment (950℃, 1 h/AC) and aging treatment (550℃, above 8 h/AC), respectively. The coarsening and globularization mechanisms of a phase in LSFed Ti-6Al-4V alloy during heat treatment were presented. To obtain good integrated mechanical properties for LSFed Ti-6Al-4V alloys, an optimized heat treatment regimen was suggested.
文摘This study performs single point incremental forming(SPIF)on two aluminum alloys(i.e.AA5754 and AA6061),and analyzes their post forming mechanical properties and microstructure evolution.The forming parameters namely wall angle(35°-55°),feed rate(1-4 m/min),spindle rotational speed(50-1000 r/min),and lubricant(grease and hydraulic oil)are varied to probe detailed processing effects.The pre-and post-SPIF mechanical properties and microstructures are characterized by conducting tensile tests and optical microscopy,respectively.It is shown that an increase in the wall angle,feed rate and rotational speed causes microscopic variations in the alloys such that the grains of AA5754 and the second phase particles of AA6061 elongate.As a result,the ultimate tensile strength of the formed parts is increased by 10%for AA5754 and by 8%for AA6061.And,the ductility of AA5754 is decreased from 22.9%to 12%and that of AA6061 is decreased from 16%to 10.7%.Regarding the lubricant effect,it is shown that the mechanical properties remain insensitive to the type of lubricant employed.These results indicate that SPIF processing modifies the microstructure of Al alloys in a way to enhance the strength at the cost of ductility.
基金supported by Scientific Research Program Funded by Shaanxi Provincial Education Department(Program No.22JK0479)Research Start-up Project of Xi’an University of Technology(Grant No.101-256082204)+5 种基金International Science and Technology Cooperation Program of Shaanxi Province(No.2023-GHZD-50)Project of Science and Technology Shaanxi Province(No.2023-JC-YB-412)Project of Science and Technology Shaanxi Province(No.2023-JC-QN-0573)Projects of Major Innovation Platforms for Scientific and Technological and Local Transformation of Scientific and Technological Achievements of Xi’an(No.20GXSF0003)Projects of Major Scientific and Technological Achievements Local Transformation of Xi’an(No.2022JHZDZH-0039)Higher Education Institution Discipline Innovation and Intelligence Base of Shaanxi Provincial(No.S2021-ZC-GXYZ-0011).
文摘Magnesium and its alloys,as a promising class of materials,is popular in lightweight application and biomedical implants due to their low density and good biocompatibility.Additive manufacturing(AM)of Mg and its alloys is of growing interest in academia and industry.The domain-by-domain localized forming characteristics of AM leads to unique microstructures and performances of AM-process Mg and its alloys,which are different from those of traditionally manufactured counterparts.However,the intrinsic mechanisms still remain unclear and need to be in-depth explored.Therefore,this work aims to discuss and analyze the possible underlying mechanisms regarding defect appearance and elimination,microstructure formation and evolution,and performance improvement,based on presenting a comprehensive and systematic review on the relationship between process parameters,forming quality,microstructure characteristics and resultant performances.Lastly,some key perspectives requiring focus for further progression are highlighted to promote development of AM-processed Mg and its alloys and accelerate their industrialization.
基金financially supported by the National Nature Science Foundation of China under Grant No.41372333,41172158China Geological Survey(grant No.1212011220123)
文摘Several argillaceous platforms lie along the Yellow River(YR) of the eastern Guide Basin, northeastern Tibetan Plateau, and their compositions, formation processes, and geomorphic evolution remain debated. Using field survey data, sample testing, and high-resolution remote sensing images, the evolution of the Erlian mudflow fans are analyzed. The data show significant differences between fans on either side of the YR. On the right bank, fans are dilute debris flows consisting of sand and gravel. On the left bank, fans are viscosity mudflows consisting of red clay. The composition and formation processes of the left bank platforms indicate a rainfall-induced pluvial landscape. Fan evolution can be divided into two stages: early-stage fans pre-date 16 ka B.P., and formed during the last deglaciation; late-stage fans post-date 8 ka B.P.. Both stages were induced by climate change. The data indicate that during the Last Glacial Maximum, the northeastern Tibetan Plateau experienced a cold and humid climate characterized by high rainfall. From 16–8 ka, the YR cut through the Erlian early mudflow fan, resulting in extensive erosion. Since 8 ka, the river channel has migrated south by at least 1.25 km, and late stage mudflow fan formation has occurred.