Sedimentary filling characteristics and controlling factors of lacustrine microbial carbonates sequence in the Santos Basin,Brazil

Based on comprehensive analysis of seismic,logging,core,thin section data,and stable isotopic compositions of carbon and oxygen,the sedimentary filling characteristics of the Lower Cretaceous Barra Velha Formation sequence in H oil field,Santos Basin,are studied,and the high-frequency sequence stratigraphic framework is established,and the spatial distribution of reef-shoal bodies are predicted and the controlling factors are discussed.During the depositional period of the Barra Velha Formation,the study area is a slope-isolated platform-slope sedimentary pattern from southwest to northeast and the change of climate background from rift to depression periods has resulted in the variation of sedimentary characteristics from the lower third-order sequence SQ1(BVE 300 Member)of low-energy deep water to the upper third-order sequence SQ2(BVE 200 and 100 members)of high-energy shallow water in the Barra Velha Formation.The activities of extensional faults and strike-slip faults in rift period and the sedimentary differentiation from platform margin to intra-platform in depression period made the sedimentary paleogeomorphology in these two periods show features of“three ridges and two depressions”.The reef-shoal bodies mainly developed in the SQ2-LHST period,with vertical development positions restricted by the periodic oscillation of the lake level,and developed on the top of each high-frequency sequence stratigraphic unit in SQ2-LHST in the platform.The strike-slip fault activity controlled the distribution of the reef-shoal bodies on the plane by changing the sedimentary paleogeomorphology.The positive flower-shaped strike-slip faults made the formation of local highlands at the margins of and inside the shallow water platforms and which became high-energy sedimentary zones,creating conditions for the development of reef-shoal bodies.

Molar-tooth Carbonate Sequences and Sr Isotopes in the Neoproterozoic for Stratigraphic Correlation: Research in the Jilin-Liaoning-Xuzhou-Huaiyang Area of the Sino-Korean Plate and Its Correlation with the Yangtze Plate

Based on a study of Neoproterozoic carbonates in the Jilin-Liaoning-Xuzhou-Huaiyang area, especially its cyclic sequence stratigraphy and Sr isotopes, two maximum sea flooding events (at 820 Ma and 835 Ma) have been identified. The resulting isochronous stratigraphic correlation proves that these Precambrian strata were connected between the Qingbaikou and the Nanhuan systems with a time range from 750 Ma to 850 Ma. The disappearance of microsparite carbonate and coming of a glacial stage offer important evidence for worldwide stratigraphic correlation and open a window for further correlation of the stratigraphic successions across the Sino-Korean and Yangtze Plates. A new correlation scheme is therefore provided based on our work.

Carbonate Sequence Stratigraphy of a Back-Arc Basin: A Case Study of the Qom Formation in the Kashan Area, Central Iran

The Qom Formation comprises Oligo-Miocene deposits from a marine succession distributed in the Central Basin of Iran. It is composed of five members designated as A-F. Little previous work exists on the sequence stratigraphy. Based on an integrated study of sequence stratigraphy with outcrop data, wells and regional seismic profiles, the Qom Formation is interpreted as a carbonate succession deposited in a mid.Tertiary back-arc basin. There are two second-order sequences （designated as SS1 and SS2） and five third-order sequences （designated as S1-S5）. Five distinct systems tracts including transgressive, highstand, forced regressive, slope margin and Iowstand have been recognized. The relationship between the sequences and lithologic sub-units has been collated and defined （S1 to S5 individually corresponding to A-C1, C2--C4, D-E, the lower and upper portions of F）; a relative sea level change curve and the sequence stratigraphic framework have been established and described in detail. The coincidence of relative sea level change between that of the determined back-arc basin and the world indicates that the sedimentary cycles of the Qom Formation are mainly controlled by eustatic cycles. The variable combination of the systems tracts and special tectonic-depositional setting causally underpin multiple sequence stratigraphic framework styles seen in the carbonates of the back-arc basin revealing： （1） a continental margin basin that developed some form of barrier, characterized by the development of multiple cycles of carbonate-evaporites; （2） a flat carbonate ramp, which occurred on the southern shelf formed by the lack of clastic supply from nearby magmatic islands plus mixed siliciclastics and carbonates that occurred on the northern shelf due to a sufficient clastics supply from the land; and （3） a forced regressive stratigraphic stacking pattern that occured on the southern shelf and in basin lows due to the uplifting of the southern shelf. Thick and widespread aggradational framework limestone usually occurs in the initial sequences （S1 and S3） of the supersequence, which led to preferential oil reservoir deposition but a lack of source and cap rocks, whereas the retrogradational and progradational framework limestone usually occurs in the later sequences （S2 and S4-S5） of the supersequence, which results in two perfect sets of source, reservoir and cap rock assemblies, so that the limestone in sub-member C2-C4 and the F-Member can be predicted as important objects for oil exploration.

Cycle-Sequences,Carbon Isotope Features and Glacio-Eustasy of the Triticites Zone in Southern Guizhou

In light of the principle of sequence stratigraphy, detailed analysis of depositionalsequences and systematical carbon isotope measurements were done for the Triticites zone ofthe typical Late Carboniferous section in the Dushan area of southern Guizhou. Two sequencesand seventeen parasequences, which can be correlated with the two sequences and seventeensubsequences in the North American Midcontinent, are distinguished in the Gzhelian, whichprovides convincing evidence of the global synchroneity of the depositional records. The inter-nal relations between carbon isotope evolution and eustasy were studied and the evolutionarycharacteristics of carbon isotopes in depositional sequences have been summarized.

Sedimentological sequence and depositional evolutionary model of Lower Triassic carbonate rocks in the South Yellow Sea Basin

Based on well logging and seismic data, combined with a comparative analysis of drilling data in the Lower Yangtze region, the sequence stratigraphic framework of the Qinglong Formation was established and divided into four third-order sequences. Each sequence is mainly composed of the transgress system tract (TST) and the high-stand system tract (HST). According to the lithology, logging curve and seismic reflection structure, the sedimentary filling characteristics and evolution law for the sequence are analyzed. The results show that each sequence is dominated by a half-cycle decline of sea level, and the rise-fall of sea level controls the distribution and evolution of sedimentary systems within the sequence. During the relative sea-level rise, sedimentation rates slow down and muddy sediments are developed. The characteristics of condensing intervals on the flooding surface are very obvious, and continental shelf and open platform deposition are mainly developed. During the relative decline of sea level, the thickness of sediments increased. The main developments were restricted platform and platform shoal environment, and locally developed evaporation platform environment.

Type division and controlling factor analysis of 3rd-order sequences in marine carbonate rocks

Type division and controlling factor analysis of 3rd-order sequence are of practical significance to tec-tonic analysis, sedimentary environment identification, and other geological researches. Based on the comprehensive analysis of carbon and oxygen isotope trends, paleobathymetry and spectral-frequency of representative well logs, 3rd-order sequences can be divided into 3 types： （a） global sea level （GSL） sequence mainly controlled by GSL change;（b） tectonic sequence mainly controlled by regional tectonic activity;and （c） composite sequence jointly controlled by GSL change and regional tectonic activity. This study aims to identify the controlling factors of 3rd-order sequences and to illustrate a new method for classification of 3rd-order sequences of the middle Permian strata in the Sichuan Basin, China. The middle Permian strata in the Sichuan Basin consist of 3 basin-contrastive 3rd-order sequences, i.e., PSQ1, PSQ2 and PSQ3. Of these, PSQ1 is a GSL sequence while PSQ2 and PSQ3 are composite sequences. The results suggest that the depositional environment was stable during the deposition of PSQ1, but was activated by tectonic activity during the deposition of the middle Permian Maokou Formation.

Study on Carbonate Sequence Stratigraphy of Ordovician in Northern Ordos Basin

The formation of carbonates is different from that of siliciclastics. The controlling factors, such as the in-situ production of carbonates the transport, local variation in depositional processes and the way of dispersal are unique to carbonates systems, and have resulted in the formation of a wide variety of stratal patterns. The authors believe that all the factors influencing the formation of carbonates, such as the evolution of carbonate platform, transgression and regression, drowning and exposing of the platform, should be taken into consideration during the study of carbonate sequence stratigraphy.This paper attempts to summarize the study procedure in outcrop sequence stratigraphy and to describe the integrated identification of condensed section, first flooding surface and maximum flooding surface, so that the framework of high-resolution sequence stratigraphy can be constructed. During the Sandokan in early Ordovician, a carbonate-siliciclastic ramp was developed in northern Ordos, which changed into a carbonate rimmed shelf or a distally steepened ramp during the Zhuozishan and Kelimoli. It was the break in the Wulalike and Middle Ordovician,changing the sedimentary setting into an aulacogen According to the basin evolution, the authors have established some different idealized models for depositional sequences and systems tracts.

STUDY ON THE SEQUENCE STRUCTURE OF SBR BY ^(13)C-NMR METHOD Ⅱ. PEAK ASSIGNMENT FOR ALIPHATIC CARBONS SPECTRA

The study on ^(13)C-NMR spectra of aliphatic carbon region of emuision-processed and solution-processed (by lithium catalyst) SBR was carried out. The assignments for more than thirty odd peaks observed experimentally were made by using 'corresponding analysis' method, combined with the empirical parameters reported in literature. The peak intensifies were calculated based on BemouUian statistic assumption.

Genetic Relationship of Minerals and Carbonate Units of Stratigraphy Sequence in the Ahmadabad Deposit (NE of Bafq) Using Data Related to Rare Earth Elements

Ahmadabad Pb-Zn ore deposit is located in the mineral area of Bahabad in Central Iran Zone. This ore deposit like other metallogenic areas in Bahabad is found in Triassic carbonate rocks. Carbonate rocks in Shotori formation have the highest frequency in the regional sequence stratigraphy. This formation is composed of TRSh1, TRSh2, TRSh3 and TRSh4 units. The TRSh3 unit hosts minerals in ore deposit Ahmadabad. Microcrystalline particles are the main constituent of these rocks. The most important minerals in this ore deposit include calamine Celestine, Cerussite and Wulfenite. The comparison of normalized ore patterns and carbonate sequence indicates that they have a specified genetic relationship. Here the TRSh2 unit is more similar to minerals.

Intercombination transitions of the carbon-like isoelectronic sequence

Energy levels, wavelengths, transition rates, oscillator strengths, and lifetimes between the 2s22p23P1,2s22p23P2,and 2s2p35S2 levels of ions in the carbon-like （C-like） isoelectronic sequence （nuclear charges Z=7-92） are calculated in the valence and core-valence limits using the multiconfiguration Dirac–Fock method. The Breit interaction, quantum electrodynamics （QED）, and finite nuclear mass effects are taken into account in subsequent relativistic configuration-interaction calculations. The calculated energies and transition rates are compared with the critically evaluated experimental values and other recent calculated results. Our calculated data are in good agreement with these data.

Storm Deposits of the Sinian Zhangqu Formation in Northern Anhui——An Upward Shallowing Carbonate Sequence

This paper studies. for the first time, the storm deposits of a carbonate sequence in the Sinian ZhangquFormation in northern Anhui. In the formation. a great number of calcareous trider sponge spicules were dis-covered in a distal storm turbidity sequence, which have provided further evidence for the correlation of theSinian Systems in North and South China from a view point of palaeontology.

Distribution of Carbon and Oxygen Isotopes in theSequence Stratigraphic Framework of the Middle andUpper Proterozoic in the Ming Tombs Area, Beijing

Abstract: This paper discusses the distribution pattern and geological significance of the carbon and oxygen isotopes (δ13C and δ18O) in the depositional sequences of Gaoyuzhuangian, Yangzhuangian and Wumishanian ages of the established Middle and Upper Proterozoic sequence stratigraphic framework in the Ming Tombs area lying in western Yanshan Mountain of Beijing. Besides, sketchy determination of δ13C and δ18O was also performed for other formations and members. The analytical results show the following: under the condition of clear-water carbonate sediments, δ13C and δ18O, featuring smaller variation of δ13C but larger variation of δ18O, can well delineate the relative change of sea level, which reflects the difference of primary sedimentary settings; in the presence of terrigenous substances, δ13C values vary greatly while δ18O slightly; the carbon and oxygen isotopes show marked changes at sequence boundaries. Besides, particular patterns can be found in regard to the distribution of carbon and oxygen isotopes within the sequences.

Significance of Carbon Isotopes in Carbonate Sequence Stratigraphy——As Exemplified by the Permian System in Southwest China

Based on the research on sequence stratigraphy of the Permian in Southwest China, in conjunction with the carbon isotope data from the typical sections at Ganluo, Sichuan and Tianlin and Mashan, Guangxi, the authors suggest that the genetic framework and internal architicture of different sequences possess quite different carbon isotopic characteristics. Therefore, the following problems can be solved in terms of carbon isotopic values, evolutionary curve patterns and structures of carbonate sequences: (1) to determe the nature of sequence boundary surface and related geological events; (2) to recognize various kinds of sedimentary system tracts; (3) to discuss the internal architicture and genetic framework of the sequences and their evolution; (4) to subdivide and correlate sedimentary sequences on a regional or global scale; and (5) to enhance the resolution of sequence stratigraphic analysis. Stable carbon isotopes have proved themselves to be valid in sequence stratigraphic studies of carbonate rocks, as demonstrated by our results presented in this paper.

Effect of inorganic carbon on anaerobic ammonium oxidation enriched in sequencing batch reactor

The present lab-scale research reveals the enrichment of anaerobic ammonium oxidation microorganism from methanogenic anaerobic granular sludge and the effect of inorganic carbon(sodium bicarbonate)on anaerobic ammonium oxidation.The enrichment of anammox bacteria was carried out in a 7.0-L sequencing batch reactor(SBR)and the effect of bicarbonate on anammox was conducted in a 3.0-L SBR.Research results,especially the biomass,showed first signs of anammox activity after 54 d cultivation with synthetic wast...

Effects of impregnation sequence on the microstructure and performances of Cu-Co based catalysts for the synthesis of higher alcohols

Silica-supported CuCo catalysts were prepared by impregnation method with different impregnation sequence for higher alcohols synthesis. These catalysts were characterized by H2-TPR, XRD, N2 adsorption, XPS techniques and CO selective hydrogenation reaction measurement. The effects of impregnation sequence on the structure and performance of catalysts were investigated, and there were important influences on the selectivity to higher alcohols. There was a strong synergistic effect between copper and cobalt for the co-impregnated sample. The CuCo/SiO2 catalyst prepared by co- impregnation showed a better yield of total alcohols, and a higher selectivity to total alcohols which reached 51.5%.

Sequence-lithofacies paleogeographic characteristics and petroleum geological significance of Lower Permian Qixia Stage in Sichuan Basin and its adjacent areas,SW China

Through the analysis of logging,field outcrops,cores and geochemical data,and based on the study of the relationships between sea level changes,sequence filling,paleo-geomorphy and lithofacies,the sequence lithofacies paleo-geography and evolution process of the Lower Permian Liangshan-Qixia Formation(Qixia Stage for short)in Sichuan Basin and its surrounding areas are restored.The Qixia Stage can be divided into three third-order sequences,in which SQ0,SQ1 and SQ2 are developed in the depression area,and SQ1 and SQ2 are only developed in other areas.The paleo-geomorphy reflected by the thickness of each sequence indicates that before the deposition of the Qixia Stage in the Early Permian,the areas surrounding the Sichuan Basin are characterized by“four uplifts and four depressions”,namely,four paleo-uplifts/paleo-lands of Kangdian,Hannan,Shennongjia and Xuefeng Mountain,and four depressions of Chengdu-Mianyang,Kangdian front,Jiangkou and Yichang;while the interior of the basin is characterized by“secondary uplifts,secondary depressions and alternating convex-concave”.SQ2 is the main shoal forming period of the Qixia Formation,and the high-energy mound shoal facies mainly developed in the highs of sedimentary paleo-geomorphy and the relative slope break zones.The distribution of dolomitic reservoirs(dolomite,limy dolomite and dolomitic limestone)has a good correlation with the sedimentary geomorphic highs and slope break zones.The favorable mound-shoal and dolomitic reservoirs are distributed around depressions at platform-margin and along highs and around sags in the basin.It is pointed out that the platform-margin area in western Sichuan Basin is still the key area for exploration at present;while areas around Chengdu-Mianyang depression and Guangwang secondary depression inside the platform and areas around sags in central Sichuan-southern Sichuan are favorable exploration areas for dolomitic reservoirs of the Qixia Formation in the next step.

Facies Analysis and Sequence Stratigraphy of the Qal'eh Dokhtar Formation(Middle-Upper Jurassic) in the West of Boshrouyeh, East Central Iran

The study area is located in the east Tabas Block in Central Iran. Facies analysis of the Qal＇eh Dokhtar Formation（middle Callovian to late Oxfordian） was carried out on two stratigraphic sections and applied to depositional environment and sequence stratigraphy interpretation. This formation conformably overlies and underlies the marly-silty Baghamshah and the calcareous Esfandiar formations, respectively. Lateral and vertical facies changes documents low-to high energy environments, including tidal-flat, beach to intertidal, lagoon, barrier, and open-marine. According to these facies associations and absence of resedimentation deposits a depositional model of a mixed carbonate-siliciclastic ramp was proposed for the Qal＇eh Dokhtar Formation. Seven third-order depositional sequences were identified in each two measured stratigraphic sections. Transgressive systems tracts（TSTs） show deepening upward trends, i.e. shallow water beach to intertidal and lagoonal facies, while highstand systems tracts（HST） show shallowing upward trends in which deep water facies are overlain by shallow water facies. All sequence boundaries（except at the base of the stratigraphic column） are of the no erosional（SB2） types. We conclude eustatic rather than tectonic factors played a dominant role in controlling carbonate depositional environments in the study area.

Geological Characteristics and Manifestations of Geological Processes of Sequence Boundaries and Their Vicinities

This paper discusses the geological characteristics and architectures of sequence boundaries and their vicinities and has proposed a classification scheme for the sequence boundaries, which can thus be grouped into three types and eight categories: type I includes exposed truncated surface, palaeosol surface, palaeokarst surface and exposed surface; type Ⅱ boundaries include structural transitional surface during sea-level fall and transgressive onlap surface; and type Ⅲ includes submarine erosional diagenetic diastem and event surface. A study has been made for the three major boundaries lying between the Permian and pre-Permian, the Permian and Triassic, and the Middle and Lower Triassic respectively in terms of multiple disciplines such as lithostratigraphy, biostratigraphy, magnetostratigraphy and carbon and oxygen isotopic geology. These three boundaries are ascribed to type I , typeⅡ and typeⅢ, respectively.

Sequence stratigraphy and lithofacies paleogeography of the Middle–Upper Cambrian Xixiangchi Group in the Sichuan Basin and its adjacent area, SW China

Based on isotopic, lithologic and electrical data and logging cycle analysis technique, stratigraphic sequences in the Middle-Upper Cambrian Xixiangchi Group in the Sichuan Basin and its adjacent area are divided, and its sedimentary characteristics and evolution are analyzed. The Xixiangchi Group can be divided into 5 third-order sequences(Sql-Sq5), of which sequences Ⅰ to Ⅲ(Sql-Sq3) are relatively complete, sequences Ⅳ and Ⅴ are denuded in the Late Cambrian because of the Dian-Chuan paleo-uplifts.Third-order sequences of the Xixiangchi Group in this area have the characteristics of thin in the west and thick in the east, showing that the Caledonian paleo-uplift is a synsedimentary paleo-uplift and the paleogeomorphology in the platform is a gentle slope. Sequence Ⅰdevelops high stand systems tract and transgressive systems tract. The other third-order sequences are dominated by highstand systems tracts, and the transgressive systems tracts last shortly in time and are limited in area. The basic features of evaporative-restricted platform of gentle slope type developed continuously in the sedimentary period of the Xixiangchi Group, its sedimentary environment of "high in west and low in east" and the change of micro paleogeomorphology in the platform control the continuous development of sedimentary facies. Open platform is developed only in sequence Ⅰ and sequence Ⅱ, and the inner beach of the platform and the edge beach of the platform are mostly developed in sequence Ⅱ and sequence Ⅲ. It indicates that there are two platform margin zones in the study area,a relatively stable, large-scale platform marginal zone in NE Guizhou-Western Hunan and Hubei, and a moving and small-scale platform marginal zone in North Chongqing-Western Hubei.

Depositional environments and sequence stratigraphy of the Bahram Formation(middleelate Devonian) in north of Kerman, south-central Iran

This study is focused on sedimentary environments, facies distribution, and sequence stratigraphy. The facies and sequence stratigraphic analyses of the Bahram Formation（middleelate Devonian） in southcentral Iran are based on two measured stratigraphic sections in the southern Tabas block. The Bahram Formation overlies red sandstones Padeha Formation in sections Hutk and Sardar and is overlain by Carboniferous carbonate deposits of Hutk Formation paraconformably, with a thickness of 354 and386 m respectively. Mixed siliciclastic and carbonate sediments are present in this succession. The field observations and laboratory studies were used to identify 14 micro/petrofacies, which can be grouped into 5 depositional environments： shore, tidal flat, lagoon, shoal and shallow open marine. A mixed carbonate-detrital shallow shelf is suggested for the depositional environment of the Bahram Formation which deepens to the east（Sardar section） and thins in southern locations（Hutk section）. Three 3rdorder cyclic siliciclastic and carbonate sequences in the Bahram Formation and one sequence shared with the overlying joint with Hutk Formation are identified, on the basis of shallowing upward patterns in the micro/pertofacies.