Nb-Mo-ZrB2 composites （V（Nb）/V（Mo） = 1） with 15v01% or 30v01% of ZrB2 were fabricated by hot-pressing sintering at 2000~C The phases, microstxucture, and mechamcal properties were then investigated. The composit...Nb-Mo-ZrB2 composites （V（Nb）/V（Mo） = 1） with 15v01% or 30v01% of ZrB2 were fabricated by hot-pressing sintering at 2000~C The phases, microstxucture, and mechamcal properties were then investigated. The composites contain Nb-Mo solid solution （denoted as （Nb, Mo）ss hereafter）, ZrB, MoB, and NbB phases. Compressive strength test results suggest that the strength of Nb-Mo-ZrB2 composites increases with increasing ZrB2 content; Nb-Mo-30vol%ZrB2 had the highest compressive strength （1905.1 MPa）. The improvement in the compressive strength of the Nb-Mo-ZrB2 composites is mainly attributed to the secondary phase strengthening oftke stiffer ZrB phase, sol- id-solution strengthening oftke （Nb, Mo）ss matrix as well as fme-grain strengtkening. The fracture toughness decreases with increasing ZrB2 content. Finally, the fracture modes oftke Nb-Mo-ZrB2 composites axe also discussed in detail.展开更多
The effects of Ni content（0–2.1wt%）on the cast and solid-solution microstructures of Cu-0.4wt%Be alloys were investigated,and the corresponding mechanisms of influence were analyzed.The results show that the amount...The effects of Ni content（0–2.1wt%）on the cast and solid-solution microstructures of Cu-0.4wt%Be alloys were investigated,and the corresponding mechanisms of influence were analyzed.The results show that the amount of precipitated phase increases in the cast alloys with increasing Ni content.When the Ni content is 0.45wt%or 0.98wt%,needle-like Be_（21）Ni_5 phases form in the grains and are mainly distributed in the interdendritic regions.When the Ni content is 1.5wt%or greater,a large number of needle-like precipitates form in the grains and chain-like Be_（21）Ni_5 and Be Ni precipitates form along the grain boundaries.The addition of Ni can substantially refine the cast and solid-solution microstructures of Cu-0.4wt%Be alloys.The hindering effects of both the dissolution of Ni into the matrix and the formation of Be–Ni precipitates on grain-boundary migration are mainly responsible for refining the cast and solid-solution microstructures of Cu-0.4wt%Be alloys.Higher Ni contents result in finer microstructures;however,given the precipitation characteristics of Be–Ni phases and their dissolution into the matrix during the solid-solution treatment,the upper limit of the Ni content is 1.5wt%–2.1wt%.展开更多
Nickel-based alloys exhibit excellent high-temperature stxengtfi and oxidation resistance; however, because of coarse grains and severe segregation in daeir welding joints, these alloys exhibit increased susceptibilit...Nickel-based alloys exhibit excellent high-temperature stxengtfi and oxidation resistance; however, because of coarse grains and severe segregation in daeir welding joints, these alloys exhibit increased susceptibility to hot cracking. In this paper, to improve the hot-cracking resistance and mechaxtical properties ofinckel-based alloy welded joints, sodium daiosulfate was used to simulate crystallization, enabling the nucleation mechanism under mechaxtical vibration to be investigated. On the basis of the results, the grain refinement mechan- ism during the gas tungsten arc welding （GTAW） of Inconel 601H alloy under wxious vibration modes and parameters was investigated. Compared witfi the GTAW process, the low-frequency mechanical vibration processes resulted in substantial grain refinement effects in the welds; thus, a higher haxdness distxibution was also achieved under the vibration conditions. In addition, the 7＇ phase exhibited a dispersed distribution and segregation was improved in the welded joints witfi vibration assistance. The results demonstxated that the generation of free crystals caused by vibration in the nucleation stage was the main mechaxtism of grain refinement. Also, free equiaxed grains and a dispersed 7＇ phase were found to improve the grain-boundary strength and reduce the segregation, contributing to preventing the initiation of welding hot cracking in nickel-based alloys.展开更多
基金financially supported by the National Natural Science Foundation of China(No.11372110)
文摘Nb-Mo-ZrB2 composites （V（Nb）/V（Mo） = 1） with 15v01% or 30v01% of ZrB2 were fabricated by hot-pressing sintering at 2000~C The phases, microstxucture, and mechamcal properties were then investigated. The composites contain Nb-Mo solid solution （denoted as （Nb, Mo）ss hereafter）, ZrB, MoB, and NbB phases. Compressive strength test results suggest that the strength of Nb-Mo-ZrB2 composites increases with increasing ZrB2 content; Nb-Mo-30vol%ZrB2 had the highest compressive strength （1905.1 MPa）. The improvement in the compressive strength of the Nb-Mo-ZrB2 composites is mainly attributed to the secondary phase strengthening oftke stiffer ZrB phase, sol- id-solution strengthening oftke （Nb, Mo）ss matrix as well as fme-grain strengtkening. The fracture toughness decreases with increasing ZrB2 content. Finally, the fracture modes oftke Nb-Mo-ZrB2 composites axe also discussed in detail.
基金financially supported by the National Key Research and Development Program of China (No.2016YFB0301300)
文摘The effects of Ni content（0–2.1wt%）on the cast and solid-solution microstructures of Cu-0.4wt%Be alloys were investigated,and the corresponding mechanisms of influence were analyzed.The results show that the amount of precipitated phase increases in the cast alloys with increasing Ni content.When the Ni content is 0.45wt%or 0.98wt%,needle-like Be_（21）Ni_5 phases form in the grains and are mainly distributed in the interdendritic regions.When the Ni content is 1.5wt%or greater,a large number of needle-like precipitates form in the grains and chain-like Be_（21）Ni_5 and Be Ni precipitates form along the grain boundaries.The addition of Ni can substantially refine the cast and solid-solution microstructures of Cu-0.4wt%Be alloys.The hindering effects of both the dissolution of Ni into the matrix and the formation of Be–Ni precipitates on grain-boundary migration are mainly responsible for refining the cast and solid-solution microstructures of Cu-0.4wt%Be alloys.Higher Ni contents result in finer microstructures;however,given the precipitation characteristics of Be–Ni phases and their dissolution into the matrix during the solid-solution treatment,the upper limit of the Ni content is 1.5wt%–2.1wt%.
基金the financial supported by the Natural Science Foundation of Hebei Province,China(No.E2017202011)
文摘Nickel-based alloys exhibit excellent high-temperature stxengtfi and oxidation resistance; however, because of coarse grains and severe segregation in daeir welding joints, these alloys exhibit increased susceptibility to hot cracking. In this paper, to improve the hot-cracking resistance and mechaxtical properties ofinckel-based alloy welded joints, sodium daiosulfate was used to simulate crystallization, enabling the nucleation mechanism under mechaxtical vibration to be investigated. On the basis of the results, the grain refinement mechan- ism during the gas tungsten arc welding （GTAW） of Inconel 601H alloy under wxious vibration modes and parameters was investigated. Compared witfi the GTAW process, the low-frequency mechanical vibration processes resulted in substantial grain refinement effects in the welds; thus, a higher haxdness distxibution was also achieved under the vibration conditions. In addition, the 7＇ phase exhibited a dispersed distribution and segregation was improved in the welded joints witfi vibration assistance. The results demonstxated that the generation of free crystals caused by vibration in the nucleation stage was the main mechaxtism of grain refinement. Also, free equiaxed grains and a dispersed 7＇ phase were found to improve the grain-boundary strength and reduce the segregation, contributing to preventing the initiation of welding hot cracking in nickel-based alloys.
