Test tools and methods for synchronizing acoustic measurements in the course of stress-strain for seafloor sediment are elaborated and the test data of 45 sediment samples from the seafloor in the South China Sea are ...Test tools and methods for synchronizing acoustic measurements in the course of stress-strain for seafloor sediment are elaborated and the test data of 45 sediment samples from the seafloor in the South China Sea are analysed. The result shows that the coarser the sediment grains are, the smaller the porosity is and the larger the unconfined compression strength is, the higher the sound velocity is. In the course of stress-strain, the sediment sound velocity varies obviously with the stress. Acoustic characteristics of sediment in different strain phases and the influence of sediment microstructure change on its sound velocity are discussed. This study will be of important significance for surveying wells of petroleum geology and evaluating the base stabilization of seafloor engineering.展开更多
Discrete dislocation dynamics(DDD)simulations reveal the evolution of dislocation structures and the interaction of dislocations.This study investigated the compression behavior of single-crystal copper micropillars u...Discrete dislocation dynamics(DDD)simulations reveal the evolution of dislocation structures and the interaction of dislocations.This study investigated the compression behavior of single-crystal copper micropillars using fewshot machine learning with data provided by DDD simulations.Two types of features are considered:external features comprising specimen size and loading orientation and internal features involving dislocation source length,Schmid factor,the orientation of the most easily activated dislocations and their distance from the free boundary.The yielding stress and stress-strain curves of single-crystal copper micropillar are predicted well by incorporating both external and internal features of the sample as separate or combined inputs.It is found that the machine learning accuracy predictions for single-crystal micropillar compression can be improved by incorporating easily activated dislocation features with external features.However,the effect of easily activated dislocation on yielding is less important compared to the effects of specimen size and Schmid factor which includes information of orientation but becomes more evident in small-sized micropillars.Overall,incorporating internal features,especially the information of most easily activated dislocations,improves predictive capabilities across diverse sample sizes and orientations.展开更多
A new method for separating complex touching equiaxed and lamellar alpha phases in the optical micrograph of titanium alloy was proposed for quantitative characterization. This new method involves three steps. First, ...A new method for separating complex touching equiaxed and lamellar alpha phases in the optical micrograph of titanium alloy was proposed for quantitative characterization. This new method involves three steps. First, concave points of the microstructural feature are identified with a threshold of the concaveness of the comer points which are extracted from the binarized image. Secondly, concave points pairs are selected from the concave points group established by means of marker circle or distance. Third, whether a candidate separation line which connects two concave points within a pair can be accepted or not is determined by the proposed four rules. The obtained results show that this method is effective on separating complex touching microstructural features.展开更多
This research considered the effect of non-natural aging on the microstructural characteristics and mechanical properties of as-cast aluminum 6063 alloys. The samples were developed through a sand casting process and ...This research considered the effect of non-natural aging on the microstructural characteristics and mechanical properties of as-cast aluminum 6063 alloys. The samples were developed through a sand casting process and machined into tensile and impact test samples before carrying out solution heat treatment at 550?C (0.83 T<sub>m</sub>) on two parts of the samples while retaining one part as the control. The two parts were further divided into sets denoted A and B and were aged at 180?C (0.27 T<sub>m</sub>) and 160?C (0.24 T<sub>m</sub>), respectively, for 12 hours. The results showed that sample A has the optimal yield strength and ultimate tensile strength of 192 and 206 MPa, respectively. Likewise, the sample gave the highest impact strength value of about 9.63 J/mm<sup>2</sup>. The observed results were supported by the optical micrograph, which revealed that the sample has evenly dispersed precipitates in its microstructure. This is deemed responsible for the observed increase in strength of the sample.展开更多
The effect of thermomechanical treatments on the microstructures and properties of Cu-2.1Ni-0.5Si- 0.2Zr alloy was investigated. The hot-rolled plates were solution treated at 920 ℃ for 1.5 h, quenched into water, co...The effect of thermomechanical treatments on the microstructures and properties of Cu-2.1Ni-0.5Si- 0.2Zr alloy was investigated. The hot-rolled plates were solution treated at 920 ℃ for 1.5 h, quenched into water, cold rolled by 70 % reduction in thickness, and then aged at 400, 450 and 500 ℃for various times. The variation in tensile strength and electrical conductivity of the alloy was measured as a function of the aging time. The results show the peak strength value of 665 MPa for the alloy aged at 450 ℃ for 2 h. However, the electrical conductivity is observed to reach a maximum of 47 % IACS aged at 450℃for 8 h. OM, SEM, and TEM were used for microstructural inspection of the alloy. Precipitation occurs preferentially at deformation bands in the cold-rolled alloy. Properties behavior is discussed in the light of microstructural features.展开更多
The selective laser melting(SLM)processed aluminum alloys have already aroused researchers’attention in aerospace,rail transport and petrochemical engineering due to the comprehensive advantages of low density,good c...The selective laser melting(SLM)processed aluminum alloys have already aroused researchers’attention in aerospace,rail transport and petrochemical engineering due to the comprehensive advantages of low density,good corrosion resistance and high mechanical performance.In this paper,an Al-14.1Mg-0.47Si-0.31Sc-0.17Zr alloy was fabricated via SLM.The characteristics of single track at different process parameters,and the influence of hatch spacing on densification,microstructural features and tensile properties of block specimens were systematically studied.The hatch spacing has an influence on the overlap ratio of single track,and further affects the internal forming quality of printed specimen.At a laser power of 160 W and scanning speed of 400 mm/s,the densification of block specimen increased first and then decreased with the increase of hatch spacing.The nearly full dense specimen(98.7%)with a tensile strength of 452 MPa was fabricated at a hatch spacing of 80μm.Typical characteristics of dimple and cleavage on the tensile fracture of the AlMgSiScZr alloy showed the mixed fracture of ductility and brittleness.展开更多
Coarse grain heat-affected zone samples of X80 pipeline steel under different heat inputs were obtained through thermal welding simulation experiments with Gleeble 3500.Charpy impact tests and a combination of multisc...Coarse grain heat-affected zone samples of X80 pipeline steel under different heat inputs were obtained through thermal welding simulation experiments with Gleeble 3500.Charpy impact tests and a combination of multiscale characterizations were conducted to investigate the influence of various microstructural features on impact toughness and crack initiation behavior.The results prove that, as the heat input increases, the number of M/A components increases, thereby degrading toughness and increasing hardness.Meanwhile, more M/A constituents tend to aggregate on prior austenite grain boundaries(PAGBs),and the overall dimensions of M/A and the width and volume fraction of the lath martensite substructure inside M/A islands would increase as well.These changes make intersections between boundary M/As and PAGBs become one of the preferred sites for crack initiation.In addition, only large-sized grotesque inclusions can act as a direct inducement of crack initiation.展开更多
Hot-dip aluminizing(HDA) is a proven surface coating technique for improving the oxidation and corrosion resistance of ferrous substrates. Although extensive studies on the HDA of plain carbon steels have been repor...Hot-dip aluminizing(HDA) is a proven surface coating technique for improving the oxidation and corrosion resistance of ferrous substrates. Although extensive studies on the HDA of plain carbon steels have been reported, studies on the HDA of stainless steels are limited. Because of the technological importance of stainless steels in high-temperature applications, studies of their microstructural development during HDA are needed. In the present investigation, the HDA of AISI 321 stainless steel was carried out in a pure Al bath. The microstructural features of the coating were studied using scanning electron microscopy and transmission electron microscopy. These studies revealed that the coating consists of two regions: an Al top coat and an aluminide layer at the interface between the steel and Al. The Al top coat was found to consist of intermetallic phases such as Al_7Cr and Al_3Fe dispersed in an Al matrix. Twinning was observed in both the Al_7Cr and the Al_3Fe phases. Furthermore, the aluminide layer comprised a mixture of nanocrystalline Fe_2Al_5, Al_7Cr, and Al. Details of the microstructural features are presented, and their formation mechanisms are discussed.展开更多
In the present study, it is expected to tailor the microstructural features, martensitic transformation temperatures and mechanical properties of Ti-V-Al shape memory alloys through adding Sn alloying elements, which ...In the present study, it is expected to tailor the microstructural features, martensitic transformation temperatures and mechanical properties of Ti-V-Al shape memory alloys through adding Sn alloying elements, which further expands their applications. Sn addition results in the monotonous rising of average valence electron number (e/a). In proportion, the single α″ martensite phase directly evolves into merely β parent phase in present Ti-V-Al-based shape memory alloys, as Sn content increases from 0.5 to 5.0 at.%. Meanwhile, Sn addition causes the reduction in the grain size. Combined with transmission electron microscopy (TEM) observation and d electron theory analysis, it can be speculated that Sn addition can suppress the precipitation of ω phase. With increasing Sn content, fracture strength invariably decreases from 962 to 792 MPa, whereas the yield strength firstly decreases and then increases. The lowest yield stress for the stress-induced martensitic transformation of 220 MPa can be obtained in Ti-V-Al shape memory alloy by adding 3.0 at.% Sn. By optimizing 1.0 at.% Sn, the excellent ductility with a largest elongation of 42.1% can be gained in Ti-V-Al shape memory alloy, which is larger than that of the reported Ti-V-Al-based shape memory alloys. Besides, as a result of solution strengthening and grain refinement, Ti-V-Al-based shape memory alloy with 5.0 at.% Sn possesses the highest yield strength, further contributing to the excellent strain recovery characteristics with 4% fully recoverable strain.展开更多
Since the last two decades, restorative dentistry has been witnessing an increased acceptance of the use of the well-known all-ceramic materials for the fabrication of single dental restorations, such as inlays, onlay...Since the last two decades, restorative dentistry has been witnessing an increased acceptance of the use of the well-known all-ceramic materials for the fabrication of single dental restorations, such as inlays, onlays, crowns, anterior and posterior fixed partial dentures (PFPDs). These restorations certainly offer the potential for better biocompatibility coupled with superior aesthetic qualities, especially when compared with the conventional prostheses made from porcelain that is fused with metal ceramic restorations. However, brittleness and extreme sensitivity of all-ceramic materials to micro-like defects or cracks that are inherently present, or may grow, in their microstructure during different laboratory fabrication steps, during necessary clinical adjustments, or from post-placement chewing activity, remain major shortcomings of these dental restorations. In fact, many researchers are of the opinion that the improved mechanical properties can significantly improve the lifetime of all-ceramic restorations and result in enhanced reliability. Therefore, efforts of researchers, as well as manufacturers, have been directed towards the improvement of the mechanical properties in order to overcome such limitations. This article reviews the characterization of the most important mechanical properties that can delineate the behavior of all-ceramic dental materials upon loading. These include fracture mechanics, the brittle nature of ceramics, the relationship between microstructural features and fracture behavior, sources of cracks and flaws that may initiate a fracture and the effect of different fabrication procedures and/or clinical adjustments on the mechanical behavior of dental ceramics are also reviewed and discussed.展开更多
The Nyakong-Manyi Shear Zone(NMSZ) is a NE-SW elongated corridor found to the northwest of the Foumban-Bankim Shear Zone(FBSZ) along the Central Cameroon Shear Zone. Controversial chronology models has been proposed f...The Nyakong-Manyi Shear Zone(NMSZ) is a NE-SW elongated corridor found to the northwest of the Foumban-Bankim Shear Zone(FBSZ) along the Central Cameroon Shear Zone. Controversial chronology models has been proposed for the kinematic evolution of the sinistral and dextral shear phases in the Tikar Plain, thus in the FBSZ;early dextral and late sinistral shear phases for some authors and early sinistral and late dextral shear for others. Moreover, the NMSZ kinematic evolution implication on the mylonitization P-T-t path in the area seem to be problematic and the present paper aim is to clear enough those problems;since this shear zone is the main mylonitic corridor that registered the left and right lateral movement in this area. The NMSZ comprises amphibolites, protomylonites, strict sensus mylonites(garnet-kyanite-sillimanite mylonite and garnet-pyroxene mylonite), ultramylonites kyanite-sillimanite and garnet-kyanite-sillimanite gneiss. Field structures testify that the investigated area recorded three deformation phases:(i) the D1deformation phase which is marked by NW-SE to N-S trending S1metamorphic foliation with low to moderate dips(15°–45°) that was transposed during the D2phase, is responsible for a regional metamorphism whose mineral paragenesis is garnet-kyanite-sillimanite;(ii) the early sinistral NNE-SSW to NE-SW shear phase D2marked by S2metamorphic and mylonitic foliations;responsible for, L2stretching mineral lineation, F2fold axes and B2boudins structures;(iii) the late dextral NE-SW shear phase D3, characterized by F3folds, B3boudins and ductile dextral C3shear planes. Mineral paragenesis garnet + kyanite + sillimanite and microstructures within gneiss testify that this rock underwent high grade regional metamorphism whose peak conditions are estimated at 11.5–13.5 kbar/850–900 ℃. After the peak of metamorphism gneiss was overprinted by high grade pressure mylonitization during the early sinistral and late dextral shear deformations. Microstructural data here indicate a high-grade mylonitization whose P-T conditions are estimated at least at around 10 kbar/750 ℃ attained during the D2. Shear markers, indicates that the studied area underwent an intense mylonitization at deep crustal deformation level, probably at the ductile-brittle boundary structural level during a major dextral shear deformation.展开更多
Conventional fatigue tests on complex components are difficult to sample,time-consuming and expensive.To avoid such problems,several popular machine learning(ML)algorithms were used and compared to predict fatigue lif...Conventional fatigue tests on complex components are difficult to sample,time-consuming and expensive.To avoid such problems,several popular machine learning(ML)algorithms were used and compared to predict fatigue life of gray cast iron(GCI)with the complex microstructures.The feature analysis shows that the fatigue life of GCI is mainly influenced by the external environment such as the stress amplitude,and the internal microstructure parameters such as the percentage of graphite,graphite length,stress concentration factor at the graphite tip,matrix microhardness and Brinell hardness.For simplicity,collected datasets with some of the above features were used to train ML models including back-propagation neural network(BPNN),random forest(RF)and eXtreme gradient boosting(XGBoost).The comparison results suggest that the three models could predict the fatigue lives of GCI,while the implemented RF algorithm is the best performing model.Moreover,the S–N curves fitted by the Basquin relation in the predicted data have a mean relative error of 15%compared to the measured data.The results have demonstrated the advantages of ML,which provides a generic way to predict the fatigue life of GCI for reducing time and cost.展开更多
The competitive effect of microstructural features including primaryα(α_(p)),secondaryα(α_(s)),grain boundaryα(α_(GB)) and β grain size on mechanical properties of a near β Ti alloy were studied with two heat ...The competitive effect of microstructural features including primaryα(α_(p)),secondaryα(α_(s)),grain boundaryα(α_(GB)) and β grain size on mechanical properties of a near β Ti alloy were studied with two heat treatment processes.The relative effect of β grain size and STA(solution treatment and ageing)processing parameters on mechanical properties were quantitatively explored by the application of Taguchi method.These results were further explained via correlating microstructure with the fracture toughness and tensile properties.It was found that large numbers of fine as precipitates and continuous α_(s) played greater roles than other features,resulting in a high strength and very low ductility(<2%)of STA process samples.The β grain size had a negative correlation with fracture toughness.In the samples prepared by BASCA( β anneal slow cooling and ageing)process,improved ductility and fracture toughness were obtained due to a lower density ofα;precipitates,a basket-weave structure and zigzag morphology of α_(GB).For this heat treatment,an increase in prior β grain size had an observable positive effect on fracture toughness.The contradictory effect of β grain size on fracture toughness found in literature was for the first time explained.It was shown that the microstructure obtained from different processes after β solution has complex effect on mechanical properties.This complexity derived from the competition between microstructure features and the overall sum of their effect on fracture toughness and tensile properties.A novel table was proposed to quasi-quantitatively unravel these competitive effects.展开更多
The influence of cooling rate on the microstructure and mechanical properties of two new ultrahigh-strength steels(UHSSs)with different levels of C,Cr and Ni has been evaluated for the as-cooled and untempered conditi...The influence of cooling rate on the microstructure and mechanical properties of two new ultrahigh-strength steels(UHSSs)with different levels of C,Cr and Ni has been evaluated for the as-cooled and untempered condition.One UHSS had higher contents of C and Cr,while the other one had a higher Ni content.On the basis of dilatation curves,microstructures,macrohardness and microhardness,continuous cooling transformation diagrams were constructed as a guide to heat treatment possibilities.Cooling rates(CRs)of 60,1 and 0.01°C/s were selected for more detailed investigations.Microstructural characterization was made by laser scanning confocal microscopy,field emission scanning electron microscopy combined with electron backscatter diffraction,electron probe microanalysis and X-ray diffraction.Mechanical properties were characterized using macrohardness,tensile and Charpy V-notch impact tests.UHSS with the higher C and Cr contents showed lower transformation temperatures and slower bainite formation kinetics than that with the higher Ni content.Higher cooling rates led to lower volume fractions and carbon contents of retained austenite together with finer prior austenite grain size,as well as effective final grain size and lath size.These changes were accompanied by higher yield and tensile strengths.The best combinations of strength and toughness were obtained with martensitic microstructures and by avoiding the formation of granular bainite accompanied by proeutectoid carbides at low CR.For the cooling rates studied,UHSS with the higher C and Cr contents showed the higher hardness and strength but at the cost of toughness.展开更多
基金funded by the Key Laboratory of Marginal Sea Geology, South China Sea Institute of Oceanology, Chinese Academy of Sciences (No. MSGL0606)the China National Natural Science Fundation (Ratification No. 40876018, 40476020)
文摘Test tools and methods for synchronizing acoustic measurements in the course of stress-strain for seafloor sediment are elaborated and the test data of 45 sediment samples from the seafloor in the South China Sea are analysed. The result shows that the coarser the sediment grains are, the smaller the porosity is and the larger the unconfined compression strength is, the higher the sound velocity is. In the course of stress-strain, the sediment sound velocity varies obviously with the stress. Acoustic characteristics of sediment in different strain phases and the influence of sediment microstructure change on its sound velocity are discussed. This study will be of important significance for surveying wells of petroleum geology and evaluating the base stabilization of seafloor engineering.
基金supported by the National Natural Science Foundation of China(Grant Nos.12192214 and 12222209).
文摘Discrete dislocation dynamics(DDD)simulations reveal the evolution of dislocation structures and the interaction of dislocations.This study investigated the compression behavior of single-crystal copper micropillars using fewshot machine learning with data provided by DDD simulations.Two types of features are considered:external features comprising specimen size and loading orientation and internal features involving dislocation source length,Schmid factor,the orientation of the most easily activated dislocations and their distance from the free boundary.The yielding stress and stress-strain curves of single-crystal copper micropillar are predicted well by incorporating both external and internal features of the sample as separate or combined inputs.It is found that the machine learning accuracy predictions for single-crystal micropillar compression can be improved by incorporating easily activated dislocation features with external features.However,the effect of easily activated dislocation on yielding is less important compared to the effects of specimen size and Schmid factor which includes information of orientation but becomes more evident in small-sized micropillars.Overall,incorporating internal features,especially the information of most easily activated dislocations,improves predictive capabilities across diverse sample sizes and orientations.
基金Projects(50935007,51175428) supported by the National Natural Science Foundation of ChinaProject(2010CB731701) supported by the National Basic Research Program of ChinaProject(B08040) supported by the Program of Introducing Talents of Discipline to Universities,China
文摘A new method for separating complex touching equiaxed and lamellar alpha phases in the optical micrograph of titanium alloy was proposed for quantitative characterization. This new method involves three steps. First, concave points of the microstructural feature are identified with a threshold of the concaveness of the comer points which are extracted from the binarized image. Secondly, concave points pairs are selected from the concave points group established by means of marker circle or distance. Third, whether a candidate separation line which connects two concave points within a pair can be accepted or not is determined by the proposed four rules. The obtained results show that this method is effective on separating complex touching microstructural features.
文摘This research considered the effect of non-natural aging on the microstructural characteristics and mechanical properties of as-cast aluminum 6063 alloys. The samples were developed through a sand casting process and machined into tensile and impact test samples before carrying out solution heat treatment at 550?C (0.83 T<sub>m</sub>) on two parts of the samples while retaining one part as the control. The two parts were further divided into sets denoted A and B and were aged at 180?C (0.27 T<sub>m</sub>) and 160?C (0.24 T<sub>m</sub>), respectively, for 12 hours. The results showed that sample A has the optimal yield strength and ultimate tensile strength of 192 and 206 MPa, respectively. Likewise, the sample gave the highest impact strength value of about 9.63 J/mm<sup>2</sup>. The observed results were supported by the optical micrograph, which revealed that the sample has evenly dispersed precipitates in its microstructure. This is deemed responsible for the observed increase in strength of the sample.
基金supported by the Project of National "863"Foundation of China(No.2006AA03Z522)Science and Technology of Beijing(No.10231103)
文摘The effect of thermomechanical treatments on the microstructures and properties of Cu-2.1Ni-0.5Si- 0.2Zr alloy was investigated. The hot-rolled plates were solution treated at 920 ℃ for 1.5 h, quenched into water, cold rolled by 70 % reduction in thickness, and then aged at 400, 450 and 500 ℃for various times. The variation in tensile strength and electrical conductivity of the alloy was measured as a function of the aging time. The results show the peak strength value of 665 MPa for the alloy aged at 450 ℃ for 2 h. However, the electrical conductivity is observed to reach a maximum of 47 % IACS aged at 450℃for 8 h. OM, SEM, and TEM were used for microstructural inspection of the alloy. Precipitation occurs preferentially at deformation bands in the cold-rolled alloy. Properties behavior is discussed in the light of microstructural features.
基金Project(51775481)supported by the National Natural Science Foundation of ChinaProject(E2019203418)supported by the Natural Science Foundation of Hebei Province,China。
文摘The selective laser melting(SLM)processed aluminum alloys have already aroused researchers’attention in aerospace,rail transport and petrochemical engineering due to the comprehensive advantages of low density,good corrosion resistance and high mechanical performance.In this paper,an Al-14.1Mg-0.47Si-0.31Sc-0.17Zr alloy was fabricated via SLM.The characteristics of single track at different process parameters,and the influence of hatch spacing on densification,microstructural features and tensile properties of block specimens were systematically studied.The hatch spacing has an influence on the overlap ratio of single track,and further affects the internal forming quality of printed specimen.At a laser power of 160 W and scanning speed of 400 mm/s,the densification of block specimen increased first and then decreased with the increase of hatch spacing.The nearly full dense specimen(98.7%)with a tensile strength of 452 MPa was fabricated at a hatch spacing of 80μm.Typical characteristics of dimple and cleavage on the tensile fracture of the AlMgSiScZr alloy showed the mixed fracture of ductility and brittleness.
文摘Coarse grain heat-affected zone samples of X80 pipeline steel under different heat inputs were obtained through thermal welding simulation experiments with Gleeble 3500.Charpy impact tests and a combination of multiscale characterizations were conducted to investigate the influence of various microstructural features on impact toughness and crack initiation behavior.The results prove that, as the heat input increases, the number of M/A components increases, thereby degrading toughness and increasing hardness.Meanwhile, more M/A constituents tend to aggregate on prior austenite grain boundaries(PAGBs),and the overall dimensions of M/A and the width and volume fraction of the lath martensite substructure inside M/A islands would increase as well.These changes make intersections between boundary M/As and PAGBs become one of the preferred sites for crack initiation.In addition, only large-sized grotesque inclusions can act as a direct inducement of crack initiation.
文摘Hot-dip aluminizing(HDA) is a proven surface coating technique for improving the oxidation and corrosion resistance of ferrous substrates. Although extensive studies on the HDA of plain carbon steels have been reported, studies on the HDA of stainless steels are limited. Because of the technological importance of stainless steels in high-temperature applications, studies of their microstructural development during HDA are needed. In the present investigation, the HDA of AISI 321 stainless steel was carried out in a pure Al bath. The microstructural features of the coating were studied using scanning electron microscopy and transmission electron microscopy. These studies revealed that the coating consists of two regions: an Al top coat and an aluminide layer at the interface between the steel and Al. The Al top coat was found to consist of intermetallic phases such as Al_7Cr and Al_3Fe dispersed in an Al matrix. Twinning was observed in both the Al_7Cr and the Al_3Fe phases. Furthermore, the aluminide layer comprised a mixture of nanocrystalline Fe_2Al_5, Al_7Cr, and Al. Details of the microstructural features are presented, and their formation mechanisms are discussed.
基金financial support from the National Natural Science Foundation of China(Nos.52101231,52101232 and 51871079)the Science Fund of Shandong Laboratory of Advanced Materials and Green Manufacturing(Yantai)(No.AMGM2021F09)+1 种基金the Natural Science Foundation of Shandong Province,China(No.ZR2021QE044)the Gansu Province Science and Technology Foundation for Youths(No.21JR7RA088).
文摘In the present study, it is expected to tailor the microstructural features, martensitic transformation temperatures and mechanical properties of Ti-V-Al shape memory alloys through adding Sn alloying elements, which further expands their applications. Sn addition results in the monotonous rising of average valence electron number (e/a). In proportion, the single α″ martensite phase directly evolves into merely β parent phase in present Ti-V-Al-based shape memory alloys, as Sn content increases from 0.5 to 5.0 at.%. Meanwhile, Sn addition causes the reduction in the grain size. Combined with transmission electron microscopy (TEM) observation and d electron theory analysis, it can be speculated that Sn addition can suppress the precipitation of ω phase. With increasing Sn content, fracture strength invariably decreases from 962 to 792 MPa, whereas the yield strength firstly decreases and then increases. The lowest yield stress for the stress-induced martensitic transformation of 220 MPa can be obtained in Ti-V-Al shape memory alloy by adding 3.0 at.% Sn. By optimizing 1.0 at.% Sn, the excellent ductility with a largest elongation of 42.1% can be gained in Ti-V-Al shape memory alloy, which is larger than that of the reported Ti-V-Al-based shape memory alloys. Besides, as a result of solution strengthening and grain refinement, Ti-V-Al-based shape memory alloy with 5.0 at.% Sn possesses the highest yield strength, further contributing to the excellent strain recovery characteristics with 4% fully recoverable strain.
文摘Since the last two decades, restorative dentistry has been witnessing an increased acceptance of the use of the well-known all-ceramic materials for the fabrication of single dental restorations, such as inlays, onlays, crowns, anterior and posterior fixed partial dentures (PFPDs). These restorations certainly offer the potential for better biocompatibility coupled with superior aesthetic qualities, especially when compared with the conventional prostheses made from porcelain that is fused with metal ceramic restorations. However, brittleness and extreme sensitivity of all-ceramic materials to micro-like defects or cracks that are inherently present, or may grow, in their microstructure during different laboratory fabrication steps, during necessary clinical adjustments, or from post-placement chewing activity, remain major shortcomings of these dental restorations. In fact, many researchers are of the opinion that the improved mechanical properties can significantly improve the lifetime of all-ceramic restorations and result in enhanced reliability. Therefore, efforts of researchers, as well as manufacturers, have been directed towards the improvement of the mechanical properties in order to overcome such limitations. This article reviews the characterization of the most important mechanical properties that can delineate the behavior of all-ceramic dental materials upon loading. These include fracture mechanics, the brittle nature of ceramics, the relationship between microstructural features and fracture behavior, sources of cracks and flaws that may initiate a fracture and the effect of different fabrication procedures and/or clinical adjustments on the mechanical behavior of dental ceramics are also reviewed and discussed.
文摘The Nyakong-Manyi Shear Zone(NMSZ) is a NE-SW elongated corridor found to the northwest of the Foumban-Bankim Shear Zone(FBSZ) along the Central Cameroon Shear Zone. Controversial chronology models has been proposed for the kinematic evolution of the sinistral and dextral shear phases in the Tikar Plain, thus in the FBSZ;early dextral and late sinistral shear phases for some authors and early sinistral and late dextral shear for others. Moreover, the NMSZ kinematic evolution implication on the mylonitization P-T-t path in the area seem to be problematic and the present paper aim is to clear enough those problems;since this shear zone is the main mylonitic corridor that registered the left and right lateral movement in this area. The NMSZ comprises amphibolites, protomylonites, strict sensus mylonites(garnet-kyanite-sillimanite mylonite and garnet-pyroxene mylonite), ultramylonites kyanite-sillimanite and garnet-kyanite-sillimanite gneiss. Field structures testify that the investigated area recorded three deformation phases:(i) the D1deformation phase which is marked by NW-SE to N-S trending S1metamorphic foliation with low to moderate dips(15°–45°) that was transposed during the D2phase, is responsible for a regional metamorphism whose mineral paragenesis is garnet-kyanite-sillimanite;(ii) the early sinistral NNE-SSW to NE-SW shear phase D2marked by S2metamorphic and mylonitic foliations;responsible for, L2stretching mineral lineation, F2fold axes and B2boudins structures;(iii) the late dextral NE-SW shear phase D3, characterized by F3folds, B3boudins and ductile dextral C3shear planes. Mineral paragenesis garnet + kyanite + sillimanite and microstructures within gneiss testify that this rock underwent high grade regional metamorphism whose peak conditions are estimated at 11.5–13.5 kbar/850–900 ℃. After the peak of metamorphism gneiss was overprinted by high grade pressure mylonitization during the early sinistral and late dextral shear deformations. Microstructural data here indicate a high-grade mylonitization whose P-T conditions are estimated at least at around 10 kbar/750 ℃ attained during the D2. Shear markers, indicates that the studied area underwent an intense mylonitization at deep crustal deformation level, probably at the ductile-brittle boundary structural level during a major dextral shear deformation.
基金This work is supported by the National Natural Science Foundation of China(NSFC)under Grant Nos.51871224 and 52130002.
文摘Conventional fatigue tests on complex components are difficult to sample,time-consuming and expensive.To avoid such problems,several popular machine learning(ML)algorithms were used and compared to predict fatigue life of gray cast iron(GCI)with the complex microstructures.The feature analysis shows that the fatigue life of GCI is mainly influenced by the external environment such as the stress amplitude,and the internal microstructure parameters such as the percentage of graphite,graphite length,stress concentration factor at the graphite tip,matrix microhardness and Brinell hardness.For simplicity,collected datasets with some of the above features were used to train ML models including back-propagation neural network(BPNN),random forest(RF)and eXtreme gradient boosting(XGBoost).The comparison results suggest that the three models could predict the fatigue lives of GCI,while the implemented RF algorithm is the best performing model.Moreover,the S–N curves fitted by the Basquin relation in the predicted data have a mean relative error of 15%compared to the measured data.The results have demonstrated the advantages of ML,which provides a generic way to predict the fatigue life of GCI for reducing time and cost.
基金the financial support from Baosteel Australia Joint Research Centre(BA16003)ARC Research Hub for Computational Particle Technology(IH140100035)funded by Australian Research Council grant LE0882821。
文摘The competitive effect of microstructural features including primaryα(α_(p)),secondaryα(α_(s)),grain boundaryα(α_(GB)) and β grain size on mechanical properties of a near β Ti alloy were studied with two heat treatment processes.The relative effect of β grain size and STA(solution treatment and ageing)processing parameters on mechanical properties were quantitatively explored by the application of Taguchi method.These results were further explained via correlating microstructure with the fracture toughness and tensile properties.It was found that large numbers of fine as precipitates and continuous α_(s) played greater roles than other features,resulting in a high strength and very low ductility(<2%)of STA process samples.The β grain size had a negative correlation with fracture toughness.In the samples prepared by BASCA( β anneal slow cooling and ageing)process,improved ductility and fracture toughness were obtained due to a lower density ofα;precipitates,a basket-weave structure and zigzag morphology of α_(GB).For this heat treatment,an increase in prior β grain size had an observable positive effect on fracture toughness.The contradictory effect of β grain size on fracture toughness found in literature was for the first time explained.It was shown that the microstructure obtained from different processes after β solution has complex effect on mechanical properties.This complexity derived from the competition between microstructure features and the overall sum of their effect on fracture toughness and tensile properties.A novel table was proposed to quasi-quantitatively unravel these competitive effects.
文摘The influence of cooling rate on the microstructure and mechanical properties of two new ultrahigh-strength steels(UHSSs)with different levels of C,Cr and Ni has been evaluated for the as-cooled and untempered condition.One UHSS had higher contents of C and Cr,while the other one had a higher Ni content.On the basis of dilatation curves,microstructures,macrohardness and microhardness,continuous cooling transformation diagrams were constructed as a guide to heat treatment possibilities.Cooling rates(CRs)of 60,1 and 0.01°C/s were selected for more detailed investigations.Microstructural characterization was made by laser scanning confocal microscopy,field emission scanning electron microscopy combined with electron backscatter diffraction,electron probe microanalysis and X-ray diffraction.Mechanical properties were characterized using macrohardness,tensile and Charpy V-notch impact tests.UHSS with the higher C and Cr contents showed lower transformation temperatures and slower bainite formation kinetics than that with the higher Ni content.Higher cooling rates led to lower volume fractions and carbon contents of retained austenite together with finer prior austenite grain size,as well as effective final grain size and lath size.These changes were accompanied by higher yield and tensile strengths.The best combinations of strength and toughness were obtained with martensitic microstructures and by avoiding the formation of granular bainite accompanied by proeutectoid carbides at low CR.For the cooling rates studied,UHSS with the higher C and Cr contents showed the higher hardness and strength but at the cost of toughness.