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Effects of V<sub>2</sub>O<sub>5</sub>Addition on Microwave Dielectric Properties of Li<sub>2</sub>ZnTi<sub>3</sub>O<sub>8</sub>Ceramics for LTCC Applications
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作者 Jianhua Zhu Jinyuan Liu +1 位作者 Songjie Lu Yong Zeng 《New Journal of Glass and Ceramics》 2019年第3期25-32,共8页
The sintering temperature of Li2ZnTi3O8 ceramics is still high for LTCC-based applications. In this work, V2O5 was doped as the sintering aid. The sintered density, phase composition, grain size, as well as microwave ... The sintering temperature of Li2ZnTi3O8 ceramics is still high for LTCC-based applications. In this work, V2O5 was doped as the sintering aid. The sintered density, phase composition, grain size, as well as microwave dielectric properties of Li2ZnTi3O8 ceramics with the addition of V2O5 were investigated. Based on our research, V2O5 doping effectively promoted the densification of Li2ZnTi3O8 ceramics at about 900°C, without affecting the main crystal phase of the ceramics. Li2ZnTi3O8 ceramics with 0.5 wt% V2O5 doping (sintered at 900°C) exhibited the best microwave dielectric properties (Qf =?22,400 GHz at about 6 GHz, εr = 25.5, and τf = -10.8 ppm/°C). The V2O5-doped Li2ZnTi3O8 ceramics were well cofired with Ag inner paste without cracks and diffusion, indicating its significant potential for LTCC applications. 展开更多
关键词 li2ZnTi3O8 Low Temperature Co-Fired ceramics microwave dielectric Properties
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MnO_(2)-CuO-TiO_(2)共掺Al_(2)O_(3)陶瓷低温烧结和微波介电性能的研究
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作者 林聪毅 陶宏磊 李蔚 《硅酸盐通报》 CAS 北大核心 2023年第10期3764-3768,共5页
作为重要微波介质材料之一,Al_(2)O_(3)陶瓷介电性能优良,在微波电路方面得到广泛应用。但Al_(2)O_(3)陶瓷的烧结温度较高,制备工序需消耗大量能源。低成本降低烧结温度对Al_(2)O_(3)陶瓷的进一步发展具有重要意义。本论文通过MnO_(2)-C... 作为重要微波介质材料之一,Al_(2)O_(3)陶瓷介电性能优良,在微波电路方面得到广泛应用。但Al_(2)O_(3)陶瓷的烧结温度较高,制备工序需消耗大量能源。低成本降低烧结温度对Al_(2)O_(3)陶瓷的进一步发展具有重要意义。本论文通过MnO_(2)-CuO-TiO_(2)掺杂实现了Al_(2)O_(3)陶瓷的低温烧结,并对其烧结行为和微波介电性能进行了研究。结果表明,MnO_(2)、CuO、TiO_(2)的质量分数分别为0.7%、0.5%、0.8%时,复合掺杂可以大幅降低Al_(2)O_(3)陶瓷的烧结温度,所获陶瓷具有良好的微波介电性能。在烧结温度为1250℃时,Al_(2)O_(3)陶瓷的密度可达3.92 g/cm^(3),介电常数εr=10.02,品质因子与谐振频率的乘积Q×f值为51239 GHz。Ti^(4+)、Mn^(4+)、Cu^(2+)固溶导致Al_(2)O_(3)晶格扭曲活化,以及低共熔物形成是促进Al_(2)O_(3)陶瓷低温烧结的原因。 展开更多
关键词 Al_(2)O_(3)陶瓷 MnO_(2)-CuO-TiO_(2) 低温烧结 微波介电性能 掺杂
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Zn_(0.15)Nb_(0.3)Ti_(0.55-x)(Co_(1/3)Nb_(2/3))_(x)O_(2)陶瓷的微波介电性能研究
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作者 张文娟 《电子元件与材料》 CAS CSCD 北大核心 2021年第2期144-149,共6页
采用固相烧结法制备Zn_(0.15)Nb_(0.3)Ti_(0.55-x)(Co_(1/3)Nb_(2/3))_(x)O_(2)(x=0,0.05,0.15,0.25,0.35,0.4,0.45,0.55)陶瓷,研究了(Co_(1/3)Nb_(2/3))^(4+)取代Ti^(4+)对陶瓷的物相、微观形貌和微波介电性能的影响。实验结果表明,当(... 采用固相烧结法制备Zn_(0.15)Nb_(0.3)Ti_(0.55-x)(Co_(1/3)Nb_(2/3))_(x)O_(2)(x=0,0.05,0.15,0.25,0.35,0.4,0.45,0.55)陶瓷,研究了(Co_(1/3)Nb_(2/3))^(4+)取代Ti^(4+)对陶瓷的物相、微观形貌和微波介电性能的影响。实验结果表明,当(Co_(1/3)Nb_(2/3))^(4+)取代量x≤0.05时,Zn_(0.15)Nb_(0.3)Ti_(0.55-x)(Co_(1/3)Nb_(2/3))_(x)O_(2)陶瓷表现出纯的金红石Zn_(0.15)Nb_(0.3)Ti_(0.55)O_(2)相;当(Co_(1/3)Nb_(2/3))^(4+)取代量x>0.15时,有第二相ZnTiNb_(2)O_(8)和ZnNb_(2)O_(6)生成。陶瓷的Q×f值随x的增大而提高,介电常数(ε_(r))和谐振频率温度系数(τ_(f))则随ZnTiNb_(2)O_(8)和ZnNb_(2)O_(6)的增多而逐渐降低。当x=0.4时,Zn_(0.15)Nb_(0.3)Ti_(0.55-x)(Co_(1/3)Nb_(2/3))_(x)O_(2)陶瓷在1075℃下烧结获得最佳的微波介电性能:ε_(r)=35.44,Q×f=25862 GHz(f=5.8 GHz),τ_(f)=5.2×10^(-6)/℃。 展开更多
关键词 微波介质陶瓷 Zn_(0.15)Nb_(0.3)Ti_(0.55-x)(Co_(1/3)Nb_(2/3))_(x)O_(2) 掺杂 介电性能 LTCC
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