Migration and transfer of chromium in soil-vegetable system and associated health risks in vicinity of ferro-alloy manufactory

Study was carried out to analyze the distribution and migration patterns,soil-to-plant transfer and potential health risks of chromium in soil-vegetable system in areas near a ferro-alloy manufactory in Hunan province.The results show that soils near sewer outlet,sewer channel and in control area are averaged 2 239.5,995.33 and 104.9 mg/kg,respectively.The total Cr has a relative accumulation in soil depth of 200-400 mm near the sewer outlet,mainly enriches in the surface layer（0-200 mm） near the sewer channel and decreases gradually in unpolluted soils.The differential concentration level of enrichment between layers is little.The results also indicate that the three vegetables of celery,lettuce and Chinese cabbage are able to convert the potentially toxic Cr（Ⅵ） species into the non-toxic Cr（Ⅲ） species,and the chromium contents in the edible parts of the vegetables are averaged 11.95 mg/kg.The transfer factors of the three vegetables follow the order：Chinese cabbage lettuce celery.The estimated total daily intake of chromium substantially exceeds the dietary allowable value,which may pose health risks to local population.

Influences of labor migration on rural household land transfer:A case study of Sichuan Province,China

The influence of labor migration on rural household land transfer has been hotly debated in academic circles, which focuses on whether part-time employment leads to land transfer. Using survey data on rural households in the Sichuan Province, and applying the theoretical framework of new economics of labor migration, this study explores the influences of labor migration on the direction and scale of land transfer from the perspective of rural household structure. The results indicate that: 1) the quantity of laborers has significant influence on the direction and scale of land transfer. The larger the on-farm labor variable(Labor), the lesser the possibility that land will be rented-out and the amount of land rented out will also be smaller. In addition, there is a greater probability that land will be rented-in and the amount of land rented-in will be greater. 2) The greater the ratio of off-farm laborers to rural household laborers(Off-farm) the greater the possibility that land will be rented-out. In addition the higher the ratio of on-farm laborers to the total household laborers(On-farm), the larger the possibility that land will be rented-in. Meanwhile, if the household has individuals at the age of 64 or older(Old) who are engaged in agriculture, there is a smaller possibility that land will be rentedout. 3) the ratio of part-time laborers to rural household laborers(Pluriactivity) have significant inverse U-shaped influences on the rent-in of land as well as the amount of land rented-in. The inflection points are 33.27% and 14.10%, respectively. Such findings confirm the significance of this study in better understanding the influence of labor migration on rural household land transfer.

Interfacial stress transfer behavior in a specially-shaped fiber/matrix pullout test

Specially designed fibers are widely used in engineering practice because the specially-designed shape can help to improve the bonding strength of the fiber and the interface. Studied in this paper is the interfacial shear stress transfer behavior on both sides of the specially designed fiber when it is being pulled out; in which automatic analysis of three-dimensional photoelasticity is employed and the finite element method is adopted. The results show that the stress transfer occurs mainly in the region near the fiber＇s embedded end where the stress reaches its critical point, leading to debonding of the interface. Before debonding, as the pullout loading increases, the peak value of shear stress transfers along the fiber from the embedded end to the interior of the matrix, and then stops at the hooked part of the fiber because of its impediment. When the interface begins to debond as the load increases, the shear stress can be transferred to the hooked part.

Oil source and migration process in oblique transfer zone of Fushan Sag,northern South China Sea

The oblique transfer zone in the Fushan Sag, a syndepositional dome sandwiched between the Bailian and Huangtong sub-sags, has been the most important exploration target. The major oil observation occurs in the E_2l_1^(L+M) and the E_2l_3~U. 46 oil and rock samples reveal that the oil in the transfer zone is mostly contributed by the Bailian sub-sag, though the source rock conditions, hydrocarbon generation and expulsion histories of the Bailian and Huangtong sub-sags are similar. The E_2l_3~U oil, characterized by high maturity, Pr/Ph ratio and oleanane/C_(30)-hopane ratio, shows a close genetic affinity with the E_2l_3~b source rocks, while the E_2l_1^(L+M) oil, characterized by lower maturity, Pr/Ph ratio and oleanane/C_(30)-hopane ratio, is suggested to be derived from the E_2l_(1+2)~b source rocks. The homogenization temperatures of aqueous fluid inclusions, taking the burial history of the reservoirs into account, reflect that the oil charge mainly occurred from mid-Miocene to Pliocene in the oblique transfer zone. The oil transporting passages include connected sand bodies, unconformities and faults in the Fushan Sag. Of these, the faults are the most complicated and significant. The faults differ sharply in the west area, the east area and the oblique transfer zone, resulting in different influence on the oil migration and accumulation. During the main hydrocarbon charge stage, the faults in the west area are characterized by bad vertical sealing and spatially dense distribution. As a result, the oil generated by the Huangtong source rocks is mostly lost along the faults during the vertical migration in the west area. This can be the mechanism proposed to explain the little contribution of the Huangtong source rocks to the oil in the oblique transfer zone. Eventually, an oil migration and accumulation model is built in the oblique transfer zone, which may provide theoretical and practical guides for the oil exploration.

Some Further Considerations about the Theory of Elastic Stress Transfer from Partially Embedded Axially Loaded Fiber to Matrix

In this paper the elastic stress transfer from the fiber to the matrix is analysed for fiber-reinforced composites when the fiber is loaded axially.The dependence of the elastic stress transfer on the as- pect ratio of the fiber,the volume fraction of the fiber,the fiber-to-matrix elastic modulus ratio and the Poisson's ratio of the fiber and the matrix has been shown in detail.

Photoperiod and Nitrogen Supply Limit the Scope of Northward Migration and Seed Transfer of Black Spruce in a Future Climate Associated with Doubled Atmospheric CO2 Concentration

The predicated changes in precipitation and temperature associated with the continued elevation of atmospheric CO2 concentration will trigger the northward shift of the Climate Envelopes for 130 North America tree species by as much as 10 degrees. However, climate envelope models do not take into account changes in other factors that may also influence the survival and growth of plants at the predicted new locations, such as photoperiod and nutrient regimes. This study investigated how photoperiod and nitrogen supply would affect the ecophysiological traits of black spruce (Picea mariana (Mill) B. S. P.) that are critical for survival and growth at new locations predicted by climate envelope models. We exposed black spruce seedlings to the photoperiod regime at the seed origin (PS) and that 10° north of the seed origin (PNM) as predicted by climate envelope models under the current and doubled atmospheric CO2 concentration and different levels of N supply (30 vs. 300 μmol·mol-1 N). We found that the PNM and the 30 μmol·mol-1 N supply both had negative impact on the development of seedling cold hardiness in the fall, and led to earlier burst of the terminal bud and greater rate of mortality in the following growing season. While the PNM stimulated seedling growth in the first growing season, the effect was not sustained in the second growing season. Our results suggest that the photoperiod regimes and poor nutrient conditions at higher latitudes will likely constrain the scope of the northward migration or seed transfer of black spruce.

On stress-forecasting strategy of earthquakes from stress buildup,stress shadow and stress transfer(SSS) based on numerical approach

Global Positioning System （GPS） and Interferometric Synthetic Aperture Radar （InSAR）, used for monitoring crust deformation, are found to be very promising in earthquake prediction subject to stress-forecasting. However, it is recognized that unless we can give reasonable explanations of these curious precursory phenomena that continue to be serendipitously observed from time to time, such high technology of GPS or InSAR is difficult to be efficiently used. Therefore, a proper model revealing the relation between earthquake evolution and stress variation, such as the phenomena of stress buildup, stress shadow and stress transfer （SSS）, is crucial to the GPS or InSAR based earthquake prediction. Here we address this question through a numerical approach of earthquake development using an intuitive physical model with a map-like configuration of discontinuous fault system. The simulation provides a physical basis for the principle of stress-forecasting of earthquakes based on SSS and for the application of GPS or InSAR in earthquake prediction. The observed SSS associated phenomena with images of stress distribution during the failure process can be continuously simulated. It is shown that the SSS are better indicators of earthquake precursors than that of seismic foreshocks, suggesting a predictability of earthquakes based on stress-forecasting strategy.

STUDIES ON STRESS TRANSFERENCE MECHANISM OF STEEL FIBRE REINFORCED CONCRETE

The stress transfer mechanism of steel fibre reinforced concrete is studied. The solutions for the stress and displacement were regarded as the superposition of ' the elementary solutions' and ' the improved solutions'. The elementary solutions were found by using two-dimensional elastic theory and the improved solutions were found by using the Love displacement function method. The calculated results indicate that the solutions possess good convergence. By comparing the three-dimensional solutions with the shear-lag solutions, evident difference may be found.

Investigation of Coulomb stress changes in south Tibet(central Himalayas) due to the 25th April 2015 M_W 7.8 Nepal earthquake using a Coulomb stress transfer model

After Mw 7.8 Nepal earthquake occurred, the rearrangement of stresses in the crust commonly leads to subsequent damaging earthquakes. We present the calculations of the coseismic stress changes that resulted from the 25th April event using models of regional faults designed according to south Tibet-Nepal structure, and show that some indicative significant stress increases. We calculate static stress changes caused by the displacement of a fault on which dislocations happen and an earthquake occurs. A Mw 7.3 earthquake broke on 12 May at a distance of - 130 km SEE of the Mw 7.8 earthquake, whose focus roughly located on high Coulomb stress change （CSC） site. Aftershocks （first 15 days after the mainshock） are associated with stress increase zone caused by the main rupture. We set receiver faults with specified strikes, dips, and rakes, on which the stresses imparted by the source fault are resolved. Four group normal faults to the north of the Nepal earthquake seismogenic fault were set as receiver faults and variant results followed. We provide a discussion on Coulomb stress transfer for the seismogenic fault, which is useful to identify potential future rupture zones.

Analysis and direct calculation of the energy migration interaction parameter in high concentration Nd^(3+) doped YAG laser crystal

The energy migration interaction parameter CDD in high concentration Nd3＋ doped YAG laser crystal was estimated using the Yokota-Tanimoto（Y-T） model and the spectral overlap model（SOM） of Kushida, respectively.Firstly, the experimental luminescence decay curves of 4F3/2 state of Nd3＋ ions in YAG laser crystal at room temperature for 2.0at.% and 3.0at.% Nd3＋ concentrations reported by Mao were fitted successfully using the Y-T model, and the parameter CDD was obtained to be 1.50×10-39 cm6/s.Secondly, the parameter CDD was directly calculated using the spectral overlap model（SOM） of Kushida;CDD was calculated to be 2.73×10-39 cm6/s.By comparing the energy migration interaction parameter CDD with the energy transfer interaction parameter CDA（1.794×10-40 cm6/s）, it was concluded that the energy migration rate between Nd3＋ ions in YAG laser crystal was about 11 times larger than the energy transfer rate, and that energy migration played a very important role in high concentration Nd3＋-doped YAG laser crystal.

Tree clusters migration into alpine tundra,Siberia

We hypothesize that in mountain windy habitat trees formed clusters(hedges)as adaptive structures for seedlings’rooting,survival,and tress’upslope migration.We studied hedges formed by Siberian pine(Pinus sibirica du Tour)and larch(Larix sibirica Ledeb.)within the treeline ecotone in southern Siberian Mountains,investigated hedges formation,evolution,habitat amelioration,and analyzed tree’s growth index(GI)dependence on the eco-climate variables(air temperature,precipitation,soil moisture,wind speed)and relief features(elevation,aspect,slope steepness,and terrain curvature).We conducted a ground survey,measured biometrical parameters of trees and hedges,determined species composition and tree physiognomy,soil types and nutrient contents,and sampled wood cores and applied dendrochronology for trees’GI analysis.With high-resolution satellite scenes for hedge detection and upslope migration,we found that winter winds and soil moisture are the main constraints of trees’settlement and growth.Hedge formation always links with wind-sheltered microtopography features(boulders,local depressions or felled trees).Once the first tree is established,a positive feedback is aroused that facilitates seedling rooting and in-hedge habitat amelioration.Trees form a streamlined dense“common crown”that mitigates adverse winter wind influence.Hedges always orient along the prevailing winds,and trees’uphill migration occurs by seedlings establishment within the leeward hedge side.Hedge growth facilitates soil formation and fertilization.The concentration of nutrients(K,P,N and S)within hedges exceeds the background by 1.5-5.5 times.Hedge extension leads to increased snow accumulation that mitigates the influence of desiccation and snow abrasion and mitigates seasonal water stress.In the extremely harsh windy habitat,inhedge trees present in mat,prostrate or krummholz forms.With warming,tree stems and even twigs turn upright.Notably that GI dependence on the wind speed is insignificant until prostrated trees get turning upright.Since that,the negative correlation between GI and wind speed is arisen with subsequent decrease since hedges form streamlined crown.Hedge growth also leads to a“phytofield”formation(i.e.,grasses,lichen,moss and small bushes growth)around the hedges that,in its turn,encourages seedling rooting which is about triple more efficient than outside the phytofield.Larch,in comparison with Siberian pine,is less often formed hedges.GI of both species is stimulated by warmer air temperature in the beginning of the growth season.Meanwhile,larch GI has stronger response to elevated temperatures and less dependent on soil moisture.This indicates larch is a potential substitute of Siberian pine in a warmer and dryer climate.Hedges in warming climate evolve into closed stands due to both in-hedge tree growth and filling gaps between hedges by different tree species.

Numerical insight into heat transfer enhancement by granules inner-migration in a moving bed:A performance comparison between slanted-stick and plow-shaped agitator

Waste heat recovery of high-temperature granules is one of the most promising sustainable energy supply and carbon reduction ways for industry.A moving bed indirect heat exchanger(MBIHE)with inner-migration was proposed for granular heat recovery.Granule migration and the enhanced heat transfer induced by two types of agitators(i.e.,agitator with slanted stick A_(s)and with plow-shaped surface A_(p))in the MBIHE are analyzed based on DEM coupled with CFD.Owing to the effective agitation,the average heat transfer coefficient in the granule side is enhanced to∼3 times compared to that without agitation.The heat recovery efficiency in the moving bed reached more than 70%with the agitations of either A_(s)or A_(p).The heat efficiency of A_(s)is∼7%higher than that of A_(p),but with at least 60%greater rotational torque.To ensure reliable agitation,the A_(p)is suggested to be adopted in the MBIHE to induce granule migration.

Calculation of Mass Concrete Temperature and Creep Stress under the Influence of Local Air Heat Transfer

Temperature-induced cracking during the construction of mass concrete is a significant concern.Numerical simulations of concrete temperature have primarily assumed that the concrete is placed in an open environment.The problem of heat transfer between the air and concrete has been simplified to the concrete’s heat dissipation boundary.However,in the case of tubular concrete structures,where air inlet and outlet are relatively limited,the internal air temperature does not dissipate promptly to the external environment as it rises.To accurately simulate the temperature and creep stress in tubular concrete structures with enclosed air spaces during construction,we establish an air–concrete coupled heat transfer model according to the principles of conjugate heat transfer,and the accuracy of the model is verified through experiments.Furthermore,we conduct a case study to analyze the impact of airflow within the ship lock corridor on concrete temperature and creep stress.The results demonstrate that enhancing airflow within the corridor can significantly reduce the maximum concrete temperature.Compared with cases in which airflow within the corridor is neglected,the maximum concrete temperature and maximum tensile stress can be reduced by 12.5℃ and 0.7 MPa,respectively,under a wind speed of 4 m/s.The results of the traditional calculation method are relatively close to those obtained at a wind speed of 1 m/s.However,the temperature reduction process in the traditional method is faster,and the method yields greater tensile stress values for the corridor location.

Characteristics of transfer zones under the influence of preexisting faults and regional stress transformation:Wenchang A subsag,Zhujiang River Mouth Basin,northern South China Sea

A transfer zone in rift basins preserves important information on regional tectonic evolution and plays significant roles in hydrocarbon accumulation.Based on the systematic analysis of 3D seismic data and hydrocarbon accumulation conditions,the geometry,kinematics,and reservoir control of a large synthetic overlapping transfer zone in the south of the Wenchang A subsag in the Zhujiang(Pearl)River Mouth basin were investigated.Results indicate that the development and evolution of the transfer zone was controlled by the interaction between pre-existing faults and regional stress transformation.The intense rifting of the main faults of the transfer zone controlled the development of source rocks and faultcontrolled slope break paleogeomorphology.The strike-slip overprint since the Oligocene is conducive to the formation of a large-scale fault-anticline trap,and the secondary faults in the transfer zone contribute to the hydrocarbon transportation.The conjugate intersection area of the NE-and NW-trending faults offers more opportunity for hydrocarbon migration and accumulation.

Stress Transfer and the Impact of the India-Eurasia Collision and the Western Pacific Subduction on the Geodynamics of the Asian Continent

The interaction between the India-Eurasia collision and the Western Pacific subduction and their contribution to recent geodynamics of the Asian continent are discussed. We perform a comparative analysis of the data available from world literature and new data on the slow strain and earthquake migration from the India-Eurasia collision and the Western Pacific subduction zones. Based on the concepts of wave dynamics of the deformation processes, a localization scheme is constructed illustrating the migration of slow strain fronts in central and eastern Asia, and the wave geodynamic impact of collision and subduction on the Asian continent is shown.

Dual-Porosity Apparent Permeability Models of Unconventional Gas Migration Based on Biot’s Porous Media

Stress-dependent permeability models are developed for the organic pores and inorganic cleats/fractures in unconventional gas reservoirs,which are modeled as Biot’s porous media of dual-porosity.Further considering multiple flow mechanisms such as dynamic effects of gas flow and surface diffusion,apparent permeability models are obtained to investigate the characteristics of unconventional gas migration.Compared to the gas transfer in single-porosity reservoirs,the gas migration ability of cleats in dual-porosity stratums rarely changes while that of organic pores is greatly improved because cleats sustain major geomechanical shrinkage deformation when the pore pressure drops.Further,the mass flux of reservoirs is dominated by the mass flux of cleats,which has a lower peak value,but a much longer production term than those in single-porosity reservoirs due to the interaction between organic pores and cleats.Parametric analysis is conducted to identify key factors significantly impacting mass flux in unconventional reservoirs.Reasons for the mass flux variation are also explored in terms of gas migration ability and pore pressure distribution.

Transfer and migration of polycyclic aromatic hydrocarbons in soil irrigated with long-term wastewater

In order to investigate the transfer and migration behavior of polycyclic aromatic hydrocarbons(PAHs)in soil with long-term wastewater irrigation,Groundwater Ubiquity Score(GUS)and fugacity method were respectively used to assess the potential entry into the groundwater and transfer capacity of PAHs.The results of assessment using GUS show that there is significant correlation between the GUS and organic carbon sorption coefficient(KOC)for PAHs and a simple assessment method with KOC was referred to evaluate contamination of groundwater.Applying fugacity method,evaluation results of transfer and migration of PAHs in soil suggest that the PAHs accumulation in the soil through long-term wastewater irrigation could be re-volatilized as secondary emission sources to atmosphere for the Low Molecular Weight(LMW)PAHs,in contrast to High Molecular Weight(HMW)PAHs for which the soil remains a sink that could absorb more PAHs.The net volatilisation flux was 0.39 g/d in upland and 0.32 g/d in paddy for LMW Nap(Naphthalene),and 0.97×10^(-3)g/d in upland and 0.37×10^(-3)g/d in paddy for LMW Phe(Phenanthrene).The net deposition was 0.72×10^(-4)g/d in upland and 0.10×10^(-3)g/d in paddy for HMW Fla(Fluoranthene),and 0.22×10^(-4)g/d in upland and 0.20×10^(-4)g/d in paddy for HMW Bap(Benzo[a]pyrene).Sensitivities of the model estimates to input parameters were tested,and the sensitivity coefficient was defined for the test.The most influential parameters were the volumes of the air,water,and organic carbon fractions in soil and the thickness of the soil.

Boosting the Energy Migration Upconversion through Inter-Shell Energy Transfer in Tb^(3+)-Doped Sandwich Structured Nanocrystals

It remained challenging to fabricate Tb^(3+)-doped lanthanide nanocrystals(NCs)to simultaneously acquire strong energy migration upconversion(EMU)emissions of Tb^(3+)while suppressing the Tm3+UV upconversion emissions that cause background biofluorescence issues in bioapplications based on Tb^(3+)-doped EMU NCs.Herein,we report a novel sandwich structured core@shell@shell scheme for the design of EMU NCs,for example,NaLuF4∶Yb/Gd@NaGdF4∶Tm@NaLuF4∶Tb NCs,wherein Yb^(3+),Tm^(3+),and Tb^(3+)are incorporated separately into the inner core,middle shell,and outer shell,respectively.We found that in the sandwich structured NCs,the effective inter-shell energy transfer from Gd^(3+)in the middle shell to Tb^(3+)in the outer shell accelerated the Yb^(3+)-Tm^(3+)five-photon upconversion and the subsequent Tm^(3+)to Gd^(3+)energy transfer processes,which could eventually lead to almost complete inhibition of Tm^(3+)UV upconversion emissions,concurrent with the strong EMU emissions of Tb^(3+).Our findings might stimulate new concepts for manipulating upconversion emissions of lanthanide NCs.

Finite element analysis of the effect of interlayer on interfacial stress transfer in layered graphene nanocomposites

Understanding the roles of interlayers in reinforcement efficiencies by layered graphene is very important in order to produce strong and light graphene based nanocomposites. The present paper uses the finite element method to evaluate the interfacial strain transfers and reinforcement efficiencies in layered graphene-polymer composites. Results indicate that the presence of compliant interlayers in layered graphene plays significant roles in the transfers of strain/stress from matrix to graphene and subsequently the reinforcement effectiveness of layered graphene. In general, the magnitude of shear strain transferred onto the rigid graphene decreases as the thickness of the interlayer increases. This trend becomes insignificant as the graphene becomes sufficiently large(s>25,000). The shear strain at the interface of graphene-matrix is also greatly influenced by the interlayer modulus. A stiffer interlayer would result in a higher shear strain transferred on the graphene. The performance of the interlayers is further affected by the property of the composite and the architecture of the layered graphene stack. If a composite contains more graphene phase, the efficiency of reinforcement by a layered graphene becomes improved. If a graphene stack contains more interlayers, the effectiveness of reinforcement at the edges of the graphene becomes negatively affected.

Stagnation-point flow of couple stress fluid with melting heat transfer

Melting heat transfer in the boundary layer flow of a couple stress fluid over a stretching surface is investigated. The developed differential equations are solved for homotopic solutions. It is observed that the velocity and the boundary layer thickness are decreasing functions of the couple stress fluid parameter. However, the temperature and surface heat transfer increase when the values of the couple stress fluid parameter increase. The velocity and temperature fields increase with an increase in the melting process of the stretching sheet.