Replacing platinum for catalyzing hydrogen evolution reaction （HER） in acidic medium remains great chal- lenges. Herein, we prepared few-layered MoS2 by ball milling as an efficient catalyst for HER in acidic medium...Replacing platinum for catalyzing hydrogen evolution reaction （HER） in acidic medium remains great chal- lenges. Herein, we prepared few-layered MoS2 by ball milling as an efficient catalyst for HER in acidic medium, The activity of as-prepared MoS2 had a strong dependence on the ball milling time, Furthermore, Ketjen Black EC 300J was added into the ball-milled MoS2 followed by a second ball milling, and the resultant MoS2/carbon black hybrid material showed a much higher HER activity than MoS2 and carbon black alone. The enhanced activity of the MoS2/carbon black hybrid material was attributed to the increased abundance of catalytic edge sites of MoS） and excellent electrical coupling to the underlving carbon network.展开更多
火电机组磨煤机存在运行条件恶劣、故障频发等问题,对磨煤机进行故障预警,可以有效防止一些常见故障的发生,从而保证火电机组的安全运行。为此,提出一种基于相互邻近度的密度峰值聚类和多元状态估计的磨煤机故障预警方法。首先,采用核...火电机组磨煤机存在运行条件恶劣、故障频发等问题,对磨煤机进行故障预警,可以有效防止一些常见故障的发生,从而保证火电机组的安全运行。为此,提出一种基于相互邻近度的密度峰值聚类和多元状态估计的磨煤机故障预警方法。首先,采用核主元分析选取磨煤机的主要状态参数,同时采用集合经验模态分解对历史运行数据进行去噪,进一步优化数据质量;然后,采用基于相互邻近度的密度峰值聚类(density peaks clustering based on mutual neighborhood degrees,DPC-MND)方法构建动态记忆矩阵,利用多元状态估计技术(multivariate state estimation techniques,MSET)对磨煤机正常运行工况下的历史数据进行建模,并确定磨煤机的运行状态。最后,以安徽某电厂ZGM113G型中速磨煤机为例进行验证,结果表明该方法可以实现对磨煤机故障的有效预警。展开更多
基金the financial support from the Ministry of Science and Technology of China (grants 2012CB215500 and 2013CB933100)the National Natural Science Foundation of China (grants 21573222 and 21103178)
文摘Replacing platinum for catalyzing hydrogen evolution reaction （HER） in acidic medium remains great chal- lenges. Herein, we prepared few-layered MoS2 by ball milling as an efficient catalyst for HER in acidic medium, The activity of as-prepared MoS2 had a strong dependence on the ball milling time, Furthermore, Ketjen Black EC 300J was added into the ball-milled MoS2 followed by a second ball milling, and the resultant MoS2/carbon black hybrid material showed a much higher HER activity than MoS2 and carbon black alone. The enhanced activity of the MoS2/carbon black hybrid material was attributed to the increased abundance of catalytic edge sites of MoS） and excellent electrical coupling to the underlving carbon network.
文摘火电机组磨煤机存在运行条件恶劣、故障频发等问题,对磨煤机进行故障预警,可以有效防止一些常见故障的发生,从而保证火电机组的安全运行。为此,提出一种基于相互邻近度的密度峰值聚类和多元状态估计的磨煤机故障预警方法。首先,采用核主元分析选取磨煤机的主要状态参数,同时采用集合经验模态分解对历史运行数据进行去噪,进一步优化数据质量;然后,采用基于相互邻近度的密度峰值聚类(density peaks clustering based on mutual neighborhood degrees,DPC-MND)方法构建动态记忆矩阵,利用多元状态估计技术(multivariate state estimation techniques,MSET)对磨煤机正常运行工况下的历史数据进行建模,并确定磨煤机的运行状态。最后,以安徽某电厂ZGM113G型中速磨煤机为例进行验证,结果表明该方法可以实现对磨煤机故障的有效预警。
