Previously, most ocean circulation models have overlooked the role of the surface waves. As a result, these models have produced insufficient vertical mixing, with an under - prediction of the ,nixing layer （ML） dep...Previously, most ocean circulation models have overlooked the role of the surface waves. As a result, these models have produced insufficient vertical mixing, with an under - prediction of the ,nixing layer （ML） depth and an over - prediction of the sea surface temperature （SST）, particularly during the summer season. As the ocean surface layer determines the lower boundary conditions of the atmosphere, this deficiency has severely limited the performance of the coupled ocean - atmospheric models and hence the climate studies. To overcome this shortcoming, a new parameterization for the wave effects in the ML model that will correct this systematic error of insufficient mixing. The new scheme has enabled the mixing layer to deepen, the surface excessive heating to be corrected, and an excellent agreement with observed global climatologic data. The study indicates that the surface waves are essential for ML formation, and that they are the primer drivers of the upper ocean dynamics; therefore, they are critical for climate studies.展开更多
Discontinuous Galerkin（DG） method is known to have several advantages for flow simulations,in particular,in fiexible accuracy management and adaptability to mesh refinement. In the present work,the DG method is deve...Discontinuous Galerkin（DG） method is known to have several advantages for flow simulations,in particular,in fiexible accuracy management and adaptability to mesh refinement. In the present work,the DG method is developed for numerical simulations of both temporally and spatially developing mixing layers. For the temporally developing mixing layer,both the instantaneous fiow field and time evolution of momentum thickness agree very well with the previous results. Shocklets are observed at higher convective Mach numbers and the vortex paring manner is changed for high compressibility. For the spatially developing mixing layer,large-scale coherent structures and self-similar behavior for mean profiles are investigated. The instantaneous fiow field for a three-dimensional compressible mixing layer is also reported,which shows the development of largescale coherent structures in the streamwise direction. All numerical results suggest that the DG method is effective in performing accurate numerical simulations for compressible shear fiows.展开更多
Numerical simulation of nanoparticle nucleation and coagulation in a mixing layer with sulfuric acid vapor binary system is performed using the large eddy simulation and the direct quadrature method of moment. The dis...Numerical simulation of nanoparticle nucleation and coagulation in a mixing layer with sulfuric acid vapor binary system is performed using the large eddy simulation and the direct quadrature method of moment. The distributions of number concentration, volume concentration, and average diameter of nanoparticles are obtained. The results show that the coherent structures have an important effect on the distributions of number concentration, volume concentration and average diameter of nanoparticles via continuously transporting and diffusing the nanoparticles to the area of low particle concentration. In the streamwise direction, the number concentration of nanoparticles decreases, while the volume concentration and the average diameter increase. The distributions of number concentration, volume concentration and average diameter of nanoparticles are spatially inhomogeneous. The characteristic time of nucleation is shorter than that of coagulation. The nucleation takes place more easily in the area of low temperature because where the number concentration of nanoparticles is high, while the intensity of coagulation is mainly affected by the number concentration. Both nucleation and coagulation result in the variation of average diameter of nanoparticles.展开更多
The co-variation of surface wind speed and sea surface temperature (SST) over the Gulf Stream frontal region is investigated using high-resolution satellite measurements and atmospheric reanalysis data. Results show t...The co-variation of surface wind speed and sea surface temperature (SST) over the Gulf Stream frontal region is investigated using high-resolution satellite measurements and atmospheric reanalysis data. Results show that the pattern of positive SST-surface wind speed correlations is anchored by strong SST gradient and marine atmospheric boundary layer (MABL) height front, with active warm and cold-ocean eddies around. The MABL has an obvious transitional structure along the strong SST front, with greater (lesser) heights over the north (south) side. The significant positive SST-surface wind-speed perturbation correlations are mostly found over both strong warm and cold eddies. The surface wind speed increases (decreases) about 0.32 (0.41) m/s and the MABL elevates (drops) approximate 55 (54) m per 1℃ of SST perturbation induced by warm (cold) eddies. The response of the surface wind speed to SST perturbations over the mesoscale eddies is mainly attributed to the momentum vertical mixing in the MABL, which is confirmed by the linear relationships between the downwind (crosswind) SST gradient and wind divergence (curl).展开更多
A series of layered mixed oxides La 4BaCu 5-x Mn x O 13+λ ( x =0—5) was prepared, characterized and used as catalysts for NO+CO reaction. It was found that all the samples were single phase having a structure with f...A series of layered mixed oxides La 4BaCu 5-x Mn x O 13+λ ( x =0—5) was prepared, characterized and used as catalysts for NO+CO reaction. It was found that all the samples were single phase having a structure with five layered perovskite. La 4BaCu 2Mn 3O 13+λ showed the highest activity in the title reaction, this could be attributed to the synergetic effect between Cu and Mn. The results of TPR, TPD and excess oxygen investigations confirmed that the Cu ion would be the active center. The displacement of the Cu ion by Mn caused the Cu ion to be more easily reducible and more content of excess oxygen, and it was beneficial to the activity of the catalyst. The reaction mechanism was also proposed.展开更多
The mixed oxides, including LaBa\-2Cu\-3O\-7, LaBaCu\-2O\-5, La\-4BaCu\-5O 12 with perovskite structure, were prepared. The catalysts were characterized by means of chemical analysis, XRD, H\-2_TPR. It was found that ...The mixed oxides, including LaBa\-2Cu\-3O\-7, LaBaCu\-2O\-5, La\-4BaCu\-5O 12 with perovskite structure, were prepared. The catalysts were characterized by means of chemical analysis, XRD, H\-2_TPR. It was found that their structures were layered ABO\-3 perovskite structure and they were the active catalysts for the NO reduction by CO. The existance of Cu 3+ is an important factor to give the catalysts a high activity for the NO reduction by CO.展开更多
基金The National Natural Science Foundation of China No.40730842the"973"project of China under contract No.2006CB403605
文摘Previously, most ocean circulation models have overlooked the role of the surface waves. As a result, these models have produced insufficient vertical mixing, with an under - prediction of the ,nixing layer （ML） depth and an over - prediction of the sea surface temperature （SST）, particularly during the summer season. As the ocean surface layer determines the lower boundary conditions of the atmosphere, this deficiency has severely limited the performance of the coupled ocean - atmospheric models and hence the climate studies. To overcome this shortcoming, a new parameterization for the wave effects in the ML model that will correct this systematic error of insufficient mixing. The new scheme has enabled the mixing layer to deepen, the surface excessive heating to be corrected, and an excellent agreement with observed global climatologic data. The study indicates that the surface waves are essential for ML formation, and that they are the primer drivers of the upper ocean dynamics; therefore, they are critical for climate studies.
基金supported by the National Natural Science Foundation of China (90716008,10572004 and 10921202)MOST 973 Project (2009CB724100) and CSSA
文摘Discontinuous Galerkin（DG） method is known to have several advantages for flow simulations,in particular,in fiexible accuracy management and adaptability to mesh refinement. In the present work,the DG method is developed for numerical simulations of both temporally and spatially developing mixing layers. For the temporally developing mixing layer,both the instantaneous fiow field and time evolution of momentum thickness agree very well with the previous results. Shocklets are observed at higher convective Mach numbers and the vortex paring manner is changed for high compressibility. For the spatially developing mixing layer,large-scale coherent structures and self-similar behavior for mean profiles are investigated. The instantaneous fiow field for a three-dimensional compressible mixing layer is also reported,which shows the development of largescale coherent structures in the streamwise direction. All numerical results suggest that the DG method is effective in performing accurate numerical simulations for compressible shear fiows.
基金supported by the Major Program of National Natural Science Foundation of China (10632070)
文摘Numerical simulation of nanoparticle nucleation and coagulation in a mixing layer with sulfuric acid vapor binary system is performed using the large eddy simulation and the direct quadrature method of moment. The distributions of number concentration, volume concentration, and average diameter of nanoparticles are obtained. The results show that the coherent structures have an important effect on the distributions of number concentration, volume concentration and average diameter of nanoparticles via continuously transporting and diffusing the nanoparticles to the area of low particle concentration. In the streamwise direction, the number concentration of nanoparticles decreases, while the volume concentration and the average diameter increase. The distributions of number concentration, volume concentration and average diameter of nanoparticles are spatially inhomogeneous. The characteristic time of nucleation is shorter than that of coagulation. The nucleation takes place more easily in the area of low temperature because where the number concentration of nanoparticles is high, while the intensity of coagulation is mainly affected by the number concentration. Both nucleation and coagulation result in the variation of average diameter of nanoparticles.
基金Supported by the China’s National Key Research and Development Projects(No.2016YFA0601803)the National Natural Science Foundation of China(Nos.41490641,41521091,U1606402)the Qingdao National Laboratory for Marine Science and Technology(No.2017ASKJ01)
文摘The co-variation of surface wind speed and sea surface temperature (SST) over the Gulf Stream frontal region is investigated using high-resolution satellite measurements and atmospheric reanalysis data. Results show that the pattern of positive SST-surface wind speed correlations is anchored by strong SST gradient and marine atmospheric boundary layer (MABL) height front, with active warm and cold-ocean eddies around. The MABL has an obvious transitional structure along the strong SST front, with greater (lesser) heights over the north (south) side. The significant positive SST-surface wind-speed perturbation correlations are mostly found over both strong warm and cold eddies. The surface wind speed increases (decreases) about 0.32 (0.41) m/s and the MABL elevates (drops) approximate 55 (54) m per 1℃ of SST perturbation induced by warm (cold) eddies. The response of the surface wind speed to SST perturbations over the mesoscale eddies is mainly attributed to the momentum vertical mixing in the MABL, which is confirmed by the linear relationships between the downwind (crosswind) SST gradient and wind divergence (curl).
文摘A series of layered mixed oxides La 4BaCu 5-x Mn x O 13+λ ( x =0—5) was prepared, characterized and used as catalysts for NO+CO reaction. It was found that all the samples were single phase having a structure with five layered perovskite. La 4BaCu 2Mn 3O 13+λ showed the highest activity in the title reaction, this could be attributed to the synergetic effect between Cu and Mn. The results of TPR, TPD and excess oxygen investigations confirmed that the Cu ion would be the active center. The displacement of the Cu ion by Mn caused the Cu ion to be more easily reducible and more content of excess oxygen, and it was beneficial to the activity of the catalyst. The reaction mechanism was also proposed.
文摘The mixed oxides, including LaBa\-2Cu\-3O\-7, LaBaCu\-2O\-5, La\-4BaCu\-5O 12 with perovskite structure, were prepared. The catalysts were characterized by means of chemical analysis, XRD, H\-2_TPR. It was found that their structures were layered ABO\-3 perovskite structure and they were the active catalysts for the NO reduction by CO. The existance of Cu 3+ is an important factor to give the catalysts a high activity for the NO reduction by CO.
