Here some steady-state experiments on oxidation of CO on Pd were performed on a molecular beam apparatus. It is found that the characteristics of the rate of CO_2 formation r versus substrate temperature T are depende...Here some steady-state experiments on oxidation of CO on Pd were performed on a molecular beam apparatus. It is found that the characteristics of the rate of CO_2 formation r versus substrate temperature T are dependent on the ratio P=P_(CO)/P_(O2) in the mixed beam. These characteristics are related to the complicated interactions of co-adsorbed CO and O particles on Pd surface.展开更多
The mechanical properties of cementitious sand and gravel damming material have been experimentally determined by means of microscopic SEM(Scanning Electron Microscopy)image analysis.The results show that the combinat...The mechanical properties of cementitious sand and gravel damming material have been experimentally determined by means of microscopic SEM(Scanning Electron Microscopy)image analysis.The results show that the combination of fly ash and water can fill the voids in cemented sand and gravel test blocks because of the presence of hydrated calcium silicate and other substances;thereby,the compactness and mechanical properties of these materials can be greatly improved.For every 10 kg/m^(3) increase in the amount of cementitious material,the density increases by about 2%,and the water content decreases by 0.2%.The amount of cementitious material used in the sand and gravel in these tests was 80-110 kg/m^(3),the water-binder ratio was 1-1.50.Moreover,the splitting tensile strength was 1/10 of the compressive strength,and the maximum strength was 7.42 MPa at 90 d.The optimal mix ratio has been found to be 50 kg of cement,60 kg of fly ash and 120 kg of water(C50F60W120).The related dry density was 2.6 g/cm^(3),the water content was 6%,and the water-binder ratio was 1.09.展开更多
Methane (CH4) emissions estimated with the Intergovernmental Panel on Climate Change (IPCC) inventory method at the city and regional scale are subject to large uncertainties.In this study,we determined the CH4:C...Methane (CH4) emissions estimated with the Intergovernmental Panel on Climate Change (IPCC) inventory method at the city and regional scale are subject to large uncertainties.In this study,we determined the CH4:CO2 emissions ratio for both Nanjing and the Yangtze River Delta (YRD),using the atmospheric CH4 and CO2 concentrations measured at a suburban site in Nanjing in the winter.The atmospheric estimate of the CH4:CO2 emissions ratio was in reasonable agreement with that calculated using the IPCC method for the YRD (within 20%),but was 200% greater for the municipality of Nanjing.The most likely reason for the discrepancy is that emissions from unmanaged landfills are omitted from the official statistics on garbage production.展开更多
Starch/polylactic acid(PLA) composites were prepared by melt extrusion, with corn starch and PLA as raw materials, glycerol as the plasticizer. Effects of starch/PLA ratio on the interdependence of two-phase and other...Starch/polylactic acid(PLA) composites were prepared by melt extrusion, with corn starch and PLA as raw materials, glycerol as the plasticizer. Effects of starch/PLA ratio on the interdependence of two-phase and other properties of the composites were studied. The combination of results of TGA with SEM indicated that the interdependence between starch and PLA was increased gradually as the starch/PLA ratio reduced. DSC results showed that the glass transition temperature(Tg), melting temperature(Tm) and degree of crystallinity of PLA in composites were increased gradually, whereas the cold crystallization temperature(Tc) was gradually decreased as the starch/PLA ratio reduced. The rheological properties of composites were closely related with the interdependence of two-phase, with reducing starch/PLA proportion, the interdependence was increased, and then the strain for storage modulus was firstl reduced and then gradually increased. Frequency scanning showed that the storage modulus and complex viscosity were decreased with reducing starch content. As the starch/PLA ratio reduced, the matrix phase PLA was increased, so that the strength of composites was increased gradually, whereas water absorption rate was decreased gradually.展开更多
A topographic target light scattering-differential optical absorption spectroscopy ('IbTaL-DOA~) system is de- veloped for measuring average concentrations along a known optical path and studying surface-near distr...A topographic target light scattering-differential optical absorption spectroscopy ('IbTaL-DOA~) system is de- veloped for measuring average concentrations along a known optical path and studying surface-near distributions of atmospheric trace gases. The telescope of the ToTaL-DOAS system points to targets which are located at known dis- tances from the measurement device and illuminated by sunlight. Average concentrations with high spatial resolution can be retrieved by receiving sunlight reflected from the targets, A filed measurement of NO2 concentration is performed with the ToTaL-DOAS system in Shijiazhuang in the autumn of 2011. The measurement data are compared with con- centrations measured by the point monitoring technique at the same site. The results show that the ToTaL-DOAS system is sensitive to the variation of NO2 concentrations along the optical path.展开更多
In recent years, the rationalization of concrete mix ratios which batches equal volumes of sand and gravel in building projects has been gaining grounds in the Cameroon construction industry. The main objective of thi...In recent years, the rationalization of concrete mix ratios which batches equal volumes of sand and gravel in building projects has been gaining grounds in the Cameroon construction industry. The main objective of this study is therefore to investigate if the concrete produced with rationalized mix ratio can be adopted as conventional mix ratio in terms of minimum required compression strength of concrete for buildings. Specifically this work compared the conventional mix ratio of 350 kg of cement: 400 liters of sand: 800 liters of gravel for a cubic meter and the rationalized batch of 350 kg of cement: 600 liters of sand: 600 liters of 5/15 gravel, 15/25 gravel and a combination of 5/15 + 15/25 gravel. Average compressive tests’results for both the conventional and the rationalized mix ratios were found to meet the minimum compressive strength of 65% at 7 days, 90% at 14 days and 99% at 28 days for gravel size combination 5/15 + 15/25. Single size gravel of 5/15 and 15/25 did not meet the minimum required compressive strength of 20 N/mm<sup>2</sup> for the rationalized mix ratio at 28 days curing based on the minimum compressive strength required, this study arrives at the conclusion that the equal volumes of sand and gravel mix ratio of 350 kg/m<sup>3</sup> of cement: 600 liters of sand: 600 liters of gravel mix ratio can be adopted as a conventional concrete mix ratio for gravel size 5/15 + 15/25.展开更多
Considering actual construction conditions of Binchuan-Heqing Highway,this paper provides the C50 mix ratio conforming to engineering requirements by strictly controlling the quality of raw materials,optimizing the de...Considering actual construction conditions of Binchuan-Heqing Highway,this paper provides the C50 mix ratio conforming to engineering requirements by strictly controlling the quality of raw materials,optimizing the design of mix ratio scientifically,preparing superior C50 concrete 0 with manufactured sand,and optimizing the concrete mix ratio based on the adjustment of fly ash replacement,water-cement ratio,polycarboxylate-type water reducer mixing amount,sand ratio,etc.The result indicates that,the water-cement ratio has a great influence on the concrete strength,and if the ratio of coal ash is high in the binding material,the early compressive strength of the concrete will increase slowly.展开更多
Objective Body fluid mixtures are complex biological samples that frequently occur in crime scenes,and can provide important clues for criminal case analysis.DNA methylation assay has been applied in the identificatio...Objective Body fluid mixtures are complex biological samples that frequently occur in crime scenes,and can provide important clues for criminal case analysis.DNA methylation assay has been applied in the identification of human body fluids,and has exhibited excellent performance in predicting single-source body fluids.The present study aims to develop a methylation SNaPshot multiplex system for body fluid identification,and accurately predict the mixture samples.In addition,the value of DNA methylation in the prediction of body fluid mixtures was further explored.Methods In the present study,420 samples of body fluid mixtures and 250 samples of single body fluids were tested using an optimized multiplex methylation system.Each kind of body fluid sample presented the specific methylation profiles of the 10 markers.Results Significant differences in methylation levels were observed between the mixtures and single body fluids.For all kinds of mixtures,the Spearman’s correlation analysis revealed a significantly strong correlation between the methylation levels and component proportions(1:20,1:10,1:5,1:1,5:1,10:1 and 20:1).Two random forest classification models were trained for the prediction of mixture types and the prediction of the mixture proportion of 2 components,based on the methylation levels of 10 markers.For the mixture prediction,Model-1 presented outstanding prediction accuracy,which reached up to 99.3%in 427 training samples,and had a remarkable accuracy of 100%in 243 independent test samples.For the mixture proportion prediction,Model-2 demonstrated an excellent accuracy of 98.8%in 252 training samples,and 98.2%in 168 independent test samples.The total prediction accuracy reached 99.3%for body fluid mixtures and 98.6%for the mixture proportions.Conclusion These results indicate the excellent capability and powerful value of the multiplex methylation system in the identification of forensic body fluid mixtures.展开更多
Based on the vertical ozone reanalysis data and total ozone column data derived from the European Centre for Medium-Range Weather Forecasts,the spatial and temporal distribution characteristics of ozone on each isobar...Based on the vertical ozone reanalysis data and total ozone column data derived from the European Centre for Medium-Range Weather Forecasts,the spatial and temporal distribution characteristics of ozone on each isobaric surface in the troposphere over the Northwest Pacific Ocean were analyzed,and the backward trajectory method was used to track the influence of typhoon on the distribution of ozone.The results show that the updraft near the typhoon center transported the air with low O_(3)content in the lower layer to the upper layer,which reduced O_(3)content in the upper layer and formed a low-value area of O_(3).The variation trend of total ozone column in the regions where typhoons"Megi"and"Fengshen"occurred was analyzed by the case analysis method.It is found that there was a low-value area of total ozone column anomaly near the typhoon center,and there was a certain correlation between typhoon intensity PDI and total ozone column anomaly at the development and maturity stages of typhoons.展开更多
Numerical simulations of two heavy rainfall cases in the Changjiang-Huaihe River basin are performed with TRMM/PR (precipitation radar) data incorporated into the PSU/NCAR meso scale model MM5. The mixing ratio of rai...Numerical simulations of two heavy rainfall cases in the Changjiang-Huaihe River basin are performed with TRMM/PR (precipitation radar) data incorporated into the PSU/NCAR meso scale model MM5. The mixing ratio of rainwater q <SUB>r</SUB> is obtained from the R −q <SUB>r</SUB> relation (R is the rainfall rate), and the mixing ratio of water vapor q <SUB>v</SUB> in the model is replaced by q <SUP>1</SUP>′<SUB>v</SUB> = q <SUB>v</SUB>+q <SUB>r</SUB>. Then, TRMM/PR data are used to modify humidity analysis obtained from conventional radiosonde data, and sensitivity experiments (STE) are performed and compared to control experiments (CTL). Results show that both the heavy rainfall distribution and its maximum amounts from STE are improved compared with those from CTL.展开更多
Experiments were carried out to ascertain multichannel discharge characteristics in a self-designed coaxial field-distortion gas switch filled with SFa-N2 or SF6-Ar gas mixtures of different mixing ratios. In these ex...Experiments were carried out to ascertain multichannel discharge characteristics in a self-designed coaxial field-distortion gas switch filled with SFa-N2 or SF6-Ar gas mixtures of different mixing ratios. In these experiments, the pressure varied from 0.1 MPa to 0.2 MPa, the voltage pulse peak applied to the switch was in the range from 40 kV to 78 kV, and the pulse rise time was 11 ns. The static breakdown strength of the gas switch gap in the switch was also measured. The results show that in general the average number of discharge channels for SF6-Ar or SF6-N2 gas mixture which contains less SFa is larger than that for gas mixture which contains more SF6, however, the average number of channels almost keeps constant as the gas mixing ratio varies when the pulse rise rate is high enough. The static breakdown strength of the gas switch gap decreases slightly as the content of argon or nitrogen increases.展开更多
Regulated and unregulated emissions from four passenger cars fueled with methanol/gasoline blends at different mixing ratios (M15,M20,M30,M50,M85 and M100) were tested over the New European Driving Cycle (NEDC).Vo...Regulated and unregulated emissions from four passenger cars fueled with methanol/gasoline blends at different mixing ratios (M15,M20,M30,M50,M85 and M100) were tested over the New European Driving Cycle (NEDC).Volatile organic compounds (VOCs) were sampled by Tenax TA and analyzed by thermal desorption-gas chromatograph/mass spectrometer (TD-GC/MS).Carbonyls were trapped on dinitrophenylhydrazine (DNPH) cartridges and analyzed by high performance liquid chromatography (HPLC).The results showed that total emissions of VOCs and BTEX (benzene,toluene,ethylbenzene,p,m,o-xylene) from all vehicles fueled with methanol/gasoline blends were lower than those from vehicles fueled with only gasoline.Compared to the baseline,the use of M85 decreased BTEX emissions by 97.4%,while the use of M15 decreased it by 19.7%.At low-to-middle mixing ratios (M15,M20,M30 and M50),formaldehyde emissions showed a slight increase while those of high mixing ratios (M85 and M100) were three times compared with the baseline gasoline only.When the vehicles were retrofitted with new three-way catalytic converters (TWC),emissions of carbon monoxide (CO),total hydrocarbon (THC),and nitrogen oxides (NOx) were decreased by 24%–50%,10%–35%,and 24%–58% respectively,compared with the cars using the original equipment manufacture (OEM) TWC.Using the new TWC,emissions of formaldehyde and BTEX were decreased,while those of other carbonyl increased.It is necessary that vehicles fueled with methanol/gasoline blends be retrofitted with a new TWC.In addition,the specific reactivity of emissions of vehicles fueled with M15 and retrofitted with the new TWC was reduced from 4.51 to 4.08 compared to the baseline vehicle.This indicates that the use of methanol/gasoline blend at a low mixing ratio may have lower effect on environment than gasoline.展开更多
In order to implement the objective mix design of hot mix asphalt adequately during the construction process, the significance of objective mixing ratio was elaborated, and the variability of materials and its control...In order to implement the objective mix design of hot mix asphalt adequately during the construction process, the significance of objective mixing ratio was elaborated, and the variability of materials and its control method were analyzed. An engineering example is used to illustrate the debugging process of asphalt mixture batching & mixing plant and the dynamic quality management methods. The results show that the set of methods can not only implement the objective mixing ratio of hot mix asphalt adequately, but also control production during the construction process effectively.展开更多
A simple method for estimating the contributions of mineral dust to PM2.5, PM10, or TSP is presented. The method is based on the assumption of external mixing of two types of particles with different PM2.5/PM10 ratios...A simple method for estimating the contributions of mineral dust to PM2.5, PM10, or TSP is presented. The method is based on the assumption of external mixing of two types of particles with different PM2.5/PM10 ratios, The method was applied to local and transported dust events observed in Tsukuba, Japan, and was compared with collocated polarization lidar measurements. The method was then applied to three dust events that occurred in Oki, Rishiri, and Ochiishi,Japan, in 2012. The results showed that the method was useful for detecting mineral dust and for qualitatively describing the mixing of dust with anthropogenic aerosols.展开更多
The object of this study was to determine the proper mixing ratio of fresh rice straw to corn steep liquor(CSL) to obtain a high protein content silage feed. The following experimental silages were generated: the cont...The object of this study was to determine the proper mixing ratio of fresh rice straw to corn steep liquor(CSL) to obtain a high protein content silage feed. The following experimental silages were generated: the control(C1), composed of fresh rice straw without CSL additive, mixed with CSL in the ratios of 4:1(C4),3:1(C3) and 2:1(C2). Lactic acid bacteria(LAB) inoculant was applied at the rate of 50 mL/kg(fresh basis)of forage to achieve a final application rate of 1 x 10~6 cfu/g of fresh matter(FM). Duplicate silos for each treatment were opened after 0,3, 7,10,20,30,45 and 60 d for microbiological and chemical analysis. The results showed that the addition of CSL significantly increased crude protein(CP) contents, and decreased neutral detergent fiber(NDF) and acid detergent fiber(ADF) contents of treatments after 60 d of ensiling(P < 0.05). The lactic acid contents in C4 and C3 were significantly higher than that in C1(P <0.05). In summary, mixing fresh rice straw with CSL at addition levels of 4:1(C4) and 3:1(C3) can improve the fermentation quality and nutrient composition of fresh rice straw silage. However, a large proportion of CSL(C3) had a negative impact on the aerobic stability of fresh rice straw.展开更多
Multiple types of oil inclusions with different fluorescence colors have been detected in the northern Dongpu depression.Recent evidences show that these inclusions may have been trapped simultaneously or during a ver...Multiple types of oil inclusions with different fluorescence colors have been detected in the northern Dongpu depression.Recent evidences show that these inclusions may have been trapped simultaneously or during a very short period.Therefore,whether these oils were mixed before trapping is unknown.In this study,we analyzed the petrography and fluorescence spectral characteristics of oil inclusions in the Wenliu uplift in the northern Dongpu depression,and assessed the data with the oil mixing ratio curve obtained in the previous experiment.The results show that there are three types of oil inclusions(type I,type II and type III)with yellow,green and blue fluorescence colors,corresponding to low-mature,medium-mature and high-mature oil,respectively.The"pure"oil inclusions,do exist in type II and type III group of oil inclusions,showing the medium-mature oil was generated from the source rock rather than being formed by the mixture of high-mature and low-mature end oils.Most of the oil inclusions are mixtures of high-mature and medium-mature end oils from the sub-sags to the Wenliu uplift,the mixing degree increases to close to 50%.The oil between the Qianliyuan sub-sag and the Wenliu uplift was mainly mixed by medium mature oils,whereas the oil between the Liutun sub-sag and the Wenliu uplift was mainly mixed by high mature oil.展开更多
The plant-made seedling-growing tray cultivation technique is an effective way to improve maize yield and quality in China’s cold northern area.However,the corn seedling nursery carrier and tray cultivation technique...The plant-made seedling-growing tray cultivation technique is an effective way to improve maize yield and quality in China’s cold northern area.However,the corn seedling nursery carrier and tray cultivation technique has been proved poor in adaptability.After comparing several nursery carriers,a design for a plant-made seedling-growing tray that is suitable for maize transplantation was proposed in which rice straw was used as the primary raw material.The preparation method,processing and structural dimensions of the tray were investigated and designed,five types of plant-made seedling-growing trays with different formulations were proposed.The shear mechanical properties and the shear strength of the plant-made seedling-growing trays were tested to determine the shear force needed for cutting through trays prepared with increasing mass ratios of rice straw and the effect of the shearing rate on the shear strength.The results showed that at a shearing rate of 100 mm/min,the maximum shear force decreased gradually as the mass ratio of straw was increased and that the hardness of the tray decreased as its shear strength decreased.Under three shearing rates(100 mm/min,200 mm/min and 500 mm/min)and a blade displacement of 10 mm,the shear force was the highest at the point at which the tray was cut through;the required shear force to cut through the tray then gradually decreased.Trays with the same straw composition showed no significant influence of shearing rate on the tray’s shear strength at shearing rates of 100 mm/min,200 mm/min or 500 mm/min.This study describes a multi-tray,single-strip nursery carrier for use in plant-made seedling-growing tray cultivation and proposes a theoretical basis for the design of a rotary transplanting device,the key part of a maize plant-made seedling-growing tray transplanter.展开更多
In this study, landfill leachate with and without pre-treatment was co-treated with municipal wastewater at different mixing ratios. The leachate pre-treatment was achieved by air stripping to removal ammonia. The obj...In this study, landfill leachate with and without pre-treatment was co-treated with municipal wastewater at different mixing ratios. The leachate pre-treatment was achieved by air stripping to removal ammonia. The objective of this study was to investigate the effect of landfill leachate on nutrient removal of the wastewater treatment process. It was demonstrated that when landfill leachate was co-treated with municipal wastewater, the high ammonia concentration in the leachate did not have a negative impact on the nitrification. The system was able to adapt to the environment and was able to improve nitrification capacity. The readily biodegradable portion of chemical oxygen demand(COD)in the leachate was utilized by the system to improve phosphorus and nitrate removal.However, this portion was small and majority of the COD ended up in the effluent thereby decreased the quality of the effluent. The study showed that the 2.5% mixing ratio of leachate with wastewater improved the overall biological nutrient removal process of the system without compromising the COD removal efficiency.展开更多
In the CO_(2)transcritical power cycle,conventional cooling water can hardly condense subcritical CO_(2)because its critical temperature is as low as 30.98°C.In order to avoid this condensing problem,CO_(2)-based...In the CO_(2)transcritical power cycle,conventional cooling water can hardly condense subcritical CO_(2)because its critical temperature is as low as 30.98°C.In order to avoid this condensing problem,CO_(2)-based mixtures have been proposed as working fluids for transcritical power cycle.They can raise the critical temperature by mixing a little C_(3)H_(8)as the secondary component to CO_(2).However,the flammability of the mixture may limit its application.This article investigated laminar flame speed of C_(3)H_(8)/CO_(2)which represents the mixture’s combustion characteristic by a so-called heat flux method and studied the inhibition mechanism of CO_(2)on the combustion based on the Premixed Laminar Flame-Speed Calculation reactor of Chemkin-Pro.The experimental results showed that the laminar flame speed shows a peak value with changing the equivalence ratio and accelerates with raising the mole fraction of the organic gas.Additionally,a slight upwards trend was observed for the corresponding equivalence ratio of the peaks.The flammable range for the equivalence ratio extended with the mole fraction of C_(3)H_(8)increasing.With the mole fraction of C_(3)H_(8)of 0.15,the maximum laminar flame speed was 12.8 cm/s,31.7%of that of the pure C_(3)H_(8).The flammable range was from 0.41 to 1.33,decreasing by 23.3%compared with that of C_(3)H_(8).A flammable critical mixing ratio was also found as 0.08/0.92 for C_(3)H_(8)/CO_(2)at the normal condition.By simulating,it was found that the most key free radical and elementary reaction which determine the inhibition of CO_(2)on the combustion are OH and H+O_(2)=O+OH,respectively.展开更多
Solid waste has interactions with its flue-gas products during combustion,which offers the possibility of regulating its pollutant emissions.Especially,these interaction pathways would be clearer under anaerobic condi...Solid waste has interactions with its flue-gas products during combustion,which offers the possibility of regulating its pollutant emissions.Especially,these interaction pathways would be clearer under anaerobic conditions when the chemical-looping combus-tion(CLC)process is used.The CLC experiments of multi-component solid waste were conducted on a homemade twin-bed reactor and the characteristics of flue gas were investigated for the effect of the mixing ratio of sewage sludge and polyvinyl chloride(PVC).The results indicated that the combustion efficiency was>99.9%for these CLC processes;the highest carbon-conversion rate was obtained at 96.3%for PVC with 60%sludge.The highest NO and SO_(2)emissions were 26%and 19%,respectively,when the sludge was mixed with 20%PVC.As the proportion of PVC blended into the sludge increased,the time when the concentration of NO in the flue-gas peaks moved backwards,while peak SO_(2)concentration moved forward.The general trend was to increase first and then de-crease.In addition,there were multiple peaks in carbon emissions,corresponding to~10%,30%and~70%of the carbon-conversion rate;nitrogen emissions reached 90%of total emissions before the carbon-conversion rate was 40%;sulphur emissions had a longer cycle and were mainly emitted between 10%and 60%of the carbon-conversion rate.The results are expected to provide a reference for solid-waste source suppressing to inhibit the generation of pollutants.展开更多
基金Project supported by National Natural Science Foundation of China
文摘Here some steady-state experiments on oxidation of CO on Pd were performed on a molecular beam apparatus. It is found that the characteristics of the rate of CO_2 formation r versus substrate temperature T are dependent on the ratio P=P_(CO)/P_(O2) in the mixed beam. These characteristics are related to the complicated interactions of co-adsorbed CO and O particles on Pd surface.
基金supported by the Scientific Research Fund of Yunnan Provincial Department of Education(2022Y286)15th Student Science and Technology Innovation and Entrepreneurship Action Fund Project of Yunnan Agricultural University(2022ZKX098)+1 种基金the Yunnan University Professional Degree Graduate Student Practical Innovation Fund Project(Grant Number ZC-22222374)the Scientific Research Fund Project of Yunnan Education Department(Grant Numbers 2023J1974 and 2023J1976).
文摘The mechanical properties of cementitious sand and gravel damming material have been experimentally determined by means of microscopic SEM(Scanning Electron Microscopy)image analysis.The results show that the combination of fly ash and water can fill the voids in cemented sand and gravel test blocks because of the presence of hydrated calcium silicate and other substances;thereby,the compactness and mechanical properties of these materials can be greatly improved.For every 10 kg/m^(3) increase in the amount of cementitious material,the density increases by about 2%,and the water content decreases by 0.2%.The amount of cementitious material used in the sand and gravel in these tests was 80-110 kg/m^(3),the water-binder ratio was 1-1.50.Moreover,the splitting tensile strength was 1/10 of the compressive strength,and the maximum strength was 7.42 MPa at 90 d.The optimal mix ratio has been found to be 50 kg of cement,60 kg of fly ash and 120 kg of water(C50F60W120).The related dry density was 2.6 g/cm^(3),the water content was 6%,and the water-binder ratio was 1.09.
基金supported by the Ministry of Education of China (Grant PCSIRT)the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)+2 种基金the National Natural Science Foundation of China (Grant No.31100359)the Natural Science Foundation of Jiangsu Province (Grant No.BK2011830)the Ningbo Planning Project of Science and Technology (Grant No.2012C50044)
文摘Methane (CH4) emissions estimated with the Intergovernmental Panel on Climate Change (IPCC) inventory method at the city and regional scale are subject to large uncertainties.In this study,we determined the CH4:CO2 emissions ratio for both Nanjing and the Yangtze River Delta (YRD),using the atmospheric CH4 and CO2 concentrations measured at a suburban site in Nanjing in the winter.The atmospheric estimate of the CH4:CO2 emissions ratio was in reasonable agreement with that calculated using the IPCC method for the YRD (within 20%),but was 200% greater for the municipality of Nanjing.The most likely reason for the discrepancy is that emissions from unmanaged landfills are omitted from the official statistics on garbage production.
基金Funded by the National Forestry Public Welfare Industry Major Projects of Scientific Research(No.201504502)National Natural Science Foundation of China(No.31200442)Supported by the Post Doctorate Research from the Ministry of Science and Technology of China(No.2014M550178)
文摘Starch/polylactic acid(PLA) composites were prepared by melt extrusion, with corn starch and PLA as raw materials, glycerol as the plasticizer. Effects of starch/PLA ratio on the interdependence of two-phase and other properties of the composites were studied. The combination of results of TGA with SEM indicated that the interdependence between starch and PLA was increased gradually as the starch/PLA ratio reduced. DSC results showed that the glass transition temperature(Tg), melting temperature(Tm) and degree of crystallinity of PLA in composites were increased gradually, whereas the cold crystallization temperature(Tc) was gradually decreased as the starch/PLA ratio reduced. The rheological properties of composites were closely related with the interdependence of two-phase, with reducing starch/PLA proportion, the interdependence was increased, and then the strain for storage modulus was firstl reduced and then gradually increased. Frequency scanning showed that the storage modulus and complex viscosity were decreased with reducing starch content. As the starch/PLA ratio reduced, the matrix phase PLA was increased, so that the strength of composites was increased gradually, whereas water absorption rate was decreased gradually.
基金Project supported by the National High Technology Research and Development of China (Grant No.2009AA063006)the National Natural Science Foundation of China (Grant No. 40905010)the Special Project of Environmental Nonprofit Industry Research,China (Grant No. 201109007)
文摘A topographic target light scattering-differential optical absorption spectroscopy ('IbTaL-DOA~) system is de- veloped for measuring average concentrations along a known optical path and studying surface-near distributions of atmospheric trace gases. The telescope of the ToTaL-DOAS system points to targets which are located at known dis- tances from the measurement device and illuminated by sunlight. Average concentrations with high spatial resolution can be retrieved by receiving sunlight reflected from the targets, A filed measurement of NO2 concentration is performed with the ToTaL-DOAS system in Shijiazhuang in the autumn of 2011. The measurement data are compared with con- centrations measured by the point monitoring technique at the same site. The results show that the ToTaL-DOAS system is sensitive to the variation of NO2 concentrations along the optical path.
文摘In recent years, the rationalization of concrete mix ratios which batches equal volumes of sand and gravel in building projects has been gaining grounds in the Cameroon construction industry. The main objective of this study is therefore to investigate if the concrete produced with rationalized mix ratio can be adopted as conventional mix ratio in terms of minimum required compression strength of concrete for buildings. Specifically this work compared the conventional mix ratio of 350 kg of cement: 400 liters of sand: 800 liters of gravel for a cubic meter and the rationalized batch of 350 kg of cement: 600 liters of sand: 600 liters of 5/15 gravel, 15/25 gravel and a combination of 5/15 + 15/25 gravel. Average compressive tests’results for both the conventional and the rationalized mix ratios were found to meet the minimum compressive strength of 65% at 7 days, 90% at 14 days and 99% at 28 days for gravel size combination 5/15 + 15/25. Single size gravel of 5/15 and 15/25 did not meet the minimum required compressive strength of 20 N/mm<sup>2</sup> for the rationalized mix ratio at 28 days curing based on the minimum compressive strength required, this study arrives at the conclusion that the equal volumes of sand and gravel mix ratio of 350 kg/m<sup>3</sup> of cement: 600 liters of sand: 600 liters of gravel mix ratio can be adopted as a conventional concrete mix ratio for gravel size 5/15 + 15/25.
文摘Considering actual construction conditions of Binchuan-Heqing Highway,this paper provides the C50 mix ratio conforming to engineering requirements by strictly controlling the quality of raw materials,optimizing the design of mix ratio scientifically,preparing superior C50 concrete 0 with manufactured sand,and optimizing the concrete mix ratio based on the adjustment of fly ash replacement,water-cement ratio,polycarboxylate-type water reducer mixing amount,sand ratio,etc.The result indicates that,the water-cement ratio has a great influence on the concrete strength,and if the ratio of coal ash is high in the binding material,the early compressive strength of the concrete will increase slowly.
基金supported by the grants from the Natural Science Foundation of Hubei Province(No.2020CFB780)the Fundamental Research Funds for the Central Universities(No.2017KFYXJJ020).
文摘Objective Body fluid mixtures are complex biological samples that frequently occur in crime scenes,and can provide important clues for criminal case analysis.DNA methylation assay has been applied in the identification of human body fluids,and has exhibited excellent performance in predicting single-source body fluids.The present study aims to develop a methylation SNaPshot multiplex system for body fluid identification,and accurately predict the mixture samples.In addition,the value of DNA methylation in the prediction of body fluid mixtures was further explored.Methods In the present study,420 samples of body fluid mixtures and 250 samples of single body fluids were tested using an optimized multiplex methylation system.Each kind of body fluid sample presented the specific methylation profiles of the 10 markers.Results Significant differences in methylation levels were observed between the mixtures and single body fluids.For all kinds of mixtures,the Spearman’s correlation analysis revealed a significantly strong correlation between the methylation levels and component proportions(1:20,1:10,1:5,1:1,5:1,10:1 and 20:1).Two random forest classification models were trained for the prediction of mixture types and the prediction of the mixture proportion of 2 components,based on the methylation levels of 10 markers.For the mixture prediction,Model-1 presented outstanding prediction accuracy,which reached up to 99.3%in 427 training samples,and had a remarkable accuracy of 100%in 243 independent test samples.For the mixture proportion prediction,Model-2 demonstrated an excellent accuracy of 98.8%in 252 training samples,and 98.2%in 168 independent test samples.The total prediction accuracy reached 99.3%for body fluid mixtures and 98.6%for the mixture proportions.Conclusion These results indicate the excellent capability and powerful value of the multiplex methylation system in the identification of forensic body fluid mixtures.
基金Supported by the National Natural Science Foundation of China(41275072).
文摘Based on the vertical ozone reanalysis data and total ozone column data derived from the European Centre for Medium-Range Weather Forecasts,the spatial and temporal distribution characteristics of ozone on each isobaric surface in the troposphere over the Northwest Pacific Ocean were analyzed,and the backward trajectory method was used to track the influence of typhoon on the distribution of ozone.The results show that the updraft near the typhoon center transported the air with low O_(3)content in the lower layer to the upper layer,which reduced O_(3)content in the upper layer and formed a low-value area of O_(3).The variation trend of total ozone column in the regions where typhoons"Megi"and"Fengshen"occurred was analyzed by the case analysis method.It is found that there was a low-value area of total ozone column anomaly near the typhoon center,and there was a certain correlation between typhoon intensity PDI and total ozone column anomaly at the development and maturity stages of typhoons.
基金This research was supported by the National Natural Science Foundation of China under Grant No.49794030.
文摘Numerical simulations of two heavy rainfall cases in the Changjiang-Huaihe River basin are performed with TRMM/PR (precipitation radar) data incorporated into the PSU/NCAR meso scale model MM5. The mixing ratio of rainwater q <SUB>r</SUB> is obtained from the R −q <SUB>r</SUB> relation (R is the rainfall rate), and the mixing ratio of water vapor q <SUB>v</SUB> in the model is replaced by q <SUP>1</SUP>′<SUB>v</SUB> = q <SUB>v</SUB>+q <SUB>r</SUB>. Then, TRMM/PR data are used to modify humidity analysis obtained from conventional radiosonde data, and sensitivity experiments (STE) are performed and compared to control experiments (CTL). Results show that both the heavy rainfall distribution and its maximum amounts from STE are improved compared with those from CTL.
基金supported by National Natural Science Foundation of China(No.51177132)
文摘Experiments were carried out to ascertain multichannel discharge characteristics in a self-designed coaxial field-distortion gas switch filled with SFa-N2 or SF6-Ar gas mixtures of different mixing ratios. In these experiments, the pressure varied from 0.1 MPa to 0.2 MPa, the voltage pulse peak applied to the switch was in the range from 40 kV to 78 kV, and the pulse rise time was 11 ns. The static breakdown strength of the gas switch gap in the switch was also measured. The results show that in general the average number of discharge channels for SF6-Ar or SF6-N2 gas mixture which contains less SFa is larger than that for gas mixture which contains more SF6, however, the average number of channels almost keeps constant as the gas mixing ratio varies when the pulse rise rate is high enough. The static breakdown strength of the gas switch gap decreases slightly as the content of argon or nitrogen increases.
基金supported by the National Natural Science Foundation of China(No.50876013)
文摘Regulated and unregulated emissions from four passenger cars fueled with methanol/gasoline blends at different mixing ratios (M15,M20,M30,M50,M85 and M100) were tested over the New European Driving Cycle (NEDC).Volatile organic compounds (VOCs) were sampled by Tenax TA and analyzed by thermal desorption-gas chromatograph/mass spectrometer (TD-GC/MS).Carbonyls were trapped on dinitrophenylhydrazine (DNPH) cartridges and analyzed by high performance liquid chromatography (HPLC).The results showed that total emissions of VOCs and BTEX (benzene,toluene,ethylbenzene,p,m,o-xylene) from all vehicles fueled with methanol/gasoline blends were lower than those from vehicles fueled with only gasoline.Compared to the baseline,the use of M85 decreased BTEX emissions by 97.4%,while the use of M15 decreased it by 19.7%.At low-to-middle mixing ratios (M15,M20,M30 and M50),formaldehyde emissions showed a slight increase while those of high mixing ratios (M85 and M100) were three times compared with the baseline gasoline only.When the vehicles were retrofitted with new three-way catalytic converters (TWC),emissions of carbon monoxide (CO),total hydrocarbon (THC),and nitrogen oxides (NOx) were decreased by 24%–50%,10%–35%,and 24%–58% respectively,compared with the cars using the original equipment manufacture (OEM) TWC.Using the new TWC,emissions of formaldehyde and BTEX were decreased,while those of other carbonyl increased.It is necessary that vehicles fueled with methanol/gasoline blends be retrofitted with a new TWC.In addition,the specific reactivity of emissions of vehicles fueled with M15 and retrofitted with the new TWC was reduced from 4.51 to 4.08 compared to the baseline vehicle.This indicates that the use of methanol/gasoline blend at a low mixing ratio may have lower effect on environment than gasoline.
文摘In order to implement the objective mix design of hot mix asphalt adequately during the construction process, the significance of objective mixing ratio was elaborated, and the variability of materials and its control method were analyzed. An engineering example is used to illustrate the debugging process of asphalt mixture batching & mixing plant and the dynamic quality management methods. The results show that the set of methods can not only implement the objective mixing ratio of hot mix asphalt adequately, but also control production during the construction process effectively.
文摘A simple method for estimating the contributions of mineral dust to PM2.5, PM10, or TSP is presented. The method is based on the assumption of external mixing of two types of particles with different PM2.5/PM10 ratios, The method was applied to local and transported dust events observed in Tsukuba, Japan, and was compared with collocated polarization lidar measurements. The method was then applied to three dust events that occurred in Oki, Rishiri, and Ochiishi,Japan, in 2012. The results showed that the method was useful for detecting mineral dust and for qualitatively describing the mixing of dust with anthropogenic aerosols.
基金funded by the National Dairy Industry and Technology System project (CARS-37)of Agriculture Ministry in China
文摘The object of this study was to determine the proper mixing ratio of fresh rice straw to corn steep liquor(CSL) to obtain a high protein content silage feed. The following experimental silages were generated: the control(C1), composed of fresh rice straw without CSL additive, mixed with CSL in the ratios of 4:1(C4),3:1(C3) and 2:1(C2). Lactic acid bacteria(LAB) inoculant was applied at the rate of 50 mL/kg(fresh basis)of forage to achieve a final application rate of 1 x 10~6 cfu/g of fresh matter(FM). Duplicate silos for each treatment were opened after 0,3, 7,10,20,30,45 and 60 d for microbiological and chemical analysis. The results showed that the addition of CSL significantly increased crude protein(CP) contents, and decreased neutral detergent fiber(NDF) and acid detergent fiber(ADF) contents of treatments after 60 d of ensiling(P < 0.05). The lactic acid contents in C4 and C3 were significantly higher than that in C1(P <0.05). In summary, mixing fresh rice straw with CSL at addition levels of 4:1(C4) and 3:1(C3) can improve the fermentation quality and nutrient composition of fresh rice straw silage. However, a large proportion of CSL(C3) had a negative impact on the aerobic stability of fresh rice straw.
基金the National Natural Science Foundation of China(No.41730421)the Major Science and Technology Project of SINOPEC during the 13th Five-Year Plan period(No.ZDP1705)。
文摘Multiple types of oil inclusions with different fluorescence colors have been detected in the northern Dongpu depression.Recent evidences show that these inclusions may have been trapped simultaneously or during a very short period.Therefore,whether these oils were mixed before trapping is unknown.In this study,we analyzed the petrography and fluorescence spectral characteristics of oil inclusions in the Wenliu uplift in the northern Dongpu depression,and assessed the data with the oil mixing ratio curve obtained in the previous experiment.The results show that there are three types of oil inclusions(type I,type II and type III)with yellow,green and blue fluorescence colors,corresponding to low-mature,medium-mature and high-mature oil,respectively.The"pure"oil inclusions,do exist in type II and type III group of oil inclusions,showing the medium-mature oil was generated from the source rock rather than being formed by the mixture of high-mature and low-mature end oils.Most of the oil inclusions are mixtures of high-mature and medium-mature end oils from the sub-sags to the Wenliu uplift,the mixing degree increases to close to 50%.The oil between the Qianliyuan sub-sag and the Wenliu uplift was mainly mixed by medium mature oils,whereas the oil between the Liutun sub-sag and the Wenliu uplift was mainly mixed by high mature oil.
基金the financially support from the Education Department Heilongjiang Province(No.2014TD010)project of the Heilongjiang Provincial Land Reclamation Bureau(No.HNK125B-07-17)Project of the Education Department Heilongjiang Province(No.12531450)。
文摘The plant-made seedling-growing tray cultivation technique is an effective way to improve maize yield and quality in China’s cold northern area.However,the corn seedling nursery carrier and tray cultivation technique has been proved poor in adaptability.After comparing several nursery carriers,a design for a plant-made seedling-growing tray that is suitable for maize transplantation was proposed in which rice straw was used as the primary raw material.The preparation method,processing and structural dimensions of the tray were investigated and designed,five types of plant-made seedling-growing trays with different formulations were proposed.The shear mechanical properties and the shear strength of the plant-made seedling-growing trays were tested to determine the shear force needed for cutting through trays prepared with increasing mass ratios of rice straw and the effect of the shearing rate on the shear strength.The results showed that at a shearing rate of 100 mm/min,the maximum shear force decreased gradually as the mass ratio of straw was increased and that the hardness of the tray decreased as its shear strength decreased.Under three shearing rates(100 mm/min,200 mm/min and 500 mm/min)and a blade displacement of 10 mm,the shear force was the highest at the point at which the tray was cut through;the required shear force to cut through the tray then gradually decreased.Trays with the same straw composition showed no significant influence of shearing rate on the tray’s shear strength at shearing rates of 100 mm/min,200 mm/min or 500 mm/min.This study describes a multi-tray,single-strip nursery carrier for use in plant-made seedling-growing tray cultivation and proposes a theoretical basis for the design of a rotary transplanting device,the key part of a maize plant-made seedling-growing tray transplanter.
基金funded by the Natural Sciences and Engineering Research Council of Canada (NSERC) under the Engage Grant (EGP 463799-2014) with collaboration with KGS Groups (Winnipeg, Canada)
文摘In this study, landfill leachate with and without pre-treatment was co-treated with municipal wastewater at different mixing ratios. The leachate pre-treatment was achieved by air stripping to removal ammonia. The objective of this study was to investigate the effect of landfill leachate on nutrient removal of the wastewater treatment process. It was demonstrated that when landfill leachate was co-treated with municipal wastewater, the high ammonia concentration in the leachate did not have a negative impact on the nitrification. The system was able to adapt to the environment and was able to improve nitrification capacity. The readily biodegradable portion of chemical oxygen demand(COD)in the leachate was utilized by the system to improve phosphorus and nitrate removal.However, this portion was small and majority of the COD ended up in the effluent thereby decreased the quality of the effluent. The study showed that the 2.5% mixing ratio of leachate with wastewater improved the overall biological nutrient removal process of the system without compromising the COD removal efficiency.
基金Projects 51776215 and 51736010 supported by National Natural Science Foundation of China are gratefully acknowledged.
文摘In the CO_(2)transcritical power cycle,conventional cooling water can hardly condense subcritical CO_(2)because its critical temperature is as low as 30.98°C.In order to avoid this condensing problem,CO_(2)-based mixtures have been proposed as working fluids for transcritical power cycle.They can raise the critical temperature by mixing a little C_(3)H_(8)as the secondary component to CO_(2).However,the flammability of the mixture may limit its application.This article investigated laminar flame speed of C_(3)H_(8)/CO_(2)which represents the mixture’s combustion characteristic by a so-called heat flux method and studied the inhibition mechanism of CO_(2)on the combustion based on the Premixed Laminar Flame-Speed Calculation reactor of Chemkin-Pro.The experimental results showed that the laminar flame speed shows a peak value with changing the equivalence ratio and accelerates with raising the mole fraction of the organic gas.Additionally,a slight upwards trend was observed for the corresponding equivalence ratio of the peaks.The flammable range for the equivalence ratio extended with the mole fraction of C_(3)H_(8)increasing.With the mole fraction of C_(3)H_(8)of 0.15,the maximum laminar flame speed was 12.8 cm/s,31.7%of that of the pure C_(3)H_(8).The flammable range was from 0.41 to 1.33,decreasing by 23.3%compared with that of C_(3)H_(8).A flammable critical mixing ratio was also found as 0.08/0.92 for C_(3)H_(8)/CO_(2)at the normal condition.By simulating,it was found that the most key free radical and elementary reaction which determine the inhibition of CO_(2)on the combustion are OH and H+O_(2)=O+OH,respectively.
基金supported by the Natural Science Foundation of Hebei Province(E2020502007)the Central University Fund Project(2020MS103).
文摘Solid waste has interactions with its flue-gas products during combustion,which offers the possibility of regulating its pollutant emissions.Especially,these interaction pathways would be clearer under anaerobic conditions when the chemical-looping combus-tion(CLC)process is used.The CLC experiments of multi-component solid waste were conducted on a homemade twin-bed reactor and the characteristics of flue gas were investigated for the effect of the mixing ratio of sewage sludge and polyvinyl chloride(PVC).The results indicated that the combustion efficiency was>99.9%for these CLC processes;the highest carbon-conversion rate was obtained at 96.3%for PVC with 60%sludge.The highest NO and SO_(2)emissions were 26%and 19%,respectively,when the sludge was mixed with 20%PVC.As the proportion of PVC blended into the sludge increased,the time when the concentration of NO in the flue-gas peaks moved backwards,while peak SO_(2)concentration moved forward.The general trend was to increase first and then de-crease.In addition,there were multiple peaks in carbon emissions,corresponding to~10%,30%and~70%of the carbon-conversion rate;nitrogen emissions reached 90%of total emissions before the carbon-conversion rate was 40%;sulphur emissions had a longer cycle and were mainly emitted between 10%and 60%of the carbon-conversion rate.The results are expected to provide a reference for solid-waste source suppressing to inhibit the generation of pollutants.