Mixed Gl2／GH2 multi-channel multi-objective control synthesis for discrete time systems

This paper proposes a new approach for multi-objective robust control. The approach extends the standard generalized l2 (Gl2) and generalized H2 (GH2) conditions to a set of new linear matrix inequality (LMI) constraints based on a new stability condition. A technique for variable parameterization is introduced to the multi-objective control problem to preserve the linearity of the synthesis variables. Consequently, the multi-channel multi-objective mixed Gl2/GH2 control problem can be solved less conservatively using computationally tractable algorithms developed in the paper.

Effect of different organic compounds on the preparation of CaO-based CO_(2) sorbents derived from wet mixing combustion synthesis

CaO based sorbents have great potential for commercial use to capture CO_(2) of power plants.In the demand of producing sorbents with better cyclic performance,CaO-based sorbents derived from different kinds of calcium precursors,containing calcium carbonate(CC-CaO),calcium gluconate monohydrate(CG-CaO),calcium citrate(CCi-CaO)and calcium acetate monohydrate(CA-CaO),were tested cyclically and compared using simultaneous thermal analyzer(STA).And further study was conducted on the sorbents modified with citric acid monohydrate and 50%gluconic acid solution by wet mixing combustion synthesis.The modified sorbents showed better performance and higher pore parameters as well as porous microstructure with more organic acid added.After 20 cycles of carbonation and calcination,the C2CCi8(CaO:citric acid=2:8 by mass ratio)and C2G8(CaO:gluconic acid=2:8 by mass ratio)sorbent possess CO_(2) capture capacity of 0.45g·g^(-1)(g CO_(2) per g sorbents)and 0.52 g·g^(-1) respectively.The citric acid was more effective for modification than gluconic acid for extended 50 cycles.Furthermore,good linear relationship between CaO conversion and specific surface area as well as pore volume were determined,of which the specific surface area showed closer correlation with CaO conversion。

Effect of elemental molar ratio on the synthesis of higher alcohols over Co-promoted alkali-modified Mo_2C catalysts supported on CNTs

A series of molybdenum carbide catalysts promoted by potassium and cobalt,supported on carbon nanotubes（CNTs） were prepared by carbothermal hydrogen reduction method using CNTs as a carbon precursor.Firstly,molybdenum and cobalt were loaded by co-precipitation method,and then potassium and additional molybdenum were impregnated to previous resultant.Different Mo/Co and K/Co molar ratio were used in catalyst synthesis.All the catalysts were characterized by ICP,BET,TEM,TPR,XRD and XPS,and the catalysts performances for higher alcohols synthesis（HAS） were investigated in a fixed-bed micro-reactor.The maximum selectivity to higher alcohols（C2＋OH） was obtained at Mo/Co and K/Mo molar ratios of 1.66 and 0.6,respectively.XRD results confirmed the formation of K-Mo-C site and Co3Mo3 C phase that might play important role in producing C2＋OH.

Study on cobalt-carbon and iron-sulfur mixed cluster complexes——Synthesis and conformational analysis of mixed cluster complexes [μ-p-CH_3C_6H_4C_2Co_2 (CO)_6 S](μ-RS)Fe_2(CO)_6

Through complexation reaction of arynyl Fe-S complexes A(μ-p-CH_3C_6H_4C≡CS)(μ- RS)Fe_2(CO)_6 with Co_2(CO)_6, eight mixed cluster complexes B[μ-p-CH_3C_6H_4C_2Co_2(CO)_6S](μ- RS)Fe_2(CO)_6 have been synthesized. Reactivity of the complexation reaction is approximately equi- valent to that of the reaction of diarylacetylene with Co_2(CO)_8. Conformational analysis has shown that R groups in complexes A are linked to sulfur atoms by a-and e-bond, whereas that in B only by art e-type of bond.

The synthesis and structural studies of mixed ligand complex,tris(1-phenyl-3-methyl-4-trifluoroacetylpyrazol-5-one)mono(1-phenyl-3-methyl-pyrazol5-one)neodymium(Ⅲ)monohydrate

A mixed ligand neodymium complex containing 1-phenyl-3-methyl-4-trifluoroacetyl- pyrazol-5-one(HPMTFP)and 1-phenyl-3-methyl-pyrazol-5-one(PMP),with molecular formula Nd(PMTFP)_3·PMP·H_2O was synthesized.Its crystal and molecular structure has been determined by single crystal X-ray diffraction method.The complex crystallizes in monoclinic system with space group C_2~5h-P2_(1/n).There are four formula units in a cell of dimensions a=12.837(3),b=23.763(5),c=16.810(4) ,β=109.58(2)°.The structure has been refined by full-matrix least-squares techniques to a final R value of 0.0487 and Rw value of 0.432.The neodymium atom is coordinated to eight oxygen atoms with the average Nd-O bond length 2.439,Its thermostability,and mass spectrum have been discussed.