Coal fly ash originated from coal combustion has high concentrations of metals. If suitable leaching techniques are identified, then coal fly ash could serve as a useful source of valuable minerals including rare eart...Coal fly ash originated from coal combustion has high concentrations of metals. If suitable leaching techniques are identified, then coal fly ash could serve as a useful source of valuable minerals including rare earth elements (REEs). In this study, three microbial strains, Candida bombicola, Phanerochaete chrysosporium and Cryptococcus curvatus were tested on their performance of leaching trace elements and REEs from fly ash. Through comparing mineral loss and leaching efficiencies resulting from indirect leaching or use of the culture supernatant, C. bombicola was identified to be the best leading to the highest mineral loss and extracting efficiencies of trace elements and REEs among the three strains. The highest mineral loss observed from using the supernatant of this yeast strain was 59.7%. Among all trace elements, As and Mo had the highest leaching efficiency of 80.9% and 79.5%. respectively. The same leaching test led to 67.7% of Yb and 64.6% of Er dissolved from the ash. This study, thus, demonstrated that bioleaching is feasible for leaching metals out of fly ash. The C. bombicola strain deserves further investigation due to its robust actions on metal leaching.展开更多
The present study proposes the mix design method of Fly Ash(FA)based geopolymer concrete using Response Surface Methodology(RSM).In this method,different factors,including binder content,alkali/binder ratio,NS/NH rati...The present study proposes the mix design method of Fly Ash(FA)based geopolymer concrete using Response Surface Methodology(RSM).In this method,different factors,including binder content,alkali/binder ratio,NS/NH ratio(sodium silicate/sodium hydroxide),NH molarity,and water/solids ratio were considered for the mix design of geopolymer concrete.The 2D contour plots were used to setup the mix design method to achieve the target compressive strength.The proposed mix design method of geopolymer concrete is divided into three categories based on curing regime,specifically one ambient curing(25°C)and two heat curing(60 and 90°C).The proposed mix design method of geopolymer concrete was validated through experimentation of M30,M50,and M70 concrete mixes at all curing regimes.The observed experimental compressive strength results validate the mix design method by more than 90%of their target strength.Furthermore,the current study concluded that the required compressive strength can be achieved by varying any factor in the mix design.In addition,the factor analysis revealed that the NS/NH ratio significantly affects the compressive strength of geopolymer concrete.展开更多
文摘Coal fly ash originated from coal combustion has high concentrations of metals. If suitable leaching techniques are identified, then coal fly ash could serve as a useful source of valuable minerals including rare earth elements (REEs). In this study, three microbial strains, Candida bombicola, Phanerochaete chrysosporium and Cryptococcus curvatus were tested on their performance of leaching trace elements and REEs from fly ash. Through comparing mineral loss and leaching efficiencies resulting from indirect leaching or use of the culture supernatant, C. bombicola was identified to be the best leading to the highest mineral loss and extracting efficiencies of trace elements and REEs among the three strains. The highest mineral loss observed from using the supernatant of this yeast strain was 59.7%. Among all trace elements, As and Mo had the highest leaching efficiency of 80.9% and 79.5%. respectively. The same leaching test led to 67.7% of Yb and 64.6% of Er dissolved from the ash. This study, thus, demonstrated that bioleaching is feasible for leaching metals out of fly ash. The C. bombicola strain deserves further investigation due to its robust actions on metal leaching.
文摘The present study proposes the mix design method of Fly Ash(FA)based geopolymer concrete using Response Surface Methodology(RSM).In this method,different factors,including binder content,alkali/binder ratio,NS/NH ratio(sodium silicate/sodium hydroxide),NH molarity,and water/solids ratio were considered for the mix design of geopolymer concrete.The 2D contour plots were used to setup the mix design method to achieve the target compressive strength.The proposed mix design method of geopolymer concrete is divided into three categories based on curing regime,specifically one ambient curing(25°C)and two heat curing(60 and 90°C).The proposed mix design method of geopolymer concrete was validated through experimentation of M30,M50,and M70 concrete mixes at all curing regimes.The observed experimental compressive strength results validate the mix design method by more than 90%of their target strength.Furthermore,the current study concluded that the required compressive strength can be achieved by varying any factor in the mix design.In addition,the factor analysis revealed that the NS/NH ratio significantly affects the compressive strength of geopolymer concrete.
