Mechanism of Fume Suppression and Performance on Asphalt of Expanded Graphite for Pavement under High Temperature Condition

Fume suppression mechanisms and the effect of expanded graphite on the performance of asphalt were studied by applying infrared spectroscopy（FT-IR）, X-ray diffraction（XRD）, scanning electron microscopy（SEM） and comprehensive thermal analysis（TG, DSC）. The experimental results confirm that asphalt which is mixed with expandable graphite will expand in the process of hot mix, and the expanded graphite layer will swell by the light component in the asphalt. The light component in the asphalt and PAHs adsorption on expanded graphite surface or part of the plug in the expanded graphite layer between plates made nucleation crystallization growth. And the Van der Waals force and the bonding of the lattice can effectively restrain the asphalt fume release. Meanwhile, the expanding agent with oxidative can spread into the asphalt, leading to asphalt oxygenated and plastic abate, while the ductility decreases. Expanded graphite, SBS modifier and environment- friendly plasticizers are used to composite modified asphalt. According to asphalt fume release experiment, normal test of asphalt performance, Brookfield viscosity test, RTFOT test and asphalt mixture tests（high temperature stability, low temperature stability, water stability）, it has been proven that the modified asphalt’s performance is better than that of matrix asphalt and equivalent to that of SBS modified asphalt. Furthermore, it has good fume suppression effect.

Testing and assessing the performance of a new warm mix asphalt with SMC

Warm mix asphalt （WMA} is a new technology which asphalt mix is produced and placed at normal temperature. It has advantages including low cost, environmentally friendly, haul-convenience, and so on. WMA has been widely tested and applied in the USA in the last decade, but it has just started in China. Recently, a new WMA using a new plastic- macromolecule-normal temperature additive, which was called ＂SMC＂ by the production company, was introduced as asphalt modifier. Based on discussing the strength forming process of this new WMA with SMC, a series of laboratory tests, including Marshall stability test （MST）, boiling test （BT）, modified immersion Marshall test （MIMT）, freeze-thaw split- ring test （FTST）, rutting test （RT）, low-temperature bending test （LTBT）, and abrasion loss test （ALT）, were conducted in this study to assess the performance of this WMA and the capability of applying it on low volume roads in China. SMC modified asphalt mixed under normal temperature is used in testing samples. It was found that this WMA product exhibited merits on its strength, which was about 6.7 kN bigger than the requirement of 5.0 kN in the JTG F40-2004, on high-temperature stability, which is about 1100 times/ram greater than the requirement of 600-1000 times/mm in the ）TG F40-2004, and on its storage stability. Based on these indicators, it is recommended that this product could be used for low volume low class roads construction. However, due to the relatively lower water resistance and low-temperature cracking resistance, this product is suggested to be applied first in the areas with warm weather and little rainfall. In order to improve the perfor- mance of this WMA with SMC, further research on this SMC asphalt modifier should be continued.