Steel slag, a by-product of the steel production industry reaches 10%–15% of crude steel output (Motz and Geiseler, 2001). Their main application lies in the field of building materials due to some containing cementi...Steel slag, a by-product of the steel production industry reaches 10%–15% of crude steel output (Motz and Geiseler, 2001). Their main application lies in the field of building materials due to some containing cementitious components, such as dicalcium silicate (C2S) and tricalcium silicate (C3S) (Waligora et al., 2010). However, blended cements with steelmaking slag show low early hydration activity, low compressive strength and bad durability because steel slag generates above 1600 ℃ with the tense and large grain size crystals, consisting of low content of C2S and C3S and high proportions of f-CaO and f-MgO compared with cement clinker.展开更多
针对钢渣体积稳定性差、钢渣-沥青混合料道路过早开裂的问题,采用二氧化硅胶体溶液对钢渣进行浸泡改性处理,通过力学性能测试、扫描电子显微镜(scanning electron microscope,SEM)检测、路用性能测试等方法研究了改性钢渣的物理力学性...针对钢渣体积稳定性差、钢渣-沥青混合料道路过早开裂的问题,采用二氧化硅胶体溶液对钢渣进行浸泡改性处理,通过力学性能测试、扫描电子显微镜(scanning electron microscope,SEM)检测、路用性能测试等方法研究了改性钢渣的物理力学性能、改性钢渣-沥青混合料的性能和钢渣的改性机理,并引入灰靶理论决策方法,综合改性钢渣-沥青混合料的各项性能指标,确定钢渣的最佳改性方案。结果表明:钢渣改性后,物理力学性能明显提高;钢渣的改性浓度越大,沥青混合料的高温性能越佳;延长钢渣的改性时间,沥青混合料的低温抗裂性能提高;且钢渣改性之后,沥青混合料的水稳定性能显著提高。基于灰靶决策理论,最终确定钢渣的最佳改性方案是在改性浓度(溶液质量分数)为3%的溶液下浸泡24 h。展开更多
Steel slag had lower activity and much lower hydration rate than cement. Quicklime and iron tailings were designed as modification agent to adjust the composition and properties of high temperature steel slag. The res...Steel slag had lower activity and much lower hydration rate than cement. Quicklime and iron tailings were designed as modification agent to adjust the composition and properties of high temperature steel slag. The results show that quicklime as modifier can greatly increase the content of cementitious minerals in modified steel slag and also promote the decomposition of RO phases and transformation of MgO in RO phase to f-MgO. After high temper- ature modification with compound modifier of quicklime and iron tailings, steel slag shows the main mineral phases of C3S, C2F and MgFe2O4. The activity index of modified steel slag at 28 days reaches 95.5% when the steel slag is modified by 15% of the compound modifier with the ratio of quicklime to iron tailings equal to 2 : 1 at 1 350 ℃. Mo- reover, the sample with the modified steel slag exhibits the dense structure of hydration paste and the main hydration products of C-S-H gels and Ca(OH)2 crystals.展开更多
基金Supported by the National Key Technologies R&D Program of China (NO. 2011BAB03B05)
文摘Steel slag, a by-product of the steel production industry reaches 10%–15% of crude steel output (Motz and Geiseler, 2001). Their main application lies in the field of building materials due to some containing cementitious components, such as dicalcium silicate (C2S) and tricalcium silicate (C3S) (Waligora et al., 2010). However, blended cements with steelmaking slag show low early hydration activity, low compressive strength and bad durability because steel slag generates above 1600 ℃ with the tense and large grain size crystals, consisting of low content of C2S and C3S and high proportions of f-CaO and f-MgO compared with cement clinker.
文摘针对钢渣体积稳定性差、钢渣-沥青混合料道路过早开裂的问题,采用二氧化硅胶体溶液对钢渣进行浸泡改性处理,通过力学性能测试、扫描电子显微镜(scanning electron microscope,SEM)检测、路用性能测试等方法研究了改性钢渣的物理力学性能、改性钢渣-沥青混合料的性能和钢渣的改性机理,并引入灰靶理论决策方法,综合改性钢渣-沥青混合料的各项性能指标,确定钢渣的最佳改性方案。结果表明:钢渣改性后,物理力学性能明显提高;钢渣的改性浓度越大,沥青混合料的高温性能越佳;延长钢渣的改性时间,沥青混合料的低温抗裂性能提高;且钢渣改性之后,沥青混合料的水稳定性能显著提高。基于灰靶决策理论,最终确定钢渣的最佳改性方案是在改性浓度(溶液质量分数)为3%的溶液下浸泡24 h。
基金Sponsored by National Key-tech Research and Development Program of China(2011BAB03B05,2013BAC12B04)
文摘Steel slag had lower activity and much lower hydration rate than cement. Quicklime and iron tailings were designed as modification agent to adjust the composition and properties of high temperature steel slag. The results show that quicklime as modifier can greatly increase the content of cementitious minerals in modified steel slag and also promote the decomposition of RO phases and transformation of MgO in RO phase to f-MgO. After high temper- ature modification with compound modifier of quicklime and iron tailings, steel slag shows the main mineral phases of C3S, C2F and MgFe2O4. The activity index of modified steel slag at 28 days reaches 95.5% when the steel slag is modified by 15% of the compound modifier with the ratio of quicklime to iron tailings equal to 2 : 1 at 1 350 ℃. Mo- reover, the sample with the modified steel slag exhibits the dense structure of hydration paste and the main hydration products of C-S-H gels and Ca(OH)2 crystals.