Metallogenic Age and Ore-forming Material Sources of the Dahongshan Fe-Cu Deposit,Yunnan Province:Insights from Molybdenite Re-Os Dating and H-O-S-Pb Isotopes

The Dahongshan Fe-Cu(-Au)deposit is a superlarge deposit in the Kangdian metallogenic belt,southwestern China,comprising approximately 458 Mt of Fe ores(40%Fe)and 1.35 Mt Cu.Two main types of Fe-Cu(-Au)mineralization are present in the Dahongshan deposit:(1)early submarine volcanic exhalation and sedimentary mineralization characterized by strata-bound fine-grained magnetite and banded Fe-Cu sulfide(pyrite and chalcopyrite)hosted in the Na-rich metavolcanic rocks;(2)late hydrothermal(-vein)type mineralization characterized by Fe-Cu sulfide veins in the hosted strata or massive coarse-grained magnetite orebodies controlled by faults.While previous studies have focused primarily on the early submarine volcanic and sedimentary mineralization of the deposit,data related to late hydrothermal mineralization is lacking.In order to establish the metallogenic age and ore-forming material source of the late hydrothermal(-vein)type mineralization,this paper reports the Re-Os dating of molybdenite from the late hydrothermal vein Fe-Cu orebody and H,O,S,and Pb isotopic compositions of the hydrothermal quartz-sulfide veins.The primary aim of this study was to establish the metallogenic age and ore-forming material source of the hydrothermal type orebody.Results show that the molybdenite separated from quartz-sulfide veins has a Re-Os isochron age of 831±11 Ma,indicating that the Dahongshan Fe-Cu deposit experienced hydrothermal superimposed mineralization in Neoproterozoic.The molybdenite has a Re concentration of 99.7-382.4 ppm,indicating that the Re of the hydrothermal vein ores were primarily derived from the mantle.The δ^(34)S values of sulfides from the hydrothermal ores are 2‰-8‰ showing multi-peak tower distribution,suggesting that S in the ore-forming period was primarily derived from magma and partially from calcareous sedimentary rock.Furthermore,the abundance of radioactive Pb increased significantly from ore-bearing strata to layered and hydrothermal vein ores,which may be related to the later hydrothermal transformation.The composition of H and O isotopes within the hydrothermal quartz indicates that the ore-forming fluid is a mixture of magmatic water and a small quantity of water.These results further indicate that the late hydrothermal orebodies were formed by the Neoproterozoic magmatic hydrothermal event,which might be related to the breakup of the Rodinia supercontinent.Mantle derived magmatic hydrothermal fluid extracted ore-forming materials from the metavolcanic rocks of Dahongshan Group and formed the hydrothermal(-vein)type Fe-Cu orebodies by filling and metasomatism.

Re-Os Isotopic Age of Molybdenite of the Jingren Deposit and its Mineralogical Significance of Magnetite,Pyrite and Chalcopyrite

The Jingren deposit is part of the Qimantage metallogenic belt within the eastern Kunlun orogenic belt,the largest metallogenic belt in Qinghai Province,northwestern China.Exploration data show that the metal resources of the Jingren deposit are greater than 93000 t in a mining area of 76.15 km2,which indicates significant exploration potential in the near future.Three W–E-trending faults,F1-3,dominate the extension of the mineralization zone,which consists of chalcopyrite,pyrite,magnetite,galena,sphalerite,and molybdenite as well as bismuth-bearing minerals.The deposit contains a large amount of late Triassic intrusive rocks,however,previous research did not reach a consensus on the timing or the origin of the mineralization owing to a lack of geochronological data and poor exposure conditions.In the present study,Re-Os isotopic dating from six molybdenite samples collected from a borehole of the granodiorite in the Jingren deposit using negative thermal ionization mass spectrometry(NTIMS)showed 187 Re and 187 Os concentrations of 0.26–4.40 ppm and 1.03–16.46 ppb,respectively,with an initial 187 Os/188 Os value of 0.06±0.19.This proves that the Jingren deposit has a metallogenic age of(225±4)Ma and is the product of united mineralization of the Qimantage metallogenic belt and that the Jingren deposit might actually be an Indosinian metallogeny.In addition,the Re content of these samples,at 0.42 ppm to 7.00 ppm shows that the mineralization was derived mainly from a crustal source.Furthermore,electron probe microanalysis(EPMA)conducted on chalcopyrite obtained from 22 metallic mineral samples revealed(Fe+Cu)/S ratios of 1.801–1.947 with an average of 1.852,which is lower than the ideal value(1.875).Besides,the main ore body formed in a relatively higher temperature environment than the surrounding rocks in the Jingren deposit.These data indicate that the Jingren deposit formed in a metallogenic environment at lower temperature.Moreover,according to the TiO_(2)-Al_(2)O_(3)-(MgO+MnO)and TiO_(2)-Al_(2)O_(3)-MgO genetic classification diagram for magnetite,the Jingren deposit most likely belongs to the skarn family.In addition,the Co-Ni-As genetic classification diagram of the pyrite indicates sedimentary and skarn genetic characteristics.

LA-ICP-MS Zircon U-Pb Dating of Intermediate-Acidic Intrusive Rocks and Molybdenite Re-Os Dating from the Bangpu Mo (Cu) Deposit, Tibet and its Geological Implication

The multi-stage intrusions of intermediate-acid magma occur in the Bangpu mining district, the petrogenic ages of which have been identified. The times and sequences of their emplacement have been collated and stipulated in detail in this paper by using the laser ablation-inductively coupled plasma-mass spectrometry （LA-ICP-MS） zircon U-Pb dating method. The ages of biotite monzogranite that were formed before mineralization in the southwest of this mining district are 70±1 Ma （mean square of weighted deviates （MSWD） =9.5, n=8） and 60.60±0.31 Ma （MSWD=3.8, n=16）, which belong to the late Cretaceous-early Paleocene in age. That means, they are products of an early tectonicmagmatic event of the collision between the Indian and Asian continentals. The ages of ore-bearing monzogranite porphyry and ore-bearing diorite porphyrite are 16.23±0.19 Ma （MSWD=2.0, n=26） and 15.16±0.09 Ma （MSWD=3.9, n=5） separately, which belong to the middle Miocene in age; namely, they are products of the Gangdese post-collision extensional stage when crust-mantle materials melted and mixed as well as magmatic intrusion simultaneously occurred. Some zircons with ages of 203.6±2.2 Ma （MSWD=1.18, n=7） were captured in the ore-bearing diorite porphyrite, which shows that there had been tectono-magmatic events in the late Triassic-early Jurassic. Molybdenum （copper） ore-bodies produced in the monzogranite porphyry and copper （molybdenum） ore-bodies produced in the diorite porphyrite are the main ore types in this ore deposit. The model ages of Re-Os isotopic dating for the 11 molybdenite are 13.97-15.84 Ma, while isochron ages are 14.09±0.49 Ma （MSWD=26）. The isochron ages of seven molybdenite from molybdenum （copper） ore with monzogranite porphyry type are 14.11±0.31 Ma （MSWD=5.2）. There is great error in the isochron ages of four molybdenite from copper （molybdenum） ore with diorite porphyrite type, and their weighted average model ages of 14.6±1.2 Ma （MSWD=41）, which generally represent the mineralization age. The results about the Re-Os isotopic dating of molybdenite in the ore of different types have limited exactly that, the minerlazation age of this ore deposits is about 14.09 Ma, which belongs to the middle Miocene mineralization. The Bangpu deposit has a uniform metallogenic dynamics background with the porphyry type and skarn-type deposits such as Jiama, Qulong and others.

Re-Os Dating of Molybdenite from the Yaogangxian Tungsten Deposit,South China,and Its Geological Significance

The Yaogangxian tungsten deposit is located in the central part of the Nanling polymetailic metallogenic province. The orebodies occur as veins. Wolframite and molybdenite are the dominant ore minerals. Two samples were selected for molybdenite Re-Os dating in order to elucidate the timing of mineralization. Re-Os datings of molybdenite from quartz-woiframite veins and disseminated in granite yield ages of 153±7 Ma and 163.2±4.2 Ma respectively. The results indicate that the Yaogangxian tungsten deposit is the product of large-scale metallogenesis in the middle Yanshanian period in South China, and that the evolution from late magmatic to postmagmatic hypothermal mineralization occurred at about 10 Ma. The rhenium content of molybdenite in the Yaogangxian tungsten deposit suggests that the ore materials originated from the crust.

LA-ICP-MS Zircon U-Pb Geochronology of the Fine-grained Granite and Molybdenite Re-Os Dating in the Wurinitu Molybdenum Deposit,Inner Mongolia,China

The Wurinitu molybdenum deposit,located in Honggor,Sonid Left Banner of Inner Mongolia,China,is recently discovered and is considered to be associated with a concealed fine-grained granite impregnated with molybdenite.The wall rocks are composed of Variscan porphyritic-like biotite granite and the Lower Ordovician Wubin'aobao Formation.LA-ICP-MS zircon U-Pb dating of the fine-grained granite reveals two stages of zircons,one were formed at 181.7±7.4 Ma and the other at 133.6±3.3 Ma.The latter age is believed to be the formation age of the fine-grained granite,while the former may reflect the age of inherited zircons,based on the morphological study of the zircon and regional geological setting.The Re-Os model age of molybdenite is 142.2±2.5 Ma,which is older than the diagenetic age of the fine-grained granite.Therefore the authors believe that the metallogenic age of the Wurinitu molybdenum deposit should be nearly 133.6±3.3 Ma or slightly later,i.e.,Early Cretaceous.Combined with regional geological background research,it is speculated that the molybdenum deposits were formed at the late Yanshanian orogenic cycle in the Hingganling-Mongolian orogenic belt,belonging to the relaxation epoch posterior to the compression and was associated with the closure of the Mongolia-Okhotsk Sea.

Re-Os Isotopic Dating of a W-Be Polymetallic Deposit in the Southern Qinling Region, China

Objective In recent years, a series of tungsten prospecting breakthroughs have been made in the southern Qinling Mountains. Especially, a new deposit type with a scheelite -beryl-molybdenite assemblage in the Zhen＇an area of Shaanxi Province was firstly discovered. This deposit is currently in a detailed investigation stage, and no detailed study has been yet conducted. This work selected one molybdenite sample from the Be （W） ores in this deposit for Re-Os isotope measurements to define the time limit of tungsten and beryllium mineralization, and to further reveal the ore-forming geological setting of rare metals in the southern Qinling region.

Late Jurassic Cu-Mo Mineralization at the Zhashui-Shanyang District,South Qinling,China:Constraints from Re-Os Molybdenite and Laser Ablation-Inductively Coupled Plasma Mass Spectrometry U-Pb Zircon Dating

The Zhashui-Shanyang district is one of the most important sulfide deposits in the Qinling Orogen where the formation of porphyry-skarn Cu-Mo deposits has a close genetic link with the Yanshannian magmatism.Laser Ablation-Inductively Coupled Plasma Mass Spectrometry（LA-ICP-MS） U-Pb zircon dating of two granodiorite intrusions（Xiaohekou and Lengshuigou deposits）was investigated in the Zhashui-Shanyang district and the rock-forming ages obtained from 148.3±2.8 to 152.6±1.2 Ma,averaging 150.5 Ma,accompanied by a younger disturbance age of 144.3±1.7 Ma in the Lengshuigou intrusion,which is in excellent agreement with published sensitive high resolution ion micro-probe（SHRIMP）zircon date on the later monzodiorite porphyry phase in the Lenshuigou deposit.Two samples were selected for molybdenite ICP-MS Re-Os isotopic analyses from the Lengshuigou granodiorite porphyry,yielding Re-Os model ages from 149.2±2.7 Ma to 150.6±3.4 Ma, with a weighted mean age of 149.7±2.1 Ma.These mineralization ages overlap rock-forming ages of the host intrusions within the error range.This implies that the mineralization occurred in the Late Jurassic,which belongs to the tectonic phase B event of the Yanshan Movement,not Cretaceous as previously thought.Therefore,the Late Jurassic mineralization of the Zhashui-Shanyang district could be connected to the large-scale Yanshan molybdenum metallogenic period,the geodynamic regime of which is attributable to the far field response of convergence of surrounding plates,perhaps the approximately westward subduction of the Izanagi plate beneath the Eurasian continent.

Molybdenite Re-Os,titanite and garnet U-Pb dating of the Magushan skarn Cu-Mo deposit,Xuancheng district,Middle-Lower Yangtze River Metallogenic Belt

The Magushan skarn Cu-Mo deposit is a representative example of the skarn mineralization occurring within the Xuancheng ore district of the Middle-Lower Yangtze River Metallogenic Belt of eastern China.The precise age of an ore deposit is important for understanding the timing of mineralization relative to other geological events in a region and to fully place the formation of a mineral deposit within the geological context of other processes that occur within the study area.Here,we present new molybdenite Re-Os and titanite and andradite garnet U-Pb ages for the Magushan deposit and use these data to outline possible approaches for identifying genetic relationships in geologically complex areas.The spatial and paragenetic relationships between the intrusions,alteration,and mineralization within the study area indicates that the formation of the Magushan deposit is genetically associated with the porphyritic granodiorite.However,this is not always the case,as some areas contain complexly zoned plutons with multiple phases of intrusion or mineralization may be distal from or may not have any clear spatial relationship to a pluton.This means that it may not be possible to determine whether the mineralization formed as a result of single or multiple magmatic/hydrothermal events.As such,the approaches presented in this study provide an approach that allows the identification of any geochronological relationships between mineralization and intrusive events in areas more complex than the study area.Previously published zircon U-Pb data for the mineralization-related porphyritic granodiorite in this area yielded an age of 134.2±1.2 Ma(MSWD=1.4)whereas the Re-Os dating of molybdenite from the study area yielded an isochron age of 137.7±2.5 Ma(MSWD=0.43).The timing of the mineralizing event in the study area was further examined by the dating of magmatic accessory titanite and skarn-related andradite garnet,yielding U-Pb ages of 136.3±2.5 Ma(MSWD=3.2)and 135.9±2.7 Ma(MSWD=2.5),respectively.The dating of magmatic and hydrothermal activity within the Magushan area yields ages around 136 Ma,strongly suggesting that the mineralization in this area formed as a result of the emplacement of the intrusion.The dates presented in this study also provide the first indication of the timing of mineralization within the Xuancheng district.providing evidence of a close genetic relationship between the formation of the mineralization within the Xuancheng district and the Early Cretaceous magmatism that occurred in this area.This in turn suggests that other Early Cretaceous intrusive rocks within this region are likely to be associated with mineralization and should be considered highly prospective for future mineral exploration.This study also indicates that the dating of garnet and titanite can also provide reliable geochronological data and evidence of the timing of mineralization and magmatism,respectively,in areas lacking other dateable minerals(e.g.,molybdenite)or where the relationship between mineralization and magmatism is unclear,for example in areas with multiple stages of magmatism,with complexly zoned plutons,and with distal skarn mineralization.

Re–Os dating of molybdenite and in-situ Pb isotopes of sulfides from the Lamo Zn–Cu deposit in the Dachang tin-polymetallic ore field, Guangxi, China

The Dachang tin-polymetallic district, Guangxi,China, is one of the largest tin ore fields in the world. Both cassiterite-sulfide and Zn–Cu skarn mineralization are hosted in the Mid-Upper Devonian carbonate-rich sediments adjacent to the underlying Cretaceous Longxianggai granite(91–97 Ma). The Lamo Zn–Cu deposit is a typical skarn deposit in the district and occurs at the contact zone between the Upper Devonian limestone and the granite.The ore minerals mainly consist of sphalerite, arsenopyrite,pyrrhotite, galena, chalcopyrite, and minor molybdenite.However, the age of mineralization and source of the metals are not well constrained. In this study, we use the molybdenite Re–Os dating method and in-situ Pb isotopes of sulfides from the Lamo deposit for the first time in order to directly determine the age of mineralization and the tracing source of metals. Six molybdenite samples yielded a more accurate Re–Os isochron age of 90.0 ± 1.1 Ma(MSWD = 0.72), which is much younger than the reported garnet Sm–Nd isochron age of 95 ± 11 Ma and quartz fluid inclusions Rb–Sr isochron age of 99 ± 6 Ma. This age is also interpreted as the age of Zn–Cu skarn mineralization in the Dachang district. Further, in this study we found that in-situ Pb isotopes of sulfides from the Lamo deposit and feldspars in the district's biotite granite and granitic porphyry dikes have a narrow range and an overlap of Pb isotopic compositions(^(206) Pb/^(204) Pb =18.417–18.594,^(207) Pb/^(204) Pb = 15.641–15.746, and^(208) Pb/^(204) Pb = 38.791–39.073), suggesting that the metals were mainly sourced from Cretaceous granitic magma.

内蒙古扎拉格阿木铜多金属矿床硫化物Re-Os年龄及其地质意义

内蒙古扎拉格阿木铜多金属矿床是近年来在大兴安岭中南段西坡发现的一处中型铜多金属矿床。矿床产出于花岗闪长岩体与中二叠统哲斯组外接触带,矿体分布受北东向断裂构造控制。本文运用Re-Os同位素定年法对主成矿阶段形成的辉钼矿和毒砂开展了成矿年龄测定,获得1件辉钼矿Re-Os模式年龄为141.81±0.84 Ma,3件毒砂Re-Os模式年龄分别为138.1±0.9、140.8±7.7和141.2±2.1 Ma,等时线年龄为137.7±1.7 Ma;4件样品的加权平均年龄为140.2±3.3 Ma。结果表明,该矿床形成于早白垩世,为燕山晚期构造-岩浆-成矿作用耦合的产物。扎拉格阿木铜多金属矿床成矿年龄的首次厘定,对该区铜多金属矿的勘查和矿床成因研究具有指示意义。

山东孔辛头铜钼矿成矿时代及物质来源:来自黄铜矿、辉钼矿Re-Os同位素证据

孔辛头铜钼矿床产于胶东地区伟德山超单元院格庄二长花岗岩与荆山群大理岩接触带形成的夕卡岩中,主矿体呈透镜状、囊状、脉状产出,受岩体内部裂隙构造控制。分别采用电感耦合等离子体质谱、热表面电离质谱Re-Os同位素测试技术对其中的辉钼矿、黄铜矿、磁铁矿进行了研究。结果显示,辉钼矿Re-Os等时线年龄为117±1 Ma,黄铜矿Re-Os等时线年龄为118.4±3.2 Ma,与区域上尚家庄钼矿床、冷家钼矿床成矿时代一致,几个矿床成因均与伟德山超单元有关,表明了胶东地区存在燕山晚期的钼矿化事件。而磁铁矿Re-Os封闭性较差,无法得到年龄。黄铜矿初始^(187)Os/^(188)Os值为0.32±0.17,表明了孔辛头铜钼矿床金属成矿物质为壳幔混合来源,形成于早白垩世太平洋板块向亚欧大陆俯冲而成的弧后拉张背景之下。

纳日贡玛斑岩钼铜矿床：玉龙铜矿带的北延--来自辉钼矿Re-Os同位素年龄的证据

纳日贡玛钼(铜)矿床位于西南"三江"北段青海南部地区,构造上位于金沙江缝合带与班公湖-怒江缝合带所夹持的羌塘地体之上,该区是吸纳和调节印度-亚洲大陆碰撞应力应变的构造转换带;受印度-亚洲大陆斜向碰撞事件的影响,区内新生代构造变形异常复杂,至51Ma 以来,区内形成了一系列 NW-SE 向的逆冲断裂系统及走滑断裂系统,并伴有少量钾质岩浆活动;纳日贡玛斑岩钼(铜)矿床便产于新生代黑云母花岗斑岩及其接触带中。长期以来,由于缺少可靠的年代学数据,人们对纳日贡玛矿床的产出环境尚不清楚,与玉龙癍岩铜矿带的关系还比较模糊。为此,本文选取了纳日贡玛钼铜矿6件辉钼矿样品进行 Re-Os 同位素测年,结果给出了一条均方差为0.79的 Re-Os 等值线,其年龄为40.86±0.85Ma,这与玉龙斑岩铜矿代的成矿年龄基本一致,应为玉龙铜矿带的北延;较大的成矿带延长范围表明,在玉龙至纳日贡玛上千公里的范围内,仍有寻找大型斑岩铜(钼)矿床的巨大潜力。

汝城高坳背钨—钼矿区花岗岩锆石U-Pb年龄、Hf同位素及矿石辉钼矿Re-Os年龄

湖南汝城高坳背钨—钼矿床是湘南地区近年发现的远景规模达大型或超大型的黑钨矿石英脉型热液钨—钼矿床,然而对该矿床与成矿有关的花岗岩的成岩年龄和钨—钼成矿年龄还缺乏研究。本文利用锆石SHRIMP U-Pb同位素定年方法对该矿区黑云母二长花岗岩进行了年龄测定,获得其侵位年龄为222.1±2.0Ma,其中还发现其锆石内核含古元古代—新太古代的继承锆石。晚三叠世年龄的锆石具低的εHf(t)值(-4.7～-10.9)和1.6～2.0Ga的Hf同位素两阶段模式年龄,表明它们的岩浆源区主要以华南古元古代基底物质或者更古老的基底物质改造而成。古元古代—新太古代继承锆石中正的εHf(t)值(4.3～8.5)的存在,暗示形成这些古老继承锆石的初始物质中有幔源物质的加入。利用辉钼矿Re-Os等时线法,获得该矿的成矿年龄为157.3±6.6Ma(n=5,MSWD=0.11)。高坳背钨—钼矿区黑云母二长花岗岩锆石年龄、Hf同位素资料和钨钼矿成矿年龄表明,花岗岩中存在古老地壳的残留锆石,说明花岗岩的物质来源可能与华南古老的陆壳基底有关,钨钼矿区黑云母二长花岗岩成岩时代为晚三叠世,而成矿时代为晚侏罗世,推测该矿深部有晚侏罗世的花岗岩存在。这些新的同位素年龄资料为研究华南同类矿床的形成演化与指导区域找矿提供了重要的地球化学依据。

含有普通锇的辉钼矿Re-Os同位素定年研究

通过大量数据统计,表明较高比例的辉钼矿中存在普通锇。普通锇可能以类质同像形式存在于辉钼矿样品中,理论上辉钼矿中可能含有较高含量普通锇。辉钼矿样品含有较高含量普通锇可能对Re-Os定年结果产生很大影响,从原理上并结合实例证实了普通锇含量对辉钼矿Re-Os年龄影响程度。对于一般辉钼矿样品来讲,如果187Os总量(放射成因187Os与非放射成因187Os之和)与普通锇比值小于20,需要考虑普通锇对Re-Os模式年龄的影响,并提出了对于含有普通锇辉钼矿模式年龄的计算方法。先做出187Os/188Os-187Re/188Os等时线,求得初始187Os/188Os值,再根据初始187Os/188Os值和单个样品的普Os含量求得非放射成因的普Os中187Os的量。最后根据Re含量以及放射成因187Os含量得到模式年龄。

东昆仑拉陵灶火钼多金属矿床地质特征及辉钼矿Re-Os同位素定年

拉陵灶火钼多金属矿床是青海祁漫塔格成矿带新发现的矽卡岩-斑岩型矿床。利用辉钼矿Re-Os同位素定年技术,11件样品和4件重复样品的模式年龄显示2个分段：214.1-223.9 Ma与235.7-240.8 Ma,187Re-187Os等时线年龄分别为（214.5±4.9）Ma和（240.8±4.0）Ma,模式年龄的加权平均值分别为（217.6±3.5）Ma和（238.4±1.2）Ma,等时线年龄与模式年龄加权平均值在误差范围内一致,表明矿床存在2期成矿作用：中三叠世和晚三叠世。辉钼矿样品中铼含量为17.40×10-6-149.52×10-6,绝大多数集中在十几至几十微克,指示其成矿物质来源为壳幔混合源。结合前人及本次研究成果表明,两次成矿作用分别与中三叠世东昆仑地区俯冲结束与碰撞开始时的板片断离作用和晚三叠世岩石圈拆沉作用有关。

赣西北大湖塘钨矿床辉钼矿Re-Os同位素定年及其意义

江西省武宁县大湖塘钨矿位于武宁县西南方向41km,赣西北地区武宁、靖安、修水3县交界处,矿区处于下扬子成矿省之江南隆起东段成矿带之西部,是与燕山期花岗质岩浆活动有关的钨矿床,也是最近刚勘查出的我国规模最大的钨矿床。本文采用辉钼矿Re-Os同位素定年技术,测得大湖塘石门寺矿段辉钼矿Re-Os等时线年龄为143.7±1.2Ma(n=6,MSWD=0.84);狮尾洞矿段辉钼矿Re-Os等时线年龄为140.9±3.6Ma(n=6,MSWD=2.30)。说明其成矿于早白垩世,与其北侧的、同处于下扬子成矿省的长江中下游成矿带九瑞-鄂东南矿集区的铜多金属矿床成岩成矿年龄非常一致,但与华南成矿省之南岭成矿带的钨矿成矿作用有诸多不同。下扬子成矿省主要为早期两大古陆碰撞对接、构造格局开始大转换时期成矿,而华南成矿省为地壳重熔形成的花岗质岩浆经过多期次和多阶段分异演化在最晚阶段富集成矿。

鄂东南地区鸡笼山矽卡岩金矿床的辉钼矿Re-Os同位素年龄及其构造意义

鄂东南地区是我国长江中下游Cu-Au-Fe-Mo成矿带中最重要的组成部分之一，其中鸡笼山金矿是是区内典型的大型矽卡岩金矿床。本文利用Re-Os同位素定年方法对鸡笼山金矿床进行了成矿时代测定，获得了辉钼矿的Re-Os同位素模式年龄范围为147．7±2．4～151．6±4．0Ma，等时线年龄为148．6±1．5Ma，与矿区内花岗闪长斑岩SHRIMP锆石U-Pb年龄151．6±0．7Ma相吻合，也与鄂东南地区其他矿田的成矿时代基本一致。鸡笼山矽卡岩金矿床可能形成于岩石圈伸展构造背景。硫同位素值为-2．5‰～5．5‰，均值为2．84‰，具有明显的塔式效应，反映了成矿物质具有岩浆来源的特征；辉钼矿中 Re 含量为174．3×10-6～871．4×10-6，平均为476．2×10-6，表明成矿物质来源属于壳幔混源型。

湘南新田岭大型钨钼矿床辉钼矿Re-Os同位素测年及其地质意义

新田岭矿床是湘南地区一大型矽卡岩-石英脉型钨钼多金属矿床,在成因上与骑田岭岩体早期侵位的角闪石黑云母二长花岗岩相关。分别对该矿床矽卡岩型和石英脉型矿石内的辉钼矿单矿物进行了Re-Os同位素测年,结果显示,矽卡岩型矿石中1件辉钼矿的187Re-187Os模式年龄为159.1±2.6Ma,6件石英脉型矿石中辉钼矿的187Re-187Os模式年龄为159.1～160.2Ma,加权平均值为159.4±1.3Ma,对应的等时线年龄为161.7±9.3Ma,与已有的矽卡岩内铁云母Ar-Ar年龄(157.1±0.3Ma)和石英脉内石英流体包裹体的Rb-Sr年龄(157.4±3.2Ma)在误差范围内相吻合,指示新田岭钨钼矿床的成矿时限大致可限定为157.1～161.7Ma,表明钨钼矿化与该区骑田岭岩体早期侵位的角闪石黑云母花岗岩(160～163Ma)具有密切的时间关系。结合已有的研究结果认为,新田岭大型钨钼矿床与骑田岭岩体早期侵位的角闪石黑云母二长花岗岩具有密切的时、空联系,而南部的芙蓉锡矿与晚期侵位的黑云母二长花岗岩更为密切,整个骑田岭A型花岗岩的侵位及相关的钨锡多金属成矿作用应为一个连续的演化过程,均为南岭地区150～160Ma钨锡多金属爆发式成矿作用的产物。该区在中-晚侏罗世(150～165Ma)岩石圈的伸展减薄背景下,软流圈地幔物质沿着深大断裂上涌,强烈的壳幔相互作用可能为大规模的花岗质岩浆活动及钨锡多金属的成矿大爆发提供了主要的热动力和部分物源。

福建紫金山矿田罗卜岭斑岩型铜钼矿床辉钼矿Re-Os定年及地质意义

罗卜岭铜钼矿床是位于紫金山矿田北东侧的一个大型斑岩型铜钼矿床,铜钼矿体产于四方花岗闪长岩和罗卜岭花岗闪长斑岩体内。通过对该矿床11件代表性辉钼矿样品进行Re-Os同位素定年,获得的模式年龄为104.7±1.6～106.5±1.5Ma,等时线年龄为104.9±1.6Ma,与赋矿围岩的成岩年龄一致,表明罗卜岭铜钼矿床形成于早白垩世,属燕山晚期构造-岩浆活动产物。由于斑岩铜钼矿床为紫金山矿田成矿流体早期演化的产物,故认为紫金山矿田成矿流体演化起始于105Ma左右。

西藏甲玛铜多金属矿辉钼矿Re-Os定年及其成矿意义

西藏墨竹工卡县甲玛铜多金属矿中,辉钼矿普遍发育,产于各类矿石中,尤其在矽卡岩型和角岩型矿石中最常见,其次是斑岩型矿石,极少量产于大理岩和结晶灰岩型矿石中。本文采集了甲玛铜多金属矿矽卡岩、角岩和斑岩中不同产状、不同形态的辉钼矿,进行Re-Os同位素定年,获得了27件样品的模式年龄为14.2～17.5Ma,等时线年龄为15.22±0.59Ma。其中,斑岩型辉钼矿等时线年龄为14.78±0.33Ma,角岩型辉钼矿等时线年龄为14.67±0.19Ma,结果一致。辉钼矿中187Re含量变化于38.75～387.4μg/g,其中,角岩中辉钼矿187Re含量为121.5～387.4μg/g,矽卡岩中为123.7～304.7μg/g,含量较高,而斑岩中辉钼矿的187Re含量相对较低,38.75～130.5μg/g,平均69.0μg/g;辉钼矿187Os含量变化情况基本与187Re相同。甲玛辉钼矿187Re值与冈底斯其他矿体的值对比,显示冈底斯成矿带斑岩-矽卡岩型矿床成矿原岩具有相对较高187Re值的特点。本文研究成果表明,甲玛大型铜多金属矿床形成于中新世Langhian期,辉钼矿为主成矿期的产物之一。鉴于辉钼矿的产出状态,以及其与黄铜矿等的共生组合关系,辉钼矿的成矿时代可代表矿区内主要矿石矿物的成矿时代,且与冈底斯成矿带上一大批大中型斑岩型铜矿的成矿时代一致,成矿集中在20～10Ma之间,形成于印度大陆与亚洲大陆碰撞之后,从而否定了前人海底喷流沉积的成因观点,为矿区内及其外围进一步的找矿指明了方向。