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电感耦合等离子体质谱法测定金红石单矿物中痕量稀土元素 被引量:12
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作者 赵楠楠 黄慧萍 +1 位作者 李艳玲 程海涛 《理化检验(化学分册)》 CAS CSCD 北大核心 2012年第7期781-784,共4页
提出了电感耦合等离子体质谱法测定金红石单矿物中痕量稀土元素。样品经过氧化钠熔融,用水浸出,以过氧化氢络合除去钛,经氢型阳离子交换树脂分离富集稀土元素。采用内标法消除基体影响。方法的检出限(3s/k)在0.001~0.062μg.L-1之间。... 提出了电感耦合等离子体质谱法测定金红石单矿物中痕量稀土元素。样品经过氧化钠熔融,用水浸出,以过氧化氢络合除去钛,经氢型阳离子交换树脂分离富集稀土元素。采用内标法消除基体影响。方法的检出限(3s/k)在0.001~0.062μg.L-1之间。应用此法测定了13份金红石样品中稀土元素的含量,测定值的相对标准偏差(n=13)均小于3.0%。 展开更多
关键词 电感耦合等离子体质谱法 单矿物 金红石 稀土元素
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电感耦合等离子体质谱法测定铬铁矿单矿物中痕量稀土元素 被引量:20
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作者 黄慧萍 李艳玲 +2 位作者 陶德刚 熊采华 方金东 《冶金分析》 EI CAS CSCD 北大核心 2005年第6期42-45,共4页
采用过氧化钠熔融铬铁矿单矿物,三乙醇胺溶液提取,在碱性溶液中沉淀,稀土元素与基体物质得到很好的分离,经氢型阳离子交换树脂分离富集,应用电感耦合等离子体质谱法(ICP-MS)对铬铁矿单矿物中13个痕量稀土元素进行测定,用103Rh作内标元... 采用过氧化钠熔融铬铁矿单矿物,三乙醇胺溶液提取,在碱性溶液中沉淀,稀土元素与基体物质得到很好的分离,经氢型阳离子交换树脂分离富集,应用电感耦合等离子体质谱法(ICP-MS)对铬铁矿单矿物中13个痕量稀土元素进行测定,用103Rh作内标元素补偿基体效应和灵敏度漂移.方法回收率为88.2%~109.8%,相对标准偏差(n=9)小于16.3%,检出限为0.001 2~0.39μg/L. 展开更多
关键词 电感耦合等离子质谱法 铬铁矿单矿物 稀土元素 碱沉淀法 阳离子交换树脂
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论岩浆成因的黄玉单矿物岩 被引量:3
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作者 沈敢富 《地质论评》 CAS CSCD 北大核心 1997年第6期607-615,共9页
业已在自然界发现中深成相、超浅成相和良好封闭相的岩浆成因黄玉单矿物岩,拥有宏观、微观岩浆成因标志,得到有关富挥发分酸性岩体成岩、成矿实验成果的有力佐证,属一类新的岩浆岩。这类岩石的分类实践表明,它们宜归入岩浆成因的云英岩... 业已在自然界发现中深成相、超浅成相和良好封闭相的岩浆成因黄玉单矿物岩,拥有宏观、微观岩浆成因标志,得到有关富挥发分酸性岩体成岩、成矿实验成果的有力佐证,属一类新的岩浆岩。这类岩石的分类实践表明,它们宜归入岩浆成因的云英岩类范畴。有理由预见,自然界存在有黄玉单矿物岩的火山类似物,尚待发现与研究。提出的岩浆黄玉单矿物岩的成岩、成矿模式,不否定黄玉化发育,但认为,盲目滥用和过分夸大蚀变作用及其成岩、成矿的重要性是不可取的。 展开更多
关键词 岩浆成因 黄玉单矿物岩 黄玉 成岩 成矿
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Comparison of mantle lithosphere beneath early Triassic kimberlite fields in Siberian craton reconstructed from deep-seated xenocrysts 被引量:1
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作者 I.V.Ashchepkov S.S.Kuligin +6 位作者 N.V.Vladykin H.Downes M.A.Vavilov E.N.Nigmatulina S.A.Babushkina N.S.Tychkov O.S.Khmelnikova 《Geoscience Frontiers》 SCIE CAS CSCD 2016年第4期639-662,共24页
Mantle xenocrysts from early Triassic kimberlite pipes from Kharamai, Ary-Mastakh and Kuranakh fields in the Anabar shield of Siberia revealing similar compositional trends were studied to estimate the superplume infl... Mantle xenocrysts from early Triassic kimberlite pipes from Kharamai, Ary-Mastakh and Kuranakh fields in the Anabar shield of Siberia revealing similar compositional trends were studied to estimate the superplume influence on the subcratonic lithosphere mantle (SCLM). Pressure-temperature (PT) reconstructions using monomineral thermobarometry for 5 phases show division of the SCLM beneath the Kharamai field into 6 units: pyroxenitic Fe-rich (1-2 GPa) and Mg-rich (2-3 GPa) layers; middle with two levels of Gar-Sp pyroxenites at - 3 and 4-5 GPa; Gar-dunite-harzburgites - 4.5-6.5 GPa subjected to llm-Px vein metasomatism; and a Mg-rich dunite lower part. In the Anabar shield (Ary-Mastakh, Dyuken and Kuranakh fields) mantle lithosphere is composed of three large units divided into two parts: upper part with amphiboles and phlogopite; two levels of pyroxenites and eclogites at 3 and 4 GPa, and a lower part composed of refertilized dunites. Diagrams showing P-Fe#Gar clusters for garnets and omphacites illustrate the differences between SCLM of these localities. Differences of Triassic SCLM from Devonian SCLM are in simple layering; abundance of Na-Cr-amphiboles and metasomatism in the upper SCLM part, thick pyroxenite-eclogite layer and lower part depletion, heated from SCLM base to 5.0 GPa. Kharamai mantle clinopyroxenes represent three geochemical types: (1) harzburgitic with inclined linear REE, HFSE troughs and elevated Th, U; (2) lherzolitic or pyroxenitic with round TRE patterns and decreasing incompatible elements; (3) eclogitic with Eu troughs, Pb peak and high LILE content. Calculated parental melts for garnets with humped REE patterns suggest dissolution of former Cpx and depression means Cpx and garnets extraction. Clinopyroxenes from Ary-Mastakh fields show less in- dined REE patterns with HMREE troughs and an increase of incompatible elements. Clinopyroxenes from Kuranakh field show flatter spoon-like REE patterns and peaks in Ba, U, Pb and St, similar to those in ophiolitic harzburgites. The PT diagrams for the mantle sections show high temperature gradients in the uppermost SCLM accompanied by an increase of P-Fe#OI upward and slightly reduced thickness of the mantle keel of the Siberian craton, resulting from the influence of the Permian-Triassic superplume, but with no signs of delamination. 展开更多
关键词 Mantle lithosphere monomineral thermobarometry Mineral geochemistry Triassic kimberlite LAYERING
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Mantle Transects in Africa According to Data of Mantle Xenocrysts and Diamond Inclusions
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作者 Igor V.ASHCHEPKOV Vladimir N.ZINCHENKO Alexandr S.IVANOV 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2021年第S01期15-17,共3页
We designed the mantle transects using the PTXFO2 diagrams(Ashchepkov et al.,2010,2013,2017)constructed(Figs.1 a–c)for mantle columns beneath kimberlite and sections of the lithospheric mantle(SCLM)under the Kaapvaal... We designed the mantle transects using the PTXFO2 diagrams(Ashchepkov et al.,2010,2013,2017)constructed(Figs.1 a–c)for mantle columns beneath kimberlite and sections of the lithospheric mantle(SCLM)under the Kaapvaal and the Congo cratons.The set of the pipes is in(Zinchenko et al.,2020,2021). 展开更多
关键词 mantle lithosphere craton transect monomineral thermobarometry oxygen fugacity PERIDOTITE eclogite garnet CLINOPYROXENE
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