The mixed complex [Ni(L)(L')](ClO4)2 has been synthesized using 2-aminoethyl- bi(3-bi-aminopropyl)amine with phen (1,10-phenanthroline) in the presence of Ni(Ⅱ) ion, and its structure was determined by X...The mixed complex [Ni(L)(L')](ClO4)2 has been synthesized using 2-aminoethyl- bi(3-bi-aminopropyl)amine with phen (1,10-phenanthroline) in the presence of Ni(Ⅱ) ion, and its structure was determined by X-ray diffraction. The crystal crystallizes in monoclinic, space group P21/c with a = 13.713(2), b = 13.1466(19), c = 14.780(2) A°, β= 97.620(3)°, V = 2640.9(7) A °^3, F(000) = 1272, Z = 4, Dc = 1.540 g/cm^3, R = 0.0536 and wR = 0.1207. The Ni^2+ ion is sixcoordinated to furnish a distorted octahedral geometry.展开更多
基金This project was supported by the National Natural Science Foundation of China (No. 50372028) and the Foundation of hhit Marine-Technology lab.
文摘The mixed complex [Ni(L)(L')](ClO4)2 has been synthesized using 2-aminoethyl- bi(3-bi-aminopropyl)amine with phen (1,10-phenanthroline) in the presence of Ni(Ⅱ) ion, and its structure was determined by X-ray diffraction. The crystal crystallizes in monoclinic, space group P21/c with a = 13.713(2), b = 13.1466(19), c = 14.780(2) A°, β= 97.620(3)°, V = 2640.9(7) A °^3, F(000) = 1272, Z = 4, Dc = 1.540 g/cm^3, R = 0.0536 and wR = 0.1207. The Ni^2+ ion is sixcoordinated to furnish a distorted octahedral geometry.