Structural and optical properties of ~ 20 nm Ge nanoislands grown on Si(100) by radio frequency (rI) magnetron sputtering under varying annealing conditions are reported. Rapid thermal annealing at a temperature...Structural and optical properties of ~ 20 nm Ge nanoislands grown on Si(100) by radio frequency (rI) magnetron sputtering under varying annealing conditions are reported. Rapid thermal annealing at a temperature of 600 ℃ for 30 s, 90 s, and 120 s are performed to examine the influence of annealing time on the surface morphology and photoluminescence properties. X-ray diffraction spectra reveal prominent Ge and GeO2 peaks highly sensitive to the annealing time. Atomic force microscope micrographs of the as-grown sample show pyramidal nanoislands with relatively high-density (~ 10^11 cm^-2). The nanoislands become dome-shaped upon annealing through a coarsening process mediated by Oswald ripening. The room temperature photoluminescence peaks for both as-grown (~ 3.29 eV) and annealed (~ 3.19 eV) samples consist of high intensity and broad emission, attributed to the effect of quantum confinement. The red shift (~ 0.10 eV) of the emission peak is attributed to the change in the size of the Ge nanoislands caused by annealing. Our easy fabrication method may contribute to the development of Ge nanostructure-based optoelectronics.展开更多
基金supported by the International Doctoral Fellowship (IDF), Ibnu Sina Institute for Fundamental Science Study and research grants of MoHE GUP. Vot No. 02H94 and 07J80
文摘Structural and optical properties of ~ 20 nm Ge nanoislands grown on Si(100) by radio frequency (rI) magnetron sputtering under varying annealing conditions are reported. Rapid thermal annealing at a temperature of 600 ℃ for 30 s, 90 s, and 120 s are performed to examine the influence of annealing time on the surface morphology and photoluminescence properties. X-ray diffraction spectra reveal prominent Ge and GeO2 peaks highly sensitive to the annealing time. Atomic force microscope micrographs of the as-grown sample show pyramidal nanoislands with relatively high-density (~ 10^11 cm^-2). The nanoislands become dome-shaped upon annealing through a coarsening process mediated by Oswald ripening. The room temperature photoluminescence peaks for both as-grown (~ 3.29 eV) and annealed (~ 3.19 eV) samples consist of high intensity and broad emission, attributed to the effect of quantum confinement. The red shift (~ 0.10 eV) of the emission peak is attributed to the change in the size of the Ge nanoislands caused by annealing. Our easy fabrication method may contribute to the development of Ge nanostructure-based optoelectronics.