Laboratory-scale carbon anodes were produced by a new method of high temperature mould pressing, and their physico-chemical properties were studied. The influence of mould pressing conditions and coal pitch addition o...Laboratory-scale carbon anodes were produced by a new method of high temperature mould pressing, and their physico-chemical properties were studied. The influence of mould pressing conditions and coal pitch addition on the bulk density, crushing strength, and oxidation resistance was analyzed. The mierostructure of carbon anodes was investigated by scanning electron microscopy （SEM）, and the mechanism of producing carbon anodes by high-temperature mould pressing was analyzed. The results show that when the anodes are produced by high-temperature mould pressing, coal pitch can expand into the coke particles and fill the pores inside the particles, which is beneficial for improving the quality of prebaked anodes. The bulk density of carbon anodes is 1.64-1.66 g/cm3, which is 0.08-0.12 g/cm3 higher than that of industrial anodes, and the oxidation resistance of carbon anodes is also significantly improved.展开更多
Pure copper rods containing continuous columnar crystals were fabricatedusing the downward CUS (Continuous Unidirectional Solidification) equipment. When the technologicalparameters were set as the ranges of mould tem...Pure copper rods containing continuous columnar crystals were fabricatedusing the downward CUS (Continuous Unidirectional Solidification) equipment. When the technologicalparameters were set as the ranges of mould temperature 1100-1300℃, cooling distance (the distancefrom the exit of the cast mould to the start point of cooling) 10-20 mm, casting speed 0.2-2.5 mm/s,cooling water (20-25℃) volume 1000-1320 L/h, and when these parameters matched reasonably, the CUSprocess was performed stably, and pure copper rods containing continuous columnar crystals withbright and smooth surface were produced. The dendritic arm spacing of the crystals in copper rodsdecreased with increasing the casting speed. The results of the texture by X-ray diffractionanalysis showed that the rods has strong <100> fiber texture.展开更多
The formation and propagation of the popular off-corner subsurface cracks in bloom continuous casting were investigated through thermo-mechanical analysis using three coupled thermo-mechanical models. A two-dimensiona...The formation and propagation of the popular off-corner subsurface cracks in bloom continuous casting were investigated through thermo-mechanical analysis using three coupled thermo-mechanical models. A two-dimensional thermo-elasto-visco-plastic finite element model was developed to predict the mould gap evolution, temperature profiles and deformation behavior of the solidified shell in the mould region. Then, a three-dimensional model was adopted to calculate the shell growth, tempera- ture history and the development of stresses and strains of the shell in the following secondary cooling zones. Finally, another three-dimensional model was used to analyze the stress distributions in the straightening region, The results showed that the off-corner cracks in the shell originated from the mould owing to the tensile strain developed in the crack sensitive regions of the solidification front, and they could be driven deeper by the possible severe surface temperature rebound and the extensive tensile stress in the secondary cooling zone, especially upon the straightening operation of the bloom casting. It is revealed that more homogenous shell temperature and thickness can be obtained through optimization of mould corner radius, casting speed and secondary cooling scheme, which help to decrease stress and strain concentration and therefore prevent the initiation of the cracks.展开更多
基金Project(090302012)supported by the Fundamental Research Funds for the Central Universities,ChinaProject(50934005)supported by the National Natural Science Foundation of China
文摘Laboratory-scale carbon anodes were produced by a new method of high temperature mould pressing, and their physico-chemical properties were studied. The influence of mould pressing conditions and coal pitch addition on the bulk density, crushing strength, and oxidation resistance was analyzed. The mierostructure of carbon anodes was investigated by scanning electron microscopy （SEM）, and the mechanism of producing carbon anodes by high-temperature mould pressing was analyzed. The results show that when the anodes are produced by high-temperature mould pressing, coal pitch can expand into the coke particles and fill the pores inside the particles, which is beneficial for improving the quality of prebaked anodes. The bulk density of carbon anodes is 1.64-1.66 g/cm3, which is 0.08-0.12 g/cm3 higher than that of industrial anodes, and the oxidation resistance of carbon anodes is also significantly improved.
基金This work was financially supported by the Major State Basic Research Project of China (G2000067206) and the National Science Fund for Distinguished Young Scientists of China (No.50125415).
文摘Pure copper rods containing continuous columnar crystals were fabricatedusing the downward CUS (Continuous Unidirectional Solidification) equipment. When the technologicalparameters were set as the ranges of mould temperature 1100-1300℃, cooling distance (the distancefrom the exit of the cast mould to the start point of cooling) 10-20 mm, casting speed 0.2-2.5 mm/s,cooling water (20-25℃) volume 1000-1320 L/h, and when these parameters matched reasonably, the CUSprocess was performed stably, and pure copper rods containing continuous columnar crystals withbright and smooth surface were produced. The dendritic arm spacing of the crystals in copper rodsdecreased with increasing the casting speed. The results of the texture by X-ray diffractionanalysis showed that the rods has strong <100> fiber texture.
文摘The formation and propagation of the popular off-corner subsurface cracks in bloom continuous casting were investigated through thermo-mechanical analysis using three coupled thermo-mechanical models. A two-dimensional thermo-elasto-visco-plastic finite element model was developed to predict the mould gap evolution, temperature profiles and deformation behavior of the solidified shell in the mould region. Then, a three-dimensional model was adopted to calculate the shell growth, tempera- ture history and the development of stresses and strains of the shell in the following secondary cooling zones. Finally, another three-dimensional model was used to analyze the stress distributions in the straightening region, The results showed that the off-corner cracks in the shell originated from the mould owing to the tensile strain developed in the crack sensitive regions of the solidification front, and they could be driven deeper by the possible severe surface temperature rebound and the extensive tensile stress in the secondary cooling zone, especially upon the straightening operation of the bloom casting. It is revealed that more homogenous shell temperature and thickness can be obtained through optimization of mould corner radius, casting speed and secondary cooling scheme, which help to decrease stress and strain concentration and therefore prevent the initiation of the cracks.
