China is home to shales of three facies:Marine shale,continental shale,and marine-continental transitional shale.Different types of shale gas are associated with significantly different formation conditions and major ...China is home to shales of three facies:Marine shale,continental shale,and marine-continental transitional shale.Different types of shale gas are associated with significantly different formation conditions and major controlling factors.This study compared the geological characteristics of various shales and analyzed the influences of different parameters on the formation and accumulation of shale gas.In general,shales in China’s several regions exhibit high total organic carbon(TOC)contents,which lays a sound material basis for shale gas generation.Marine strata generally show high degrees of thermal evolution.In contrast,continental shales manifest low degrees of thermal evolution,necessitating focusing on areas with relatively high degrees of thermal evolution in the process of shale gas surveys for these shales.The shales of the Wufeng and Silurian formations constitute the most favorable shale gas reservoirs since they exhibit the highest porosity among the three types of shales.These shales are followed by those in the Niutitang and Longtan formations.In contrast,the shales of the Doushantuo,Yanchang,and Qingshankou formations manifest low porosities.Furthermore,the shales of the Wufeng and Longmaxi formations exhibit high brittle mineral contents.Despite a low siliceous mineral content,the shales of the Doushantuo Formation feature a high carbonate mineral content,which can increase the shales’brittleness to some extent.For marine-continental transitional shales,where thin interbeds of tight sandstone with unequal thicknesses are generally found,it is recommended that fracturing combined with drainage of multiple sets of lithologic strata should be employed to enhance their shale gas production.展开更多
Recently, a new promising type of marine shale gas reservoir, carbonate-rich shale, has been discovered.But the mechanical properties of this type of shale were still unrevealed and the corresponding reservoir stimula...Recently, a new promising type of marine shale gas reservoir, carbonate-rich shale, has been discovered.But the mechanical properties of this type of shale were still unrevealed and the corresponding reservoir stimulation design was lack of guidance. Using the deep downhole cores of an exploratory carbonate-rich shale gas well, the physical and mechanical parameters and failure mechanism of the whole reservoir section were acquired and evaluated systematically, by performing XRD, tri-axial compression, Brazilian splitting, and fracture toughness tests. A new model was established to evaluate the reservoir brittleness based on fracture morphology and stress-strain curve. Recommended strategy for reservoir stimulation was discussed. Results showed that(1) Carbonate-rich shale possessed high compressive strength and high Young's modulus, which were improved by 10.74% and 3.37% compared to that of siliceous shale. It featured high tensile strength and fracture toughness, with insignificant anisotropy.(2) With the content of carbonate minerals increasing, the shear failure morphology transformed from sparse and wide brittle fractures to diffusely distributed and subtle plastic cracks.(3) The brittleness index order was: siliceous shale, clay-rich shale, carbonate-rich shale, and limestone.(4) The special properties of carbonate-rich shale were rooted in the inherent feature of carbonate minerals(high strength, high elastic modulus,and cleavage structure), resulting in greater challenge in reservoirs stimulation. The above findings would promote the understanding of carbonate-rich shale reservoirs and provide reference for the optimum design of reservoir stimulation.展开更多
The shale oil reservoir within the Yanchang Formations of Ordos Basin harbors substantial oil and gas resources and has recently emerged as the primary focus of unconventional oil and gas exploration and development.D...The shale oil reservoir within the Yanchang Formations of Ordos Basin harbors substantial oil and gas resources and has recently emerged as the primary focus of unconventional oil and gas exploration and development.Due to its complex pore and throat structure,pronounced heterogeneity,and tight reservoir characteristics,the techniques for conventional oil and gas exploration and production face challenges in comprehensive implementation,also indicating that as a vital parameter for evaluating the physical properties of a reservoir,permeability cannot be effectively estimated.This study selects 21 tight sandstone samples from the Q area within the shale oil formations of Ordos Basin.We systematically conduct the experiments to measure porosity,permeability,ultrasonic wave velocities,and resistivity at varying confining pressures.Results reveal that these measurements exhibit nonlinear changes in response to effective pressure.By using these experimental data and effective medium model,empirical relationships between P-and S-wave velocities,permeability and resistivity and effective pressure are established at logging and seismic scales.Furthermore,relationships between P-wave impedance and permeability,and resistivity and permeability are determined.A comparison between the predicted permeability and logging data demonstrates that the impedance–permeability relationship yields better results in contrast to those of resistivity–permeability relationship.These relationships are further applied to the seismic interpretation of shale oil reservoir in the target layer,enabling the permeability profile predictions based on inverse P-wave impedance.The predicted results are evaluated with actual production data,revealing a better agreement between predicted results and logging data and productivity.展开更多
Supercritical CO_(2)(SC-CO_(2)) fracturing, being a waterless fracturing technology, has garnered increasing attention in the shale oil reservoir exploitation industry. Recently, a novel pre-SC-CO_(2) hybrid fracturin...Supercritical CO_(2)(SC-CO_(2)) fracturing, being a waterless fracturing technology, has garnered increasing attention in the shale oil reservoir exploitation industry. Recently, a novel pre-SC-CO_(2) hybrid fracturing method has been proposed, which combines the advantages of SC-CO_(2) fracturing and hydraulic fracturing. However, the specific impacts of different pre-SC-CO_(2) injection conditions on the physical parameters, mechanical properties, and crack propagation behavior of shale reservoirs remain unclear. In this study, we utilize a newly developed “pre-SC-CO_(2) injection → water-based fracturing” integrated experimental device. Through experimentation under in-situ conditions, the impact of pre-SC-CO_(2) injection displacement and volume on the shale mineral composition, mechanical parameters, and fracture propagation behavior are investigated. The findings of the study demonstrate that the pre-injection SC-CO_(2) leads to a reduction in clay and carbonate mineral content, while increasing the quartz content. The correlation between quartz content and SC-CO_(2) injection volume is positive, while a negative correlation is observed with injection displacement. The elastic modulus and compressive strength exhibit a declining trend, while Poisson's ratio shows an increasing trend. The weakening of shale mechanics caused by pre-injection of SC-CO_(2) is positively correlated with the injection displacement and volume.Additionally, pre-injection of SC-CO_(2) enhances the plastic deformation behavior of shale, and its breakdown pressure is 16.6% lower than that of hydraulic fracturing. The breakdown pressure demonstrates a non-linear downward trend with the gradual increase of pre-SC-CO_(2) injection parameters.Unlike hydraulic fracturing, which typically generates primary fractures along the direction of the maximum principal stress, pre-SC-CO_(2) hybrid fracturing leads to a more complex fracture network. With increasing pre-SC-CO_(2) injection displacement, intersecting double Y-shaped complex fractures are formed along the vertical axis. On the other hand, increasing the injection rate generates secondary fractures along the direction of non-principal stress. The insights gained from this study are valuable for guiding the design of pre SC-CO_(2) hybrid fracturing in shale oil reservoirs.展开更多
For the analysis of the formation damage caused by the compound function of drilling fluid and fracturing fluid,the prediction method for dynamic invasion depth of drilling fluid is developed considering the fracture ...For the analysis of the formation damage caused by the compound function of drilling fluid and fracturing fluid,the prediction method for dynamic invasion depth of drilling fluid is developed considering the fracture extension due to shale minerals erosion by oil-based drilling fluid.With the evaluation for the damage of natural and hydraulic fractures caused by mechanical properties weakening of shale fracture surface,fracture closure and rock powder blocking,the formation damage pattern is proposed with consideration of the compound effect of drilling fluid and fracturing fluid.The formation damage mechanism during drilling and completion process in shale reservoir is revealed,and the protection measures are raised.The drilling fluid can deeply invade into the shale formation through natural and induced fractures,erode shale minerals and weaken the mechanical properties of shale during the drilling process.In the process of hydraulic fracturing,the compound effect of drilling fluid and fracturing fluid further weakens the mechanical properties of shale,results in fracture closure and rock powder shedding,and thus induces stress-sensitive damage and solid blocking damage of natural/hydraulic fractures.The damage can yield significant conductivity decrease of fractures,and restrict the high and stable production of shale oil and gas wells.The measures of anti-collapse and anti-blocking to accelerate the drilling of reservoir section,forming chemical membrane to prevent the weakening of the mechanical properties of shale fracture surface,strengthening the plugging of shale fracture and reducing the invasion range of drilling fluid,optimizing fracturing fluid system to protect fracture conductivity are put forward for reservoir protection.展开更多
To reduce CO_(2) emissions in response to global climate change,shale reservoirs could be ideal candidates for long-term carbon geo-sequestration involving multi-scale transport processes.However,most current CO_(2) s...To reduce CO_(2) emissions in response to global climate change,shale reservoirs could be ideal candidates for long-term carbon geo-sequestration involving multi-scale transport processes.However,most current CO_(2) sequestration models do not adequately consider multiple transport mechanisms.Moreover,the evaluation of CO_(2) storage processes usually involves laborious and time-consuming numerical simulations unsuitable for practical prediction and decision-making.In this paper,an integrated model involving gas diffusion,adsorption,dissolution,slip flow,and Darcy flow is proposed to accurately characterize CO_(2) storage in depleted shale reservoirs,supporting the establishment of a training database.On this basis,a hybrid physics-informed data-driven neural network(HPDNN)is developed as a deep learning surrogate for prediction and inversion.By incorporating multiple sources of scientific knowledge,the HPDNN can be configured with limited simulation resources,significantly accelerating the forward and inversion processes.Furthermore,the HPDNN can more intelligently predict injection performance,precisely perform reservoir parameter inversion,and reasonably evaluate the CO_(2) storage capacity under complicated scenarios.The validation and test results demonstrate that the HPDNN can ensure high accuracy and strong robustness across an extensive applicability range when dealing with field data with multiple noise sources.This study has tremendous potential to replace traditional modeling tools for predicting and making decisions about CO_(2) storage projects in depleted shale reservoirs.展开更多
The mechanical property of mudstone/shale in coal measures is a key factor of engineering mechanics that influences the development of shale gas. A rock mechanics test was performed in order to analyze the complete st...The mechanical property of mudstone/shale in coal measures is a key factor of engineering mechanics that influences the development of shale gas. A rock mechanics test was performed in order to analyze the complete stress-strain mechanic characteristics and influence factors of mudstone/shale in paralic coal measures, from the Carboniferous-Permian periods in a coal field of Northern China. The relationship between the mechanical properties of mudstone/shale in coal measures, and its chemical component, water content are established, and their models are constructed. Research results show that mud- stone/shale has low mechanical strength, low elastic modulus and a high Poisson's ratio. The complete stress-strain curve has apparent elastoplastic deformation characteristics, and after reaching peak strength, it exhibits obvious strain softening characteristics. The uniaxial compressive strength of mudstone/shale and its elastic modulus increases exponentially with the increase of SiO2 content, and as the ignition loss increases, the uniaxial compressive strength and elastic modulus of mudstone/shale will decrease according to the law of power function. The compressive strength of mudstone/shale and its elastic modulus will decrease with the increase of water content in mudstone/shale.展开更多
To fully exploit the technical advantages of the large-depth and high-precision artificial source electromagnetic method in the complex structure area of southern Sichuan and compensate for the shortcomings of the con...To fully exploit the technical advantages of the large-depth and high-precision artificial source electromagnetic method in the complex structure area of southern Sichuan and compensate for the shortcomings of the conventional electromagnetic method in exploration depth,precision,and accuracy,the large-depth and high-precision wide field electromagnetic method is applied to the complex structure test area of the Luochang syncline and Yuhe nose anticline in the southern Sichuan.The advantages of the wide field electromagnetic method in detecting deep,low-resistivity thin layers are demonstrated.First,on the basis of the analysis of physical property data,a geological–geoelectric model is established in the test area,and the wide field electromagnetic method is numerically simulated to analyze and evaluate the response characteristics of deep thin shale gas layers on wide field electromagnetic curves.Second,a wide field electromagnetic test is conducted in the complex structure area of southern Sichuan.After data processing and inversion imaging,apparent resistivity logging data are used for calibration to develop an apparent resistivity interpretation model suitable for the test area.On the basis of the results,the characteristics of the electrical structure change in the shallow longitudinal formation of 6 km are implemented,and the transverse electrical distribution characteristics of the deep shale gas layer are delineated.In the prediction area near the well,the subsequent data verification shows that the apparent resistivity obtained using the inversion of the wide field electromagnetic method is consistent with the trend of apparent resistivity revealed by logging,which proves that this method can effectively identify the weak response characteristics of deep shale gas formations in complex structural areas.This experiment,it is shown shows that the wide field electromagnetic method with a large depth and high precision can effectively characterize the electrical characteristics of deep,low-resistivity thin layers in complex structural areas,and a new set of low-cost evaluation technologies for shale gas target layers based on the wide field electromagnetic method is explored.展开更多
Under the policy background and advocacy of carbon capture,utilization,and storage(CCUS),CO_(2)-EOR has become a promising direction in the shale oil reservoir industry.The multi-scale pore structure distribution and ...Under the policy background and advocacy of carbon capture,utilization,and storage(CCUS),CO_(2)-EOR has become a promising direction in the shale oil reservoir industry.The multi-scale pore structure distribution and fracture structure lead to complex multiphase flow,comprehensively considering multiple mechanisms is crucial for development and CO_(2) storage in fractured shale reservoirs.In this paper,a multi-mechanism coupled model is developed by MATLAB.Compared to the traditional Eclipse300 and MATLAB Reservoir Simulation Toolbox(MRST),this model considers the impact of pore structure on fluid phase behavior by the modified Peng—Robinson equation of state(PR-EOS),and the effect simultaneously radiate to Maxwell—Stefan(M—S)diffusion,stress sensitivity,the nano-confinement(NC)effect.Moreover,a modified embedded discrete fracture model(EDFM)is used to model the complex fractures,which optimizes connection types and half-transmissibility calculation approaches between non-neighboring connections(NNCs).The full implicit equation adopts the finite volume method(FVM)and Newton—Raphson iteration for discretization and solution.The model verification with the Eclipse300 and MRST is satisfactory.The results show that the interaction between the mechanisms significantly affects the production performance and storage characteristics.The effect of molecular diffusion may be overestimated in oil-dominated(liquid-dominated)shale reservoirs.The well spacing and injection gas rate are the most crucial factors affecting the production by sensitivity analysis.Moreover,the potential gas invasion risk is mentioned.This model provides a reliable theoretical basis for CO_(2)-EOR and sequestration in shale oil reservoirs.展开更多
The differences in organic matter abundance and rock composition between shale and mudstone determine the discrepancy of their contributions to the formation of conventional and shale oil/gas reservoirs.The evaluation...The differences in organic matter abundance and rock composition between shale and mudstone determine the discrepancy of their contributions to the formation of conventional and shale oil/gas reservoirs.The evaluation criteria of source rocks are different in the future exploration in self-sourced petroleum systems.Shales are deposited in deep/semi-deep lacustrine,with low sedimentation rate and chemical depositions of various degrees,while mudstones are mostly formed in shallow lacustrine/lakeside,with high deposition rate and density flow characteristics.Three factors contribute to the enrichment of organic matter in shales,including the"fertility effect"caused by volcanic ash deposition and hydrothermal injection,excessive and over-speed growth of organisms promoted by radioactive materials,and deep-water anaerobic environment and low sedimentation rate to protect the accumulation of organic matter from dilution.Lamellations in shales are easy to be stripped into storage space,and acid water produced during hydrocarbon generation can dissolve some particles to generate new pores.The massive mudstones with high clay content are of poor matrix porosity.Shales with high total organic carbon,developed laminations,relatively good reservoir property,and high brittle mineral content,are the most favorable lithofacies for shale oil exploration and development.It is necessary to conduct investigation on the differences between shale and mudstone reservoirs,to identify resources distribution in shale and mudstone formations,determine the type and standard of"sweet-spot"evaluation parameters,optimize"sweet-spot areas/sections",and adopt effective development technologies,which is of great significance to objectively evaluate the total amount and economy of shale oil resources,as well as the scale of effective exploitation.展开更多
Extant research on Paleozoic mudstone is well developed in the Tarim Basin, while the research on Carboniferous mudstone is relatively weak. Through systematic study of lithology, geochemical characteristics,reservoir...Extant research on Paleozoic mudstone is well developed in the Tarim Basin, while the research on Carboniferous mudstone is relatively weak. Through systematic study of lithology, geochemical characteristics,reservoir characteristics and gas–bearing properties of Carboniferous mudstone in the Tarim Basin, this study aims to provide a geological basis for the Paleozoic shale gas exploration and development, favorable zone optimization, and resource potential evaluation in the Tarim Basin. The results show that the sedimentary environments of organic-rich mudstone in the study area were mainly basin facies and slope facies. Lithology is dominated by black carbonaceous mudstone, followed by calcareous mudstone, siliceous mudstone, and siliceous rocks. Mudstone is mainly developed in the Kalashayi Formation,which is located in the Bachu and Markit slope belt, with the cumulative thickness of 30–200 m. The organic carbon content is commonly more than 0.4%, and the organic matter types are type II and type III. Thermal evolution degree is widely distributed from a low mature to over mature stage, and different tectonic units have a greater difference. The contents of quartz plus feldspar are between 12% and 82.5%, with an average of 45.8%. Thecontent distribution of clay mineral is from 12% to 57%,with an average of 38.2%. Carbonate minerals(mainly siderite) content is below 50%. The brittle mineral content of the mudstone is approximately 65%, with a strong compressibility, and the mudstone has the material basis of forming crack and natural fracture. Microscopic pores in micro–nanometer level are well developed in the mudstone, including micro bedding joint, microcrack,interbedded pores of clay mineral, nanoscale intragranular or edge pores in the massive organic matter, bioclastic micropores, and mineral dissolution pores, etc. According to the standards provided by the Ministry of Land and Resources in China, the Kalashayi Formation in Bamai Area is a favorable area for shale gas development.展开更多
This study is based on the sedimentation conditions, organic geochemistry, storage spaces, physical properties, lithology and gas content of the shale gas reservoirs in Longmaxi Formation of the Jiaoshiba area and the...This study is based on the sedimentation conditions, organic geochemistry, storage spaces, physical properties, lithology and gas content of the shale gas reservoirs in Longmaxi Formation of the Jiaoshiba area and the gas accumulation mode is summarized and then compared with that in northern America. The shale gas reservoirs in the Longmaxi Formation in Jiaoshiba have good geological conditions, great thickness of quality shales, high organic content, high gas content, good physical properties, suitable depth, good preservation conditions and good reservoir types. The quality shales at the bottom of the deep shelf are the main target interval for shale gas exploration and development. Shale gas in the Longmaxi Formation has undergone three main reservoiring stages:the early stage of hydrocarbon generation and compaction when shale gas reservoirs were first formed; the middle stage of deep burial and large-scale hydrocarbon generation, which caused the enrichment of reservoirs with shale gas; the late stage of uplift, erosion and fracture development when shale gas reservoirs were finally formed.展开更多
Hydrocarbon production from shale has attracted much attention in the recent years. When applied to this prolific and hydrocarbon rich resource plays, our understanding of the complexities of the flow mechanism(sorpt...Hydrocarbon production from shale has attracted much attention in the recent years. When applied to this prolific and hydrocarbon rich resource plays, our understanding of the complexities of the flow mechanism(sorption process and flow behavior in complex fracture systems- induced or natural) leaves much to be desired. In this paper, we present and discuss a novel approach to modeling, history matching of hydrocarbon production from a Marcellus shale asset in southwestern Pennsylvania using advanced data mining, pattern recognition and machine learning technologies. In this new approach instead of imposing our understanding of the flow mechanism, the impact of multi-stage hydraulic fractures, and the production process on the reservoir model, we allow the production history, well log, completion and hydraulic fracturing data to guide our model and determine its behavior. The uniqueness of this technology is that it incorporates the so-called "hard data" directly into the reservoir model, so that the model can be used to optimize the hydraulic fracture process. The "hard data" refers to field measurements during the hydraulic fracturing process such as fluid and proppant type and amount, injection pressure and rate as well as proppant concentration. This novel approach contrasts with the current industry focus on the use of "soft data"(non-measured, interpretive data such as frac length, width,height and conductivity) in the reservoir models. The study focuses on a Marcellus shale asset that includes 135 wells with multiple pads, different landing targets, well length and reservoir properties. The full field history matching process was successfully completed using this data driven approach thus capturing the production behavior with acceptable accuracy for individual wells and for the entire asset.展开更多
This study analyzed the characteristics and types of the Lower Silurian shale gas reservoirs in and around Sichuan Basin through field observations, slices, Ar-ion-beam milling, scanning electron microscopy, and x-ray...This study analyzed the characteristics and types of the Lower Silurian shale gas reservoirs in and around Sichuan Basin through field observations, slices, Ar-ion-beam milling, scanning electron microscopy, and x-ray diffraction analysis of 25 black shale outcrops and samples. Two main types of shale gas reservoirs were determined, i.e., fractures and pores. Fractures were classified into five categories, i.e., giant, large, medium, small, and micro, according to the features of the shale gas reservoirs, effect of fracture on gas accumulation, and fracture nature. Pore types include organic matter pores, mineral pores(mineral surface, intraparticle, interparticle, and corrosional pore), and nanofractures. The various fracture types, fracture scales, pore types, and pore sizes exert different controls over the gas storage and production capacity. Pores serve as a reservoir for gas storage and, the gas storage capacity can be determined using pores; fractures serve as pathways for gas migration, and gas production capacity can be determined using them.展开更多
Lacustrine shale from the Qingshankou Formatin of Songliao basin and the Shahejie Formation of Bohai Bay basin, and marine shale from the lower Cambrian Jinmenchong Formation of Qiannan depression were analysed by usi...Lacustrine shale from the Qingshankou Formatin of Songliao basin and the Shahejie Formation of Bohai Bay basin, and marine shale from the lower Cambrian Jinmenchong Formation of Qiannan depression were analysed by using rock pyrolysis, TOC (total organic carbon), XRD (X-ray diffraction), SEM (scanning electron microscope), FE-SEM (field emission scanning electron microscope), high pressure mercury intrusion, and low pressure N2 and CO2 gas adsorption experiments, in aim to reveal their reservoir features. The results show that: (1) the width of micro-pores of all the studied samples mainly ranges from 0.45 to 0.7 nm indicated by CO2 isotherms, and the width of meso-pores is less than 10 nm, with type IV adsorption isotherms and type H2 hysteresis loop, indicative of "ink-bottle"-shaped pores. Good correlations exist among pore volume, surface area and averaged pore diameter, and a good positive correlation exists between micro-pore volume and TOC content; however, there is no obvious correlation between meso-pore volume and TOC content; (2) interparticle pores, pores among the edge of mineral grains and organic matter pores were all identified in marine and lacustrine shale, among which the interparticle pores may be influence by dissolution effect. Not all bitumen develops organic matter pore, and only high to over mature bitumen present pores. Now the description methods of micrometer scale pores developed in shale are very lack. Micro- fractures developed in Jiyang depression and dissolution interparticle pores developed in Songliao Basin should be the accumulation sites for shale oil in lacustrine shale, and can be as sweet spots.展开更多
The Upper Ordovician-Lower Silurian Longmaxi Shale in the Upper Yangtze block represents one of the most important shale gas plays in China. The shale composition, porosity, organic thermal maturity, and methane sorpt...The Upper Ordovician-Lower Silurian Longmaxi Shale in the Upper Yangtze block represents one of the most important shale gas plays in China. The shale composition, porosity, organic thermal maturity, and methane sorption were investigated at the Qilongcun section in the Dingshan area, southeastern Sichuan Basin. The results show that the Upper Ordovician-Lower Silurian Longmaxi Shale contains: (1) sapropelic I organic matter; (2) a 40-m thick bedded sequence where total organic carbon (TOC) content is 〉 2%; (3) a 30-m thick layer at the base of the Longmaxi Shale with a brittle mineral content higher than 50%; and (4) a mean methane adsorption capacity of 1.80 cm3/g (7 MPa pressure). A positive correlation between TOC and sorbed gas indicates that organic matter content exerts an important control on methane storage capacity. Based on the analysis of the shale reservoir characteristics, the lower member of the Longmaxi Shale can thus be considered a favorable stratum for shale gas exploration and exploitation. It has similar reservoir characteristics with the Longmaxi Shale in the Jiaoshiba area tested with a high-yield industrial gas flow. However, based on tectonic analysis, differences in the level of industrial gas flow between the low-yield study area and the high-yield Jiaoshiba area may result from different tectonic preservation conditions. Evidence from these studies indicates the shale gas potential of the Longmaxi Shale is constrained by the reservoir and preservation conditions.展开更多
The Upper Ordovician Wufeng-Lower Silurian Longmaxi shale is widely distributed in the Sichuan Basin and its periphery,which is the key stratum for marine shale gas exploration and development(E&D)in China.Based o...The Upper Ordovician Wufeng-Lower Silurian Longmaxi shale is widely distributed in the Sichuan Basin and its periphery,which is the key stratum for marine shale gas exploration and development(E&D)in China.Based on sedimentary environment,material basis,storage space,fracability and reservoir evolution data,the reservoir characteristics of the Wufeng-Longmaxi shale and their significance for shale gas E&D are systematically compared and analyzed in this paper.The results show that(1)the depocenter of the Wufeng(WF)-Longmaxi(LM)shale gradually migrates from east to west.The high-quality shale reservoirs in the eastern Sichuan Basin are mainly siliceous shales,which are primarily distributed in the graptolite shale interval of WF2-LM5.The high-quality reservoirs in the southern Sichuan Basin are mainly calcareous-siliceous and organic-rich argillaceous shales,which are distributed in the graptolite shale interval of WF2-LM7.(2)Deep shale gas(the burial depth>3500 m)in the Sichuan Basin has high-ultrahigh pressure and superior physical properties.The organic-rich siliceous,calcareous-siliceous and organic-rich argillaceous shales have suitable reservoir properties.The marginal area of the Sichuan Basin has a higher degree of pressure relief,which leads to the argillaceous and silty shales evolving into direct cap rocks with poor reservoir/good sealing capacity.(3)Combining shale gas exploration practices and impacts of lithofacies,depth,pressure coefficient and brittle-ductile transition on the reservoir properties,it is concluded that the favorable depth interval of the Wufeng-Longmaxi shale gas is 2200~4000 m under current technical conditions.(4)Aiming at the differential reservoir properties of the Wufeng-Longmaxi shale in the Sichuan Basin and its periphery,several suggestions for future research directions and E&D of shale gas are formulated.展开更多
Shale gas resources are considered to be extremely abundant in southern China,which has dedicated considerable attention to shale gas exploration in recent years.Exploration of shale gas has considerably progressed an...Shale gas resources are considered to be extremely abundant in southern China,which has dedicated considerable attention to shale gas exploration in recent years.Exploration of shale gas has considerably progressed and several breakthroughs have been made in China.However,shale gas explorations are still scarce.Summary and detailed analysis studies on black shale reservoirs are still to be performed for many areas.This lack of information slows the progress of shale gas explorations and results in low quantities of stored black shale.The Carboniferous Dawuba Formation,which is widely distributed and considerably thick,is one of the black shale formations targeted for shale gas exploration in southern China in the recent years.The acquisition and analysis of total organic carbon,vitrinite reflectance,types of organic matter,mineral composition,porosity,and permeability are basic but important processes.In addition,we analyzed the microscopic pores present in the shale.This study also showesd the good gas content of the Dawuba Formation,as well as the geological factors affecting its gas content and other characteristics.To understand the prospect of exploration,we compared this with other shale reservoirs which have been already successfully explored for gas.Our comparison showesd that those shale reservoirs have similar but not identical geological characteristics.展开更多
To investigate the height growth of multi-cluster fractures during variable fluid-viscosity fracturing in a layered shale oil reservoir,a two-dimensional finite element method(FEM)-discrete fracture network(DFN)model ...To investigate the height growth of multi-cluster fractures during variable fluid-viscosity fracturing in a layered shale oil reservoir,a two-dimensional finite element method(FEM)-discrete fracture network(DFN)model coupled with flow,stress and damage is proposed.A traction-separation law is used to describe the mixed-mode response of the damaged adhesive fractures,and the cubic law is used to describe the fluid flow within the fractures.The rock deformation is controlled by the in-situ stress,fracture cohesion and fluid pressure on the hydraulic fracture surface.The coupled finite element equations are solved by the explicit time difference method.The effects of the fracturing treatment parameters including fluid viscosity,pumping rate and cluster spacing on the geometries of multifractures are investigated.The results show that variable fluid-viscosity injection can improve the complexity of the fracture network and height of the main fractures simultaneously.The pumping rate of15 m^(3)/min,variable fluid-viscosity of 3-9-21-36-45 mPa s with a cluster spacing of 7.5 m is the ideal treatment strategy.The field application shows that the peak daily production of the application well with the optimized injection procedu re of variable fluid-viscosity fracturing is 171 tons(about 2.85 times that of the adjacent well),which is the highest daily production record of a single shale oil well in China,marking a strategic breakthrough of commercial shale oil production in the Jiyang Depression,Shengli Oilfield.The variable fluid-viscosity fracturing technique is proved to be very effective for improving shale oil production.展开更多
As an important pilot target for shale gas exploration and development in China,the Longmaxi Formation shale in the Dianqianbei Area is characterized by high content of nitrogen,which severely increases exploration ri...As an important pilot target for shale gas exploration and development in China,the Longmaxi Formation shale in the Dianqianbei Area is characterized by high content of nitrogen,which severely increases exploration risk.Accordingly,this study explores the genesis of shale gas reservoir and the mechanism of nitrogen enrichment through investigating shale gas compositions,isotope features,and geochemical characteristics of associated gases.The high-nitrogen shale gas reservoir in the Longmaxi Formation is demonstrated to be a typical dry gas reservoir.Specifically,the alkane carbon isotope reversal is ascribed to the secondary cracking of crude oil and the Rayleigh fractionation induced by the basalt mantle plume.Such a thermogenic oil-type gas reservoir is composed of both oil-cracking gas and kerogen-cracking gas.The normally high nitrogen content(18.05%-40.92%) is attributed to organic matter cracking and thermal ammoniation in the high-maturity stage.Specifically,the high heat flow effect of the Emeishan mantle plume exacerbates the thermal cracking of organic matter in the Longmaxi Formation shale,accompanied by nitrogen generation.In comparison,the abnormally high nitrogen content(86.79%-98.54%) is ascribed to the communication between the atmosphere and deep underground fluids by deep faults,which results in hydrocarbon loss and nitrogen intrusion,acting as the key factor for deconstruction of the primary shale gas reservoir.Results of this study not only enrich research on genetic mechanism of high-maturity N_@ shale gas reservoirs,but also provide theoretical guidance for subsequent gas reservoir resource evaluation and well-drilling deployment in this area.展开更多
基金supported by the project of the China Geological Survey for shale gas in Southern China(DD20221852)the National Natural Science Foundation of China(42242010,U2244208)。
文摘China is home to shales of three facies:Marine shale,continental shale,and marine-continental transitional shale.Different types of shale gas are associated with significantly different formation conditions and major controlling factors.This study compared the geological characteristics of various shales and analyzed the influences of different parameters on the formation and accumulation of shale gas.In general,shales in China’s several regions exhibit high total organic carbon(TOC)contents,which lays a sound material basis for shale gas generation.Marine strata generally show high degrees of thermal evolution.In contrast,continental shales manifest low degrees of thermal evolution,necessitating focusing on areas with relatively high degrees of thermal evolution in the process of shale gas surveys for these shales.The shales of the Wufeng and Silurian formations constitute the most favorable shale gas reservoirs since they exhibit the highest porosity among the three types of shales.These shales are followed by those in the Niutitang and Longtan formations.In contrast,the shales of the Doushantuo,Yanchang,and Qingshankou formations manifest low porosities.Furthermore,the shales of the Wufeng and Longmaxi formations exhibit high brittle mineral contents.Despite a low siliceous mineral content,the shales of the Doushantuo Formation feature a high carbonate mineral content,which can increase the shales’brittleness to some extent.For marine-continental transitional shales,where thin interbeds of tight sandstone with unequal thicknesses are generally found,it is recommended that fracturing combined with drainage of multiple sets of lithologic strata should be employed to enhance their shale gas production.
基金sponsored by the “National Natural Science Foundation of China” (No. U22B6003), (No. 52104010), and (No. 52104046)。
文摘Recently, a new promising type of marine shale gas reservoir, carbonate-rich shale, has been discovered.But the mechanical properties of this type of shale were still unrevealed and the corresponding reservoir stimulation design was lack of guidance. Using the deep downhole cores of an exploratory carbonate-rich shale gas well, the physical and mechanical parameters and failure mechanism of the whole reservoir section were acquired and evaluated systematically, by performing XRD, tri-axial compression, Brazilian splitting, and fracture toughness tests. A new model was established to evaluate the reservoir brittleness based on fracture morphology and stress-strain curve. Recommended strategy for reservoir stimulation was discussed. Results showed that(1) Carbonate-rich shale possessed high compressive strength and high Young's modulus, which were improved by 10.74% and 3.37% compared to that of siliceous shale. It featured high tensile strength and fracture toughness, with insignificant anisotropy.(2) With the content of carbonate minerals increasing, the shear failure morphology transformed from sparse and wide brittle fractures to diffusely distributed and subtle plastic cracks.(3) The brittleness index order was: siliceous shale, clay-rich shale, carbonate-rich shale, and limestone.(4) The special properties of carbonate-rich shale were rooted in the inherent feature of carbonate minerals(high strength, high elastic modulus,and cleavage structure), resulting in greater challenge in reservoirs stimulation. The above findings would promote the understanding of carbonate-rich shale reservoirs and provide reference for the optimum design of reservoir stimulation.
基金supports from the National Natural Science Foundation of China(42104110,41974123,42174161,and 12334019)the Natural Science Foundation of Jiangsu Province(BK20210379,BK20200021)+1 种基金the Postdoctoral Science Foundation of China(2022M720989)the Fundamental Research Funds for the Central Universities(B210201032).
文摘The shale oil reservoir within the Yanchang Formations of Ordos Basin harbors substantial oil and gas resources and has recently emerged as the primary focus of unconventional oil and gas exploration and development.Due to its complex pore and throat structure,pronounced heterogeneity,and tight reservoir characteristics,the techniques for conventional oil and gas exploration and production face challenges in comprehensive implementation,also indicating that as a vital parameter for evaluating the physical properties of a reservoir,permeability cannot be effectively estimated.This study selects 21 tight sandstone samples from the Q area within the shale oil formations of Ordos Basin.We systematically conduct the experiments to measure porosity,permeability,ultrasonic wave velocities,and resistivity at varying confining pressures.Results reveal that these measurements exhibit nonlinear changes in response to effective pressure.By using these experimental data and effective medium model,empirical relationships between P-and S-wave velocities,permeability and resistivity and effective pressure are established at logging and seismic scales.Furthermore,relationships between P-wave impedance and permeability,and resistivity and permeability are determined.A comparison between the predicted permeability and logging data demonstrates that the impedance–permeability relationship yields better results in contrast to those of resistivity–permeability relationship.These relationships are further applied to the seismic interpretation of shale oil reservoir in the target layer,enabling the permeability profile predictions based on inverse P-wave impedance.The predicted results are evaluated with actual production data,revealing a better agreement between predicted results and logging data and productivity.
基金funded by Science Foundation of China University of Petroleum, Beijing (No. 2462021YXZZ009)The Strategic Cooperation Technology Projects of CNPC and CUPB (No. ZLZX 2020-01)Innovation Capability Support of Shaanxi (Program No. 2023-CX-TD-31) Technical Innovation Team for Low Carbon Environmental Protection and Enhanced Oil Recovery in Unconventional Reservoirs。
文摘Supercritical CO_(2)(SC-CO_(2)) fracturing, being a waterless fracturing technology, has garnered increasing attention in the shale oil reservoir exploitation industry. Recently, a novel pre-SC-CO_(2) hybrid fracturing method has been proposed, which combines the advantages of SC-CO_(2) fracturing and hydraulic fracturing. However, the specific impacts of different pre-SC-CO_(2) injection conditions on the physical parameters, mechanical properties, and crack propagation behavior of shale reservoirs remain unclear. In this study, we utilize a newly developed “pre-SC-CO_(2) injection → water-based fracturing” integrated experimental device. Through experimentation under in-situ conditions, the impact of pre-SC-CO_(2) injection displacement and volume on the shale mineral composition, mechanical parameters, and fracture propagation behavior are investigated. The findings of the study demonstrate that the pre-injection SC-CO_(2) leads to a reduction in clay and carbonate mineral content, while increasing the quartz content. The correlation between quartz content and SC-CO_(2) injection volume is positive, while a negative correlation is observed with injection displacement. The elastic modulus and compressive strength exhibit a declining trend, while Poisson's ratio shows an increasing trend. The weakening of shale mechanics caused by pre-injection of SC-CO_(2) is positively correlated with the injection displacement and volume.Additionally, pre-injection of SC-CO_(2) enhances the plastic deformation behavior of shale, and its breakdown pressure is 16.6% lower than that of hydraulic fracturing. The breakdown pressure demonstrates a non-linear downward trend with the gradual increase of pre-SC-CO_(2) injection parameters.Unlike hydraulic fracturing, which typically generates primary fractures along the direction of the maximum principal stress, pre-SC-CO_(2) hybrid fracturing leads to a more complex fracture network. With increasing pre-SC-CO_(2) injection displacement, intersecting double Y-shaped complex fractures are formed along the vertical axis. On the other hand, increasing the injection rate generates secondary fractures along the direction of non-principal stress. The insights gained from this study are valuable for guiding the design of pre SC-CO_(2) hybrid fracturing in shale oil reservoirs.
基金Supported by the Key Fund Project of the National Natural Science Foundation of China and Joint Fund of Petrochemical Industry(Class A)(U1762212)National Natural Science Foundation of China(52274009)"14th Five-Year"Forward-looking and Fundamental Major Science and Technology Project of CNPC(2021DJ4402)。
文摘For the analysis of the formation damage caused by the compound function of drilling fluid and fracturing fluid,the prediction method for dynamic invasion depth of drilling fluid is developed considering the fracture extension due to shale minerals erosion by oil-based drilling fluid.With the evaluation for the damage of natural and hydraulic fractures caused by mechanical properties weakening of shale fracture surface,fracture closure and rock powder blocking,the formation damage pattern is proposed with consideration of the compound effect of drilling fluid and fracturing fluid.The formation damage mechanism during drilling and completion process in shale reservoir is revealed,and the protection measures are raised.The drilling fluid can deeply invade into the shale formation through natural and induced fractures,erode shale minerals and weaken the mechanical properties of shale during the drilling process.In the process of hydraulic fracturing,the compound effect of drilling fluid and fracturing fluid further weakens the mechanical properties of shale,results in fracture closure and rock powder shedding,and thus induces stress-sensitive damage and solid blocking damage of natural/hydraulic fractures.The damage can yield significant conductivity decrease of fractures,and restrict the high and stable production of shale oil and gas wells.The measures of anti-collapse and anti-blocking to accelerate the drilling of reservoir section,forming chemical membrane to prevent the weakening of the mechanical properties of shale fracture surface,strengthening the plugging of shale fracture and reducing the invasion range of drilling fluid,optimizing fracturing fluid system to protect fracture conductivity are put forward for reservoir protection.
基金This work is funded by National Natural Science Foundation of China(Nos.42202292,42141011)the Program for Jilin University(JLU)Science and Technology Innovative Research Team(No.2019TD-35).The authors would also like to thank the reviewers and editors whose critical comments are very helpful in preparing this article.
文摘To reduce CO_(2) emissions in response to global climate change,shale reservoirs could be ideal candidates for long-term carbon geo-sequestration involving multi-scale transport processes.However,most current CO_(2) sequestration models do not adequately consider multiple transport mechanisms.Moreover,the evaluation of CO_(2) storage processes usually involves laborious and time-consuming numerical simulations unsuitable for practical prediction and decision-making.In this paper,an integrated model involving gas diffusion,adsorption,dissolution,slip flow,and Darcy flow is proposed to accurately characterize CO_(2) storage in depleted shale reservoirs,supporting the establishment of a training database.On this basis,a hybrid physics-informed data-driven neural network(HPDNN)is developed as a deep learning surrogate for prediction and inversion.By incorporating multiple sources of scientific knowledge,the HPDNN can be configured with limited simulation resources,significantly accelerating the forward and inversion processes.Furthermore,the HPDNN can more intelligently predict injection performance,precisely perform reservoir parameter inversion,and reasonably evaluate the CO_(2) storage capacity under complicated scenarios.The validation and test results demonstrate that the HPDNN can ensure high accuracy and strong robustness across an extensive applicability range when dealing with field data with multiple noise sources.This study has tremendous potential to replace traditional modeling tools for predicting and making decisions about CO_(2) storage projects in depleted shale reservoirs.
基金Supported by the National Basic Research Program of China (973 Program) (2012CB214705) the National Natural Science Foundation of China 41172145, 41030422) the Shanxi Provincial Basic Research Program-Coal Bed Methane Joint Research Foundation (2012012014)
文摘The mechanical property of mudstone/shale in coal measures is a key factor of engineering mechanics that influences the development of shale gas. A rock mechanics test was performed in order to analyze the complete stress-strain mechanic characteristics and influence factors of mudstone/shale in paralic coal measures, from the Carboniferous-Permian periods in a coal field of Northern China. The relationship between the mechanical properties of mudstone/shale in coal measures, and its chemical component, water content are established, and their models are constructed. Research results show that mud- stone/shale has low mechanical strength, low elastic modulus and a high Poisson's ratio. The complete stress-strain curve has apparent elastoplastic deformation characteristics, and after reaching peak strength, it exhibits obvious strain softening characteristics. The uniaxial compressive strength of mudstone/shale and its elastic modulus increases exponentially with the increase of SiO2 content, and as the ignition loss increases, the uniaxial compressive strength and elastic modulus of mudstone/shale will decrease according to the law of power function. The compressive strength of mudstone/shale and its elastic modulus will decrease with the increase of water content in mudstone/shale.
文摘To fully exploit the technical advantages of the large-depth and high-precision artificial source electromagnetic method in the complex structure area of southern Sichuan and compensate for the shortcomings of the conventional electromagnetic method in exploration depth,precision,and accuracy,the large-depth and high-precision wide field electromagnetic method is applied to the complex structure test area of the Luochang syncline and Yuhe nose anticline in the southern Sichuan.The advantages of the wide field electromagnetic method in detecting deep,low-resistivity thin layers are demonstrated.First,on the basis of the analysis of physical property data,a geological–geoelectric model is established in the test area,and the wide field electromagnetic method is numerically simulated to analyze and evaluate the response characteristics of deep thin shale gas layers on wide field electromagnetic curves.Second,a wide field electromagnetic test is conducted in the complex structure area of southern Sichuan.After data processing and inversion imaging,apparent resistivity logging data are used for calibration to develop an apparent resistivity interpretation model suitable for the test area.On the basis of the results,the characteristics of the electrical structure change in the shallow longitudinal formation of 6 km are implemented,and the transverse electrical distribution characteristics of the deep shale gas layer are delineated.In the prediction area near the well,the subsequent data verification shows that the apparent resistivity obtained using the inversion of the wide field electromagnetic method is consistent with the trend of apparent resistivity revealed by logging,which proves that this method can effectively identify the weak response characteristics of deep shale gas formations in complex structural areas.This experiment,it is shown shows that the wide field electromagnetic method with a large depth and high precision can effectively characterize the electrical characteristics of deep,low-resistivity thin layers in complex structural areas,and a new set of low-cost evaluation technologies for shale gas target layers based on the wide field electromagnetic method is explored.
基金supported by the National Natural Science Foundation of China(No.52174038 and No.52004307)China Petroleum Science and Technology Project-Major Project-Research on Tight Oil-Shale Oil Reservoir Engineering Methods and Key Technologies in Ordos Basin(No.ZLZX2020-02-04)Science Foundation of China University of Petroleum,Beijing(No.2462018YJRC015)。
文摘Under the policy background and advocacy of carbon capture,utilization,and storage(CCUS),CO_(2)-EOR has become a promising direction in the shale oil reservoir industry.The multi-scale pore structure distribution and fracture structure lead to complex multiphase flow,comprehensively considering multiple mechanisms is crucial for development and CO_(2) storage in fractured shale reservoirs.In this paper,a multi-mechanism coupled model is developed by MATLAB.Compared to the traditional Eclipse300 and MATLAB Reservoir Simulation Toolbox(MRST),this model considers the impact of pore structure on fluid phase behavior by the modified Peng—Robinson equation of state(PR-EOS),and the effect simultaneously radiate to Maxwell—Stefan(M—S)diffusion,stress sensitivity,the nano-confinement(NC)effect.Moreover,a modified embedded discrete fracture model(EDFM)is used to model the complex fractures,which optimizes connection types and half-transmissibility calculation approaches between non-neighboring connections(NNCs).The full implicit equation adopts the finite volume method(FVM)and Newton—Raphson iteration for discretization and solution.The model verification with the Eclipse300 and MRST is satisfactory.The results show that the interaction between the mechanisms significantly affects the production performance and storage characteristics.The effect of molecular diffusion may be overestimated in oil-dominated(liquid-dominated)shale reservoirs.The well spacing and injection gas rate are the most crucial factors affecting the production by sensitivity analysis.Moreover,the potential gas invasion risk is mentioned.This model provides a reliable theoretical basis for CO_(2)-EOR and sequestration in shale oil reservoirs.
基金Supported by the China National Science and Technology Major Project(2016ZX05046,2017ZX05001)
文摘The differences in organic matter abundance and rock composition between shale and mudstone determine the discrepancy of their contributions to the formation of conventional and shale oil/gas reservoirs.The evaluation criteria of source rocks are different in the future exploration in self-sourced petroleum systems.Shales are deposited in deep/semi-deep lacustrine,with low sedimentation rate and chemical depositions of various degrees,while mudstones are mostly formed in shallow lacustrine/lakeside,with high deposition rate and density flow characteristics.Three factors contribute to the enrichment of organic matter in shales,including the"fertility effect"caused by volcanic ash deposition and hydrothermal injection,excessive and over-speed growth of organisms promoted by radioactive materials,and deep-water anaerobic environment and low sedimentation rate to protect the accumulation of organic matter from dilution.Lamellations in shales are easy to be stripped into storage space,and acid water produced during hydrocarbon generation can dissolve some particles to generate new pores.The massive mudstones with high clay content are of poor matrix porosity.Shales with high total organic carbon,developed laminations,relatively good reservoir property,and high brittle mineral content,are the most favorable lithofacies for shale oil exploration and development.It is necessary to conduct investigation on the differences between shale and mudstone reservoirs,to identify resources distribution in shale and mudstone formations,determine the type and standard of"sweet-spot"evaluation parameters,optimize"sweet-spot areas/sections",and adopt effective development technologies,which is of great significance to objectively evaluate the total amount and economy of shale oil resources,as well as the scale of effective exploitation.
文摘Extant research on Paleozoic mudstone is well developed in the Tarim Basin, while the research on Carboniferous mudstone is relatively weak. Through systematic study of lithology, geochemical characteristics,reservoir characteristics and gas–bearing properties of Carboniferous mudstone in the Tarim Basin, this study aims to provide a geological basis for the Paleozoic shale gas exploration and development, favorable zone optimization, and resource potential evaluation in the Tarim Basin. The results show that the sedimentary environments of organic-rich mudstone in the study area were mainly basin facies and slope facies. Lithology is dominated by black carbonaceous mudstone, followed by calcareous mudstone, siliceous mudstone, and siliceous rocks. Mudstone is mainly developed in the Kalashayi Formation,which is located in the Bachu and Markit slope belt, with the cumulative thickness of 30–200 m. The organic carbon content is commonly more than 0.4%, and the organic matter types are type II and type III. Thermal evolution degree is widely distributed from a low mature to over mature stage, and different tectonic units have a greater difference. The contents of quartz plus feldspar are between 12% and 82.5%, with an average of 45.8%. Thecontent distribution of clay mineral is from 12% to 57%,with an average of 38.2%. Carbonate minerals(mainly siderite) content is below 50%. The brittle mineral content of the mudstone is approximately 65%, with a strong compressibility, and the mudstone has the material basis of forming crack and natural fracture. Microscopic pores in micro–nanometer level are well developed in the mudstone, including micro bedding joint, microcrack,interbedded pores of clay mineral, nanoscale intragranular or edge pores in the massive organic matter, bioclastic micropores, and mineral dissolution pores, etc. According to the standards provided by the Ministry of Land and Resources in China, the Kalashayi Formation in Bamai Area is a favorable area for shale gas development.
基金supported by the Sinopec Key Project named Whole Evaluation on Shale Gas Exploration and Targets Optimization in Sichuan Basin and Its Marginal Areas
文摘This study is based on the sedimentation conditions, organic geochemistry, storage spaces, physical properties, lithology and gas content of the shale gas reservoirs in Longmaxi Formation of the Jiaoshiba area and the gas accumulation mode is summarized and then compared with that in northern America. The shale gas reservoirs in the Longmaxi Formation in Jiaoshiba have good geological conditions, great thickness of quality shales, high organic content, high gas content, good physical properties, suitable depth, good preservation conditions and good reservoir types. The quality shales at the bottom of the deep shelf are the main target interval for shale gas exploration and development. Shale gas in the Longmaxi Formation has undergone three main reservoiring stages:the early stage of hydrocarbon generation and compaction when shale gas reservoirs were first formed; the middle stage of deep burial and large-scale hydrocarbon generation, which caused the enrichment of reservoirs with shale gas; the late stage of uplift, erosion and fracture development when shale gas reservoirs were finally formed.
基金RPSEA and U.S.Department of Energy for partially funding this study
文摘Hydrocarbon production from shale has attracted much attention in the recent years. When applied to this prolific and hydrocarbon rich resource plays, our understanding of the complexities of the flow mechanism(sorption process and flow behavior in complex fracture systems- induced or natural) leaves much to be desired. In this paper, we present and discuss a novel approach to modeling, history matching of hydrocarbon production from a Marcellus shale asset in southwestern Pennsylvania using advanced data mining, pattern recognition and machine learning technologies. In this new approach instead of imposing our understanding of the flow mechanism, the impact of multi-stage hydraulic fractures, and the production process on the reservoir model, we allow the production history, well log, completion and hydraulic fracturing data to guide our model and determine its behavior. The uniqueness of this technology is that it incorporates the so-called "hard data" directly into the reservoir model, so that the model can be used to optimize the hydraulic fracture process. The "hard data" refers to field measurements during the hydraulic fracturing process such as fluid and proppant type and amount, injection pressure and rate as well as proppant concentration. This novel approach contrasts with the current industry focus on the use of "soft data"(non-measured, interpretive data such as frac length, width,height and conductivity) in the reservoir models. The study focuses on a Marcellus shale asset that includes 135 wells with multiple pads, different landing targets, well length and reservoir properties. The full field history matching process was successfully completed using this data driven approach thus capturing the production behavior with acceptable accuracy for individual wells and for the entire asset.
基金supported by the National Natural Science Foundation of China(Grant No.41202103)
文摘This study analyzed the characteristics and types of the Lower Silurian shale gas reservoirs in and around Sichuan Basin through field observations, slices, Ar-ion-beam milling, scanning electron microscopy, and x-ray diffraction analysis of 25 black shale outcrops and samples. Two main types of shale gas reservoirs were determined, i.e., fractures and pores. Fractures were classified into five categories, i.e., giant, large, medium, small, and micro, according to the features of the shale gas reservoirs, effect of fracture on gas accumulation, and fracture nature. Pore types include organic matter pores, mineral pores(mineral surface, intraparticle, interparticle, and corrosional pore), and nanofractures. The various fracture types, fracture scales, pore types, and pore sizes exert different controls over the gas storage and production capacity. Pores serve as a reservoir for gas storage and, the gas storage capacity can be determined using pores; fractures serve as pathways for gas migration, and gas production capacity can be determined using them.
基金jointly supported by grants from the Natural Science Foundation of China(grants No.41402110 and 41330313)“Fundamental Research Funds for the Central Universities”(grants No.14CX05017A and 13CX05013A)
文摘Lacustrine shale from the Qingshankou Formatin of Songliao basin and the Shahejie Formation of Bohai Bay basin, and marine shale from the lower Cambrian Jinmenchong Formation of Qiannan depression were analysed by using rock pyrolysis, TOC (total organic carbon), XRD (X-ray diffraction), SEM (scanning electron microscope), FE-SEM (field emission scanning electron microscope), high pressure mercury intrusion, and low pressure N2 and CO2 gas adsorption experiments, in aim to reveal their reservoir features. The results show that: (1) the width of micro-pores of all the studied samples mainly ranges from 0.45 to 0.7 nm indicated by CO2 isotherms, and the width of meso-pores is less than 10 nm, with type IV adsorption isotherms and type H2 hysteresis loop, indicative of "ink-bottle"-shaped pores. Good correlations exist among pore volume, surface area and averaged pore diameter, and a good positive correlation exists between micro-pore volume and TOC content; however, there is no obvious correlation between meso-pore volume and TOC content; (2) interparticle pores, pores among the edge of mineral grains and organic matter pores were all identified in marine and lacustrine shale, among which the interparticle pores may be influence by dissolution effect. Not all bitumen develops organic matter pore, and only high to over mature bitumen present pores. Now the description methods of micrometer scale pores developed in shale are very lack. Micro- fractures developed in Jiyang depression and dissolution interparticle pores developed in Songliao Basin should be the accumulation sites for shale oil in lacustrine shale, and can be as sweet spots.
基金supported by Science and Technology Support Program of Sichuan Province(No.15ZC1390)National Natural Science Foundation of China(No.41102064)
文摘The Upper Ordovician-Lower Silurian Longmaxi Shale in the Upper Yangtze block represents one of the most important shale gas plays in China. The shale composition, porosity, organic thermal maturity, and methane sorption were investigated at the Qilongcun section in the Dingshan area, southeastern Sichuan Basin. The results show that the Upper Ordovician-Lower Silurian Longmaxi Shale contains: (1) sapropelic I organic matter; (2) a 40-m thick bedded sequence where total organic carbon (TOC) content is 〉 2%; (3) a 30-m thick layer at the base of the Longmaxi Shale with a brittle mineral content higher than 50%; and (4) a mean methane adsorption capacity of 1.80 cm3/g (7 MPa pressure). A positive correlation between TOC and sorbed gas indicates that organic matter content exerts an important control on methane storage capacity. Based on the analysis of the shale reservoir characteristics, the lower member of the Longmaxi Shale can thus be considered a favorable stratum for shale gas exploration and exploitation. It has similar reservoir characteristics with the Longmaxi Shale in the Jiaoshiba area tested with a high-yield industrial gas flow. However, based on tectonic analysis, differences in the level of industrial gas flow between the low-yield study area and the high-yield Jiaoshiba area may result from different tectonic preservation conditions. Evidence from these studies indicates the shale gas potential of the Longmaxi Shale is constrained by the reservoir and preservation conditions.
基金granted by the National Science and Technology Major Project of the Ministry of Science and Technology of China (Grant No. 2017ZX05036002–001)National Natural Science Foundation of China (No. 41202103, 41872124)SINOPEC Ministry of Science and Technology Project (Grant No. P17027–2)
文摘The Upper Ordovician Wufeng-Lower Silurian Longmaxi shale is widely distributed in the Sichuan Basin and its periphery,which is the key stratum for marine shale gas exploration and development(E&D)in China.Based on sedimentary environment,material basis,storage space,fracability and reservoir evolution data,the reservoir characteristics of the Wufeng-Longmaxi shale and their significance for shale gas E&D are systematically compared and analyzed in this paper.The results show that(1)the depocenter of the Wufeng(WF)-Longmaxi(LM)shale gradually migrates from east to west.The high-quality shale reservoirs in the eastern Sichuan Basin are mainly siliceous shales,which are primarily distributed in the graptolite shale interval of WF2-LM5.The high-quality reservoirs in the southern Sichuan Basin are mainly calcareous-siliceous and organic-rich argillaceous shales,which are distributed in the graptolite shale interval of WF2-LM7.(2)Deep shale gas(the burial depth>3500 m)in the Sichuan Basin has high-ultrahigh pressure and superior physical properties.The organic-rich siliceous,calcareous-siliceous and organic-rich argillaceous shales have suitable reservoir properties.The marginal area of the Sichuan Basin has a higher degree of pressure relief,which leads to the argillaceous and silty shales evolving into direct cap rocks with poor reservoir/good sealing capacity.(3)Combining shale gas exploration practices and impacts of lithofacies,depth,pressure coefficient and brittle-ductile transition on the reservoir properties,it is concluded that the favorable depth interval of the Wufeng-Longmaxi shale gas is 2200~4000 m under current technical conditions.(4)Aiming at the differential reservoir properties of the Wufeng-Longmaxi shale in the Sichuan Basin and its periphery,several suggestions for future research directions and E&D of shale gas are formulated.
基金the financial support provided by the 1:50000 Shale Gas Geological Survey of Southern Chinathe Investigation and Evaluation of Shale Gas Resources in Guizhou Province
文摘Shale gas resources are considered to be extremely abundant in southern China,which has dedicated considerable attention to shale gas exploration in recent years.Exploration of shale gas has considerably progressed and several breakthroughs have been made in China.However,shale gas explorations are still scarce.Summary and detailed analysis studies on black shale reservoirs are still to be performed for many areas.This lack of information slows the progress of shale gas explorations and results in low quantities of stored black shale.The Carboniferous Dawuba Formation,which is widely distributed and considerably thick,is one of the black shale formations targeted for shale gas exploration in southern China in the recent years.The acquisition and analysis of total organic carbon,vitrinite reflectance,types of organic matter,mineral composition,porosity,and permeability are basic but important processes.In addition,we analyzed the microscopic pores present in the shale.This study also showesd the good gas content of the Dawuba Formation,as well as the geological factors affecting its gas content and other characteristics.To understand the prospect of exploration,we compared this with other shale reservoirs which have been already successfully explored for gas.Our comparison showesd that those shale reservoirs have similar but not identical geological characteristics.
基金funded by the National Natural Science Foundation of China(Nos.52192622,51874253,U20A202)
文摘To investigate the height growth of multi-cluster fractures during variable fluid-viscosity fracturing in a layered shale oil reservoir,a two-dimensional finite element method(FEM)-discrete fracture network(DFN)model coupled with flow,stress and damage is proposed.A traction-separation law is used to describe the mixed-mode response of the damaged adhesive fractures,and the cubic law is used to describe the fluid flow within the fractures.The rock deformation is controlled by the in-situ stress,fracture cohesion and fluid pressure on the hydraulic fracture surface.The coupled finite element equations are solved by the explicit time difference method.The effects of the fracturing treatment parameters including fluid viscosity,pumping rate and cluster spacing on the geometries of multifractures are investigated.The results show that variable fluid-viscosity injection can improve the complexity of the fracture network and height of the main fractures simultaneously.The pumping rate of15 m^(3)/min,variable fluid-viscosity of 3-9-21-36-45 mPa s with a cluster spacing of 7.5 m is the ideal treatment strategy.The field application shows that the peak daily production of the application well with the optimized injection procedu re of variable fluid-viscosity fracturing is 171 tons(about 2.85 times that of the adjacent well),which is the highest daily production record of a single shale oil well in China,marking a strategic breakthrough of commercial shale oil production in the Jiyang Depression,Shengli Oilfield.The variable fluid-viscosity fracturing technique is proved to be very effective for improving shale oil production.
基金financially supported by the National Science and Technology Major Project (2017ZX05063002–009)National Natural Science Foundation of China (41772150)+1 种基金Sichuan Province’s Key Project of Research and Development (18ZDYF0884)Qian Ke He Platform Talents [2017]5789-16。
文摘As an important pilot target for shale gas exploration and development in China,the Longmaxi Formation shale in the Dianqianbei Area is characterized by high content of nitrogen,which severely increases exploration risk.Accordingly,this study explores the genesis of shale gas reservoir and the mechanism of nitrogen enrichment through investigating shale gas compositions,isotope features,and geochemical characteristics of associated gases.The high-nitrogen shale gas reservoir in the Longmaxi Formation is demonstrated to be a typical dry gas reservoir.Specifically,the alkane carbon isotope reversal is ascribed to the secondary cracking of crude oil and the Rayleigh fractionation induced by the basalt mantle plume.Such a thermogenic oil-type gas reservoir is composed of both oil-cracking gas and kerogen-cracking gas.The normally high nitrogen content(18.05%-40.92%) is attributed to organic matter cracking and thermal ammoniation in the high-maturity stage.Specifically,the high heat flow effect of the Emeishan mantle plume exacerbates the thermal cracking of organic matter in the Longmaxi Formation shale,accompanied by nitrogen generation.In comparison,the abnormally high nitrogen content(86.79%-98.54%) is ascribed to the communication between the atmosphere and deep underground fluids by deep faults,which results in hydrocarbon loss and nitrogen intrusion,acting as the key factor for deconstruction of the primary shale gas reservoir.Results of this study not only enrich research on genetic mechanism of high-maturity N_@ shale gas reservoirs,but also provide theoretical guidance for subsequent gas reservoir resource evaluation and well-drilling deployment in this area.