Poly(ethylenimine)-assisted synthesis of hollow carbon spheres comprising multi-sized Ni species for CO_(2) electroreduction

Electrochemical CO_(2) reduction to produce value-added chemicals and fuels is one of the research hotspots in the field of energy conversion.The development of efficient catalysts with high conductivity and readily accessible active sites for CO_(2) electroreduction remains challenging yet indispensable.In this work,a reliable poly(ethyleneimine)(PEI)-assisted strategy is developed to prepare a hollow carbon nanocomposite comprising a single-site Ni-modified carbon shell and confined Ni nanoparticles(NPs)(denoted as Ni@NHCS),where PEI not only functions as a mediator to induce the highly dispersed growth of Ni NPs within hollow carbon spheres,but also as a nitrogen precursor to construct highly active atomically-dispersed Ni-Nx sites.Benefiting from the unique structural properties of Ni@NHCS,the aggregation and exposure of Ni NPs can be effectively prevented,while the accessibility of abundant catalytically active Ni-Nx sites can be ensured.As a result,Ni@NHCS exhibits a high CO partial current density of 26.9 mA cm^(-2) and a Faradaic efficiency of 93.0% at-1.0 V vs.RHE,outperforming those of its PEI-free analog.Apart from the excellent activity and selectivity,the shell confinement effect of the hollow carbon sphere endows this catalyst with long-term stability.The findings here are anticipated to help understand the structure-activity relationship in Ni-based carbon catalyst systems for electrocatalytic CO_(2) reduction.Furthermore,the PEI-assisted synthetic concept is potentially applicable to the preparation of high-performance metal-based nanoconfined materials tailored for diverse energy conversion applications and beyond.

Co/Co_(7)Fe_(3)heterostructures with controllable alloying degree on carbon spheres as bifunctional electrocatalyst forrechargeable zinc-air batteries

Exploring efficient and nonprecious metal electrocatalysts of oxygen reduction reaction(ORR)and oxygen evolution reaction(OER)is crucial for developing rechargeable zinc-air batteries(ZABs).Herein,an alloying-degree control strategy was employed to fabricate nitrogen-doped carbon sphere(NCS)decorated with dual-phase Co/Co_(7)Fe_(3)heterojunctions(CoFe@NCS).The phase composition of materials has been adjusted by controlling the alloying degree.The optimal CoFe_(0.08)@NCS electrocatalyst displays a half-wave potential of 0.80 V for ORR and an overpotential of 283 mV at 10 mA·cm^(-2)for OER in an alkaline electrolyte.The intriguing bifunctional electrocatalytic activity and durability is attributed to the hierarchically porous structure and interfacial electron coupling of highly-active Co_(7)Fe_(3)alloy and metallic Co species.When the CoFe_(0.08)@NCS material is used as air-cathode catalyst of rechargeable liquid-state zinc-air battery(ZAB),the device shows a high peak power-density(157 mW·cm^(-2))and maintains a stable voltage gap over 150 h,outperforming those of the benchmark(Pt/C+RuO_(2))-based device.In particular,the as-fabricated solid-state flexible ZAB delivers a reliable compatibility under different bending conditions.Our work provides a promising strategy to develop metal/alloy-based electrocatalysts for the application in renewable energy conversion technologies.

基于Photo Sphere Viewer的轻量化可量测街景系统研究

随着新型基础测绘体系发展,测绘技术和装备不断升级,大量街景数据随着车载激光扫描工作一并被采集。针对该数据路线随机性大、密集程度高等特点,以及传统街景地图系统插件受限、扩展性不强、无法量测等局限,本文设计了基于Photo Sphere Viewer的轻量化可量测街景系统,在开源插件的基础上实现了对其组件的扩充、实现了行进方向、地图交互等系统功能的设计优化,进一步实现了基于深度图的街景地图量测功能。生产作业队伍对系统的使用结果表明,该系统可以辅助生产作业队伍进行属性采集、纹理更新、数据检查等多项工作,操作灵活便捷,且具有较强的可扩展性,便于基于生产需求进行改进调整,提高了生产效率,为新型基础测绘成果进一步深化应用提供了良好的借鉴作用。

Geant4 simulation of multi-sphere spectrometer response function and the detection of 241Am–Be neutron spectrum

This paper is aimed at detecting the neutron spectrum of^(241)Am–Be, a widely used neutron source, with the SP9 ~3He proportional counter, which is a multi-sphere spectrometer system of eight thermal neutron detectors embedded in eight polyethylene(PE) spheres of varying diameters. The transport processes of a neutron in the multi-sphere spectrometer are simulated using the Geant4 code. Two sets of response functions of the PE spheres are obtained for calculating the^(241)Am–Be neutron spectrum.Response Function 1 utilizes the thermal neutron scattering model G4 Neutron HPThermal Scattering for neutron energies of ≤4 eV, and Response Function 2 has no thermal treatment. Neutron spectra of an^(241)Am–Be neutron source are measured and compared to those calculated by using the response functions. The results show that response function with thermal treatment is more accurate and closer to the real spectrum.

A Bi-layer Composite Film Based on TiO_2 Hollow Spheres, P25,and Multi-walled Carbon Nanotubes for Efficient Photoanode of Dye-sensitized Solar Cell

A bi-layer photoanode for dye-sensitized solar cell(DSSC) was fabricated, in which TiO_2 hollow spheres(THSs) were designed as a scattering layer and P25/multi-walled carbon nanotubes(MWNTs) as an under-layer. The THSs were synthesized by a sacrifice template method and showed good light scattering ability as an over-layer of the photoanode. MWNTs were mixed with P25 to form an under-layer of the photoanode to improve the electron transmission ability of the photoanode. The power conversion efficiency of this kind of DSSC with bi-layer was enhanced to 5.13 %,which is 14.25 % higher than that of pure P25 DSSC.Graphical Abstract A bi-layer composite photoanode based on P25/MWNTs-THSs with improved light scattering and electron transmission, which will provide a new insight into fabrication and structure design of highly efficient dyesensitized solar cells.

Simulation and calibration of the response function of multi-sphere neutron spectrometer

In order to realize the on-line real-time measurement of neutron spectrum of ITER fusion,this paper presents a multi-sphere spectrometer system which consists of eight thermal neutron detectors,namely SP9 3He proportional counter,embedded in eight different diameter polyethylene spheres.The response function of eight polyethylene spheres of multi-sphere neutron spectrometer was calculated after the simulation of the neutron transport processes in multi-sphere spectrometer by adopting software Geant4.The peak of the response function is in the low energy region for smaller diameter polyethylene sphere.As the polyethylene sphere diameter increased,the peak of the response function moves to the high energy region.The experimental calibration adopts 241Am-Be neutron source.The relative error between normalized data of experiment 4πsolid angle counts and normalized data of simulated detection efficiency of 4in to 8in polyethylene sphere is from 1.152%to 12.222%.The experimental results verify the response function of the simulation.All these results provide a theoretical and experimental basis for solving the on-line real-time neutron spectrum of ITER fusion.

Approximate Electromagnetic Cloaking of a Dielectric Sphere Using Homogeneous Isotropic Multi-Layered Materials

In cloaking, a body is hidden from detection by surrounding it by a coating consisting of an unusual anisotropic nonhomogeneous material. The permittivity and permeability of such a cloak are determined by the coordinate transformation of compressing a hidden body into a point or a line. The radially-dependent spherical cloaking shell can be approximately discretized into many homogeneous anisotropic layers;each anisotropic layer can be replaced by a pair of equivalent isotropic sub-layers, where the effective medium approximation is used to find the parameters of these two equivalent sub-layers. In this work, the scattering properties of cloaked dielectric sphere is investigated using a combination of approximate cloaking, where the dielectric sphere is transformed into a small sphere rather than to a point, together with discretizing the cloaking material using pairs of homogeneous isotropic sub-layers. The back-scattering normalized radar cross section, the scattering patterns are studied and the total scattering cross section against the frequency for different number of layers and transformed radius.

CLASSIFICATIONS OF DUPIN HYPERSURFACES IN LIE SPHERE GEOMETRY

This is a survey of local and global classification results concerning Dupin hypersurfaces in S^(n)(or R^(n))that have been obtained in the context of Lie sphere geometry.The emphasis is on results that relate Dupin hypersurfaces to isoparametric hypersurfaces in spheres.Along with these classification results,many important concepts from Lie sphere geometry,such as curvature spheres,Lie curvatures,and Legendre lifts of submanifolds of S^(n)(or R^(n)),are described in detail.The paper also contains several important constructions of Dupin hypersurfaces with certain special properties.

Prediction of Coefficient of Restitution for Impact Elastoplastic Spheres Considering Finite Plate Thickness

Collisions between objects are a relatively common phenomenon in nature.Analyses of collision processes can greatly contribute to solving problems such as impact-rub faults and particle impacts.The coefficient of restitution is a critical parameter in the analysis of collision processes.Many experiments have shown that the coefficient of restitution is closely related to the plate thickness,and the smaller the plate thickness,the more inaccurate the coefficient of restitution predicted by the existing model,which seriously affects the process of collision analysis.To remedy this shortcoming,this paper proposes a plate thickness influence factor with the ratio of sphere diameter to plate thickness as the variable.The plate thickness influence factor can optimize the coefficient of restitution model to effectively predict the coefficient of restitution of impacting elastoplastic spheres with finite plate thickness.Finally,the validity of the new model is verified using a large amount of experimental data.

Recent advances in producing hollow carbon spheres for use in sodium−sulfur and potassium−sulfur batteries

Sodium-sulfur(Na-S)and potassium-sulfur(K-S)batteries for use at room temperature have received widespread attention because of the abundance and low cost of their raw materials and their high energy density.However,their development is restricted by the shuttling of polysulfides,large volume expansion and poor conductivity.To overcome these obstacles,an effective approach is to use carbon-based materials with abundant space for the sulfur that has sulfiphilic sites to immobilize it,and a high electrical conductivity.Hollow carbon spheres(HCSs)with a controllable structure and composition are promising for this purpose.We consider recent progress in optimizing the electrochemical performance of Na-/K-S batteries by using these materials.First,the advantages of HCSs,their synthesis methods,and strategies for preparing HCSs/sulfur composite materials are reviewed.Second,the use of HCSs in Na-/K-S batteries,along with mechanisms underlying the resulting performance improvement,are discussed.Finally,prospects for the further development of HCSs for metal−S batteries are presented.

Core-shell mesoporous carbon hollow spheres as Se hosts for advanced Al-Se batteries

Incorporating a selenium(Se)positive electrode into aluminum(Al)-ion batteries is an effective strategy for improving the overall battery performance.However,the cycling stability of Se positive electrodes has challenges due to the dissolution of intermediate reaction products.In this work,we aim to harness the advantages of Se while reducing its limitations by preparing a core-shell mesoporous carbon hollow sphere with a titanium nitride(C@TiN)host to load 63.9wt%Se as the positive electrode material for Al-Se batteries.Using the physical and chemical confinement offered by the hollow mesoporous carbon and TiN,the obtained core-shell mesoporous carbon hollow spheres coated with Se(Se@C@TiN)display superior utilization of the active material and remarkable cycling stability.As a result,Al-Se batteries equipped with the as-prepared Se@C@TiN composite positive electrodes show an initial discharge specific capacity of 377 mAh·g^(-1)at a current density of 1000 mA·g^(-1)while maintaining a discharge specific capacity of 86.0 mAh·g^(-1)over 200 cycles.This improved cycling performance is ascribed to the high electrical conductivity of the core-shell mesoporous carbon hollow spheres and the unique three-dimensional hierarchical architecture of Se@C@TiN.

Spherically Symmetric Problem of General Relativity for a Fluid Sphere

The paper is devoted to a spherically symmetric problem of General Relativity (GR) for a fluid sphere. The problem is solved within the framework of a special geometry of the Riemannian space induced by gravitation. According to this geometry, the four-dimensional Riemannian space is assumed to be Euclidean with respect to the space coordinates and Riemannian with respect to the time coordinate. Such interpretation of the Riemannian space allows us to obtain complete set of GR equations for the external empty space and the internal spaces for incompressible and compressible perfect fluids. The obtained analytical solution for an incompressible fluid is compared with the Schwarzchild solution. For a sphere consisting of compressible fluid or gas, a numerical solution is presented and discussed.

Exactly Solvable Two-Parameter Models of Relativistic δ′s -Sphere Interactions in Quantum Mechanics

We make a systematic study of two-parameter models of δ ′ s -sphere interaction and δ ′ s -sphere plus a Coulomb interaction. Where δ ′ s interaction denotes the δ ′ -sphere interaction of the second kind. We provide the mathematical definitions of Hamiltonians and obtain new results for both models, in particular the resolvents equations, spectral properties and some scattering quantities.

不同文化圈中级水平留学生礼貌原则习得的实验研究

采用移动窗口技术和在线选择任务,以25名汉文化圈和24名欧美文化圈留学生为被试,考察了不同文化背景中级水平留学生礼貌原则各准则的习得特点与规律。结果表明:(1)汉文化圈留学生对一致准则和同情准则的习得效果最好,损惠准则和谦逊准则次之,赞誉准则较弱;(2)欧美文化圈留学生对同情准则的习得效果最好,赞誉准则次之,损惠准则、谦逊准则和一致准则较弱:(3)汉文化圈和欧美文化圈中级水平留学生对同情准则的习得效果一样好,前者对损惠准则、谦逊准则和一致准则的习得效果优于后者,后者对赞誉准则的习得效果优于前者。根据实验结果,初步建构了不同文化圈留学生礼貌原则各准则的心理层级系统。

基于单积分球技术的最佳样本厚度研究及油茶籽油鉴伪

为减少单积分球技术采集光谱数据过程中的光损失,探索了油茶籽油检测时光损失量最小的样本厚度,并研究在此样本厚度下鉴别掺伪油茶籽油的能力。采用蒙特卡罗(MC)算法模拟单积分球技术下样本的测量,将模拟出的反射率(MR)和透射率(MT)作为实际值,单积分球采集的数据作为预测值,将实际值与预测值之间的平均相对误差(MRE)和均方根误差(RMSE)作为评价指标,确定最佳的样本厚度。按不同掺伪比例制备了230组样本,采集最佳样本厚度的掺伪油茶籽油光谱数据,结合逆向倍增(IAD)算法得到样本的吸收系数(μ_(a))和约化散射系数(μ_(s)′)。将μ_(a)和μ_(s)′经过均值中心化预处理之后,利用Kennard-Stone(K-S)算法以7∶3的比例将样本划分成训练集和测试集,分别建立基于支持向量机(SVM)和随机森林(RF)的多分类定性鉴别模型。结果表明:样本厚度为14mm时,MR和MT的MRE和RMSE均相对较小;μ_(a)和μ_(s)′建立的SVM模型鉴别准确率分别为97.10%和95.65%,建立的RF模型鉴别准确率分别为98.55%和97.10%。因此,基于最佳样本厚度下的单积分球技术结合SVM和RF模型,可有效实现油茶籽油的快速鉴伪。

基于Sector/Sphere的气相色谱质谱联用多样本并行对齐算法

针对气相色谱质谱联用(GC-MS)数据处理过程复杂且计算量大、处理时间过长而严重拖延实验进度的问题,以多样本保留时间对齐为例,设计了基于分布式平台Sector/Sphere的GC-MS数据处理并行框架,实现了多样本并行对齐算法。首先分布式计算所有样本的相似度矩阵;然后依据层次聚类原理将原样本集划分为小样本集,分布式对齐各小样本集内部的样本;最后以各小样本集的平均样本作为对齐依据合并各样本集的对齐结果。实验结果表明:多样本并行对齐算法的错误率为2.9%,由4台PC组成的集群处理大量样本时,最高加速比达到3.29;能够在保证较高正确率的前提下提升计算速度,解决处理时间过长的问题。

Size-controlled preparation of hollow silica spheres and glyphosate release

Different-sized hollow SiO2 spheres of 249–1348 nm in diameter were successfully prepared by using Na2SiO3 as the precursor and using polystyrene and polystyrene-methyl acrylic acid latexes as the templates. The diameter and shell thickness of the hollow SiO2 spheres increase with increasing the latex template diameter at a given mass ratio of SiO2 to latex template. The diameter and shell thickness of the hollow SiO2 spheres also increase with increasing the mass ratios of SiO2 to latex template. The presence of carboxylic acid groups on the surfaces of polystyrene-methyl acrylic acid latex templates favors the formation of dense and uniform SiO2 shells. The hollow SiO2 sphere is constructed by mesoporous shell with large specific surface area. When glyphosate is used as a release model chemical, glyphosate release rate is tuned by varying the shell thickness.

基于HL7和WebSphere MQ的用药决策系统的设计及实现

目的开发用药决策支持系统,用于辅助管理、规范诊疗行为,使临床用药趋于合理。方法系统应用IBM Web Sphere MQ V7.0消息中间件获取医院各信息系统患者诊疗数据,并进行用药决策分析;数据按HL7标准格式封装、传输和解码,实现医院各信息系统间信息交互。结果建立了临床用药规则信息库、常用诊断信息库,系统实现了用药合理性决策支持功能。结论基于HL7和Web Sphere MQ的用药决策系统设计符合我院的实际需求,并能提升临床用药质量,减少临床药师的工作量,提升医院药事工作效率。

Preparation and in vitro release studies of thymosin-loaded PLA microspheres

To obtain a kind of convenient oral dosage form of protein, which can be fully absorbed and is efficient and safe, the thymosin-loaded PLA（polylactic acid） microspheres are prepared by the emulsification- solvent evaporation method and the orthogonal design is used to optimize the technology of preparation. The form of the medicament microspheres of thymosin are proved by differential thermal analysis （DTA）. The drug content is determined by the Lowry method, and the package ratio of medicament microspheres of thymosin and drug release in vitro are calculated. The results show that the average diameter and encapsulation efficiency of the product prepared according to the optimized formulation are 13. 8 μm and 80. 7%, respectively. The in vitro release behavior within 12 h can be described by the Higuchi equation with T1/2 = 295 rain. There are no significant changes in size distribution and residual drug contents after being stored at 25℃ and 40 ℃ for 90 d, respectively. Due to the fact that its thymosin content and package ratio meet the requirement, and its releasing half life is long, the thymosin-loaded PLA microsohere has a favorable application future.