Numerical Simulation Study of Oil-Water Emulsion Separation in an Ultrasonic Field:Effect of Coupling between Acoustic and Flow Field Parameters

In this study,the separation and coalescence of oil-in-water emulsions are explored in an ultrasonic field using the lattice Boltzmann method.By simulating the propagation of ultrasonic waves,this study focuses on examining the effects of acoustic wave frequency,the ratio of oil to water components,and the aspect ratio of the boundary on the emulsification and separation processes of oil-water mixtures.The following conclusions are drawn.①Frequency affects the speed of oil droplet separation,leading to an increase in droplet size over time.Larger droplets are found near the source,while smaller droplets are distributed throughout the wave web.②As the boundary aspect ratio increases,the emulsification efficiency of the droplets weakens,and the system takes longer to stabilize.③Emulsions with a higher component of oil can better resist acoustic waves.④At the same acoustic frequency,longer wavelength ultrasonic fields promote the formation of uniformly distributed,smaller oil droplets,which is beneficial to the storage of emulsions.These numerical simulation results offer insights for optimizing conditions for oil-in-water separation and serve as a numerical reference for the study of oil-in-water emulsion separation in ultrasonic environments.

Modulating charge separation and transfer for high-performance photoelectrodes via built-in electric field

Constructing a built-in electric field has emerged as a key strategy for enhancing charge separation and transfer,thereby improving photoelectrochemical performance.Recently,considerable efforts have been devoted to this endeavor.This review systematically summarizes the impact of built-in electric fields on enhancing charge separation and transfer mechanisms,focusing on the modulation of built-in electric fields in terms of depth and orderliness.First,mechanisms and tuning strategies for built-in electric fields are explored.Then,the state-of-the-art works regarding built-in electric fields for modulating charge separation and transfer are summarized and categorized according to surface and interface depth.Finally,current strategies for constructing bulk built-in electric fields in photoelectrodes are explored,and insights into future developments for enhancing charge separation and transfer in high-performance photoelectrochemical applications are provided.

Separation of up-going and down-going wave fields of vertical cable data

The vertical cable method for acquiring and processing pre-stack 3-D marine seismic data is based on the technology developed by the US Navy for antisubmarine warfare. In order to achieve the maximum utili- zation of vertical cable field data, a new separation method of the up-going and down-going wave fields of the vertical cable data processing was developed in this paper, which is different from the separation of the down-going and up-going wave fields of normal VSP data processing. In tests with synthetic modeling data and actual field data, this newly developed method performs well and is also computationally simpler without pre-assumption conditions.

Numerical study on flow separation control over NACA0015 aerofoil using electromagnetic fields

In this study, a flow solver was developed based on the governing RANS equations of compressible flows and was further extended to include the effects of electromagnetic forces namely Lorentz forces. Lorentz forces may be added as a source term in the governing fluid flow equations. Numerical studies were carried out for NACA0015 aerofoil at high angles of incidences from 15° to 30° and compared with some available cases of experimental and incompressible numerical solutions. The hydrodynamics performance was improved using a magnetic momentum coefficient of up to 0.048. The size of flow separation zone was decreased or completely eliminated by increasing this coefficient. The overall drag was not changed considerably, however the overall lift was increased up to 80 percent at stall angles.

Influence of mode conversions in the skull on transcranial focused ultrasound and temperature fields utilizing the wave field separation method： A numerical study

Transcranial focused ultrasound is a booming noninvasive therapy for brain stimuli. The Kelvin–Voigt equations are employed to calculate the sound field created by focusing a 256-element planar phased array through a monkey skull with the time-reversal method. Mode conversions between compressional and shear waves exist in the skull. Therefore, the wave field separation method is introduced to calculate the contributions of the two waves to the acoustic intensity and the heat source, respectively. The Pennes equation is used to depict the temperature field induced by ultrasound. Five computational models with the same incident angle of 0？and different distances from the focus for the skull and three computational models at different incident angles and the same distance from the focus for the skull are studied. Numerical results indicate that for all computational models, the acoustic intensity at the focus with mode conversions is 12.05%less than that without mode conversions on average. For the temperature rise, this percentage is 12.02%. Besides, an underestimation of both the acoustic intensity and the temperature rise in the skull tends to occur if mode conversions are ignored. However, if the incident angle exceeds 30？, the rules of the over-and under-estimation may be reversed. Moreover,shear waves contribute 20.54% of the acoustic intensity and 20.74% of the temperature rise in the skull on average for all computational models. The percentage of the temperature rise in the skull from shear waves declines with the increase of the duration of the ultrasound.

Separate Analysis of Remote Sensing Information of Structures of Different Geological Periods and Quantitative Study of Corresponding Tectonic Stress Fields

The structural feature shown on a remote sensing image is a synthetic result ofcombination of the deformations produced during the entire geological history of an area.Therefore, the respective tectonic stress field of each of the different stages in the complexdeformation of an area can be reconstructed in three steps: (1) geological structures formed atdifferent times are distinguished in remote sensing image interpretation; (2) structuraldeformation fields at different stages are determined by analyzing relationships betweenmicrostructures (joints and fractures) and the related structures (folds and faults); and (3)tectonic stress fields at different stages are respectively recovered through a study of the featuresof structural deformation fields in different periods. Circular structures and related circlular and radial joints are correlated in space to con-cealed structural rises. The authors propose a new method for establishing a natural model ofthe concealed structural rises and calculating the tectonic stress field by using quantitative dataof the remote sensing information of circular structures and related linear structures.

Binary fluids in mesoporous materials: Phase separation studied by NMR relaxation and diffusion

Relaxation and diffusion measurements were carried out on single and binary liquids filling the pore space of controlled porous glass Vycor with an average pore size of about 4 nm.The dispersion of the longitudinal relaxation time Tr is discussed as a means to identify liquid-surface interaction based on existing models developed for metal-free glass surfaces.In addition,the change of T1 and T2 with respect to their bulk values is discussed,in particular T2 serves as a probe for the strength of molecular interactions.As the native glass surface is polar and contains a large amount of hydroxyl groups,a pronounced interaction of polar and protic adsorbate liquids is expected;however,the T dispersion,and the corresponding reduction of T2,are also observed for non-polar liquids such as alkanes and cyclohexane.Deuterated liquids are employed for simplifying data analysis in binary systems,but also for separating the respective contributions of intra-and intermolecular interactions to the overall relaxation rate.Despite the lack of paramagnetic impurities in the glass material,H and 2H relaxation dispersions of equivalent molecules are frequently found to differ from each other,suggesting intermolecular relaxation mechanisms for the'H nuclei.The variation of the T dispersion when comparing single and binary systems gives clear evidence for the preferential adsorption of one of the two liquids,suggesting complete phase separation in several cases.Measurement of the apparent tortuosity by self-diffusion experiments supports the concept of a local variation of sample composition within the porespace.

Separation efficiency of alumina particles in Al melt under high frequency magnetic field

The effects of separation time and magnetic induction intensity on the separation efficiency of alumina particles with diameters varying from 30 to 200 μm in aluminum melt were investigated. The experimental results show that the particle-accumulated layer is formed in the periphery of the solidified specimen when the diameter of the separated molten metal, the magnetic induction intensity and the separation time are 10 mm, 0.04 T and 1 s, respectively. When the separation time is 2 s, the particle-accumulated layer can be observed obviously and the separation efficiency is about 80%. There are few alumina particles in the inner of the solidified specimen when the separation time is 3 s. The separation efficiency higher than 85% can be achieved when the separation time is longer than 3 s. When the magnetic induction intensity is 0.06 T, the visible particle-accumulated layer can be formed in 1 s and the separation efficiency is higher than 95%. The experimental results were compared with the calculated results at last.

A Sound Field Separation and Reconstruction Technique Based on Reciprocity Theorem and Fourier Transform

We show a method to separate the sound field radiated by a signal source from the sound field radiated by noise sources and to reconstruct the sound field radiated by the signal source. The proposed method is based on reciprocity theorem and the Fourier transform. Both the sound field and its gradient on a measurement surface are needed in the method. Evanescent waves are considered in the method, which ensures a high resolution reconstruction in the near field region of the signal source when evanescent waves can be measured. A simulation is given to verify the method and the influence of measurement noise on the method is discussed.

Internal electric field modulation by copper vacancy concentration of cuprous sulfide nanosheets for enhanced selective CO_(2) photoreduction

Although the internal electric field(IEF)of photocatalysts is acknowledged as a potent driving force for photocharge separation,modulating the IEF intensity to achieve enhanced photocatalytic performances remains a challenge.Herein,cuprous sulfide nanosheets with different Cu vacancy concentration were employed to study IEF modulation and corresponding direct charge transfer.Among the samples,Cu_(1.8)S nanosheets possessed intensified IEF intensity compared with those of Cu_(2)S and Cu_(1.95)S nanosheets,suggesting that an enhanced IEF intensity could be achieved by introducing more Cu vacancies.This intensified IEF of Cu_(1.8)S nanosheets induced numerous photogenerated electrons to migrate to its surface,and the dissociative electrons were then captured by Cu vacancies,resulting in efficient charge separation spatially.In addition,the Cu vacancies on Cu_(1.8)S nanosheets accumulated electrons as active sites to lower the energy barrier of rate-determining step of CO_(2)photoreduction,leading to the selective conversion of CO_(2)to CO.Herein,the manipulation of IEF intensity through Cu vacancy concentration regulation of cuprous sulfide photocatalysts for efficient charge separation has been discussed,providing a scientific strategy to rationally improve photocata lytic performances for solar energy conversion.

Continuous Separation of Inclusions from Aluminum Melt Flowing in a Circular Pipe using a High Frequency Magnetic Field

The continuous separation of inclusions from aluminum melt flowing in a circular pipe using a high frequency magnetic field was investigated both theoretically and experimentally. The separation efficiency was calculated based on the trajectory method and compared with experimental results. It is found that the separation efficiency is a function ofnondimensional parameters ti . The effective way to improve the separation efficiency is to increase the effective magnetic flux density and decrease the pipe radius, and the value of should be kept about 2 in order to obtain the optimum separation efficiency.

VSe_(2)/V_(2)C heterocatalyst with built-in electric field for efficient lithium-sulfur batteries:Remedies polysulfide shuttle and conversion kinetics

Lithium sulfur(Li-S)battery is a kind of burgeoning energy storage system with high energy density.However,the electrolyte-soluble intermediate lithium polysulfides(Li PSs)undergo notorious shuttle effect,which seriously hinders the commercialization of Li-S batteries.Herein,a unique VSe_(2)/V_(2)C heterostructure with local built-in electric field was rationally engineered from V_(2)C parent via a facile thermal selenization process.It exquisitely synergizes the strong affinity of V_(2)C with the effective electrocatalytic activity of VSe_(2).More importantly,the local built-in electric field at the heterointerface can sufficiently promote the electron/ion transport ability and eventually boost the conversion kinetics of sulfur species.The Li-S battery equipped with VSe_(2)/V_(2)C-CNTs-PP separator achieved an outstanding initial specific capacity of 1439.1 m A h g^(-1)with a high capacity retention of 73%after 100 cycles at0.1 C.More impressively,a wonderful capacity of 571.6 mA h g^(-1)was effectively maintained after 600cycles at 2 C with a capacity decay rate of 0.07%.Even under a sulfur loading of 4.8 mg cm^(-2),areal capacity still can be up to 5.6 m A h cm^(-2).In-situ Raman tests explicitly illustrate the effectiveness of VSe_(2)/V_(2)C-CNTs modifier in restricting Li PSs shuttle.Combined with density functional theory calculations,the underlying mechanism of VSe_(2)/V_(2)C heterostructure for remedying Li PSs shuttling and conversion kinetics was deciphered.The strategy of constructing VSe_(2)/V_(2)C heterocatalyst in this work proposes a universal protocol to design metal selenide-based separator modifier for Li-S battery.Besides,it opens an efficient avenue for the separator engineering of Li-S batteries.

Tuning the phase separation in La_(0.325)Pr_(0.3)Ca_(0.375)MnO_3 using the electric double-layer field effect

Electric double-layer field effect experiments were performed on ultrathin films of La0.325Pr0.3Ca0.375MnO3, which is noted for its micrometer-scale phase separation. A clear change of resistance up to 220% was observed and the characteristic metal-insulator transition temperature Tp was also shifted. The changes of both the resistance and Tp, suggest that the electric field induced not only tuning of the carrier density but also rebalancing of the phase separation states. The change of the charge-ordered insulating phase fraction was estimated to be temperature dependent, and a maximum of 16% was achieved in the phase separation regime. This tuning effect was partially irreversible, which might be due to an oxygen vacancy migration that is driven by the huge applied electric field.

Capillary Electrophoretic Separation of Proteins under the Control of Radial Electric Field

Separation of basic proteins was performed using a homemade field-modulated capillary electrophoresis system. The resolution. elution and even wall adsorption can be regulated by ad-lusting the radial rather than axial voltage applied. Selection of running buffer and pH was found to be critical.

Energetic Laser-Ion Acceleration by Strong Charge-Separation Field

The laser-ion acceleration from the ultra-short and ultra-intense laser-matter interactions attracts more and more interest nowadays. When a laser pulse interacts with a target, relativistic electrons are generated in a period of few femtoseconds and driven away by the ponderomotive force, then a huge charge-separation field forms. In general cases, the ion acceleration is determined by this charge-separation field and the scale length of the plasma density. A general time-dependent solution is obtained to describe laser-plasma isothermal expansions into a vacuum, which is the fundamental theory of the laser-ion acceleration. It is adequate for non-quasi-neutral plasmas and different types of the scale length of the density gradient. The previous solutions are some special cases of our general solution. It is found that there exist both a compression layer of the ion velocity distribution and a potential well for sorue initial conditions. However, many unaccounted idiographic solutions, which may be used to reveal new mechanisms of ion acceleration, may be deduced from our general solutions.

Phase-field simulation of phase separation in Ni_(75)Al_xV_(25-x) alloy with elastic stress

The phase separation in Ni75AlxV25-x alloys incorporated with the elastic stress was investigated using the microscopic phase-field model. The final morphology ofγ' andθis similar in spatial alignment, but the volume fraction ofγ' phase increases and that ofθdecreases as the Al concentration increases. For the small elastic interactions of early-stage phase separation, the coarsening ofγ' andθcan be approximated by a linear growth law as predicated by Lifshitz and Slyozov and Wangner (LSW) theory. As the elastic interactions increase at late-stage coarsening, the growth rate decreases, and the growth presents quick increase at early-stage and slows down at late-stage.

Erythrocyte Separation Using Gravitational Field Flow Effect

This research aims to simulate a gravity flow fractionation—the process to fractionate erythrocytes through gravitational field using ANSYS simulation software. A particular microfluidic channel was designed as a separation device. The gravitational equilibrium conditions of the erythrocytes and gravitational field as the parameters were chosen, then deriving the erythrocytes’ path through numerical simulations. After the actual analog measurements, there is no big difference between the flow velocity and the pressure under +/–10% atmosphere condition. According to the simulation results, the particle with the size 8 μm (similar to the erythrocyte size) can be separated to the outside channel and discharged from the collecting area, other particles with the size 9 μm will stay in the fluid motion and can be collected in the final collection area for preservation. Through the analog analysis by using the software-ANSYS-Fluent, the complete flowing path of the particles and the feasibility of the Gravity-Flow Fractionation can be directly proven.

Efficient Particle Separation in Microfluid Channel with Inhomogeneous Magnetic Field

In this paper, we combined magnetostatics and laminar flow in microfluidics and studied a particle separation scheme employing magnetophoretic force in inhomogeneous magnetic field. A detailed model and analysis is shown and the proposed scheme is capable of efficiently separating magnetic particles with different permeability and sizes. The method shows a way to separate efficient particles and could potentially be implemented in biological and chemical systems.

Microfluidic separation of particles by synergistic effect of geometry-induced hydrodynamics and magnetic field

Microfluidic combined with magnetic field have been demonstrated to be the promising solutions for fast and low-damage particles separation.However,the difficulties in the precise layout of magnets and accurate prediction of particle trajectories lead to under and over separation of target particles.A novel particle separation lab-on-chip(LOC)prototype integrated with microstructures and micropolar arrays is designed and characterized.Meanwhile,a numerical model for the separation of magnetic particles by the synergistic effect of geometry-induced hydrodynamics and magnetic field is constructed.The effect of geometry and magnetic field layout on particle deflection is systematically analyzed to implement accurate prediction of particle trajectories.It is found that the separation efficiency of magnetic particles increased from 50.2%to 91.7%and decreased from 88.6%to 85.7%in the range of depth factors from 15µm to 27µm and width factors from 30µm to 60µm,respectively.In particular,the combined effect of the offset distance of permanent magnets and the distance from the main flow channel exhibits a significant difference from the conventional perception.Finally,the developed LOC prototype was generalized for extension to arbitrary systems.This work provides a new insight and robust method for the microfluidic separation of magnetic particles.