A detailed acquisition,analysis,and representation of biological systems exhibiting different functions is required to develop unique bio-inspired multifunctional conceptual designs and methods.This paper presents BIK...A detailed acquisition,analysis,and representation of biological systems exhibiting different functions is required to develop unique bio-inspired multifunctional conceptual designs and methods.This paper presents BIKAS:Bio-inspired Knowledge Acquisition and Simulacrum,a knowledge database of biological systems exhibiting various functionalities,developed based on case-based bio-inspired examples from literature.The knowledge database represents the biological features,their characteristics,and the function exhibited by the biological feature as a combination of its integrated structure and structural strategy.Furthermore,this knowledge database is utilized by the Expandable Domain Integrated Design(xDID)model that works on classifying,mapping,and representing biological features into their respective geometric designations called Domains.The combination of features from the Domains results in the generation of multifunctional conceptual designs.In addition,Meta-level design factors are proposed to aid designers in filtering the biological features and their respective functions having a similar structural strategy,thus aiding designers in rapidly selecting and emulating biological functions.展开更多
The earth-abundant and high-performance catalysts are crucial for commercial implementation of hydrogen evolution reaction(HER).Herein,a multifunctional site strategy to construct excellent HER catalysts by incorporat...The earth-abundant and high-performance catalysts are crucial for commercial implementation of hydrogen evolution reaction(HER).Herein,a multifunctional site strategy to construct excellent HER catalysts by incorporating iridium(Ir)ions on the atomic scale into orthorhombic-CoSe2(Ir-CoSe_(2))was reported.Outstanding hydrogen evolution activity in alkaline media such as a low overpotential of 48.7 mV at a current density of 10 mA cm^(-2)and better performance than commercial Pt/C catalysts at high current densities were found in the Ir-CoSe_(2) samples.In the experiments and theoretical calculations,it was revealed that Ir enabled CoSe_(2)to form multifunctional sites to synergistically catalyze alkaline HER by promoting the adsorption and dissociation of H_(2)O(Ir sites)and optimizing the binding energy for H^(*)on Co sites.It was noticeable that the electrolytic system comprising the Ir-CoSe_(2)electrode not only produced hydrogen efficiently via HER,but also degraded organic pollutants(Methylene blue).The cell voltage of the dual-function electrolytic system was 1.58 V at the benchmark current density of 50 mA cm^(-2),which was significantly lower than the conventional water splitting voltage.It was indicated that this method was a novel strategy for designing advanced HER electrocatalysts by constructing multifunctional catalytic sites for hydrogen production and organic degradation.展开更多
基金supported by the Natural Sciences and Engineering Research Council of Canada Discovery Grant RGPIN-2018-05971 and MEDA(McGill Engineering Doctoral Award).
文摘A detailed acquisition,analysis,and representation of biological systems exhibiting different functions is required to develop unique bio-inspired multifunctional conceptual designs and methods.This paper presents BIKAS:Bio-inspired Knowledge Acquisition and Simulacrum,a knowledge database of biological systems exhibiting various functionalities,developed based on case-based bio-inspired examples from literature.The knowledge database represents the biological features,their characteristics,and the function exhibited by the biological feature as a combination of its integrated structure and structural strategy.Furthermore,this knowledge database is utilized by the Expandable Domain Integrated Design(xDID)model that works on classifying,mapping,and representing biological features into their respective geometric designations called Domains.The combination of features from the Domains results in the generation of multifunctional conceptual designs.In addition,Meta-level design factors are proposed to aid designers in filtering the biological features and their respective functions having a similar structural strategy,thus aiding designers in rapidly selecting and emulating biological functions.
基金the financial support of the Doctoral Research Initiation Foundation of Linyi University(LYDX2020BS016)the National Natural Science Foundation of Shandong Province(ZR2021QB208,ZR2022MB054)+4 种基金the National Natural Science Foundation of China(22305262)SIAT Innovation Program for Excellent Young Researchers(2022)Shenzhen Science and Technology Program Grant(RCJC20200714114435061,ZDSYS20220527171406014)the City University of Hong Kong Donation Research Grants(9220061 and 9229021)City University of Hong Kong Strategic Research Grant(SRG 7005505)。
文摘The earth-abundant and high-performance catalysts are crucial for commercial implementation of hydrogen evolution reaction(HER).Herein,a multifunctional site strategy to construct excellent HER catalysts by incorporating iridium(Ir)ions on the atomic scale into orthorhombic-CoSe2(Ir-CoSe_(2))was reported.Outstanding hydrogen evolution activity in alkaline media such as a low overpotential of 48.7 mV at a current density of 10 mA cm^(-2)and better performance than commercial Pt/C catalysts at high current densities were found in the Ir-CoSe_(2) samples.In the experiments and theoretical calculations,it was revealed that Ir enabled CoSe_(2)to form multifunctional sites to synergistically catalyze alkaline HER by promoting the adsorption and dissociation of H_(2)O(Ir sites)and optimizing the binding energy for H^(*)on Co sites.It was noticeable that the electrolytic system comprising the Ir-CoSe_(2)electrode not only produced hydrogen efficiently via HER,but also degraded organic pollutants(Methylene blue).The cell voltage of the dual-function electrolytic system was 1.58 V at the benchmark current density of 50 mA cm^(-2),which was significantly lower than the conventional water splitting voltage.It was indicated that this method was a novel strategy for designing advanced HER electrocatalysts by constructing multifunctional catalytic sites for hydrogen production and organic degradation.