Molecular dynamics study of coupled layer thickness and strain rate effect on tensile behaviors of Ti/Ni multilayered nanowires

Novel properties and applications of multilayered nanowires(MNWs)urge researchers to understand their mechanical behaviors comprehensively.Using the molecular dynamic simulation,tensile behaviors of Ti/Ni MNWs are investigated under a series of layer thickness values(1.31,2.34,and 7.17 nm)and strain rates(1.0×10^(8)s^(-1)≤ε≤5.0×10^(10)s^(-1)).The results demonstrate that deformation mechanisms of isopachous Ti/Ni MNWs are determined by the layer thickness and strain rate.Four distinct strain rate regions in the tensile process can be discovered,which are small,intermediate,critical,and large strain rate regions.As the strain rate increases,the initial plastic behaviors transform from interface shear(the shortest sample)and grain reorientation(the longest sample)in small strain rate region to amorphization of crystalline structures(all samples)in large strain rate region.Microstructure evolutions reveal that the disparate tensile behaviors are ascribed to the atomic fractions of different structures in small strain rate region,and only related to collapse of crystalline atoms in high strain rate region.A layer thickness-strain rate-dependent mechanism diagram is given to illustrate the couple effect on the plastic deformation mechanisms of the isopachous nanowires.The results also indicate that the modulation ratio significantly affects the tensile properties of unequal Ti/Ni MNWs,but barely affect the plastic deformation mechanisms of the materials.The observations from this work will promote theoretical researches and practical applications of Ti/Ni MNWs.

Effect of sub-layer thickness on magnetic and giant magnetoresistance properties of Ni–Fe/Cu/Co/Cu multilayered nanowire arrays

Ni-Fe/Cu/Co/Cu multilayered nanowire arrays were electrodeposited into anodic aluminum oxide template by using dual-bath method at room temperature. Scanning electron microscopy and transmission electron microscopy were used to characterize the morphology and structure of the multilayered nanowire arrays. Vibrating sample magnetometer and physical property measurement system were used to measure their magnetic and giant magnetoresistance （GMR） properties. The effect of sub-layer thickness on the magnetic and GMR properties was investigated. The results indicate that magnetic properties of electmdeposited nanowires are not affected obviously by Cu layer thickness, while magnetic layers （Ni-Fe and Co layers） have significant influence. In addition, GMR ratio presents an oscillatory behavior as Cu layer thickness changes. The magnetic and GMR properties of the multilayered nanowire arrays are optimum at room temperature for the material structure of Ni-Fe （25 nm）/Cu （15 nm）/Co （25 nm）/Cu （15 nm） with 30 deposition cycles.

Polymer Solar Cells Using a PEDOT:PSS/Cu Nanowires/PEDOT:PSS Multilayer as the Anode Interlayer

We compare the electrical, optical, and surface properties of the PEDOT：PSS/Cu nanowires （Cu NWs）/PEDOT： PSS （PCP） multilayer for organic solar cells. It is demonstrated that the electrical and optical properties of the PEDOT could be improved by the insertion of a Cu NW layer due to its very low resistivity and surface morphology. The organic bulk heterojunction solar cell fabricated on the multil^yer exhibits a higher power conversion ef^ciency than devices based on the PEDOT：PSS or PEDOT：PSS/Cu NWs layer. Moreover, the PCP multilayer can improve cell-performances such as a fill factor and the internal resistance in the device due to horizontally well-aligned Cu NWs. The results suggest that the PCP multilayer is a promising low-cost and low-temperature processing buffer layer candidate for low-cost organic photovoltaics.

The effect of substrate on magnetic properties of Co/Cu multilayer nanowire arrays

Ordered Co/Cu multilayer nanowire arrays have been fabricated into anodic aluminium oxide templates with Ag and Cu substrate by direct current electrodeposition. This paper studies the morphology, structure and magnetic properties by transmission electron microscopy, selective area electron diffraction, x-ray diffraction, and vibrating sample magnetometer. X-ray diffraction patterns reveal that both as-deposited nanowire arrays films exhibit face-centred cubic structure. Magnetic measurements indicate that the easy magnetization direction of Co/Cu multilayer nanowire arrays films on Ag substrate is perpendicular to the long axis of nanowire, whereas the easy magnetization direction of the sample with Cu substrate is parallel to the long axis of nanowire. The change of easy magnetization direction attributed to different substrates, and the magnetic properties of the nanowire arrays are discussed.