Prediction of rock fragmentation in a fiery seam of an open-pit coal mine in India

Spontaneous combustion of coal increases the temperature in adjoining overburden strata of coal seams and poses a challenge when loading blastholes.This condition,known as hot-hole blasting,is dangerous due to the increased possibility of premature explosions in loaded blastholes.Thus,it is crucial to load the blastholes with an appropriate amount of explosives within a short period to avoid premature detonation caused by high temperatures of blastholes.Additionally,it will help achieve the desired fragment size.This study tried to ascertain the most influencial variables of mean fragment size and their optimum values adopted for blasting in a fiery seam.Data on blast design,rock mass,and fragmentation of 100 blasts in fiery seams of a coal mine were collected and used to develop mean fragmentation prediction models using soft computational techniques.The coefficient of determination(R^(2)),root mean square error(RMSE),mean absolute error(MAE),mean square error(MSE),variance account for(VAF)and coefficient of efficiency in percentage(CE)were calculated to validate the results.It indicates that the random forest algorithm(RFA)outperforms the artificial neural network(ANN),response surface method(RSM),and decision tree(DT).The values of R^(2),RMSE,MAE,MSE,VAF,and CE for RFA are 0.94,0.034,0.027,0.001,93.58,and 93.01,respectively.Multiple parametric sensitivity analyses(MPSAs)of the input variables showed that the Schmidt hammer rebound number and spacing-to-burden ratio are the most influencial variables for the blast fragment size.The analysis was finally used to define the best blast design variables to achieve optimum fragment size from blasting.The optimum factor values for RFA of S/B,ld/B and ls/ld are 1.03,1.85 and 0.7,respectively.

Measurement of overburden failure zones in close-multiple coal seams mining

In the Kaiping Coal field,mining of five coal seams,located within 80 m in the Kailuan Group,#5,#7,#8,#9 and#12 coal seam,is difficult due to small interburden thickness,concentrated stress distributions,high coal seam metamorphism,and complex geological conditions.By using the ZTR12 geological penetration radar(GPR)survey combined with borehole observations,the overburden caving due to mining of the five coals seams was measured.The development characteristics of full-cover rock fractures after mining were obtained from the GPR scan,which provides a measurement basis for the control of rock strata in close multiple coal seam mining.For the first time,it was found that the overburden caving pattern shows a periodic triangular caved characteristic.Furthermore,it is proposed that an upright triangular collapsed pile masonry and an inverted triangular with larger fragments piled up alternately appear in the lower gob.The research results show that the roof structure formed in the gob area can support the key overlying strata,which is beneficial to ensure the integrity and stability of the upper coal seams in multiple-seam mining of close coal seams.

Geotechnical considerations for concurrent pillar recovery in close-distance multiple seams

Room-and-pillar mining with pillar recovery has historically been associated with more than 25% of all ground fall fatalities in underground coal mines in the United States.The risk of ground falls during pillar recovery increases in multiple-seam mining conditions.The hazards associated with pillar recovery in multiple-seam mining include roof cutters, roof falls, rib rolls, coal outbursts, and floor heave.When pillar recovery is planned in multiple seams, it is critical to properly design the mining sequence and panel layout to minimize potential seam interaction.This paper addresses geotechnical considerations for concurrent pillar recovery in two coal seams with 21 m of interburden under about 305 m of depth of cover.The study finds that, for interburden thickness of 21 m, the multiple-seam mining influence zone in the lower seam is directly under the barrier pillar within about 30 m from the gob edge of the upper seam.The peak stress in the interburden transfers down at an angle of approximately 20°away from the gob, and the entries and crosscuts in the influence zone are subjected to elevated stress during development and retreat.The study also suggests that, for full pillar recovery in close-distance multiple-seam scenarios,it is optimal to superimpose the gobs in both seams, but it is not necessary to superimpose the pillars.If the entries and/or crosscuts in the lower seam are developed outside the gob line of the upper seam,additional roof and rib support needs to be considered to account for the elevated stress in the multiple-seam influence zone.

Layout and support design of a coal roadway in ultra-close multiple-seams

A roadway within ultra-close multiple-seams(RUCMSs) is one of the most difficult supported coal roadways to deal with in underground coal mines. This is usually due to the unknown stress distributions, improper roadway layout, and unreasonable support parameters. In order to solve this support problem and effectively save RUCMSs from frequent and abrupt disasters(such as serious deformation of the surrounding rock, roof cave ins, and coal side collapse), a comprehensive method is adopted here which includes theoretical analysis, numerical simulation, and field monitoring. A mechanical model was constructed to determine the stress distribution in the coal pillar after two sides of a longwall panel had been mined. Based on this model, the horizontal, vertical, and tangential stress equations for the plane below the floor of the upper-left coal pillar were deduced. In addition, a typical coal mine(the Jinggonger colliery, located in Shuozhou city, Shanxi province, China) with an average distance between its 9# and 11# coal seams of less than 8.0 was chosen to conduct research on the proper layout and reasonable support required for a typical coal roadway located within coal seam 11#. Using FLAC3D(Fast Lagrangian Analysis of Continua in 3-Dimensions) numerical software, eight schemes were designed with different horizontal distances(d) between the center lines of the coal pillar and the roadway in the lower coal seam(RLCS). The simulations and detailed analysis indicate that the proper distances required are between 22.5 and 27.5 m. A total of 20 simulation schemes were used to investigate the factors influencing the support provided by the key bolts(bolt length, spacing, distance between two rows, installation angle, and pre-tightening force). The results were analyzed and used to determine reasonable values for the support parameters. Field results show that the stability and strength of the RLCS can be effectively safeguarded using a combination of researched stress distribution characteristics, proper layout of the RLCS, and correct support parameters.

Unanticipated multiple seam stresses from pillar systems behaving as pseudo gob–case histories

Underground coal mining in the U.S. is conducted in numerous regions where previous workings exist above and/or below an actively mined seam. Miners know that overlying or underlying fully extracted coal areas, also known as gob regions, can result in abutment stresses that affect the active mining. If there was no full extraction, and the past mining consists entirely of intact pillars, the stresses on the active seam are usually minimal. However, experience has shown that in some situations there has been sufficient yielding in overlying or underlying pillar systems to cause stress transfer to the adjoining larger pillars or barriers, which in turn, transfer significant stresses onto the workings of the active seam. In other words, the overlying or underlying pillar system behaves as a ‘‘pseudo gob." The presence of a pseudo gob is often unexpected, and the consequences can be severe. This paper presents several case histories, summarized briefly below, that illustrate pseudo gob phenomenon:(1) pillar rib degradation at a West Virginia mine at 335 m depth that contributed to a rib roll fatality,(2) pillar rib deterioration at a Western Kentucky mine at 175 m depth that required pillar size adjustment and installation of supplemental bolting,(3) roof deterioration at an eastern Kentucky mine at 400 m depth that stopped mine advance and required redirecting the section development,(4) coal burst on development at an eastern Kentucky mine at 520 m depth that had no nearby pillar recovery, and(5) coal burst on development at a West Virginia mine at the relatively shallow depth of 335 m that also had no nearby pillar recovery. The paper provides guidance so that when an operation encounters a potential pseudo gob stress interaction the hazard can be mitigated based on an understanding of the mechanism encountered.

Reservoir reconstruction technologies for coalbed methane recovery in deep and multiple seams

Multiple coal seams widely develop in the deep Chinese coal-bearing strata. Ground in situ stress and coal seam gas pressure increase continuously with the increase of the mining depth, and coal and gas outburst disasters become increasingly severe. When the coal is very deep, the gas content and pressure will elevate and thus coal seams tends to outburst-prone seams. The safety and economics of exploited firstmined coal seams are tremendously restricted. Meanwhile, the multiple seams occurrence conditions resulted in different methane pressure systems in the coal-bearing strata, which made the reservoir reconstruction of coal difficult. Given the characteristics of low saturation, low permeability, strong anisotropy and soft coal of Chinese coal seams, a single hydraulic fracturing surface well for reservoir reconstruction to pre-drain the coalbed methane(CBM) of multiple seams concurrently under the different gas pressure systems has not yet gained any breakthroughs. Based on analyses of the main features of deep CBM reservoirs in China, current gas control methods and the existing challenges in deep and multiple seams, we proposed a new technology for deep CBM reservoir reconstruction to realize simultaneous high-efficiency coal mining and gas extraction. In particular, we determined the first-mined seam according to the principles of effectiveness and economics, and used hydraulic fracturing surface well to reconstruct the first-mined seam which enlarges the selection range of the first-mined seam. During the process of mining first-mined seam, adjacent coal seams could be reconstructed under the mining effect which promoted high-efficiency pressure relief gas extraction by using spatial and comprehensive gas drainage methods(combination of underground and ground CBM extraction methods). A typical integrated reservoir reconstruction technology, ‘‘One well for triple use", was detailed introduced and successfully applied in the Luling coal mine. The application showed that the proposed technology could effectively promote coal mining safety and simultaneously high-efficiency gas extraction.

Evaluation of gas production from multiple coal seams： A simulation study and economics

Gas production from multiple coal seams has become common practice in many coal basins around the world. Although gas production rates are typically enhanced, the economic viability of such practice is not well studied. In order to investigate the technical and economic feasibility of multiple coal seams production, reservoir simulation integrated with economics modelling was performed to study the effect of important reservoir properties of the secondary coal seam on production and economic performance using both vertical and horizontal wells. The results demonstrated that multiple seam gas production of using both vertical and horizontal wells have competitive advantage over single layer production under most scenarios. Gas content and permeability of the secondary coal seam are the most important reservoir properties that have impact on the economic feasibility of multiple seam gas production. The comparison of vertical well and horizontal well performance showed that horizontal well is more economically attractive for both single well and gas field. Moreover, wellhead price is the most sensitive to the economic performance, followed by operating costs and government subsidy. Although the results of reservoir simulation combined with economic analysis are subject to assumptions, multiple seam gas production is more likely to maintain profitability compared with single layer production.

Effect of ω-3 Polyunsaturated Fatty Acid on Toll-like Receptors in Patients with Severe Multiple Trauma

This study examined the effects of ω-3 polyunsaturated fatty acid（ω-3PUFA） on the expression of toll-like receptor 2（TLR2）,toll-like receptor 4（TLR4） and some related inflammatory factors in peripheral blood mononuclear cells（PBMCs） of patients with early-stage severe multiple trauma.Thirty-two patients who were admitted to the Department of Traumatic Surgery,Tongji Hospital（Wuhan,China） between May 2010 and November 2010,and diagnosed as having severe multiple trauma with a injury severity score（ISS） no less than 16,were enrolled in the study and divided into two groups at random（n=16 in each）：ω-3PUFA group and control group in which routine parenteral nutrition supplemented with ω-3PUFA or not was administered to the patients in two groups for consecutive 7 days.Peripheral blood from these patients was collected within 2 h of admission（day 0）,and 1,3,5 and 7 days after the nutritional support.PBMCs were isolated and used for detection of the mRNA and protein expression of TLR2 and TLR4 by using real-time PCR and flow cytometry respectively,the levels of NF-κB by quantum dots-based immunofluorescence assay,the levels of TNF-α,IL-2,IL-6 and COX-2 by ELISA,respectively.The results showed that the mRNA and protein expression of TLR2 and TLR4 in PBMCs was significantly lower in ω-3PUFA group than in control group 5 and 7 days after nutrition support（both P0.05）.The levels of TNF-α,IL-2,IL-6 and COX-2 were found to be substantially decreased in PBMCs in ω-3PUFA group as compared with control group at 5th and 7th day（P0.05 for all）.It was concluded that ω-3PUFA can remarkably decrease the expression of TLR2,TLR4 and some related inflammatory factors in NF-κB signaling pathway in PBMCs of patients with severe multiple trauma,which suggests that ω-3PUFA may suppress the excessive inflammatory response meditated by the TLRs/NF-κB signaling pathway.

Multiple cycles of magnetic activity in the Sun and Sun-like stars and their evolution

The wavelet transform method for high-quality time-frequency analysis is applied to sets of observations of relative sunspot numbers and stellar chromosphere fluxes of 10 Sun-like stars. Wavelet analysis of solar data shows that in a certain interval of time there are several cycles of activity with pe- riods of duration which vary considerably from each other： from quasi-biennial cycles to lO0-yr cycles. Cyclic activity was detected in almost all Sun-like stars that we examined, even those that previously were not considered as stars with cyclic activity according to analysis using a Scargle periodogram. The durations of solar and stellar cycles significantly change during the observation period.

Multiple Regression Analysis of Influencing Factors on Yield of New Sugarcane Variety Yuetang 03-373

[Objectives]The purpose of this study was to provide reference for cultivation and promotion of a new sugarcane variety Yuetang 03-373,on the basis of analyzing and summarizing the characters of the variety.[Methods]Correlation,multiple regression and path analyses were performed for the yield and yield components of Yuetang 03-373.[Results]Correlation analysis shows that cane yield was significantly correlated with millable stalk number,stalk length and stalk diameter,and among them,the correlation with millable stalk number was the strongest.Multiple regression and path analyses show that millable stalk number contributed the most to cane yield,followed by stalk length,and stalk diameter contributed the least.The regression equation of cane yield against the three yield components was y=-2.8713+1.5497x1+5.8990x2-395.4294x3(R=0.9672**).[Conclusions]Millable stalk number and stalk length were the important and major factors for high yield of Yuetang 03-373,indicating that Yuetang 03-373 is a sugarcane variety of millable stalk type.In cultivation,full play should be given to the advantage of Yuetang 03-373 in millable stalk number,as well as stalk length(plant height),in order to achieve the purpose of increasing yield.

Multiple Ionization of Argon Induced by Carbon Ions at 20-500 keV/u Energies

We measure the multiple ionization cross-section ratios Rk1 of Ar impacted by Cw＋ （q= 1-3） ions in the energy range of 20-500 keV/u. The measured ratios Rkl increase with the projectile energy at lower energies, and reach the maximum at energies of 50-150 keV/u, then decrease for higher energies, We also use the classical over barrier ionization model to calculate the ratios Rk1, and the calculation results are in good agreement with the data, which suggest that the multiple ionization process is described by the sequential over-barrier ionization process,

Rare Aggressive Form of Multiple Myeloma with Diffuse Osteosclerosis and Elevated CA 15-3 Levels

We report the case of a 56-year-old female who had recently been examined for back and epigastric pain, and was diagnosed in the internal medicine ward as having an aggressive rare form of multiple myeloma with diffuse osteoblastic bone lesions. She also had high levels of breast tumor marker (CA 15-3), severe tumor lysis syndrome, and pleural and central nervous system involvement. A few cases of multiple myeloma with diffuse osteosclerosis that are not part of POEMS syndrome (polyneuropathy, organomegaly, endocrinopathy, monoclonal gammopathy, skin changeshave) have been described. None of these cases were as aggressive as our case. To our knowledge it is the first report describing an elevation in CA 15-3 in conjunction with multiple myeloma.

Key technologies and equipment for a fully mechanized top-coal caving operation with a large mining height at ultra-thick coal seams

Thick and ultra-thick coal seams are main coal seams for high production rate and high efficiency in Chinese coal mines, which accounts for 44 % of the total minable coal reserve. A fully mechanized top-coal caving mining method is a main underground coal extraction method for ultra-thick coal seams. The coal extraction technologies for coal seams less than 14 m thick were extensively used in China. However, for coal seams with thickness greater than 14 m, there have been no reported cases in the world for underground mechanical extraction with safe performance, high efficiency and high coal recovery ratio. To deal with this case, China Coal Technology ＆ Engineering Group, Datong Coal Mine Group, and other 15 organizations in China launched a fundamental and big project to develop coal mining technologies and equipment for coal seams with thicknesses greater than 14 m. After the completion of the project, a coal extraction method was developed for top-coal caving with a large mining height, as well as a ground control theory for ultra-thick coal seams. In addition, the mining technology for top-coal caving with a large mining height, the ground support technology for roadway in coal seams with a large cross-section, and the prevention and control technology for gas and fire hazards were developed and applied. Furthermore, a hydraulic support with a mining height of 5.2 m, a shearer with high reliability, and auxiliary equipment were developed and manufactured. Practical implication on the technologies and equipment developed was successfully completed at the No. 8105 coal face in the Tashan coal mine, Datong, China. The major achievements of the project are summarized as follows： 1. A top-coal caving method for ultra-thick coal seams is proposed with a cutting height of 5 m and a top-coal caving height of 15 m. A structural mechanical model of overlying strata called cantilever beam-articulated rock beam is established. Based on the model, the load resistance of the hydraulic support with a large mining height for top-coal caving method is determined. With the analysis, the movement characteristics of the top coal and above strata are evaluated during top-coal caving operation at the coal face with a large mining height. Furthermore, there is successful development of comprehensive technologies for preventing and controlling spalling of the coal wall, and the top-coal caving technology with high efficiency and high recovery at the top-coal caving face with a large mining height. This means that the technologies developed have overcome the difficulties in strata control, top-coal caving with high efficiency and high coal recovery, and enabled to achieve a production rate of more than 10 Mtpa at a single top-coal caving face with a large mining height in ultra-thick coal seams; 2. A hydraulic support with 5.2 m supporting height and anti-rockburst capacity, a shearer with high reliability, a scraper conveyor with a large power at the back of face, and a large load and long distance headgate belt conveyor have been successfully developed for a top-coal caving face with large mining height. The study has developed the key technologies for improving the reliability of equipment at the coal face and has overcome the challenges in equipping the top-coal caving face with a large mining height in ultra-thick coal seams; 3. The deformation characteristics of a large cross-section roadway in ultra-thick coal seams are discovered. Based on the findings above, a series of bolt materials with a high yielding strength of 500-830 MPa and a high extension ratio, and cable bolt material with a 1 × 19 structure, large tonnage and high extension ratio are developed. In addition, in order to achieve a safe roadway and a fast face advance, installation equipment for high pre-tension bolt is developed to solve the problems with the support of roadway in coal seams for top-coal caving operation with a large mining height; 4. The characteristics of gas distribution and uneven emission at top-coal caving face with large mining height in ultra-thick coal seams are evaluated. With the application of the technologies of gas drainage in the roof, the difficulties in gas control for high intensive top-coal caving mining operations, known as ＂low gas content, high gas emission＂, are solved. In addition, large flow-rate underground mobile equipment for making nitrogen are developed to solve the problems with fire prevention and safe mining at a top-coal caving face with large mining height and production rate of more than 10 Mtpa. A case study to apply the developed technologies has been conducted at the No. 8105 face, the Tashan coal mine in Datong, China. The case study demonstrates that the three units of equipment, i.e., the support, shearer and scraper conveyor, are rationally equipped. Average equipment usage at the coal face is 92.1%. The coal recovery ratio at the coal face is up to 88.9 %. In 2011, the coal production at the No. 8105 face reached 10.849 Mtpa, exceeding the target of 10 Mtpa for a topcoal caving operation with large mining height performed by Chinese-made mining equipment. The technologies and equipment developed provide a way for extracting ultra-thick coal seams. Currently, the technologies and equipment are used in 13 mining areas in China including Datong, Pingshuo, Shendong and Xinjiang. With the exploitation of coal resources in Western China, there is great potential for the application of the technologies and equipment developed.

A case study of multi-seam coal mine entry stability analysis with strength reduction method

In this paper,the advantage of using numerical models with the strength reduction method(SRM) to evaluate entry stability in complex multiple-seam conditions is demonstrated.A coal mine under variable topography from the Central Appalachian region is used as a case study.At this mine,unexpected roof conditions were encountered during development below previously mined panels.Stress mapping and observation of ground conditions were used to quantify the success of entry support systems in three room-and-pillar panels.Numerical model analyses were initially conducted to estimate the stresses induced by the multiple-seam mining at the locations of the affected entries.The SRM was used to quantify the stability factor of the supported roof of the entries at selected locations.The SRM-calculated stability factors were compared with observations made during the site visits,and the results demonstrate that the SRM adequately identifies the unexpected roof conditions in this complex case.It is concluded that the SRM can be used to effectively evaluate the likely success of roof supports and the stability condition of entries in coal mines.

Prediction of cavity growth rate during underground coal gasification using multiple regression analysis

During underground coal gasification （UCG）, whereby coal is converted to syngas in situ, a cavity is formed in the coal seam. The cavity growth rate （CGR） or the moving rate of the gasification face is affected by controllable （operation pressure, gasification time, geometry of UCG panel） and uncontrollable （coal seam properties） factors. The CGR is usually predicted by mathematical models and laboratory experiments, which are time consuming, cumbersome and expensive. In this paper, a new simple model for CGR is developed using non-linear regression analysis, based on data from 1 l UCG field trials. The empirical model compares satisfactorily with Perkins model and can reliably predict CGR.

Coalbed methane desorption characteristics controlled by coalification and its implication on gas co-production from multiple coal seams

In this work,CH4 isothermal adsorption measurements were carried out on 64 coal samples collected from western Guizhou Province of China,and the coalbed methane(CBM)desorption processes were quantitatively analyzed.The results show that the Langmuir volume and the Langmuir pressure are controlled by coalification,and tend to increase as the vitrinite reflectance changes from 0.98% to 4.3%.Based on a division method of CBM desorption stages,the CBM desorption process were divided into four stages(inefficient,slow,fast and sensitive desorption stages)by three key pressure nodes(the initial,turning and sensitive pressures).The fast and sensitive desorption stages with high desorption efficiency are the key for achieving high gas production.A theoretical chart of the critical desorption pressure(P_(cd))and its relationship with different pressure nodes was established.The higher-rank coals have the higher initial,turning and sensitive pressures,with larger difference between pressure nodes.Most CBM wells only undergo partial desorption stages due to the differences in P_(cd) caused by the present-gas content.Under the same gas content conditions,the higher the coal rank,the less desorption stages that CBM needs to go through.During coalbed methane co-production from multiple coal seams within vertically superposed pressure systems,the reservoir pressure,the P_(cd),the initial working liquid level(WLL)height,and coal depth are key factors for evaluating whether coal seams can produce CBM simultaneously.It must be ensured that each production layer enters at least the fast desorption stage prior to that the WLL was lower than the depth of each layer.Only on this basis can all layers achieve the maximum gas production.

多煤层重复采动回采巷道失稳机理与控制技术

戊9-10-22290工作面为平煤六矿三水平二采区的孤岛工作面,风巷外段在采掘服务期间将会受到上覆戊8及下伏五矿己组回采影响,采掘时空关系异常复杂。目的为探讨多煤层重复采动回采巷道失稳机理与控制技术,方法基于采掘工作面应力时-空演化关系,提出平煤六矿戊9-10-22290工作面风巷外段全生命周期内的围岩控制方法,并进行现场工程应用。结果结果表明:上覆近距离煤层开采后,巷道顶板出现拉剪破坏;本煤层和下伏煤层回采过程中,巷道将逐段受到超前支承压力作用;根据巷道围岩所处的扰动时-空过程和高应力环境,提出“高预应力高强锚杆+锚索+深孔爆破卸压”的抗压-让压-卸压相结合的综合围岩控制技术。现场工业性试验表明,巷道服务期间两帮最大变形量为347 mm,顶板下沉和底板鼓起均在可控范围内,能够满足矿井安全生产需求,取得较好的技术和经济效益,结论研究结果可为类似条件下的回采巷道围岩控制提供参考。

近距离“薄-中-厚”交错分布煤层群上行协调开采定量判别研究

开滦矿区开平煤田煤系地层80 m范围内交错分布“薄-中-厚”5层可采煤层,该类煤层群的安全高效回收需要上行与下行相协调的开采模式,关键难题在于如何判断在多层采空区下煤层上行开采的可行性。本文以开滦矿区多年上行开采经验为研究背景,采用理论分析、数据统计和现场实测等方法,对开滦矿区近距离煤层上行开采的扰动破坏影响进行研究。基于上行开采的采动影响系数与间深比判别法,结合煤层群开采层间扰动影响、煤系地层分布、岩层物理力学性质、覆岩破断特征等多因素,提出上行开采综合性判别指标,建立上行协调开采的“可行度”定量判别式与评价体系;通过统计分析30个上行开采案例,提出上行开采可行度的区域划分方法;应用钻孔窥视与地质雷达探测技术实测了覆岩裂隙发育程度及破碎情况。结果表明:12-1号煤层的垮落带范围为15.4~21.2 m,观测段内岩层整体下沉量为0.1~0.4 m,验证了钱家营矿1692工作面上行开采方案的合理性;计算分析了范各庄矿全井田66个钻孔上行开采可行度,预测出井田范围内存在的危险区域,有效指导范各庄矿12号煤层→9号煤层上行开采可行性的问题。同时,通过对“可行度”判别式的研究,给出了开滦矿区近距离煤层、极近距离煤层及煤层群的判别依据。该方法在开滦矿区现场工程实践中成效显著,为安全高效开采近距离煤层群资源提供新的理论依据。

自动固相微萃取(SPM E)GC-MS、GC-MS-MS法检测环境水中有机磷杀虫剂的研究

固相微萃取(solid-phase microextraction,SPME)是20世纪90年代发展起来的一种样品前处理技术,与传统的液-液提取、液-固提取相比,SPME更适用于提取、浓缩液态或气态的挥发性和半挥发性物质,SPME技术可将采样、萃取、浓缩和样本引入集中于一个步骤完成,尤其随着自动SPME与GC-MS等联用技术的日益完善,使SPME技术优点得到更充分的发挥.……

西部矿区多煤层采动地表沉陷无人机观测方法研究

西部矿区煤矿开采具有浅埋深、薄基岩、多煤层开采、地表环境脆弱等特点,为化解开采地表沉陷传统观测方法覆盖范围小、作业强度高、自动化程度低等难题,引入无人机(Unmanned Aerial Vehicle, UAV)摄影测量技术观测并分析某煤矿工作面地表沉陷规律。结果表明:UAV摄影测量观测开采沉陷的中误差为4.4 cm,满足地表沉陷整体观测需求;获取的2.53 km^(2)测区范围内地表整体沉陷模型可准确反映矿区地表沉陷区域及沉陷幅度;受多煤层开采影响地表沉陷模型呈不均匀盆状,沿工作面走向、倾向沉陷曲线均呈现不对称现象,最大沉陷值3.18 m。