Arson presents a challenging crime scene for fire investigators worldwide. Key to the investigation of suspected arson cases is the analysis of fire debris for the presence of accelerants or ignitable liquids. This st...Arson presents a challenging crime scene for fire investigators worldwide. Key to the investigation of suspected arson cases is the analysis of fire debris for the presence of accelerants or ignitable liquids. This study has investigated the application and method development of vapor phase mid-Infrared (mid-IR) spectroscopy using a field portable quantum cascade laser (QCL) based system for the detection and identification of accelerant residues such as gasoline, diesel, and ethanol in fire debris. A searchable spectral library of various ignitable fluids and fuel components measured in the vapor phase was constructed that allowed for real-time identification of accelerants present in samples using software developed in-house. Measurement of vapors collected from paper material that had been doused with an accelerant followed by controlled burning and then extinguished with water showed that positive identification could be achieved for gasoline, diesel, and ethanol. This vapor phase mid-IR QCL method is rapid, easy to use, and has the sensitivity and discrimination capability that make it well suited for non-destructive crime scene sample analysis. Sampling and measurement can be performed in minutes with this 7.5 kg instrument. This vibrational spectroscopic method required no time-consuming sample pretreatment or complicated solvent extraction procedure. The results of this initial feasibility study demonstrate that this portable fire debris analyzer would greatly benefit arson investigators performing analysis on-site.展开更多
We report on the design and fabrication of λ-7.2μm distributed feedback quantum cascade lasers lot very high temperature cw operation and low electrical power consumption. The cw operation is reported above 90℃. Fo...We report on the design and fabrication of λ-7.2μm distributed feedback quantum cascade lasers lot very high temperature cw operation and low electrical power consumption. The cw operation is reported above 90℃. For a 2-mm-long and 10-μm-wide laser coated with high-reflectivity on the rear facet, more than 170mW of output power is obtained at 20℃ with a threshold power consumption of 2.4 W, corresponding to 30mW with a threshold power consumption of 3.9 W at 90℃. Robust single-mode emission with a side-mode suppression ratio above 25 dB is continuously tunable by the heat sink temperature or injection current.展开更多
We report an external cavity quantum cascade laser (EC-QCL) operating near 6.9μm using the Littman Metcalf configuration. The EC-QCL works in a pulsed mode and can be tuned continuously from 1340 to 1640cm^-1 by on...We report an external cavity quantum cascade laser (EC-QCL) operating near 6.9μm using the Littman Metcalf configuration. The EC-QCL works in a pulsed mode and can be tuned continuously from 1340 to 1640cm^-1 by only tilting the tuning mirror. The fine tuning ability of the EC-QCL is demonstrated by measuring the absorption spectrum of water in the ambient air with a lock-in amplifier.展开更多
A multimode interference(MMI)structure is designed to simplify the fabrication of quantum cascade laser(QCL)phase-locked arrays.The MMI geometry is optimized with a sufficient output channel distance to accommodate co...A multimode interference(MMI)structure is designed to simplify the fabrication of quantum cascade laser(QCL)phase-locked arrays.The MMI geometry is optimized with a sufficient output channel distance to accommodate conventional photolithography and wet etching process by which power amplifier array is fabricated without using the complicated two-step etching-regrowth or dry etching technique.The far-field pattern with periodically modulated peaks reveals that the beams from the arrays are phase-locked.Furthermore,the frequency tuning performance of the MMI-based phase-locked arrays is studied using the Littrow-configuration external cavity structure.A wavelength tuning range of more than 60 cm^(−1) is demonstrated,which will eventually realize the high power,frequency tunable,large-scale phase-locked arrays,and their application in spectroscopy.展开更多
<div style="text-align:justify;"> In this paper, we report a single-mode Fabry-Pérot long wave infrared quantum cascade lasers based on the double phonon resonance active region design. For room t...<div style="text-align:justify;"> In this paper, we report a single-mode Fabry-Pérot long wave infrared quantum cascade lasers based on the double phonon resonance active region design. For room temperature CW operation, the wafer with 35 stages was processed into buried heterostructure lasers. For a 4 mm long and 13 μm wide laser with high-reflectivity (HR) coating on the rear facet, continuous wave output power of 43 mW at 288 K and 5 mW at 303 K is obtained with threshold current densities of 2.17 and 2.7 kA/cm2. The lasing wavelength is around 10.5 μm. Single mode emission was observed for this particular device over the whole investigated current and temperature range. </div>展开更多
The pulse generation from active mode-locking terahertz quantum cascade laser is studied by Maxwell-Bloch equations.It is shown that longer dephasing time will lead to multiple pulses generation from the laser.The dep...The pulse generation from active mode-locking terahertz quantum cascade laser is studied by Maxwell-Bloch equations.It is shown that longer dephasing time will lead to multiple pulses generation from the laser.The dependence of output field on modulation length and radio-frequency parameters is obtained.In order to achieve short pulse generation,the DC bias should close to threshold value and modulation length should be shorter than 0.256 mm.The output pulse is unstable and the envelope shows many oscillations in the presence of spatial hole burning,resulting destabilization of mode-locking.展开更多
In this paper, we report a single-mode Fabry-Pérot long wave infrared quantum cascade lasers based on the double phonon resonance active region design. For room temperature CW operation, the wafer with 35 stages ...In this paper, we report a single-mode Fabry-Pérot long wave infrared quantum cascade lasers based on the double phonon resonance active region design. For room temperature CW operation, the wafer with 35 stages was processed into buried heterostructure lasers. For a 4 mm long and 13 μm wide laser with high-reflectivity (HR) coating on the rear facet, continuous wave output power of 43 mW at 288 K and 5 mW at 303 K is obtained with threshold current densities of 2.17 and 2.7 kA/cm2. The lasing wavelength is around 10.5 μm. Single mode emission was observed for this particular device over the whole investigated current and temperature range.展开更多
For non-invasive measurement of blood glucose levels, a measurement system based on mid-infrared, attenuated-total-reflection spectroscopy equipped with hollow optical fibers, a trapezoidal multi-reflection prism, and...For non-invasive measurement of blood glucose levels, a measurement system based on mid-infrared, attenuated-total-reflection spectroscopy equipped with hollow optical fibers, a trapezoidal multi-reflection prism, and two fixed-wavelength quantum cascade lasers emitting different wavelengths is proposed. From the absorption spectra of lip mucosa measured by Fourier-transform infrared spectrometry, two wavelengths, 1152 cm-1 for absorption by glucose and 1186 cm-1 for the background, were chosen. To reduce measurement errors, the power distribution on the prism surface was investigated, and it was found that some high-intensity spots appear on the prism surface due to the coherency of the laser beam. This inhomogeneous power distribution causes measurement errors for slight movements of the lip mucosa. To homogenize the intensity distribution on the prism, a lens to excite higher modes in the fiber was introduced, and the incident angle was changed to suppress interference due to back-reflected light. These improvements increased the measurement stability, and in-vivo experiments demonstrated that the measured optical absorption correlates well with blood glucose levels.展开更多
An external cavity quantum cascade laser (QCL) array with a wide tuning range and high output power is pre- sented. The coherent QCL array combined with a diffraction grating and gold mirror is tuned in the Littrow ...An external cavity quantum cascade laser (QCL) array with a wide tuning range and high output power is pre- sented. The coherent QCL array combined with a diffraction grating and gold mirror is tuned in the Littrow configuration. Taking advantage of the single-lobed fundamental supermode far-field pattern, the tuning capa- bility of 30.6cm-1 is achieved with a fixed injected current of 3.5 A at room temperature. Single-mode emission can be observed in the entire process. The maximum single-mode output power of the external cavity setup is as high as 25mW and is essential in real applications.展开更多
We report on the room-temperature cascade laser (QCL) at λ -4.7μm. cw operation of a surface grating Both grating design and material distributed feedback (DFB) quantum optimization are used to decrease the thre...We report on the room-temperature cascade laser (QCL) at λ -4.7μm. cw operation of a surface grating Both grating design and material distributed feedback (DFB) quantum optimization are used to decrease the threshold current density and to increase the output power. For a high-reflectivity-coated 13-μm-wide and 4- mm-long laser, high wall-plug efficiency of 6% is obtained at 20℃ from a single facet producing over I W of ew output power. The threshold current density of DFB QCL is as low as 1.13kA/cm^2 at 10℃ and 1.34kA/cm2 at 30℃ in cw mode. Stable single-mode emission with a side-mode suppression ratio of about 30 dB is observed in tile working temperature range of 20-50℃.展开更多
A quantum cascade laser(QCL) based system for simultaneous detection of CO and CO_2 is developed.The QCL can scan over two neighboring CO(2055.40 cm^(-1)) and CO_2(2055.16 cm^(-1)) lines with a single curren...A quantum cascade laser(QCL) based system for simultaneous detection of CO and CO_2 is developed.The QCL can scan over two neighboring CO(2055.40 cm^(-1)) and CO_2(2055.16 cm^(-1)) lines with a single current scan.The wavelength modulation spectroscopy( f = 20 k Hz) is utilized to enhance the signal-to-noise ratio.A white cell with an effective optical path length of 74 m is used.The calibration of the sensor is performed and minimum detection limits of 1.3 ppb(1 × 10^(-9))for CO and 0.44 ppm(1 × 10^(-6)) for CO_2 are achieved.展开更多
We report a type-Ⅱ GaSb-based interband cascade laser operating a continuous wave at room temperature. The cascade region of interband cascade laser was designed using the ‘W’ configuration of the active quantum we...We report a type-Ⅱ GaSb-based interband cascade laser operating a continuous wave at room temperature. The cascade region of interband cascade laser was designed using the ‘W’ configuration of the active quantum wells and the ‘Carrier Rebalancing’ method in the electron injector. The devices were processed into narrow ridges and mounted epitaxial side down on a copper heat sink. The 25-μm-wide, 3-mm-long ridge without coated facets generated 41.4 mW of continuous wave output power at T = 15℃. And a low threshold current density of 267 A/cm;is achieved. The emission wavelength of the ICL is 3452.3 nm at 0.5 A.展开更多
This paper reviews the basic properties of the SiGe alloy, presents some new results on its electronic and optical properties, and discusses the approach that has been followed to model quantum wells containing SiGe l...This paper reviews the basic properties of the SiGe alloy, presents some new results on its electronic and optical properties, and discusses the approach that has been followed to model quantum wells containing SiGe layers for applications in quantum cascade lasers. The shape of the confining potential, the subband energies and their eigen envelope wave functions are calculated by solving a one-dimensional Schr?dinger equation. The calculations of optical parameters are used to optimize the Si/SiGe quantum cascade structures. Our results are found to be in good agreement with other calculations.展开更多
A compact prototype based on mid-infrared wavelength modulation spectroscopy(WMS)is developed for the simul-taneous monitoring of NO,NO2,and NH3 in the urban area.Three quantum cascade lasers(QCLs)with central fre...A compact prototype based on mid-infrared wavelength modulation spectroscopy(WMS)is developed for the simul-taneous monitoring of NO,NO2,and NH3 in the urban area.Three quantum cascade lasers(QCLs)with central frequencies around 1900.0 cm^-1,1600.0 cm^-1,and 1103.4 cm^-1are used for NO,NO2,and NH3detections,respectively,by timedivision multiplex.An open-path multi-pass cell of 60-m optical path length is applied to the instrument for high sensitivity and reducing the response time to less than 1 s.The prototype achieves a sub-ppb detection limit for all the three target gases with an average time of about 100 s.The instrument is installed in the Jiangsu environmental monitoring center to conduct performance tests on ambient air.Continuous 24-hour measurements show good agreement with the results of a reference instrument based on the chemiluminescence technique.展开更多
文摘Arson presents a challenging crime scene for fire investigators worldwide. Key to the investigation of suspected arson cases is the analysis of fire debris for the presence of accelerants or ignitable liquids. This study has investigated the application and method development of vapor phase mid-Infrared (mid-IR) spectroscopy using a field portable quantum cascade laser (QCL) based system for the detection and identification of accelerant residues such as gasoline, diesel, and ethanol in fire debris. A searchable spectral library of various ignitable fluids and fuel components measured in the vapor phase was constructed that allowed for real-time identification of accelerants present in samples using software developed in-house. Measurement of vapors collected from paper material that had been doused with an accelerant followed by controlled burning and then extinguished with water showed that positive identification could be achieved for gasoline, diesel, and ethanol. This vapor phase mid-IR QCL method is rapid, easy to use, and has the sensitivity and discrimination capability that make it well suited for non-destructive crime scene sample analysis. Sampling and measurement can be performed in minutes with this 7.5 kg instrument. This vibrational spectroscopic method required no time-consuming sample pretreatment or complicated solvent extraction procedure. The results of this initial feasibility study demonstrate that this portable fire debris analyzer would greatly benefit arson investigators performing analysis on-site.
基金Supported by the National Basic Research Program of China under Grant No 2013CB632801the National Key Research and Development Program under Grant No 2016YFB0402303+2 种基金the National Natural Science Foundation of China under Grant Nos61435014,61627822,61574136 and 61306058the Key Projects of Chinese Academy of Sciences under Grant No ZDRW-XH-2016-4the Beijing Natural Science Foundation under Grant No 4162060
文摘We report on the design and fabrication of λ-7.2μm distributed feedback quantum cascade lasers lot very high temperature cw operation and low electrical power consumption. The cw operation is reported above 90℃. For a 2-mm-long and 10-μm-wide laser coated with high-reflectivity on the rear facet, more than 170mW of output power is obtained at 20℃ with a threshold power consumption of 2.4 W, corresponding to 30mW with a threshold power consumption of 3.9 W at 90℃. Robust single-mode emission with a side-mode suppression ratio above 25 dB is continuously tunable by the heat sink temperature or injection current.
基金Supported by the National Natural Science Foundation of China under Grant Nos 11174098 and 11574107the SelfDetermined Research Funds of Central China Normal University under Grant No CCNU15A02034
文摘We report an external cavity quantum cascade laser (EC-QCL) operating near 6.9μm using the Littman Metcalf configuration. The EC-QCL works in a pulsed mode and can be tuned continuously from 1340 to 1640cm^-1 by only tilting the tuning mirror. The fine tuning ability of the EC-QCL is demonstrated by measuring the absorption spectrum of water in the ambient air with a lock-in amplifier.
基金supported by the National Basic Research Program of China(Grant Nos.2018YFA0209103 and 2018YFB2200504)the National Natural Science Foundation of China(Grant Nos.61991430,61774146,61790583,61674144,61774150,and 61805168)+1 种基金the Beijing Municipal Science&Technology Commission,China(Grant No.Z201100004020006)the Key Projects of the Chinese Academy of Sciences(Grant Nos.2018147,YJKYYQ20190002,QYZDJ-SSW-JSC027,and XDB43000000).
文摘A multimode interference(MMI)structure is designed to simplify the fabrication of quantum cascade laser(QCL)phase-locked arrays.The MMI geometry is optimized with a sufficient output channel distance to accommodate conventional photolithography and wet etching process by which power amplifier array is fabricated without using the complicated two-step etching-regrowth or dry etching technique.The far-field pattern with periodically modulated peaks reveals that the beams from the arrays are phase-locked.Furthermore,the frequency tuning performance of the MMI-based phase-locked arrays is studied using the Littrow-configuration external cavity structure.A wavelength tuning range of more than 60 cm^(−1) is demonstrated,which will eventually realize the high power,frequency tunable,large-scale phase-locked arrays,and their application in spectroscopy.
文摘<div style="text-align:justify;"> In this paper, we report a single-mode Fabry-Pérot long wave infrared quantum cascade lasers based on the double phonon resonance active region design. For room temperature CW operation, the wafer with 35 stages was processed into buried heterostructure lasers. For a 4 mm long and 13 μm wide laser with high-reflectivity (HR) coating on the rear facet, continuous wave output power of 43 mW at 288 K and 5 mW at 303 K is obtained with threshold current densities of 2.17 and 2.7 kA/cm2. The lasing wavelength is around 10.5 μm. Single mode emission was observed for this particular device over the whole investigated current and temperature range. </div>
基金Project supported by the National Key Research and Development Program of China(Grant No.2017YFF0106302)the National Natural Science Foundation of China(Grant Nos.61975225 and 61927813)Shanghai International Cooperation Project,China(Grant No.18590780100).
文摘The pulse generation from active mode-locking terahertz quantum cascade laser is studied by Maxwell-Bloch equations.It is shown that longer dephasing time will lead to multiple pulses generation from the laser.The dependence of output field on modulation length and radio-frequency parameters is obtained.In order to achieve short pulse generation,the DC bias should close to threshold value and modulation length should be shorter than 0.256 mm.The output pulse is unstable and the envelope shows many oscillations in the presence of spatial hole burning,resulting destabilization of mode-locking.
文摘In this paper, we report a single-mode Fabry-Pérot long wave infrared quantum cascade lasers based on the double phonon resonance active region design. For room temperature CW operation, the wafer with 35 stages was processed into buried heterostructure lasers. For a 4 mm long and 13 μm wide laser with high-reflectivity (HR) coating on the rear facet, continuous wave output power of 43 mW at 288 K and 5 mW at 303 K is obtained with threshold current densities of 2.17 and 2.7 kA/cm2. The lasing wavelength is around 10.5 μm. Single mode emission was observed for this particular device over the whole investigated current and temperature range.
文摘For non-invasive measurement of blood glucose levels, a measurement system based on mid-infrared, attenuated-total-reflection spectroscopy equipped with hollow optical fibers, a trapezoidal multi-reflection prism, and two fixed-wavelength quantum cascade lasers emitting different wavelengths is proposed. From the absorption spectra of lip mucosa measured by Fourier-transform infrared spectrometry, two wavelengths, 1152 cm-1 for absorption by glucose and 1186 cm-1 for the background, were chosen. To reduce measurement errors, the power distribution on the prism surface was investigated, and it was found that some high-intensity spots appear on the prism surface due to the coherency of the laser beam. This inhomogeneous power distribution causes measurement errors for slight movements of the lip mucosa. To homogenize the intensity distribution on the prism, a lens to excite higher modes in the fiber was introduced, and the incident angle was changed to suppress interference due to back-reflected light. These improvements increased the measurement stability, and in-vivo experiments demonstrated that the measured optical absorption correlates well with blood glucose levels.
基金Supported by the National Basic Research Program of China under Grant No 2013CB632801the National Key Research and Development Program of China under Grant No 2016YFB0402303+2 种基金the National Natural Science Foundation of China under Grant Nos 61435014,61627822,61574136,61306058 and 61404131the Key Projects of Chinese Academy of Sciences under Grant No ZDRW-XH-2016-4the Beijing Natural Science Foundation under Grant No 4162060
文摘An external cavity quantum cascade laser (QCL) array with a wide tuning range and high output power is pre- sented. The coherent QCL array combined with a diffraction grating and gold mirror is tuned in the Littrow configuration. Taking advantage of the single-lobed fundamental supermode far-field pattern, the tuning capa- bility of 30.6cm-1 is achieved with a fixed injected current of 3.5 A at room temperature. Single-mode emission can be observed in the entire process. The maximum single-mode output power of the external cavity setup is as high as 25mW and is essential in real applications.
基金Supported by the National Basic Research Program of China under Grant Nos 2013CB632801 and 2013CB632803the National Natural Science Foundation of China under Grant Nos 61435014,61306058 and 61274094the Beijing Natural Science Foundation under Grant No 4144086
文摘We report on the room-temperature cascade laser (QCL) at λ -4.7μm. cw operation of a surface grating Both grating design and material distributed feedback (DFB) quantum optimization are used to decrease the threshold current density and to increase the output power. For a high-reflectivity-coated 13-μm-wide and 4- mm-long laser, high wall-plug efficiency of 6% is obtained at 20℃ from a single facet producing over I W of ew output power. The threshold current density of DFB QCL is as low as 1.13kA/cm^2 at 10℃ and 1.34kA/cm2 at 30℃ in cw mode. Stable single-mode emission with a side-mode suppression ratio of about 30 dB is observed in tile working temperature range of 20-50℃.
基金Project supported by the National Key Scientific Instrument and Equipment Development Project of China(Grnat No.2014YQ060537)the National Basic Research Program of China(Grant No.2013CB632803)+1 种基金the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant No.XDA05040102)the National Natural Science Foundation of China(Grant No.41405134)
文摘A quantum cascade laser(QCL) based system for simultaneous detection of CO and CO_2 is developed.The QCL can scan over two neighboring CO(2055.40 cm^(-1)) and CO_2(2055.16 cm^(-1)) lines with a single current scan.The wavelength modulation spectroscopy( f = 20 k Hz) is utilized to enhance the signal-to-noise ratio.A white cell with an effective optical path length of 74 m is used.The calibration of the sensor is performed and minimum detection limits of 1.3 ppb(1 × 10^(-9))for CO and 0.44 ppm(1 × 10^(-6)) for CO_2 are achieved.
基金Project supported by the Major Program of the National Natural Science Foundation of China(Grant No.61790580)the National Natural Science Foundation of China(Grant No.61435012)the National Basic Research Program of China(Grant No.2014CB643903)
文摘We report a type-Ⅱ GaSb-based interband cascade laser operating a continuous wave at room temperature. The cascade region of interband cascade laser was designed using the ‘W’ configuration of the active quantum wells and the ‘Carrier Rebalancing’ method in the electron injector. The devices were processed into narrow ridges and mounted epitaxial side down on a copper heat sink. The 25-μm-wide, 3-mm-long ridge without coated facets generated 41.4 mW of continuous wave output power at T = 15℃. And a low threshold current density of 267 A/cm;is achieved. The emission wavelength of the ICL is 3452.3 nm at 0.5 A.
文摘This paper reviews the basic properties of the SiGe alloy, presents some new results on its electronic and optical properties, and discusses the approach that has been followed to model quantum wells containing SiGe layers for applications in quantum cascade lasers. The shape of the confining potential, the subband energies and their eigen envelope wave functions are calculated by solving a one-dimensional Schr?dinger equation. The calculations of optical parameters are used to optimize the Si/SiGe quantum cascade structures. Our results are found to be in good agreement with other calculations.
基金Project supported by the National Key Scientific Instrument and Equipment Development,China(Grant No.2014YQ060537)the National Key Research and Development Program,China(Grant No.2016YFC0201103)
文摘A compact prototype based on mid-infrared wavelength modulation spectroscopy(WMS)is developed for the simul-taneous monitoring of NO,NO2,and NH3 in the urban area.Three quantum cascade lasers(QCLs)with central frequencies around 1900.0 cm^-1,1600.0 cm^-1,and 1103.4 cm^-1are used for NO,NO2,and NH3detections,respectively,by timedivision multiplex.An open-path multi-pass cell of 60-m optical path length is applied to the instrument for high sensitivity and reducing the response time to less than 1 s.The prototype achieves a sub-ppb detection limit for all the three target gases with an average time of about 100 s.The instrument is installed in the Jiangsu environmental monitoring center to conduct performance tests on ambient air.Continuous 24-hour measurements show good agreement with the results of a reference instrument based on the chemiluminescence technique.