We perform a kinetically complete measurement on the fragmentation of Coulomb explosion of 1-120 molecules in intense few-cycle linearly and circularly polarized laser fields. Both the fragmentations of 1t203+ and H...We perform a kinetically complete measurement on the fragmentation of Coulomb explosion of 1-120 molecules in intense few-cycle linearly and circularly polarized laser fields. Both the fragmentations of 1t203+ and H204+ reveal the concerted pathway of dissociation. The length of the OH bond prior to the Coulomb explosion of both molecular ions is sensitive to the laser pulse duration and laser intensity. However, the bending angle of H-O-H is less sensitive to the pulse duration and laser intensity. We introduce the mechanism of charge resonance enhanced double ionization to elucidate the triple (or quadruple) dissociative ionization dynamics of H20, in which two electrons are non-adiabatically localized at the protons of the precursor ion H2O^+ (or H2O^2+) and are released simultaneously due to the over barrier ionization in the combined laser field and molecular ionic potential. Such charge resonance enhanced multiple ionization is not suppressed in few-cycle laser fields and elliptically polarized laser fields.展开更多
As technologies scale down in size, multiple-transistors being affected by a single ion has become a universal phenomenon, and some new effects are present in single event transients (SETs) due to the charge sharing...As technologies scale down in size, multiple-transistors being affected by a single ion has become a universal phenomenon, and some new effects are present in single event transients (SETs) due to the charge sharing collection of the adjacent multiple-transistors. In this paper, not only the off-state p-channel metal–oxide semiconductor field-effect transistor (PMOS FET), but also the on-state PMOS is struck by a heavy-ion in the two-transistor inverter chain, due to the charge sharing collection and the electrical interaction. The SET induced by striking the off-state PMOS is efficiently mitigated by the pulse quenching effect, but the SET induced by striking the on-state PMOS becomes dominant. It is indicated in this study that in the advanced technologies, the SET will no longer just be induced by an ion striking the off-state transistor, and the SET sensitive region will no longer just surround the off-state transistor either, as it is in the older technologies. We also discuss this issue in a three-transistor inverter in depth, and the study illustrates that the three-transistor inverter is still a better replacement for spaceborne integrated circuit design in advanced technologies.展开更多
We study the problem of multiple node upset (MNU) using three-dimensional device simulation. The results show the transient floating node and charge lateral diffusion are the key reasons for MNU. We compare the MNU ...We study the problem of multiple node upset (MNU) using three-dimensional device simulation. The results show the transient floating node and charge lateral diffusion are the key reasons for MNU. We compare the MNU with multiple bit upset (MBU),and find that their characteristics are different. Methods to avoid MNU are also discussed.展开更多
The propagation of vortex beam in atmospheric turbulence is of significant importance in theoretical study and practical applications. Based on extended Huygens-Fresnel integral and the Rytov approximation, the averag...The propagation of vortex beam in atmospheric turbulence is of significant importance in theoretical study and practical applications. Based on extended Huygens-Fresnel integral and the Rytov approximation, the average capacity of orbital angular momentum(OAM)-multiplexed Laguerre-Gaussian(LG) beam propagating through non-Kolmogorov turbulence is presented, and the analytical expression of spiral spectrum of LG beam has been deduced. The average capacity of FSO system is numerically calculated and the influence of exponent parameter, transmission height, structure constant, wavelength, outer scale and inner scale on average capacity are also analyzed in detail. Outcomes show that smaller structure constant, outer scale, higher transmission height and larger wavelength, inner scale are conducive to improve average capacity in different extent. Results acquires in this paper have potential application value in optical communication within non-Kolmogorov turbulence.展开更多
The driving voltage of an organic light-emitting diode(OLED) is lowered by employing molybdenum trioxide(MoO3)/N,N'-bis(naphthalene-1-yl)-N,N'-bis(phe-nyl)-benzidine(NPB) multiple quantum well(MQW) struc...The driving voltage of an organic light-emitting diode(OLED) is lowered by employing molybdenum trioxide(MoO3)/N,N'-bis(naphthalene-1-yl)-N,N'-bis(phe-nyl)-benzidine(NPB) multiple quantum well(MQW) structure in the hole transport layer.For the device with double quantum well(DQW) structure of ITO/[MoO3(2.5 nm)/NPB(20 nm)]2/Alq3(50 nm)/LiF(0.8 nm)/Al(120 nm)],the turn-on voltage is reduced to 2.8 V,which is lowered by 0.4 V compared with that of the control device(without MQW structures),and the driving voltage is 5.6 V,which is reduced by 1 V compared with that of the control device at the 1000 cd/m2.In this work,the enhancement of the injection and transport ability for holes could reduce the driving voltage for the device with MQW structure,which is attributed not only to the reduced energy barrier between ITO and NPB,but also to the forming charge transfer complex between MoO3 and NPB induced by the interfacial doping effect of MoO3.展开更多
As a kind of special acoustic field, the helical wavefront of an acoustic vortex(AV) beam is demonstrated to have a pressure zero with phase singularity at the center in the transverse plane. The orbital angular mom...As a kind of special acoustic field, the helical wavefront of an acoustic vortex(AV) beam is demonstrated to have a pressure zero with phase singularity at the center in the transverse plane. The orbital angular momentum of AVs can be applied to the field of particle manipulation, which attracts more and more attention in acoustic researches. In this paper,by using the simplified circular array of point sources, dual coaxial AV beams are excited by the even-and odd-numbered sources with the topological charges of l_E and l_O based on the phase-coded approach, and the composite acoustic field with an on-axis center-AV and multiple off-axis sub-AVs can be generated by the superimposition of the AV beams for|l_E| ≠ |l_O|. The generation of edge phase dislocation is theoretically derived and numerically analyzed for l_E=-l_O. The numbers and the topological charges as well as the locations of the center-AV and sub-AVs are demonstrated, which are proved to be determined by the topological charges of the coaxial AV beams. The proposed approach breaks through the limit of only one on-axis AV with a single topological charge along the beam axis, and also provides the feasibility of off-axis particle trapping with multiple AVs in object manipulation.展开更多
We investigate the impact of heavy ion irradiation on a hypothetical static random access memory (SRAM) device. Influences of the irradiation angle, critical charge, drain-drain spacing, and dimension of device stru...We investigate the impact of heavy ion irradiation on a hypothetical static random access memory (SRAM) device. Influences of the irradiation angle, critical charge, drain-drain spacing, and dimension of device structure on the device sensitivity have been studied. These prediction and simulated results are interpreted with MUFPSA, a Monte Carlo code based on Geant4. The results show that the orientation of ion beams and device with different critical charge exert indis- pensable effects on multiple-bit upsets (MBUs), and that with the decrease in spacing distance between adjacent cells or the dimension of the cells, the device is more susceptible to single event effect, especially to MBUs at oblique incidence.展开更多
The energy and centrality dependencies of charged particle pseudorapidity density in relativistic nuclear collisions were studied using a hadron and string cascade model, JPCIAE. Both the relativistic experimental da...The energy and centrality dependencies of charged particle pseudorapidity density in relativistic nuclear collisions were studied using a hadron and string cascade model, JPCIAE. Both the relativistic experimental data and the PHOBOS and PHENIX Au+Au data at RHIC energy could be fairly reproduced within the framework of JPCIAE model and without retuning the model parameters. The predictions for collisions at the LHC energy were also given. We computed the participant nucleon distributions using different methods. It was found that the number of participant nucleons is not a well defined variable both experimentally and theoretically. Thus it may be inappropriate to use the charged particle pseudorapidity density per participant pair as a function of the number of participant nucleons for distinguishing various theoretical models.展开更多
This paper is concerned with the determination of currents and charges in hypercomplex extensions of the Feynman-Dyson derivation of the Maxwell-Faraday equations. We analyze the appearance of charges and currents in ...This paper is concerned with the determination of currents and charges in hypercomplex extensions of the Feynman-Dyson derivation of the Maxwell-Faraday equations. We analyze the appearance of charges and currents in non-Abelian versions of that approach: SU(2), SU(3) and G2. The structure constants of G2 Lie algebra are computed explicitly. Finally, we suggest a seven-dimensional treatment of color.展开更多
基于荷电状态(state of charge,SOC)控制储能系统参与一次调频时,由于储能系统出力约束条件较为单一,因而限制了储能系统的性能。针对此问题提出一种基于储能系统多重约束的一次调频策略。首先,把通过双层模糊控制方法确定储能系统多时...基于荷电状态(state of charge,SOC)控制储能系统参与一次调频时,由于储能系统出力约束条件较为单一,因而限制了储能系统的性能。针对此问题提出一种基于储能系统多重约束的一次调频策略。首先,把通过双层模糊控制方法确定储能系统多时间尺度调频死区作为第1重约束条件,避免火电机组与储能电池频繁动作。其次,将SOC作为第2重约束条件,约束因子作为第3重约束条件,基于logistic曲线构建惯性与下垂综合控制模型,约束储能系统出力。最后,通过高精度SOC构建快速均衡函数,缩短SOC均衡时间。通过搭建仿真模型分别在阶跃负荷扰动和连续负荷扰动的工况下验证所提控制策略有效性。展开更多
光电化学(PEC)分解水是一种清洁可持续的获取氢燃料的方法,其中产氧半反应(OER)是制约整个水分解过程效率的关键步骤.因此,光阳极的性能是决定太阳能到氢能转化效率的关键因素.在各种水氧化光阳极材料中,赤铁矿(α-Fe_(2)O_(3))因具有...光电化学(PEC)分解水是一种清洁可持续的获取氢燃料的方法,其中产氧半反应(OER)是制约整个水分解过程效率的关键步骤.因此,光阳极的性能是决定太阳能到氢能转化效率的关键因素.在各种水氧化光阳极材料中,赤铁矿(α-Fe_(2)O_(3))因具有良好的化学稳定性、合适的带隙(~2.1 eV)、无毒、储量丰富等优点而成为最有前途的光阳极材料之一.然而,α-Fe_(2)O_(3)丰富的受体表面态和缓慢的水氧化动力学导致光生电荷复合严重,限制了其在光电化学中的实际应用.因此,有必要对α-Fe_(2)O_(3)进行表面工程设计以提高水氧化效率.本文提出了一种新方法,以金属有机框架(Ti-MOFs)为模板,在Ti-Fe_(2)O_(3)表面煅烧合成TiO_(2)层,然后将富活性位点的ZIF-67加载在TiO_(2)/Ti-Fe_(2)O_(3)上作为助催化剂,制备出具有较好光电化学性能的ZIF-67/TiO_(2)/Ti-Fe_(2)O_(3)复合光阳极.X射线衍射、高分辨透射电镜、X射线光电子能谱和拉曼光谱等表征结果证实成功合成了ZIF-67/TiO_(2)/Ti-Fe_(2)O_(3).同时,氮气等温吸附脱附曲线和表面接触角测试结果表明,MOFs衍生的TiO_(2)为介孔材料.采用表面光伏技术、光致发光光谱、飞秒-瞬态吸收光谱和电化学阻抗谱分析,研究了光生电荷的分离和复合行为.结果表明,MOFs衍生的TiO_(2)不仅可以作为钝化层有效抑制了表面复合,还作为Ti-Fe_(2)O_(3)的电子阻挡层,显著减少了电子向表面的流失,从而大大提高了Ti-Fe_(2)O_(3)表面和体相的电荷分离效率.进一步的累积电荷量测试、电化学阻抗谱和Bode图分析显示,负载MOFs衍生TiO_(2)后,可以明显促进光生空穴向电解质的注入,其多孔结构也可以增加反应接触面积,这有利于光生电荷在固液界面传输.此外,理论计算结果表明,Ti-Fe_(2)O_(3)水氧化速控步骤的能垒(ΔG=3.38 eV)明显高于TiO_(2)(ΔG=1.67 eV),说明OER更容易在TiO_(2)/Ti-Fe_(2)O_(3)表面发生,这与其光电流密度结果一致.为进一步提高反应活性和加快水氧化动力学,负载助催化剂ZIF-67后,ZIF-67/TiO_(2)/Ti-Fe_(2)O_(3)复合光阳极实现了较好的光电化学性能,其在1.23 V vs.RHE时光电流密度高达4.04 mA cm^(‒2),是Ti-Fe_(2)O_(3)的9.3倍,并且复合光阳极的入射光子电流转换效率和空穴注入效率分别达到93%(390 nm)和91%.综上所述,本研究通过MOFs衍生的TiO_(2)和ZIF-67助催化剂改性α-Fe_(2)O_(3)光阳极,显著提升了其光电化学水氧化性能.其中,MOFs衍生TiO_(2)不仅优化了电荷分离,还促进了光生空穴的注入,从而显著提高其光电化学水氧化性能.本研究为构筑高性能的有机-无机杂化光阳极提供了新思路.展开更多
In this study,a comprehensive analysis of jets and underlying events as a function of charged particle multiplicity in proton-proton(pp)collisions at a center-of-mass energy of √s=7 TeV is conducted.Various Monte Car...In this study,a comprehensive analysis of jets and underlying events as a function of charged particle multiplicity in proton-proton(pp)collisions at a center-of-mass energy of √s=7 TeV is conducted.Various Monte Carlo(MC)event generators,including Pythia8.308,EPOS 1.99,EPOSLHC,EPOS4_(Hydro),and EPOS4_(noHydro),are employed to predict particle production.The predictions from these models are compared with experimental data from the CMS collaboration.The charged particles are categorized into those associated with underlying events and those linked to jets,and the analysis is restricted to charged particles with|η|<2.4 and p_T>0.25 GeV/c.By comparing the MC predictions with CMS data,we find that EPOS4_(Hydro),EPOSLHC,and Pythia8 consistently reproduce the experimental results for all charged particles,underlying events,intrajets,and leading charged particles.For charged jet rates with p_T^(ch.jet)>5 GeV/c,EPOS4_(Hydro)and Pythia8 perform exceptionally well.In the case of charged jet rates with p_T^(ch.jet)→30 GeV/c,EPOSLHC reproduces satisfactorily good results,whereas EPOS4 Hydro exhibits good agreement with the data at higher charged particle multiplicities compared to the other models.This can be attributed to the conversion of energy into flow when"Hydro=on"leading to an increase in multiplicity.The EPOSLHC model describes the data better owing to the new collective flow effects,correlated flow treatment,and parameterization compared to EPOS 1.99.However,the examination of the jet p_T spectrum and normalized charged p_T density reveals that EPOS4_(Hydro),EPOS4_(noHydro),and EPOSLHC exhibit good agreement with the experimental results,whereas Pythia8 and EPOS 1.99 do not perform as well owing to the lack of correlated flow treatment.展开更多
基金Supported by the National Basic Research Program of China under Grant No 2013CB922403the National Natural Science Foundation of China under Grant Nos 11125416,11434002,11121091 and 11134001
文摘We perform a kinetically complete measurement on the fragmentation of Coulomb explosion of 1-120 molecules in intense few-cycle linearly and circularly polarized laser fields. Both the fragmentations of 1t203+ and H204+ reveal the concerted pathway of dissociation. The length of the OH bond prior to the Coulomb explosion of both molecular ions is sensitive to the laser pulse duration and laser intensity. However, the bending angle of H-O-H is less sensitive to the pulse duration and laser intensity. We introduce the mechanism of charge resonance enhanced double ionization to elucidate the triple (or quadruple) dissociative ionization dynamics of H20, in which two electrons are non-adiabatically localized at the protons of the precursor ion H2O^+ (or H2O^2+) and are released simultaneously due to the over barrier ionization in the combined laser field and molecular ionic potential. Such charge resonance enhanced multiple ionization is not suppressed in few-cycle laser fields and elliptically polarized laser fields.
基金Project supported by the Key Program of the National Natural Science Foundation of China (Grant No. 61133007)the National Natural Science Foundation of China (Grant Nos. 61006070 and 61076025)
文摘As technologies scale down in size, multiple-transistors being affected by a single ion has become a universal phenomenon, and some new effects are present in single event transients (SETs) due to the charge sharing collection of the adjacent multiple-transistors. In this paper, not only the off-state p-channel metal–oxide semiconductor field-effect transistor (PMOS FET), but also the on-state PMOS is struck by a heavy-ion in the two-transistor inverter chain, due to the charge sharing collection and the electrical interaction. The SET induced by striking the off-state PMOS is efficiently mitigated by the pulse quenching effect, but the SET induced by striking the on-state PMOS becomes dominant. It is indicated in this study that in the advanced technologies, the SET will no longer just be induced by an ion striking the off-state transistor, and the SET sensitive region will no longer just surround the off-state transistor either, as it is in the older technologies. We also discuss this issue in a three-transistor inverter in depth, and the study illustrates that the three-transistor inverter is still a better replacement for spaceborne integrated circuit design in advanced technologies.
文摘We study the problem of multiple node upset (MNU) using three-dimensional device simulation. The results show the transient floating node and charge lateral diffusion are the key reasons for MNU. We compare the MNU with multiple bit upset (MBU),and find that their characteristics are different. Methods to avoid MNU are also discussed.
基金supported by the National Science Fund for Distinguished Young Scholars of China (Grant No. 61225003)National Natural Science Foundation of China (Grant No. 61101005 and No. 61471051)Beijing Higher Education Young Elite Teacher Project
文摘The propagation of vortex beam in atmospheric turbulence is of significant importance in theoretical study and practical applications. Based on extended Huygens-Fresnel integral and the Rytov approximation, the average capacity of orbital angular momentum(OAM)-multiplexed Laguerre-Gaussian(LG) beam propagating through non-Kolmogorov turbulence is presented, and the analytical expression of spiral spectrum of LG beam has been deduced. The average capacity of FSO system is numerically calculated and the influence of exponent parameter, transmission height, structure constant, wavelength, outer scale and inner scale on average capacity are also analyzed in detail. Outcomes show that smaller structure constant, outer scale, higher transmission height and larger wavelength, inner scale are conducive to improve average capacity in different extent. Results acquires in this paper have potential application value in optical communication within non-Kolmogorov turbulence.
基金Project supported by the National Natural Science Foundation of China (Grant Nos. 60906022 and 60676051)the Natural Science Foundation of Tianjin,China (Grant No. 10JCYBJC01100)+1 种基金the Scientific Developing Foundation of Tianjin Education Commission,China (Grant No. 2011ZD02)the Jiangsu Natural Science Development Foundation for University,China (Grant No. 09KJB140006)
文摘The driving voltage of an organic light-emitting diode(OLED) is lowered by employing molybdenum trioxide(MoO3)/N,N'-bis(naphthalene-1-yl)-N,N'-bis(phe-nyl)-benzidine(NPB) multiple quantum well(MQW) structure in the hole transport layer.For the device with double quantum well(DQW) structure of ITO/[MoO3(2.5 nm)/NPB(20 nm)]2/Alq3(50 nm)/LiF(0.8 nm)/Al(120 nm)],the turn-on voltage is reduced to 2.8 V,which is lowered by 0.4 V compared with that of the control device(without MQW structures),and the driving voltage is 5.6 V,which is reduced by 1 V compared with that of the control device at the 1000 cd/m2.In this work,the enhancement of the injection and transport ability for holes could reduce the driving voltage for the device with MQW structure,which is attributed not only to the reduced energy barrier between ITO and NPB,but also to the forming charge transfer complex between MoO3 and NPB induced by the interfacial doping effect of MoO3.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11474166 and 11604156)the Science and Technology Cooperation Projects of People’s Republic of China–Romania(Grant No.42-23)+2 种基金the Natural Science Foundation of Jiangsu Province,China(Grant No.BK20161013)the Postdoctoral Science Foundation of China(Grant No.2016M591874)the Priority Academic Program Development of Jiangsu Higher Education Institutions,China
文摘As a kind of special acoustic field, the helical wavefront of an acoustic vortex(AV) beam is demonstrated to have a pressure zero with phase singularity at the center in the transverse plane. The orbital angular momentum of AVs can be applied to the field of particle manipulation, which attracts more and more attention in acoustic researches. In this paper,by using the simplified circular array of point sources, dual coaxial AV beams are excited by the even-and odd-numbered sources with the topological charges of l_E and l_O based on the phase-coded approach, and the composite acoustic field with an on-axis center-AV and multiple off-axis sub-AVs can be generated by the superimposition of the AV beams for|l_E| ≠ |l_O|. The generation of edge phase dislocation is theoretically derived and numerically analyzed for l_E=-l_O. The numbers and the topological charges as well as the locations of the center-AV and sub-AVs are demonstrated, which are proved to be determined by the topological charges of the coaxial AV beams. The proposed approach breaks through the limit of only one on-axis AV with a single topological charge along the beam axis, and also provides the feasibility of off-axis particle trapping with multiple AVs in object manipulation.
基金Project supported by the National Natural Science Foundation of China (Grant Nos. 11179003, 10975164, 10805062, and 11005134)
文摘We investigate the impact of heavy ion irradiation on a hypothetical static random access memory (SRAM) device. Influences of the irradiation angle, critical charge, drain-drain spacing, and dimension of device structure on the device sensitivity have been studied. These prediction and simulated results are interpreted with MUFPSA, a Monte Carlo code based on Geant4. The results show that the orientation of ion beams and device with different critical charge exert indis- pensable effects on multiple-bit upsets (MBUs), and that with the decrease in spacing distance between adjacent cells or the dimension of the cells, the device is more susceptible to single event effect, especially to MBUs at oblique incidence.
文摘The energy and centrality dependencies of charged particle pseudorapidity density in relativistic nuclear collisions were studied using a hadron and string cascade model, JPCIAE. Both the relativistic experimental data and the PHOBOS and PHENIX Au+Au data at RHIC energy could be fairly reproduced within the framework of JPCIAE model and without retuning the model parameters. The predictions for collisions at the LHC energy were also given. We computed the participant nucleon distributions using different methods. It was found that the number of participant nucleons is not a well defined variable both experimentally and theoretically. Thus it may be inappropriate to use the charged particle pseudorapidity density per participant pair as a function of the number of participant nucleons for distinguishing various theoretical models.
文摘This paper is concerned with the determination of currents and charges in hypercomplex extensions of the Feynman-Dyson derivation of the Maxwell-Faraday equations. We analyze the appearance of charges and currents in non-Abelian versions of that approach: SU(2), SU(3) and G2. The structure constants of G2 Lie algebra are computed explicitly. Finally, we suggest a seven-dimensional treatment of color.
文摘基于荷电状态(state of charge,SOC)控制储能系统参与一次调频时,由于储能系统出力约束条件较为单一,因而限制了储能系统的性能。针对此问题提出一种基于储能系统多重约束的一次调频策略。首先,把通过双层模糊控制方法确定储能系统多时间尺度调频死区作为第1重约束条件,避免火电机组与储能电池频繁动作。其次,将SOC作为第2重约束条件,约束因子作为第3重约束条件,基于logistic曲线构建惯性与下垂综合控制模型,约束储能系统出力。最后,通过高精度SOC构建快速均衡函数,缩短SOC均衡时间。通过搭建仿真模型分别在阶跃负荷扰动和连续负荷扰动的工况下验证所提控制策略有效性。
文摘光电化学(PEC)分解水是一种清洁可持续的获取氢燃料的方法,其中产氧半反应(OER)是制约整个水分解过程效率的关键步骤.因此,光阳极的性能是决定太阳能到氢能转化效率的关键因素.在各种水氧化光阳极材料中,赤铁矿(α-Fe_(2)O_(3))因具有良好的化学稳定性、合适的带隙(~2.1 eV)、无毒、储量丰富等优点而成为最有前途的光阳极材料之一.然而,α-Fe_(2)O_(3)丰富的受体表面态和缓慢的水氧化动力学导致光生电荷复合严重,限制了其在光电化学中的实际应用.因此,有必要对α-Fe_(2)O_(3)进行表面工程设计以提高水氧化效率.本文提出了一种新方法,以金属有机框架(Ti-MOFs)为模板,在Ti-Fe_(2)O_(3)表面煅烧合成TiO_(2)层,然后将富活性位点的ZIF-67加载在TiO_(2)/Ti-Fe_(2)O_(3)上作为助催化剂,制备出具有较好光电化学性能的ZIF-67/TiO_(2)/Ti-Fe_(2)O_(3)复合光阳极.X射线衍射、高分辨透射电镜、X射线光电子能谱和拉曼光谱等表征结果证实成功合成了ZIF-67/TiO_(2)/Ti-Fe_(2)O_(3).同时,氮气等温吸附脱附曲线和表面接触角测试结果表明,MOFs衍生的TiO_(2)为介孔材料.采用表面光伏技术、光致发光光谱、飞秒-瞬态吸收光谱和电化学阻抗谱分析,研究了光生电荷的分离和复合行为.结果表明,MOFs衍生的TiO_(2)不仅可以作为钝化层有效抑制了表面复合,还作为Ti-Fe_(2)O_(3)的电子阻挡层,显著减少了电子向表面的流失,从而大大提高了Ti-Fe_(2)O_(3)表面和体相的电荷分离效率.进一步的累积电荷量测试、电化学阻抗谱和Bode图分析显示,负载MOFs衍生TiO_(2)后,可以明显促进光生空穴向电解质的注入,其多孔结构也可以增加反应接触面积,这有利于光生电荷在固液界面传输.此外,理论计算结果表明,Ti-Fe_(2)O_(3)水氧化速控步骤的能垒(ΔG=3.38 eV)明显高于TiO_(2)(ΔG=1.67 eV),说明OER更容易在TiO_(2)/Ti-Fe_(2)O_(3)表面发生,这与其光电流密度结果一致.为进一步提高反应活性和加快水氧化动力学,负载助催化剂ZIF-67后,ZIF-67/TiO_(2)/Ti-Fe_(2)O_(3)复合光阳极实现了较好的光电化学性能,其在1.23 V vs.RHE时光电流密度高达4.04 mA cm^(‒2),是Ti-Fe_(2)O_(3)的9.3倍,并且复合光阳极的入射光子电流转换效率和空穴注入效率分别达到93%(390 nm)和91%.综上所述,本研究通过MOFs衍生的TiO_(2)和ZIF-67助催化剂改性α-Fe_(2)O_(3)光阳极,显著提升了其光电化学水氧化性能.其中,MOFs衍生TiO_(2)不仅优化了电荷分离,还促进了光生空穴的注入,从而显著提高其光电化学水氧化性能.本研究为构筑高性能的有机-无机杂化光阳极提供了新思路.
基金Supported by Princess Nourah bint Abdulrahman University Researchers Supporting Project number(PNURSP2024R106)Princess Nourah bint Abdulrahman University,Riyadh,Saudi Arabia。
文摘In this study,a comprehensive analysis of jets and underlying events as a function of charged particle multiplicity in proton-proton(pp)collisions at a center-of-mass energy of √s=7 TeV is conducted.Various Monte Carlo(MC)event generators,including Pythia8.308,EPOS 1.99,EPOSLHC,EPOS4_(Hydro),and EPOS4_(noHydro),are employed to predict particle production.The predictions from these models are compared with experimental data from the CMS collaboration.The charged particles are categorized into those associated with underlying events and those linked to jets,and the analysis is restricted to charged particles with|η|<2.4 and p_T>0.25 GeV/c.By comparing the MC predictions with CMS data,we find that EPOS4_(Hydro),EPOSLHC,and Pythia8 consistently reproduce the experimental results for all charged particles,underlying events,intrajets,and leading charged particles.For charged jet rates with p_T^(ch.jet)>5 GeV/c,EPOS4_(Hydro)and Pythia8 perform exceptionally well.In the case of charged jet rates with p_T^(ch.jet)→30 GeV/c,EPOSLHC reproduces satisfactorily good results,whereas EPOS4 Hydro exhibits good agreement with the data at higher charged particle multiplicities compared to the other models.This can be attributed to the conversion of energy into flow when"Hydro=on"leading to an increase in multiplicity.The EPOSLHC model describes the data better owing to the new collective flow effects,correlated flow treatment,and parameterization compared to EPOS 1.99.However,the examination of the jet p_T spectrum and normalized charged p_T density reveals that EPOS4_(Hydro),EPOS4_(noHydro),and EPOSLHC exhibit good agreement with the experimental results,whereas Pythia8 and EPOS 1.99 do not perform as well owing to the lack of correlated flow treatment.