OPTICAL PHASE CONJUGATION RESPONSE OF PHOTOINDUCED POLYMER FILMS CONTAINING AZOBENZENE MOIETIES WITH CHIRAL GROUP

An optically active monomer containing azobenzene moieties with chiral group (s-2-methyl-butyl), 4-[2-(methacryloyloxy)ethyloxy] -4'-(s-2-methyl-1-butyloxycarbonyl) azobenzene (M1) was synthesized. Polymer (PM1) possessing optical phase conjugated response was obtained by homopolymerization of the optically active monomer (M1) using free radical polymerization. The polymer was very soluble in common solvents and good optical quality films could be easily fabricated by spin coating. The optical phase conjugated responses of the polymer PM1 were measured by degenerate four-wave mixing (DFWM). In comparison with polymer containing no chiral group, it was found from the preliminary measurement of photoisomeric change that optical phase conjugated response of the PM1 in the long-range order hexagonal symmetry microstructure could be easily controlled by choosing the appropriate polarization direction of the irradiating beams (514.5 nm) and the irradiating number, presumably due to the chiral group in the PM1 molecular structure. For the case of the polymer investigated here, a chiral group side chain was introduced to increase optical phase conjugated response intensity with different polarization directions of the irradiating beams, which aims originally at searching for a new photoactive material.

Gas‐phase fluorination of conjugated microporous polymer microspheres for effective interfacial stabilization in lithium metal anodes

Lithium(Li)metal anodes have attracted extensive attention due to their ultrahigh theoretical capacity and low potential.However,the uneven deposition of Li near the unstable electrode/electrolyte interfaces leads to the growth of Li dendrites and the degradation of active electrodes.Herein,we directly fluorinate alkyne-containing conjugated microporous polymers(ACMPs)microspheres with fluorine gas(F_(2))to introduce a novel fluorinated interlayer as an interfacial stabilizer in lithium metal batteries.Using density functional theory methods,it is found that as-prepared fluorinated ACMP(FACMP)has abundant partially ionic C–F bonds.The C–F bonds with electrochemical lability yield remarkable lithiophilicity during cycling.The in situ reactions between the active C–F bonds and Li ions enable transfer of lithium fluoride microcrystals to the solid electrolyte interphase(SEI)layers,guaranteeing effective ionic distribution and smooth Li deposition.Consequently,Li metal electrodes with the fluorinated interlayers demonstrate excellent cycling performances in both half-batteries and full cells with a lithium bis(trifluoromethanesulfonyl)imide electrolyte as well as a nonfluorinated lithium bis(oxalate)borate electrolyte system.This strategy is highly significant in customizable SEI layers to stabilize electrode interfaces and ensure high utilization of Li metal anodes,especially in a nonfluorinated electrolyte.

Theoretical study on phase conjugation in weakly injected vertical-cavity surface-emitting lasers

This paper gives a detailed theoretical investigation on phase conjugation induced by nearly degenerate fourwave mixing in single mode vertical-cavity surface-emitting lasers （VCSELs） with weak optical injection. Considering VCSELs that can work in linearly polarized or elliptically polarized states, it derives the theoretical expression of the conjugated field by small signal analysis based on the vectoral rate equations-the spin-flip model. For linearly polarized state, VCSELs show similar conjugate spectra to edge-emitting semiconductor lasers. For the elliptically polarized state, dichroism and birefringence parameters as well as the spin-flip rate can change the conjugate spectra. Especially, when frequency detuning of the probe and pump waves is between the positive and negative relaxation oscillation frequency, changes are evident. For specific values of parameters, conjugate efficiency between 20 dB to 40 dB are obtained.

Wavefront correction of Ti:sapphire terawatt laser with varying precision of phase conjugation between deformable mirror and wavefront sensor

The phase conjugation between the deformable mirror and the wavefront sensor in the aberration correction of a terawatt Ti：sapphire laser is studied experimentally and theoretically in this paper. At varying values of phase- conjugation precision, we focus the corresponding beams into spots of the same size of 5.1 μm × 5.3 μm with a f/4 parabola in the 32 TW/36 fs Ti：sapphire laser system. The results show that the precision of conjugation can induce an intensity modulation but does not significantly affect the wavefront correction.

Characteristics and suppression of beam distortion in a high repetition rate nanosecond stimulated Brillouin scattering phase conjugation mirror

The stimulated Brillouin scattering phase conjugation mirror (SBS-PCM) based on liquid media is widely used in high-power laser systems due to its robust thermal load capacity, high energy conversion efficiency and improved beam quality. Nevertheless, with an increase in the pump repetition rate, thermally-induced blooming and optical breakdown can emerge, leading to distortions in the Stokes beam. In this study, we delved into the thermal effects in liquid SBS-PCMs employing hydrodynamic analysis, establishing a relationship between beam profile distortion and the thermal convection field. We calculated the temperature and convection velocity distribution based on the pump light parameters and recorded the corresponding beam profiles. The intensities of the beam profiles were modulated in alignment with the convection directions, reaching a velocity peak of 2.85 mm/s at a pump pulse repetition rate of 250 Hz. The residual sum of squares (RSS) was employed to quantify the extent of beam profile distortion relative to a Gaussian distribution. The RSS escalated to 7.8, in contrast to 0.7 of the pump light at a pump pulse repetition rate of 500 Hz. By suppressing thermal convection using a high-viscosity medium, we effectively mitigated beam distortion. The RSS was reduced to 0.7 at a pump pulse repetition rate of 500 Hz, coinciding with a twentyfold increase in viscosity, thereby enhancing the beam quality. By integrating hydrodynamic analysis, we elucidated and mitigated distortion with targeted solutions. Our research offers an interdisciplinary perspective on studying thermal effects and contributes to the application of SBS-PCMs in high-repetition-rate laser systems by unveiling the mechanism of photothermal effects.

Orientation-enhanced nonlinear optical properties and phase-conjugate reflective system of a novel Azobenzene doped polymer film

This paper reports that the nonlinear refractive index of a novel organic optical storage film doped azodiphenylamine polymer is measured by using the Z-scan technique. The nonlinear refractive index up to 3.7× 10^-6 cm^2/W induced by thermo-optical effect is obtained. It indicates that the sample has excellent optical non- linear properties. The physical mechanism of the great nonlinear optical effect is analysed and the optical conjugate characteristic is also discussed with degenerate four-wave-mixing. The phase conjugate wave diffracted from the formative refractive index grating in the sample is acquired and its equivalent reflectivity reaches about 22%. On this basis, the reflective wave phase-conjugated mirror system was designed, and the image aberration experienced in propagation in the storage experiment is corrected by using the system.

The signal synchronization transmission of a spatiotemporal chaos network constituted by a laser phase-conjugate wave

The signal synchronization transmission of a spatiotemporal chaos network is investigated. The structure of the coupling function between connected nodes of the complex network and the value range of the linear term coefficient of the separated configuration in state equation of the node are obtained through constructing an appropriate Lyapunov function. Each node of the complex network is a laser spatiotemporal chaos model in which the phase-conjugate wave and the unilateral coupled map lattice are taken as a local function and a spatially extended system, respectively. The simulation results show the effectiveness of the signal synchronization transmission principle of the network.

Beam Coupling due to Self－Pumped Phase Conjugate Reflection in Photorefractive Crystals

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Optical patterns in spatially coupled phase-conjugate systems

Various pattern evolutions are presented in one- and two-dimensional spatially coupled phase-conjugate systems （SCPCSs）. As the system parameters change, different patterns are obtained from the period-doubling of kink-antikinks in space to the spatiotemporal chaos in a one-dimensional SCPCS. The homogeneous symmetric states induce symmetry breaking from the four corners and the boundaries, finally leading to spatiotemporal chaos with the increase of the iteration time in a two-dimensional SCPCS. Numerical simulations are very helpful for understanding the complex optical phenomena.

基于PRP共轭梯度的图像去噪算法

两阶段算法是去除椒盐噪声的一类非常有效的方法.该文设计了一类PRP共轭梯度法来求解两阶段法中的无约束最优化问题.该方法具有两个显著特点:搜索方向具有充分下降性;结合一类定制的Armijo型非精确线搜索,其点列的梯度趋于零,而不是通常共轭梯度法的下极限趋于零.将所设计方法及一些经典的共轭梯度法应用到两阶段算法的最优化问题中,数值结果表明该文设计的方法在收敛速度与计算精度方面都具有优势.

A Hermitian Opetator Conjugate to Two-Mode Number-Difference Operator

For the Shapiro-Wagner-Hradil phase detection description the canonical commutation relation between phase angleψand two-mode number-difference operator D=a^(†)a-b^(†)b is constructed.Departing from[ψ,D]=-i,the phase angle Hermitian operator is derived in the newly obtained representation<ξ|,where|ξ>is the common eigenket of a+b^(†)and b+a^(†).

Research on Phase Detection of Liquid Crystal Optical Device

The technology for phase detection of liquid crystal optical device is a difficult research in current domestic and overseas. However, for the existing liquid crystal optical device, aiming at the poor anti-vibration capability and poor versatile of phase detection, the complexity of phase retrieval algorithm, we propose a new phase measurement principle and experimental methods of liquid crystal optical device. It is a phase measurement method based on the combination of phase- shifting interferometer and phase conjugation technology. The deflection characteristics of the liquid crystal device means the device can implement phase modulation to only one direction of polarized light while is completely transparent to orthogonal polarized light. We put forward the phase shift of the orthogonal polarization phase shift interferometer method, using phase shifting interference as well as the combination of phase conjugate means to achieve its phase measurement. So we can retrieves devices modulation phase simply and efficiently combines with phase- shifting interferometer technology.

一种新的固液共轭沸腾传热LB模型

为了避免沸腾传热格子玻尔兹曼(LB)模型中因固液能量传递速率一致而导致的模拟误差,尝试性地将温度弛豫时间τT引入到固体和液体的物性参数λ、cp中,成功获得了不同的能量传递速率,得到了一种新的固液共轭沸腾传热格子玻尔兹曼伪势模型。在验证了模型的准确性、稳定性和合理性后,采用固液共轭传热模型和原始伪势模型对不同润湿性表面的沸腾传热过程进行了数值模拟。结果表明:由于原始伪势模型忽视了固、液区域不同的传热能力,导致计算获得的气泡根部周围存在范围较大的低密度相变区,该区域的存在对气泡产生了额外相间作用力,大大改变了气泡的壁面接触角。而共轭传热模型通过引入温度弛豫时间函数实现了对固体和液体区域不同的热物理性质的表征,获得的低密度相变区范围很小,程度更低,壁面接触角更接近于设置的气泡接触角。在除超亲水表面外的其他润湿性表面,共轭传热模型获得的实际接触角的最大相对误差为8.6%,较原始伪势模型降低了9.8%,更能准确地描述实际的沸腾换热微观过程。

非线性光学激光合束技术研究进展

回顾了非线性光学激光合束技术的发展历程,阐述了基于光学相位共轭和基于非线性放大过程的合束思想和基本原理,梳理了重叠耦合、种子注入和布里渊四波混频增强相位锁定激光合束方式的标志性成果,总结了等离子体交叉光束能量转移、金刚石拉曼放大和液体布里渊放大激光合束技术的优势和瓶颈。面向高峰值功率、高平均功率、高重复频率激光输出的实现需求,基于布里渊放大激光合束技术具备系统结构简单、功率负载高且散热效率高的优点,提出了实现单脉冲能量100 J、脉冲宽度10 ns、重复频率10 Hz合束激光输出的可行性方案。

Highly Selective Molecular Recognition of Biologically Active Substances Using Liquid Phase Separation

The development of new chiral stationary phases has been very important in the a ccurate analysis of drug enantiomers and their metabolites in biological samples during drug discovery and development. New chiral stationary phases have been d eveloped using conalbumin and flavoprotein from chicken egg whites, which have b een applied to a broad range of drug enantiomers. The application and characteri zation of these two chiral columns for high-performance liquid chromatograp hy have been documented. Both specific and non-specific interactions, based on the silica gel surface and linker moiety, influenced retention and chiral separa tion of solutes. Interactions between drug enantiomers and proteins, as a pseudo chiral stationary phase, were investigated with affinity capillary electrophore sis, in order to avoid the effects of non-specific interactions. The chiral dis crimination region for ketoprofen on the flavoprotein surface was concluded to c onsist of an α-helix structure. Studies with chemically modified flavoprot ein indicated that two types of interactions at the chiral discrimination region were required for chiral separation: a π-π interaction between a tryptophan residue and the aromatic ring of ketoprofen, and an ionic interaction between th e carboxyl group of ketoprofen and an amino and carboxyl group of the protein. I n the bod y, drugs and biologically active substances having a carboxyl group have been kn own to transform various metabolites such as acyl glucuronide. The acyl adenylat e has also been noted as a chemically active intermediate of coenzyme A ligation . Both the acyl adenylate and the acyl glucuronide produced protein adducts by r eacting with nucleophilic groups such as amino groups on protein molecules. To c haracterize both active intermediates and protein adducts, analytical techniques conferring highly selective molecular recognition, such as high-performance li quid chromatography and mass spectrometry, were required.

Security enhanced underwater visible light communication system based on chaotic phase scrambling and conjugate frequency hopping

We propose an encryption technique for underwater visible light communication[UVLC]based on chaotic phase scrambling[PS]and conjugate frequency hopping[CFH].The technique is experimentally tested using an 8-level pulse amplitude modulation[PAM-8]and a 1.2 m underwater link.The security key of the phase scrambling code is generated according to a logistic map,and the frequency hopping is achieved by adding the same zero frequency points to the signal spectrum.The maximum transmission rate of 2.1 Gbit/s is measured with bit-error-rate[BER]below 7%the hard-decision forward error correction[HD-FEC]threshold of 3.8×10^(-3).

A new circulating two-cell structure for stimulated Brillouin scattering phase conjugation mirrors with 1-J load and 10-Hz repetition rate

A new approach to realize high-energy and high-power stimulated Brillouin scattering phase conjugation mirrors （SBS-PCMs） is described.The reflectivity of SBS-PCM is investigated under a 10-Hz repetition rate and a high energy load.The relationship between reflectivity and input energy is examined experimentally with different PCM structures,focus lengths,and medium cell structures.A medium cell with a circulating structure is designed,and its advantage is demonstrated through an experimental comparison with traditional PCM structures.The 30-cm focus lens and 150-cm collimation lens are optimized when the input energy reaches 1010 mJ at 10-Hz repetition rate.Therefore,a reflectivity of 84.7% and a higher energy load using the circulating two-cell structure are achieved.

Optimized optical phase conjugation conf iguration for f iber nonlinearity compensation in CO-OFDM systems

The optimized optical phase conjugation （OPC） configuration is proposed for the 40-Gb/s CO-OFDM system. The proposed configuration for nonlinear cancellation is systematically depicted in transmission links with lumped amplification. Numerical simulations are performed to demonstrate effectiveness. Simulation results show that mid-span spectral inversion （MSSI） can partially compensate for nonlinear distortions. Moreover, its optimized configuration can further improve system performances and increase nonlinear compensation effectiveness. Compared with MSSI, the maximal Q factor, nonlinear threshold, and transmission distance of optimized OPC configuration increase by over 1.6 dB, 2 dB, and 2 times, respectively.