ZrO2-mullite nano-ceramics were fabricated by in-situ controlled crystallizing from SiO2-Al2O3-ZrO2 amorphous bulk. The thermal transformation sequences of the SiO2-Al2O3-ZrO2 amorphous bulk were investigated by X-ray...ZrO2-mullite nano-ceramics were fabricated by in-situ controlled crystallizing from SiO2-Al2O3-ZrO2 amorphous bulk. The thermal transformation sequences of the SiO2-Al2O3-ZrO2 amorphous bulk were investigated by X-ray diffraction, infrared spectrum, scanning electron microscope and differential scanning calorimetric. And the mechanical properties of the nano-ceramics were studied. The results show that the bulks are still in amorphous state at 900 ℃ and the t-ZrO2 forms at about 950 ℃ with a faint spinel-like phase which changes into mullite on further heating. ZrO2 and mullite become major phases at 1 100 ℃ and an amount of m-ZrO2 occur at the same time. The sample heated at 950 ℃ for 2 h and then at 1 100 ℃ for 1 h shows very dense and homogenous microstructure with ball-like grains in size of 20-50 nm. With the increase of crystallization temperature up to 1 350 ℃, the grains grow quickly and some grow into lath-shaped grains with major diameter of 5 μm. After two-step treatment the highest micro-hardness, flexural strength and fracture toughness of the samples are 13.72 GPa, 520 MPa and 5.13 MPa·m1/2, respectively.展开更多
Alpha-alumina(α-Al_2O_3) platelets were prepared via solid-state reaction using pseudo-boehmite as the starting material, while NH_4F and nano-SiO_2 were used as additives, and nitric acid was used as the binder. The...Alpha-alumina(α-Al_2O_3) platelets were prepared via solid-state reaction using pseudo-boehmite as the starting material, while NH_4F and nano-SiO_2 were used as additives, and nitric acid was used as the binder. The effect of these additives on properties of the alumina platelets was determined via scanning electron microscopy, X-ray diffraction, and measurements of the surface area and silicon content. A mechanism governing their role in the synthesis process was proposed. The results indicated that NH_4F could promote the formation of highly crystalline platelets. Addition of nano-SiO_2 could lead to increase in the diameter and reduction in the thickness of the platelets, and could also prevent their transformation to α-Al_2O_3. This addition weakened the effect of NH_4F because of the reaction of nano-SiO_2 with F-species and the formation of volatile SiF_4.展开更多
Nanoparticles are increasingly being used to improve the friction and wear performance of polymers. In this study, we investigated the tribological behavior and energy dissipation characteristics of nano-Al_2O_3-reinf...Nanoparticles are increasingly being used to improve the friction and wear performance of polymers. In this study, we investigated the tribological behavior and energy dissipation characteristics of nano-Al_2O_3-reinforced polytetrafluoroethylenepolyphenylene sulfide(PTFE-PPS) composites in a sliding system. The tribological behaviors of the composites were evaluated under different normal loads(100–300 N) at a high linear velocity(2 m/s) using a block-on-ring tester. Addition of the nano-Al_2O_3 filler improved the antiwear performance of the PTFE-PPS composites, and the friction coefficient increased slightly. The lowest wear rate was obtained when the nano-Al_2O_3 content was 3%(volume fraction). Further, the results indicated a linear correlation between wear and the amount of energy dissipated, even though the wear mechanism changed with the nano-Al_2O_3 content, independent of the normal load applied.展开更多
Metal and nano-ceramic nanocomposite coatings were prepared on the gray cast iron surface by the electrodeposition method. The Ni-Co was used as the metal matrix,and nano-Al2O3 was chosen as the second-phase particula...Metal and nano-ceramic nanocomposite coatings were prepared on the gray cast iron surface by the electrodeposition method. The Ni-Co was used as the metal matrix,and nano-Al2O3 was chosen as the second-phase particulates. To avoid poor inter-face bonding and stress distribution,the gradient structure of biology materials was found as the model and therefore the gradient composite coating was prepared. The morphology of the composite coatings was flatter and the microstructure was denser than that of pure Ni-Co coatings. The composite coatings were prepared by different current densities,and the 2-D and 3-D morphologies of the surface coatings were observed. The result indicated that the 2-D structure became rougher and the 3-D surface density of apices became less when the current density was increased. The content of nanoparticulates reached a maximum value at the current density of 40mA·cm^-2,at the same time the properties including microhardness and wear-resistance were analyzed. The microhardness reached a maximum value and the wear volume was also less at the current density of 40mA·cm^-2. The reason was that nano-Al2O3 particles caused dispersive strengthening and grain refining.展开更多
基金Project(2003AA332040) supported by the National High Technology Research and Development Program of China
文摘ZrO2-mullite nano-ceramics were fabricated by in-situ controlled crystallizing from SiO2-Al2O3-ZrO2 amorphous bulk. The thermal transformation sequences of the SiO2-Al2O3-ZrO2 amorphous bulk were investigated by X-ray diffraction, infrared spectrum, scanning electron microscope and differential scanning calorimetric. And the mechanical properties of the nano-ceramics were studied. The results show that the bulks are still in amorphous state at 900 ℃ and the t-ZrO2 forms at about 950 ℃ with a faint spinel-like phase which changes into mullite on further heating. ZrO2 and mullite become major phases at 1 100 ℃ and an amount of m-ZrO2 occur at the same time. The sample heated at 950 ℃ for 2 h and then at 1 100 ℃ for 1 h shows very dense and homogenous microstructure with ball-like grains in size of 20-50 nm. With the increase of crystallization temperature up to 1 350 ℃, the grains grow quickly and some grow into lath-shaped grains with major diameter of 5 μm. After two-step treatment the highest micro-hardness, flexural strength and fracture toughness of the samples are 13.72 GPa, 520 MPa and 5.13 MPa·m1/2, respectively.
基金supported by the Technology Development(Commission) Project of SINOPEC Catalyst Co.Ltd(Grant No.14-05-01)
文摘Alpha-alumina(α-Al_2O_3) platelets were prepared via solid-state reaction using pseudo-boehmite as the starting material, while NH_4F and nano-SiO_2 were used as additives, and nitric acid was used as the binder. The effect of these additives on properties of the alumina platelets was determined via scanning electron microscopy, X-ray diffraction, and measurements of the surface area and silicon content. A mechanism governing their role in the synthesis process was proposed. The results indicated that NH_4F could promote the formation of highly crystalline platelets. Addition of nano-SiO_2 could lead to increase in the diameter and reduction in the thickness of the platelets, and could also prevent their transformation to α-Al_2O_3. This addition weakened the effect of NH_4F because of the reaction of nano-SiO_2 with F-species and the formation of volatile SiF_4.
基金Project(51165022)supported by the National Natural Science Foundation of ChinaProject(20122117)supported by the Lanzhou Science and Technology Bureau Foundation,ChinaProject(1310RJZA036)supported by the Natural Science Foundation of Gansu Province,China
文摘Nanoparticles are increasingly being used to improve the friction and wear performance of polymers. In this study, we investigated the tribological behavior and energy dissipation characteristics of nano-Al_2O_3-reinforced polytetrafluoroethylenepolyphenylene sulfide(PTFE-PPS) composites in a sliding system. The tribological behaviors of the composites were evaluated under different normal loads(100–300 N) at a high linear velocity(2 m/s) using a block-on-ring tester. Addition of the nano-Al_2O_3 filler improved the antiwear performance of the PTFE-PPS composites, and the friction coefficient increased slightly. The lowest wear rate was obtained when the nano-Al_2O_3 content was 3%(volume fraction). Further, the results indicated a linear correlation between wear and the amount of energy dissipated, even though the wear mechanism changed with the nano-Al_2O_3 content, independent of the normal load applied.
基金the National Natural Science Foundation of China (No50635030)the National Basic Research of China (No2007CB616913)the Program for New Century Excellent Talents in University (2005)
文摘Metal and nano-ceramic nanocomposite coatings were prepared on the gray cast iron surface by the electrodeposition method. The Ni-Co was used as the metal matrix,and nano-Al2O3 was chosen as the second-phase particulates. To avoid poor inter-face bonding and stress distribution,the gradient structure of biology materials was found as the model and therefore the gradient composite coating was prepared. The morphology of the composite coatings was flatter and the microstructure was denser than that of pure Ni-Co coatings. The composite coatings were prepared by different current densities,and the 2-D and 3-D morphologies of the surface coatings were observed. The result indicated that the 2-D structure became rougher and the 3-D surface density of apices became less when the current density was increased. The content of nanoparticulates reached a maximum value at the current density of 40mA·cm^-2,at the same time the properties including microhardness and wear-resistance were analyzed. The microhardness reached a maximum value and the wear volume was also less at the current density of 40mA·cm^-2. The reason was that nano-Al2O3 particles caused dispersive strengthening and grain refining.
