It is normally difficult to prepare nano-sized Ba0.5Sr0.5Co0.8Fe0.2O3-δ（BSCF） oxide at high temperature due to its high surface activity. The complexing process, which has successfully applied in the synthesis of n...It is normally difficult to prepare nano-sized Ba0.5Sr0.5Co0.8Fe0.2O3-δ（BSCF） oxide at high temperature due to its high surface activity. The complexing process, which has successfully applied in the synthesis of nano Sm0.15Ce0.85I1.925 with crystallite size down to 5 nml, just resulted in a coarse BSCF with crystaUite size of 41.9 nm at 900℃. We applied a novel process by simply modifying the solid precursor from the complexing process with concentrated nitric acid treatment. The obtained BSCF powder had a crystaUite size of -25 nm even calcined at 1000℃. The small crystaUite size is extremely promising to enhance the electrochemical performance of cathode for solid oxide fuel cell dramatically.展开更多
基金This work is also sponsored by the National Basic Research Program of China （No. 2003CB615702）the National Natural Science Foundation of China （No. 20646002, 20576051 and 20436030）+1 种基金Scientific Research Foundation for the Returned 0verseas China Scholars from State Ministry of Education （No. 2004527）Nanjing Ministry of Personnel.
文摘It is normally difficult to prepare nano-sized Ba0.5Sr0.5Co0.8Fe0.2O3-δ（BSCF） oxide at high temperature due to its high surface activity. The complexing process, which has successfully applied in the synthesis of nano Sm0.15Ce0.85I1.925 with crystallite size down to 5 nml, just resulted in a coarse BSCF with crystaUite size of 41.9 nm at 900℃. We applied a novel process by simply modifying the solid precursor from the complexing process with concentrated nitric acid treatment. The obtained BSCF powder had a crystaUite size of -25 nm even calcined at 1000℃. The small crystaUite size is extremely promising to enhance the electrochemical performance of cathode for solid oxide fuel cell dramatically.
