The microporous nanocry'sta1line TiO2 electrode with large surface roughness factor hasbeen prepared on a conducting glass support. Modification of the TiO2 electrode by in situ preparingquantum sized RuS2 particl...The microporous nanocry'sta1line TiO2 electrode with large surface roughness factor hasbeen prepared on a conducting glass support. Modification of the TiO2 electrode by in situ preparingquantum sized RuS2 particles on the surface of TiO2 electrode extends the optical absorptionspectrum and photocurrent action specmim into visible region. In addition, compared with RuS2 bulknlaterials- a blue shifi in both absorption spectrum and photocurrent action speCtrum of RuS2rriO2elcctrode is obserived and explained in terms of quantum sized effect.展开更多
Since the prototype of a dye-sensitized solar cell(DSSC)was reported in 1991 by M. Gratzel,it has aroused intensive interest over the past decade due to its low cost and simple preparation procedure.The typical cell c...Since the prototype of a dye-sensitized solar cell(DSSC)was reported in 1991 by M. Gratzel,it has aroused intensive interest over the past decade due to its low cost and simple preparation procedure.The typical cell consists of a dye-coated mesoporous nanocrystalline TiO_2 film sandwiched between two transparent electroldes.A liquid electrolyte,traditionally containing the trioidide/iodide redox couple,fills the pores of the mesoporous nanocrystalline TiO_2 film and contacts the nanoparticles.Photoexcite...展开更多
文摘The microporous nanocry'sta1line TiO2 electrode with large surface roughness factor hasbeen prepared on a conducting glass support. Modification of the TiO2 electrode by in situ preparingquantum sized RuS2 particles on the surface of TiO2 electrode extends the optical absorptionspectrum and photocurrent action specmim into visible region. In addition, compared with RuS2 bulknlaterials- a blue shifi in both absorption spectrum and photocurrent action speCtrum of RuS2rriO2elcctrode is obserived and explained in terms of quantum sized effect.
文摘Since the prototype of a dye-sensitized solar cell(DSSC)was reported in 1991 by M. Gratzel,it has aroused intensive interest over the past decade due to its low cost and simple preparation procedure.The typical cell consists of a dye-coated mesoporous nanocrystalline TiO_2 film sandwiched between two transparent electroldes.A liquid electrolyte,traditionally containing the trioidide/iodide redox couple,fills the pores of the mesoporous nanocrystalline TiO_2 film and contacts the nanoparticles.Photoexcite...
