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Coherence of nonlinear Bloch dynamics of Bose-Einstein condensates in deep optical lattices
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作者 张爱霞 张薇 +3 位作者 王杰 胡潇文 米来来 薛具奎 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第4期297-303,共7页
Atomic interaction leads to dephasing and damping of Bloch oscillations(BOs)in optical lattices,which limits observation and applications of BOs.How to obtain persistent BOs is particularly important.Here,the nonlinea... Atomic interaction leads to dephasing and damping of Bloch oscillations(BOs)in optical lattices,which limits observation and applications of BOs.How to obtain persistent BOs is particularly important.Here,the nonlinear Bloch dynamics of the Bose-Einstein condensate with two-body and three-body interactions in deep optical lattices is studied.The damping rate induced by interactions is obtained.The damping induced by two-body interaction plays a dominant role,while the damping induced by three-body interaction is weak.However,when the two-body and three-body interactions satisfy a threshold,long-lived coherent BOs are observed.Furthermore,the Bloch dynamics with periodical modulation of linear force is studied.The frequencies of linear force corresponding to resonance and pseudoresonance are obtained,and rich dynamical phenomena,i.e.,stable and strong BOs,drifting and dispersion of wave packet,are predicted.The controllable Bloch dynamics is provided with the periodic modulation of the linear force. 展开更多
关键词 Bose-Einstein condensate atomic interaction Bloch oscillations
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Dynamics of bubble-shaped Bose-Einstein condensates on two-dimensional cross-section in micro-gravity environment 被引量:1
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作者 张铁夫 李成蹊 刘伍明 《Chinese Physics B》 SCIE EI CAS CSCD 2023年第9期200-205,共6页
We investigated the dynamic evolution and interference phenomena of bubble-shaped Bose-Einstein condensates achievable in a micro-gravity environment.Using numerical solutions of the Gross-Pitaevskii equation describi... We investigated the dynamic evolution and interference phenomena of bubble-shaped Bose-Einstein condensates achievable in a micro-gravity environment.Using numerical solutions of the Gross-Pitaevskii equation describing the dynamic evolution of the bubble-shaped Bose-Einstein condensates,we plotted the evolution of the wave function density distribution on its two-dimensional(2D)cross-section and analysed the resulting patterns.We found that changes in the strength of atomic interactions and initial momentum can affect the dynamic evolution of the bubble-shaped Bose-Einstein condensates and their interference fringes.Notably,we have observed that when the initial momentum is sufficiently high,the thickness of the bubble-shaped Bose-Einstein condensate undergoes a counterintuitive thinning,which is a counterintuitive result that requires further investigation.Our findings are poised to advance our comprehension of the physical essence of bubble-shaped Bose-Einstein condensates and to facilitate the development of relevant experiments in microgravity environments. 展开更多
关键词 boson systems ultracold gases dynamic properties of condensates
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Novel interface engineering of LDH-based materials on Mg alloy for efficient photocatalytic systems considering the geometrical linearity of condensed phosphates 被引量:3
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作者 Mosab Kaseem Ananda Repycha Safira Arash Fattah-alhosseini 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2024年第1期267-280,共14页
This study presents a facile and rapid method for synthesizing novel Layered Double Hydroxide(LDH)nanoflakes,exploring their application as a photocatalyst,and investigating the influence of condensed phosphates'g... This study presents a facile and rapid method for synthesizing novel Layered Double Hydroxide(LDH)nanoflakes,exploring their application as a photocatalyst,and investigating the influence of condensed phosphates'geometric linearity on their photocatalytic properties.Herein,the Mg O film,obtained by plasma electrolysis of AZ31 Mg alloys,was modified by growing an LDH film,which was further functionalized using cyclic sodium hexametaphosphate(CP)and linear sodium tripolyphosphate(LP).CP acted as an enhancer for flake spacing within the LDH structure,while LP changed flake dispersion and orientation.Consequently,CP@LDH demonstrated exceptional efficiency in heterogeneous photocatalysis,effectively degrading organic dyes like Methylene blue(MB),Congo red(CR),and Methyl orange(MO).The unique cyclic structure of CP likely enhances surface reactions and improves the catalyst's interaction with dye molecules.Furthermore,the condensed phosphate structure contributes to a higher surface area and reactivity in CP@LDH,leading to its superior photocatalytic performance compared to LP@LDH.Specifically,LP@LDH demonstrated notable degradation efficiencies of 93.02%,92.89%,and 88.81%for MB,MO,and CR respectively,over a 40 min duration.The highest degradation efficiencies were observed in the case of the CP@LDH sample,reporting 99.99%for MB,98.88%for CR,and 99.70%for MO.This underscores the potential of CP@LDH as a highly effective photocatalyst for organic dye degradation,offering promising prospects for environmental remediation and water detoxification applications. 展开更多
关键词 Plasma electrolysis Layered Double Hydroxide condensed phosphates Adsorption capacity Photocatalytic efficiency
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Facile synthesis of hierarchical NaX zeolite from natural kaolinite for efficient Knoevenagel condensation 被引量:2
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作者 Wen Xiao Peng Dong +6 位作者 Chan Wang Jingdong Xu Tiesen Li Haibo Zhu Tinghai Wang Renwei Xu Yuanyuan Yue 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第1期75-84,共10页
Zeolite catalysts have found extensive applications in the synthesis of various fine chemicals.However,the micropores of zeolites impose diffusion limitations on bulky molecules,greatly reducing the catalytic efficien... Zeolite catalysts have found extensive applications in the synthesis of various fine chemicals.However,the micropores of zeolites impose diffusion limitations on bulky molecules,greatly reducing the catalytic efficiency.Herein,we explore an economic and environmentally friendly method for synthesizing hierarchical NaX zeolite that exhibits improved catalytic performance in the Knoevenagel condensation reaction for producing the useful fine chemical 2-cyano-3-phenylacrylate.The synthesis was achieved via a low-temperature activation of kaolinite and subsequent in-situ transformation strategy without any template or seed.Systematic characterizations reveal that the synthesized NaX zeolite has both intercrystalline and intra-crystalline mesopores,smaller crystal size,and larger external specific surface area compared to commercial NaX zeolite.Detailed mechanism investigations show that the inter-crystalline mesopores are generated by stacking smaller crystals formed from in-situ crystallization of the depolymerized kaolinite,and the intra-crystalline mesopores are inherited from the pores in the depolymerized kaolinite.This synthesis strategy provides an energy-saving and effective way to construct hierarchical zeolites,which may gain wide applications in fine chemical manufacturing. 展开更多
关键词 Hierarchical NaX zeolite Template-free synthesis Natural kaolinite Knoevenagel condensation
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Quantum Brayton Refrigeration Cycle with Finite-Size Bose-Einstein Condensates
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作者 袁结红 阮慧琳 +2 位作者 刘德华 何济洲 王建辉 《Chinese Physics Letters》 SCIE EI CAS CSCD 2023年第10期19-23,共5页
We consider a quantum Brayton refrigeration cycle consisting of two isobaric and two adiabatic processes,using an ideal Bose gas of finite particles confined in a harmonic trap as its working substance.Quite generally... We consider a quantum Brayton refrigeration cycle consisting of two isobaric and two adiabatic processes,using an ideal Bose gas of finite particles confined in a harmonic trap as its working substance.Quite generally,such a machine falls into three different cases,classified as the condensed region,non-condensed phase,and regime across the critical point.When the refrigerator works near the critical region,both figure of merit and cooling load are significantly improved due to the singular behavior of the specific heat,and the coefficient of performance at maximum figure of merit is much larger than the Curzon-Ahlborn value.With the machine in the non-condensed regime,the coefficient of performance for maximum figure of merit agrees well with the Curzon-Ahlborn value. 展开更多
关键词 VALUE condensed CRITICAL
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Mode dynamics of Bose–Einstein condensates in a single-well potential
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作者 应耀俊 孙李真 李海彬 《Chinese Physics B》 SCIE EI CAS CSCD 2023年第10期254-261,共8页
We investigate dynamics of Bose–Einstein condensates(BECs) in a single-well potential using the mode-coupling method. Symmetry is shown to play a key role in the coupling between modes. A proper mode-coupling theory ... We investigate dynamics of Bose–Einstein condensates(BECs) in a single-well potential using the mode-coupling method. Symmetry is shown to play a key role in the coupling between modes. A proper mode-coupling theory of the dynamics of BECs in a single-well potential should include at least four modes. In this context, the ideal BEC system can be decomposed into two independent subsystems when the coupling is caused by external potential perturbation and is linear. The mode dynamics of non-ideal BECs with interaction shows rich behavior. The combination of nonlinear coupling and initial condition leads to the different regimes of mode dynamics, from regularity to non-regularity, which also indicates a change of the dependence of coupling on the symmetry of modes. 展开更多
关键词 Bose–Einstein condensate mode-coupling DYNAMICS SYMMETRY
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Special breathing structures induced by bright solitons collision in a binary dipolar Bose–Einstein condensates
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作者 张根 吕李政 +1 位作者 高鹏 杨战营 《Chinese Physics B》 SCIE EI CAS CSCD 2023年第11期16-23,共8页
We numerically investigate the breathing dynamics induced by collision between bright solitons in a binary dipolar Bose–Einstein condensates, whose dipole–dipole interaction and contact interaction are attractive. W... We numerically investigate the breathing dynamics induced by collision between bright solitons in a binary dipolar Bose–Einstein condensates, whose dipole–dipole interaction and contact interaction are attractive. We identify three special breathing structures, such as snakelike special breathing structure, mixed breathing structure, and divide breathing structure.The characteristics of these breathing structures can be described by breathing frequency ?, maximum breathing amplitude A and lifetime τ, which can be manipulated by atomic number Ni and interspecies scattering length a12. Meanwhile, the above breathing structures can realize the process of quasi-transition with a reasonable Ni and a12. Additionally, the collision of two special breathing structures also can bring more abundant breathing dynamics. Our results provide a reference for the study of soliton interactions and deepen the understanding of soliton properties in a binary dipolar Bose–Einstein condensates. 展开更多
关键词 dipolar Bose-Einstein condensates SOLITON soliton collision
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Probability of Obtaining the Planck Constant, in a Universe Modeled as a Giant Black Hole by Bose Einstein Condensates of Gravitons Using Hawking Argument and Scaling
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作者 Andrew Walcott Beckwith 《Journal of High Energy Physics, Gravitation and Cosmology》 CAS 2023年第1期134-141,共8页
We use the methodology of A. D. Linde to model the probability of obtaining a cosmological constant which is in turn affected by scaling arguments for a Bose Einstein gravitational condensate as given by Chavanis, in ... We use the methodology of A. D. Linde to model the probability of obtaining a cosmological constant which is in turn affected by scaling arguments for a Bose Einstein gravitational condensate as given by Chavanis, in 2015. The net result, is that the scaling argument so provided allows for a gravitational constant commensurate with the size of the Universe, using arguments which appear to be simple but which give, if one has the conditions for modeling the Universe as a “black hole” virtually 100 % chance for the cosmological constant arising. 展开更多
关键词 Black Hole Bose Einstein condensate Planck Constant Massive Graviton Hubble Parameter
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Nonlinear modes coupling of trapped spin-orbit coupled spin-1 Bose-Einstein condensates
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作者 王杰 梁俊成 +3 位作者 鱼自发 张安庆 张爱霞 薛具奎 《Chinese Physics B》 SCIE EI CAS CSCD 2023年第9期163-171,共9页
We study analytically and numerically the nonlinear collective dynamics of quasi-one-dimensional spin-orbit coupled spin-1 Bose-Einstein condensates trapped in harmonic potential.The ground state of the system is dete... We study analytically and numerically the nonlinear collective dynamics of quasi-one-dimensional spin-orbit coupled spin-1 Bose-Einstein condensates trapped in harmonic potential.The ground state of the system is determined by minimizing the Lagrange density,and the coupled equations of motions for the center-of-mass coordinate of the condensate and its width are derived.Then,two low energy excitation modes in breathing dynamics and dipole dynamics are obtained analytically,and the mechanism of exciting the anharmonic collective dynamics is revealed explicitly.The coupling among spin-orbit coupling,Raman coupling and spin-dependent interaction results in multiple external collective modes,which leads to the anharmonic collective dynamics.The cooperative effect of spin momentum locking and spin-dependent interaction results in coupling of dipolar and breathing dynamics,which strongly depends on spin-dependent interaction and behaves distinct characters in different phases.Interestingly,in the absence of spin-dependent interaction,the breathing dynamics is decoupled from spin dynamics and the breathing dynamics is harmonic.Our results provide theoretical evidence for deep understanding of the ground sate phase transition and the nonlinear collective dynamics of the system. 展开更多
关键词 spin-orbit coupled spin-1 Bose-Einstein condenses collective excitations nonlinear modes coupling
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Phase behavior of gas condensate in porous media using real-time computed tomography scanning
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作者 Wen-Long Jing Lei Zhang +5 位作者 Ai-Fen Li Jun-Jie Zhong Hai Sun Yong-Fei Yang Yu-Long Cheng Jun Yao 《Petroleum Science》 SCIE EI CAS CSCD 2024年第2期1032-1043,共12页
The phase behavior of gas condensate in reservoir formations differs from that in pressure-volume-temperature(PVT)cells because it is influenced by porous media in the reservoir formations.Sandstone was used as a samp... The phase behavior of gas condensate in reservoir formations differs from that in pressure-volume-temperature(PVT)cells because it is influenced by porous media in the reservoir formations.Sandstone was used as a sample to investigate the influence of porous media on the phase behavior of the gas condensate.The pore structure was first analyzed using computed tomography(CT)scanning,digital core technology,and a pore network model.The sandstone core sample was then saturated with gas condensate for the pressure depletion experiment.After each pressure-depletion state was stable,realtime CT scanning was performed on the sample.The scanning results of the sample were reconstructed into three-dimensional grayscale images,and the gas condensate and condensate liquid were segmented based on gray value discrepancy to dynamically characterize the phase behavior of the gas condensate in porous media.Pore network models of the condensate liquid ganglia under different pressures were built to calculate the characteristic parameters,including the average radius,coordination number,and tortuosity,and to analyze the changing mechanism caused by the phase behavior change of the gas condensate.Four types of condensate liquid(clustered,branched,membranous,and droplet ganglia)were then classified by shape factor and Euler number to investigate their morphological changes dynamically and elaborately.The results show that the dew point pressure of the gas condensate in porous media is 12.7 MPa,which is 0.7 MPa higher than 12.0 MPa in PVT cells.The average radius,volume,and coordination number of the condensate liquid ganglia increased when the system pressure was between the dew point pressure(12.7 MPa)and the pressure for the maximum liquid dropout,Pmax(10.0 MPa),and decreased when it was below Pmax.The volume proportion of clustered ganglia was the highest,followed by branched,membranous,and droplet ganglia.This study provides crucial experimental evidence for the phase behavior changing process of gas condensate in porous media during the depletion production of gas condensate reservoirs. 展开更多
关键词 Gas condensate Pressure depletion Real-time micro-computed tomography scanning Distribution of condensate liquid
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Experimental Investigation on Condensate Revaporization During Gas Injection Development in Fractured Gas Condensate Reservoirs
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作者 Lei Zhang Yingxu He +3 位作者 Jintao Wu Haojun Wu Lei Huang Linna Sun 《哈尔滨工程大学学报(英文版)》 CSCD 2024年第3期575-582,共8页
The gas field in the Bohai Bay Basin is a fractured metamorphic buried-hill reservoir with dual-media characteristics. The retrograde vaporization mechanism observed in this type of gas condensate reservoir differs si... The gas field in the Bohai Bay Basin is a fractured metamorphic buried-hill reservoir with dual-media characteristics. The retrograde vaporization mechanism observed in this type of gas condensate reservoir differs significantly from that observed in sand gas condensate reservoirs. However, studies on improving the recovery of fractured gas condensate reservoirs are limited;thus, the impact of retrograde vaporization on condensate within fractured metamorphic buried-hill reservoirs remains unclear. To address this gap, a series of gas injection experiments are conducted in pressure-volume-temperature(PVT) cells and long-cores to investigate the retrograde vaporization effect of condensate using different gas injection media in fractured gas condensate reservoirs. We analyze the variation in condensate volume, gas-to-oil ratio, and condensate recovery during gas injection and examine the influence of various gas injection media(CO_(2), N_(2), and dry gas) under different reservoir properties and varying gas injection times. The results demonstrate that the exchange of components between injected gas and condensate significantly influences condensate retrograde vaporization in the formation. Compared with dry gas injection and N_(2) injection,CO_(2) injection exhibits a superior retrograde vaporization effect. At a CO_(2) injection volume of 1 PV, the percentage shrinkage volume of condensate is 13.82%. Additionally, at the maximum retrograde condensation pressure, CO_(2) injection can increase the recovery of condensate by 22.4%. However, the condensate recovery is notably lower in fractured gas condensate reservoirs than in homogeneous reservoirs, owing to the creation of dominant gas channeling by fractures, which leads to decreased condensate recovery. Regarding gas injection timing, the effect of gas injection at reservoir pressure on improving condensate recovery is superior to that of gas injection at the maximum retrograde condensation pressure. This research provides valuable guidance for designing gas injection development plans and dynamic tracking adjustments for fractured gas condensate reservoirs. 展开更多
关键词 Buried-hill fractured reservoir Gas condensate reservoir Retrograde condensation CO_(2)injection Retrograde vaporization
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Dynamical nonlinear excitations induced by interaction quench in a two-dimensional box-trapped Bose-Einstein condensate
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作者 牛真霞 高超 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第2期209-215,共7页
Manipulating nonlinear excitations,including solitons and vortices,is an essential topic in quantum many-body physics.A new progress in this direction is a protocol proposed in[Phys.Rev.Res.2043256(2020)]to produce da... Manipulating nonlinear excitations,including solitons and vortices,is an essential topic in quantum many-body physics.A new progress in this direction is a protocol proposed in[Phys.Rev.Res.2043256(2020)]to produce dark solitons in a one-dimensional atomic Bose–Einstein condensate(BEC)by quenching inter-atomic interaction.Motivated by this work,we generalize the protocol to a two-dimensional BEC and investigate the generic scenario of its post-quench dynamics.For an isotropic disk trap with a hard-wall boundary,we find that successive inward-moving ring dark solitons(RDSs)can be induced from the edge,and the number of RDSs can be controlled by tuning the ratio of the after-and before-quench interaction strength across different critical values.The role of the quench played on the profiles of the density,phase,and sound velocity is also investigated.Due to the snake instability,the RDSs then become vortex–antivortex pairs with peculiar dynamics managed by the initial density and the after-quench interaction.By tuning the geometry of the box traps,demonstrated as polygonal ones,more subtle dynamics of solitons and vortices are enabled.Our proposed protocol and the discovered rich dynamical effects on nonlinear excitations can be realized in near future cold-atom experiments. 展开更多
关键词 Bose-Einstein condensate quench interaction SOLITON vortex
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Interference-induced suppression of particle emission from a Bose-Einstein condensate in lattice with time-periodic modulations
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作者 Long-Quan Lai Zhao Li 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第10期153-158,共6页
Emission of matter-wave jets from a parametrically driven condensate has attracted significant experimental and theoretical attention due to the appealing visual effects and potential metrological applications.In this... Emission of matter-wave jets from a parametrically driven condensate has attracted significant experimental and theoretical attention due to the appealing visual effects and potential metrological applications.In this work,we investigate the collective particle emission from a Bose-Einstein condensate confined in a one-dimensional lattice with periodically modulated interparticle interactions.We give the regimes for discrete modes,and find that the emission can be distinctly suppressed.The configuration induces a broad band,but few particles are ejected due to the interference of the matter waves.We further qualitatively model the emission process and demonstrate the short-time behaviors.This engineering provides a way to manipulate the propagation of particles and the corresponding dynamics of condensates in lattices,and may find application in the dynamical excitation control of other nonequilibrium problems with time-periodic driving. 展开更多
关键词 Bose-Einstein condensate matter-wave jet periodic modulation
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Effects of drive imbalance on the particle emission from a Bose-Einstein condensate in a one-dimensional lattice
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作者 赖龙泉 李照 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第3期238-243,共6页
Time-periodic driving has been an effective tool in the field of nonequilibrium quantum dynamics,which enables precise control of the particle interactions.We investigate the collective emission of particles from a Bo... Time-periodic driving has been an effective tool in the field of nonequilibrium quantum dynamics,which enables precise control of the particle interactions.We investigate the collective emission of particles from a Bose-Einstein condensate in a one-dimensional lattice with periodic drives that are separate in modulation amplitudes and relative phases.In addition to the enhancement of particle emission,we find that amplitude imbalances lead to energy shift and band broadening,while typical relative phases may give rise to similar gaps.These results offer insights into the specific manipulations of nonequilibrium quantum systems with tone-varying drives. 展开更多
关键词 Bose-Einstein condensate particle emission periodic drive
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Chromatin condensation but not DNA integrity of pig sperm is greater in the sperm-rich fraction
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作者 Estel Viñolas-Vergés Jordi Ribas-Maynou +4 位作者 Isabel Barranco Camila Peres Rubio Sergi Bonet Jordi Roca Marc Yeste 《Journal of Animal Science and Biotechnology》 SCIE CAS CSCD 2024年第1期171-181,共11页
Background Protamination and condensation of sperm chromatin as well as DNA integrity play an essential role during fertilization and embryo development.In some mammals,like pigs,ejaculates are emitted in three separa... Background Protamination and condensation of sperm chromatin as well as DNA integrity play an essential role during fertilization and embryo development.In some mammals,like pigs,ejaculates are emitted in three separate fractions:pre-sperm,sperm-rich(SRF)and post sperm-rich(PSRF).These fractions are known to vary in volume,sperm concentration and quality,as well as in the origin and composition of seminal plasma(SP),with differences being also observed within the SRF one.Yet,whether disparities in the DNA integrity and chromatin condensation and pro-tamination of their sperm exist has not been interrogated.Results This study determined chromatin protamination(Chromomycin A3 test,CMA_(3)),condensation(Dibromobi-mane test,DBB),and DNA integrity(Comet assay)in the pig sperm contained in the first 10 m L of the SRF(SRF-P1),the remaining portion of the sperm-rich fraction(SRF-P2),and the post sperm-rich fraction(PSRF).While chromatin protamination was found to be similar between the different ejaculate fractions(P>0.05),chromatin condensation was seen to be greater in SRF-P1 and SRF-P2 than in the PSRF(P=0.018 and P=0.004,respectively).Regarding DNA integrity,no differences between fractions were observed(P>0.05).As the SRF-P1 has the highest sperm concentra-tion and ejaculate fractions are known to differ in antioxidant composition,the oxidative stress index(OSi)in SP,calcu-lated as total oxidant activity divided by total antioxidant capacity,was tested and confirmed to be higher in the SRF-P1 than in SRF-P2 and PSRF(0.42±0.06 vs.0.23±0.09 and 0.08±0.00,respectively;P<0.01);this index,in addition,was observed to be correlated to the sperm concentration of each fraction(Rs=0.973;P<0.001).Conclusion While sperm DNA integrity was not found to differ between ejaculate fractions,SRF-P1 and SRF-P2 were observed to exhibit greater chromatin condensation than the PSRF.This could be related to the OSi of each fraction. 展开更多
关键词 CHROMATIN condensation DNA integrity Ejaculate fractions PIG Protamination SPERM
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Controllable Condensation of Aromatics and Its Mechanisms in Carbonization
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作者 Fan Xi Wang Chunlu +3 位作者 Luo Yang Ren Qiang Shen Haiping Long Jun 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS CSCD 2024年第1期34-46,共13页
In order to obtain liquefied products with higher yields of aromatic molecules to produce mesophase pitch,a good understanding of the relevant reaction mechanisms is required.Reactive molecular dynamics simulations we... In order to obtain liquefied products with higher yields of aromatic molecules to produce mesophase pitch,a good understanding of the relevant reaction mechanisms is required.Reactive molecular dynamics simulations were used to study the thermal reactions of pyrene,1-methylpyrene,7,8,9,10-tetrahydrobenzopyrene,and mixtures of pyrene with 1-octene,cyclohexene,or styrene.The reactant conversion rates,reaction rates,and product distributions were calculated and compared,and the mechanisms were analyzed and discussed.The results demonstrated that methyl and naphthenic structures in aromatics might improve the conversion rates of reactants in hydrogen transfer processes,but their steric hindrances prohibited the generation of high polymers.The naphthenic structures could generate more free radicals and presented a more obvious inhibition effect on the condensation of polymers compared with the methyl side chains.It was discovered that when different olefins were mixed with pyrene,1-octene primarily underwent pyrolysis reactions,whereas cyclohexene mainly underwent hydrogen transfer reactions with pyrene and styrene,mostly producing superconjugated biradicals through condensation reactions with pyrene.In the mixture systems,the olefins scattered aromatic molecules,hindering the formation of pyrene trimers and higher polymers.According to the reactive molecular dynamics simulations,styrene may enhance the yield of dimer and enable the controlled polycondensation of pyrene. 展开更多
关键词 CARBONIZATION controllable condensation AROMATICS MECHANISMS molecular simulation
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Supersonic expansion and condensation characteristics of hydrogen gas under different temperature conditions
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作者 Xinyue Duan Zeyu Zhang +4 位作者 Ziyuan Zhao Yang Liu Liang Gong Xuewen Cao Jiang Bian 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第5期220-226,共7页
This paper introduced supersonic expansion liquefaction technology into the field of hydrogen liquefaction.The mathematical model for supersonic condensation of hydrogen gas in a Laval nozzle model was established.The... This paper introduced supersonic expansion liquefaction technology into the field of hydrogen liquefaction.The mathematical model for supersonic condensation of hydrogen gas in a Laval nozzle model was established.The supersonic expansion and condensation characteristics of hydrogen gas under different temperature conditions were investigated.The simulation results show that the droplet number rises rapidly from 0 at the nozzle throat as the inlet temperature increases,and the maximum droplet number generated is 1.339×10^(18)kg^(-1)at inlet temperature of 36.0 K.When hydrogen nucleation occurs,the droplet radius increases significantly and shows a positive correlation with the increase in the inlet temperature,and the maximum droplet radii are 6.667×10^(-8)m,1.043×10^(-7)m,and 1.099×10^(-7)m when the inlet temperature is 36.0 K,36.5 K,and 37.0 K,respectively.The maximum nucleation rate decreases with increasing inlet temperature,and the nucleation region of the Laval nozzle becomes wider.The liquefaction efficiency can be effectively improved by lowering the inlet temperature.This is because a lower inlet temperature provides more subcooling,which allows the hydrogen to reach the thermodynamic conditions required for large-scale condensation more quickly. 展开更多
关键词 HYDROGEN LIQUEFACTION SUPERSONIC condensATION Laval nozzle Computational fluid dynamics
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Biochemistry and transcriptome analysis reveal condensed tannins alleviate liver injury induced by regulating cholesterol metabolism pathway
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作者 Xiangxin Li Yijing Pu +4 位作者 Bangdi Liu Xiaoming Fang Wenjun Peng Weibo Jiang Wenli Tian 《Food Science and Human Wellness》 SCIE CSCD 2024年第2期909-919,共11页
Free cholesterol has been considered to be a critical risk factor of nonalcoholic fatty liver disease(NAFLD).It remains unknown whether dietary intake of condensed tannins(CTs)have distinguishable effects to alleviate... Free cholesterol has been considered to be a critical risk factor of nonalcoholic fatty liver disease(NAFLD).It remains unknown whether dietary intake of condensed tannins(CTs)have distinguishable effects to alleviate liver damage caused by a high cholesterol diet.Male C57BL/6 mice were fed a high cholesterol diet for 6 weeks,and given CTs treatment at a dosage of 200 mg/(kg·day)at the same time.The results indicated that compared with mice fed a normal diet,a high cholesterol diet group resulted in significant weight loss,dysregulation of lipid metabolism in blood and liver,and oxidative stress in the liver,but CTs treatment dramatically reversed these negative effects.Hematoxylin and eosin(H&E)staining and frozen section observation manifested that CTs treatment could effectively reduce the deposition of liver cholesterol and tissue necrosis caused by high cholesterol intake.CTs alleviated liver injury mainly by regulating the expression of related genes in cholesterol metabolism pathway and AMPK phosphorylation.Our results confirmed that CTs have remarkable cholesterol lowering and anti-liver injury effects in vivo. 展开更多
关键词 condensed tannins High cholesterol Liver injury ANTIOXIDANTS Transcriptomic analysis
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Structural Elucidation of the Polymeric Condensed Tannins of Acacia nilotica Subspecies by ^(13)C NMR, MALDI-TOF and TMA as Sources of Bioadhesives
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作者 Zeinab Osman Antonio Pizzi Bertrand Charrier 《Journal of Renewable Materials》 EI CAS 2024年第7期1291-1310,共20页
Tannin was extracted from different subspecies of Acacia nilotica,Acacia nilotica nilotica(Ann),Acacia nilotica tomentosa(Ant)and Acacia nilotica adansonii(Ana).The aim was to elucidate their structure and evaluate th... Tannin was extracted from different subspecies of Acacia nilotica,Acacia nilotica nilotica(Ann),Acacia nilotica tomentosa(Ant)and Acacia nilotica adansonii(Ana).The aim was to elucidate their structure and evaluate their reactivity as bioadhesives in the wood industry.The extracts were prepared by hot water extraction(90°C tem-perature).Their gel time with paraformaldehyde was used atfirst to compare their reactivity.The tannin contents and the percentage of total polyphenolic materials in different solutions of the extracts spray dried powder were determined by the hide powder method.Concentrated solutions(47%)were tested by both MALDI ToF,13CNMR.The thermomechanical analysis(TMA)was performed to evaluate their modulus of elasticity(MOE)at different pHs.The gel times of all the three tannin extracts showed that their reactivity and it was com-parable to other known procyanidin/prodelphinidin tannin extract types.Ana,Ann and Ant showed highest per-cent of total polyphenolic materials at 70%,64%,and 57%,respectively.The 13CNMR spectra showed that the three subspecies of condensed tannins were mainly constituted of procyanidins(PC)and prodelphinidins(PD)in slightly different ratios.Ann(56.5%PC and 43.4%PD),Ant(57%PC and 43%PD)and Ana(58%PC and 42%PD).MALDI–TOF spectra showed the presence offlavonoid monomers,and oligomers some of which linked to short carbohydrates monomers or dimers.TMA revealed that the three types of tannins had high MOE at their initial pH(5). 展开更多
关键词 Acacia nilotica condensed tannins PROCYANIDINS prodelphinidins 13C NMR MALDI-TOF
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A new model simulating the development of gas condensate reservoirs
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作者 Yang Yang Zengmin Lun +2 位作者 Rui Wang Maolei Cui Wei Hu 《Energy Geoscience》 EI 2024年第1期239-248,共10页
A new simulation model for the development of gas condensate reservoirs is introduced based on the influence that phase change,non-Darcy flow,and capillary pressure have on the production of gas condensates.The model ... A new simulation model for the development of gas condensate reservoirs is introduced based on the influence that phase change,non-Darcy flow,and capillary pressure have on the production of gas condensates.The model predicts well performance,including bottom-hole pressure,oil/gas production rate,oil/gas recovery,gaseoil ratio,and the change in produced fluid composition.It also calculates dynamic characters,such as the change of pressure field and oil/gas saturation field during the development of gas condensate reservoirs.The model is applicable to different boundary conditions(both constant-pressure and sealed boundary)and different production modes(both constant-pressure and constant-volume production modes).Model validation attempted using numerical simulation results for sealed boundary conditions with constant-pressure production mode has shown a relatively good match,proving its validity.For constant-pressure boundary conditions with constant-volume production mode,four stages are defined according to the dynamic behavior of production performance in the development of gas condensate reservoirs. 展开更多
关键词 Gas condensate reservoir Phase behavior Numerical simulation Pseudo-pressure method
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