Nitrogen rejection from low quality natural gas by pressure swing adsorption experiments and simulation using dynamic adsorption isotherms

In order to remove N_(2) from low quality natural gas,a mathematical model has been established by Aspen adsorption,using the CH_(4)-selective sorbent silicalite-1 pellets.The dynamic adsorption isotherm was first simulated by breakthrough simulation of a CH_(4)/N_(2) mixture at different adsorption pressures and feed flow rates based on breakthrough experiments.The resulting simulated CH_(4) dynamic adsorption amounts were very close to the experimental data at three different adsorption pressures(100,200,and 300 kPa).Moreover,a single-bed,three-step pressure swing adsorption(PSA)experiment was performed,and the results were in good agreement with the simulated data,further corroborating the accuracy of the gas dynamic adsorption isotherm obtained by the simulation method.Finally,based on the simulated dynamic adsorption isotherm of CH_(4) and N_(2),a four-bed,eight-step PSA process has been designed,which enriched 75%(vol)CH_(4) and 80%(vol)CH_(4) to 95%(vol)and 99%(vol),and provided 99%(vol)recovery.

Thermodynamic analysis and combined cycle research on recoverable pressure energy in natural gas pipeline

Current research and ways of capturing mechanical energy are discussed in this paper. By the aid of the comprehensive thermodynamic analysis and Aspen simulation tool, the amount of a vailable work that can be produced from capturing the pressure energy has been calculated. Based on the comprehensive thermodynamic analysis, two systems have been proposed to capture pressure energy of natural gas to generate electricity. In this study, the expression of exergy is given which can be used in evaluating purposes. A problem with this multidisciplinary study is the complicated boundary condition. In conclusion, a technical prospect on recoverable natural gas pressure energy has been presented based on total energy system theory.

A review of pressure transient analysis in reservoirs with natural fractures,vugs and/or caves

A review of the pressure transient analysis of flow in reservoirs having natural fractures,vugs and/or caves is presented to provide an insight into how much knowledge has been acquired about this phenomenon and to highlight the gaps still open for further research.A comparison-based approach is adopted which involved the review of works by several authors and identifying the limiting assumptions,model restrictions and applicability.Pressure transient analysis provides information to aid the identification of important features of reservoirs.It also provides an explanation to complex reservoir pressuredependent variations which have led to improved understanding and optimization of the reservoir dynamics.Pressure transient analysis techniques,however,have limitations as not all its models find application in naturally fractured and vuggy reservoirs as the flow dynamics differ considerably.Pollard’s model presented in 1953 provided the foundation for existing pressure transient analysis in these types of reservoirs,and since then,several authors have modified this basic model and come up with more accurate models to characterize the dynamic pressure behavior in reservoirs with natural fractures,vugs and/or caves,with most having inherent limitations.This paper summarizes what has been done,what knowledge is considered established and the gaps left to be researched on.

Natural Characteristic of Thin-Wall Pipe under Uniformly Distributed Pressure

Natural characteristics of thin?wall pipe of the compressor under uniformly distributed pressure were presented in this paper based on a cylindrical shell model. In the traditional method, the beam model was usually used to analyze the pipe system. In actual fact, the pipe segment of the compressor was always broken in the form of a long crack or a partial hole and the phenomenon was hardly explained by beam model. According to the structure characteristic of compressor pipe segment, whose radius is large and thickness is little, shell model shows the advantage in this kind of pipe problem. Based on Sanders’ shell theory, the vibration di erential equation of pipe was established by apply?ing the energy method. The influences of length to radius ratio(L/R), thickness to radius ratio(h/R), circumferential wave number(n) and pressure(q) on the natural frequencies of pipe were analyzed. The study shows: Pressure and structural parameters have a great e ect on the natural characteristics of the pipe. Natural frequency increases as the pressure increases, especially for the higher mode. The sensitivity of natural frequency on pressure becomes stronger with h/R ratio increases; when L/R ratio is greater than a certain critical value, the influence of the pressure on natural frequency will no longer be obvious. The value of n corresponding to the minimum natural frequency also depends on the value of pressure. In the end, analysis of the forced vibration of a specific pipeline model was given and the modal shapes were illustrated to understand the break of the pipe. The research here will provide the theory support for the dynamic design of related pressure pipe and further experiment study should be employed.

A study of hydrate plug formation in a subsea natural gas pipeline using a novel high-pressure flow loop

The natural gas pipeline from Platform QKI8-1 in the southwest of Bohai Bay to the onshore processing facility is a subsea wet gas pipeline exposed to high pressure and low temperature for a long distance. Blockages in the pipeline occur occasionally. To maintain the natural gas flow in the pipeline, we proposed a method for analyzing blockages and ascribed them to the hydrate formation and agglomeration. A new high-pressure flow loop was developed to investigate hydrate plug formation and hydrate particle size, using a mixture of diesel oil, water, and natural gas as experimental fluids. The influences of pressure and initial flow rate were also studied. Experimental results indicated that when the flow rate was below 850 kg/h, gas hydrates would form and then plug the pipeline, even at a low water content （10%） of a water/oil emulsion. Furthermore, some practical suggestions were made for daily management of the subsea pipeline.

Study on Pressure Swing Adsorption Removing C_(2)^(+) from Natural Gas as Raw Material for Thermal Chlorination

The experimental investigation demonstrates that a satisfactory result can be expected for pressure swing adsorption (PSA) purification of natural gas as raw material for thermal chlorination process. Using hh-4 molecular sieve as adsorbent for removing C+2 components, the suitable adsorption pressure is 0.4-0.45 MPa, desorption vacuum is 0.08-0.09 MPa and circulation time is 20-21 min.

Study on the nature of pressure signals in a bubbling fluidized bed

In this study on the nature of pressure signals generated by a deterministic or stochastic process in a bubbling fluidized bed, pressure fluctuation measurements were carried out in a 300-mm-diamet column at 0.090 m and 0.40 m above the distributor for different gas velocities. The method of detecting deterministic dynamic underlying pressure signals is proposed on the basis of predictability of pressure fluctuations. The deterministic nature of dynamics in fluidizing system was verified. The deterministic level of dynamics in fluidizing system was analyzed for different locations of pressure measurements and different gas velocities.

Theoretical investigation on the steady-state natural circulation characteristics of a new type of pressurized water reactor

This article presents a theoretical investigation on the steady-state natural circulation characteristics of a new type of pressurized water reactor. Through numerically solving the one-dimensional steady-state single-phase conservative equations for the primary circuit and the steady-state two-phase drift-flux conservative equations for the secondary side of the steam generator, the natural circulation characteristics were studied. On the basis of the pre- liminary calculation analysis, it was found that natural circulation mass flow rate was proportional to the exponential function of the power and that the value of the exponent is related to the operating conditions of the secondary side of the steam generator. The higher the outlet pressure of the secondary side of the steam generator, the higher the pri- mary natural circulation mass flow rate. The larger height difference between the core center and the steam generator center is favorable for the heat removal capacity of the natural circulation.

Rapidly Estimating Natural Gas Compressibility Factor

Natural gases containing sour components exhibit different gas compressibility factor （Z） behavior than do sweet gases. Therefore, a new accurate method should be developed to account for these differences. Several methods are available today for calculating the Z-factor from an equation of state. However, these equations are more complex than the foregoing correlations, involving a large number of parameters, which require more complicated and longer computations. The aim of this study is to develop a simplified calculation method for a rapid estimating Z-factor for sour natural gases containing as much as 90% total acid gas. In this article, two new correlations are first presented for calculating the pseudo- critical pressure and temperature of the gas mixture as a function of the gas specific gravity. Then, a simple correlation on the basis of the standard gas compressibility factor chart is introduced for a quick estimation of sweet gases＇ compressibility factor as a function of reduced pressure and temperature. Finally, a new corrective term related to the mole fractions of carbon dioxide and hydrogen sulfide is developed.

Evaluation of gas-liquid separation performance of natural gas filters

Fibrous filters are often used to remove contaminants including both dusts and liquid droplets from natural gas. This paper aims to evaluate the gas-liquid separation performance of three types of cartridge filters used in the West-East natural gas transmission project. The comparison of the original pressure drop of clean filters and the evolution of pressure drop as liquid droplets deposited in the filter media are described. The original pressure drops of these filters were similar but the pressure drops at a steady state were different. Fractional efficiency was used to study the separation performance of cartridge filters. Droplets at the outlet of the filters had small diameters, no more than 3 μm, but were very numerous. The effect of filtration velocity on gas-liquid separation performance was analyzed. Higher filtration velocity indicated better gas-liquid separation performance. Finally the quality factor related to pressure drop and filtration efficiency was applied to evaluate the gas-liquid separation performance.

Natural consolidation characteristics of viscous debris flow deposition

Pore water pressure and water content are important indicators to both deposition and consolidation of debris flows, enabling a direct assessment of consolidation degree. This article gained a more comprehensive understanding about the entire consolidation process and focused on exploring pore water pressure and volumetric water content variations of the deposit body during natural consolidation under different conditions taking the viscous debris flow mass as a study subject and by flume experiments. The results indicate that, as the color of the debris changed from initial dark green to grayish-white color, the initial deposit thickness declined by 3% and 2.8% over a permeable and impermeable sand bed, respectively. A positive correlation was observed between pore water pressure and depth in the deposit for both scenarios, with deeper depths being related to greater pore water pressure. For the permeable environment, the average dissipation rate of pore water pressure measured at depths of 0.10 m and 0.05 m were 0.0172 Pa/d and 0.0144 Pa/d, respectively, showing a positivechanging trend with increasing depth. Under impermeable conditions, the average dissipation rates at different depths were similar, while the volumetric water content in the deposit had a positive correlation with depth. The reduction of water content in the deposit accelerated with depth under impermeable sand bed boundary conditions, but was not considerably correlated with depth under permeable sand bed boundary conditions. However, the amount of discharged water from the deposit was greater and consolidation occurred faster in permeable conditions. This indicates that the permeability of the boundary sand bed has a significant impact on the progress of consolidation. This research demonstrates that pore water and pressure dissipations are present during the entire viscous debris consolidation process. Contrasting with dilute flows, pore pressure dissipation in viscous flows cannot be completed in a matter of minutes or even hours, requiring longer completion time — 3 to 5 days and even more. Additionally, the dissipation of the pore water pressure lagged the reduction of the water content. During the experiment, the dissipation rate fluctuated substantially, indicating a close relationship betweenthe dissipation process and the physical properties of broadly graded soils.

Research and application of thermal insulation effect of natural gas hydrate freezing corer based on the wireline-coring principle

Natural gas hydrate(NGH)holds great promise as a source of clean energy.It is critical for acquiring the largest possible in situ NGH core for NGH eigen features and resource assessment.However,the existing NGH coring technology has limitations,such as temperature increments,limited coring diameters,low coring rates,and complex coring structures.Therefore,this study designs and proposes an NGH freezing coring(NGHFC)method and verifies the freezing and coring capacities of the NGHFC method in laboratories and experimental wells.Results suggest that NGHFC shows good freezing and heat-retention properties.A freezing core heat transfer model is developed.According to the actual air temperature and operating time,the optimum initial temperature of the cold source can be determined using this model.The average coring rate of NGHFC can reach 77.86%.The research results will provide a new idea of coring gas hydrates.

Gas-water-rock interactions and factors affecting gas storage capacity during natural gas storage in a low permeability aquifer

Gas-water-rock interactions during natural gas storage in a low permeability aquifer and main factors affecting the storage capacity were investigated in laboratory with core experiments. The results showed that gas injection flow rate had a major impact on stored gas volume and stored gas volume is higher at high flow rate. Gas storage volume ranged between 6%-20% of the pore space at experimental condition. Enhancing injection pressure can enhance gas storage volume. Statistics showed that injection flow rate had a greater influence on the gas storage volume than pressure. The retention time also had an impact on the gas storage process. Most of the natural gas was trapped in the reservoir and could not be produced after long time of retention. Atomic absorption spectroscopy indicated that ions concentrations of the brine and water evaporation increased when gas was injected into brine saturated core, and precipitation might occur, reducing porosity and permeability of core. Gas chromatography analysis showed that the concentration of carbon dioxide in the natural gas decreased and the concentration of methane increased after storage in the core.

Thermodynamic Study on the Compositions of Fluid Phases in the C-O-H System Under High Temperature and Pressure

Based on the fluid phase equilibrium of the C-O-H system, the compositions of var-ious fluid phases under high temperatures and pressures have been calculated in terms of the available thermodynamic data and new P-V-T data and on the assumption of PT = ΣPi in this paper. The results indicate that in this system there are 5 major fluid phases in different pro-portions at various T and P. CH4 is the dominant phase (about 70% ) under relatively lower T and P. Its proportion obviously decreases with increasing T, P and fo2. The results pro-vide sufficient theoretical grounds for discussing the possibility of CH4 formation and the physical-chemical conditions of its stable occurrence and proportion in the geological environment.

The Relationship between Natural Resources and Population Development in Liaocheng City

According to the relevant data about the land resources and population in Liaocheng City from 1999 to 2008, by using the research method of bearing capacity of natural resources, the thesis analyzes the relationship between natural resources and dynamic change of population in Liaocheng City. The results show that the farmland tends to diminish on the whole, and forests, garden land, urban-rural settlements and land for enterprises and mining increase slowly. Based on the analysis of the dynamic relationship between land resources and population, we conclude that the land resources still can bear the current population in Liaocheng City, but the population development inflict critical pressure on the forest resources and water resources.

Mixture Preparation and Combustion of CNG Low-Pressure Compound Direct Injection Spark-Ignited Engines

A set of compressed natural gas (CNG) multi-point direct injection system of spark-ignited engines and the corresponding measurement and data acquisition systems were developed in this paper. Based on different injection modes, the mixture formation and combustion of CNG low-pressure direct injection (LPDI) engines were studied under varying factors such as air/ fuel ratio, injection timing. Meanwhile, three-dimensional simulations were adopted to explain the mixture formation mechanisms of CNG low-pressure compound direct injection (LPCDI) mode. On the basis of test results and simulation of the mixture homogeneous degree, the conception of injection window was proposed, and the LPCDI mode was proved to be more beneficial to the mixture concentration stratification formation in cylinder under lean-burning conditions, which resulted in effective combustion and stability.

Application of the Distance to Natural (D2N) Index and Statistical Analysis of Different Anthropic Uses of the Río Grande De Comitán Watershed, Chiapas, México

The intensification of anthropic uses (i.e., increase of the hemerobic condition) threatens the remnants of native vegetation due to the reduction of its self-regulation capacity. In this research, the Distance to Nature (D2N) index for land use and land cover was applied in the Río Grande de Comitán watershed (Southern Mexico) to answer the following questions: 1) What were the land use dynamics observed in the Rio Grande de Comitán watershed in the trajectory through 1999, 2009 and 2019? 2) Does the subcategorization of the D2N allow one to identify which anthropic uses influence more the territorial expression of the watershed? To answer these questions, we performed a supervised classification of land use and land cover was performed in this watershed, and for the D2N index, the classification was simplified to three-category scale for the subcategorization of the anthropic component. Through Principal Component Analysis (PCA), we identified that agricultural anthropogenic use had the greatest influence on territorial expression. The reported scenario indicates a trend of gradual and continuous reduction of naturalness over the last 20 years. Additionally, the D2N index proved to be a useful tool to demonstrate both the anthropic impact, with the simplified scale, and the component that most influences the territory, by subcategorizing the anthropic scale.

基于停泵压降数据的页岩气井单段裂缝参数反演——以长宁N209井区页岩气井为例

水平井多级分段多簇压裂是页岩气藏有效开发的关键技术,准确评价缝网参数是开展压裂效果评估、压裂工艺优化和压后产能预测等工作的重要前提.传统页岩气井压裂裂缝参数表征主要采用裂缝扩展模拟与现场监测等手段,对压裂施工停泵压降曲线的信息挖掘与利用不足.采用数字滤波方法消除停泵压降数据的水锤波动,利用分形裂缝表征页岩气井压裂缝网,结合数值试井分析实现了单段裂缝参数反演,建立了一套基于停泵压降数据的缝网参数反演工作流程.该成果在长宁公司N209井区压裂井成功应用,并对裂缝参数评价结果与一体化压裂模拟和产气剖面测试等反演结果进行了验证.结果表明,基于停泵阶段压降数据的单段裂缝参数反演结果显著提升了参数解释精度,有助于揭示页岩气井段间产气能力差异的原因;气井产能与裂缝总长和裂缝表面积的相关性明显高于利用广域电磁法确定的压裂改造体积,其中,早期日产气量与总缝长相关性最高;预计最终回收率与裂缝表面积相关性最高;缝网总长与单簇压裂液规模强线性相关,反映了长宁区块页岩气井压裂工艺2.0的技术先进性.获取页岩气井单段裂缝参数可为产能主控因素分析和压裂效果评价提供更加有效的分析指标.

致密砂岩气运移的临界动力学条件探讨

物理模拟是认识地下油气运移和聚集机理的重要方法和手段,为了更深入地认识深层条件下致密储层天然气运移的机理,以延安气田上古生界山西组致密砂岩气为例,设计了实验模型和边界条件。基于超低渗岩石多相渗流核磁共振在线模拟实验,探讨致密砂岩中天然气运移的临界压力、临界物性动力学条件,进而分析影响天然气运聚的控制因素。选取山西组不同砂岩类型包括石英净砂岩、富石英低塑性颗粒岩屑石英砂岩、富塑性颗粒岩屑砂岩和富凝灰质杂基石英砂岩样品,代表不同孔渗分布区间的岩石相储层,进行了恒定低注入流量、不同流速(流量)和不同压差充注实验。结果表明,致密砂岩储层的临界充注压力主要受岩石相和渗透率控制,渗透率较高的优势岩石相具有更低的临界充注压力,石英净砂岩天然气临界注入压力一般小于1.2 MPa,即使是物性很差的富塑性颗粒岩屑砂岩和富凝灰质杂基石英砂岩的天然气临界注入压力一般也小于1.5 MPa。同时,致密砂岩也没有绝对的天然气充注物性下限,但致密砂岩的充注效率、含气饱和度与储层物性,尤其是渗透率呈正相关,优势岩石相越发育、渗透率越高,充注效率和含气饱和度也越高。

深井自然风压数值模拟及计算模型研究

对处于基建期的鑫汇金矿自然风压进行现场测试,获取夏季及冬季自然风压数值。采用fluent软件进行建模,用现场测得的自然风压数据验证模型的可靠性。在此基础上,通过正交模拟实验探究入风温度、热源热量、地温梯度、相对湿度对深井自然风压的影响。极差分析结果表明,各因素对深井自然风压的影响程度为:冬季入风温度>热源热量>地温梯度>相对湿度;夏季热源热量>入风温度>地温梯度>相对湿度。利用SPSS软件对正交实验数据进行拟合,并结合现场实测数据,建立了鑫汇金矿深井自然风压计算模型,为鑫汇金矿深部矿区通风系统的设计和风机选型提供了理论依据。