To meet the requirements of marine natural gas hydrate exploitation,it is necessary to improve the penetration of completion sand control string in the large curvature borehole.In this study,large curvature test wells...To meet the requirements of marine natural gas hydrate exploitation,it is necessary to improve the penetration of completion sand control string in the large curvature borehole.In this study,large curvature test wells were selected to carry out the running test of sand control string with pre-packed screen.Meanwhile,the running simulation was performed by using the Landmark software.The results show that the sand control packer and screen can be run smoothly in the wellbore with a dogleg angle of more than 20°/30 m and keep the structure stable.Additionally,the comprehensive friction coefficient is 0.4,under which and the simulation shows that the sand control string for hydrate exploitation can be run smoothly.These findings have important guiding significance for running the completion sand control string in natural gas hydrate exploitation.展开更多
Regression Analysis of Ashaka Clay-Bonded Sand has been successfully carried out. The study data were generated at the National Metallurgical Development Centre, Jos Sand Testing Laboratory. The result of the regressi...Regression Analysis of Ashaka Clay-Bonded Sand has been successfully carried out. The study data were generated at the National Metallurgical Development Centre, Jos Sand Testing Laboratory. The result of the regression analysis showed that both dry compression strength and dry shear strength have a very strong relationship with clay content and moisture content. The correlation coefficient, coefficient of determination and the coefficient of multiple determination in each relationship was very high. The coefficient of multiple determination for the relationship between dry compression strength, clay content and moisture content was 0.91, while that of dry shear strength, clay and moisture content was 0.97. Two mathematical models have been developed for the estimation of dry compression strength and dry shear strength on the shop floor.展开更多
Thomas Hobbes(1588-1679)put forward"state of nature",a term of political theory which had completely changed the Western political philosophy. Deeply influenced by this concept, Daniel Defoe(1660-1731) showe...Thomas Hobbes(1588-1679)put forward"state of nature",a term of political theory which had completely changed the Western political philosophy. Deeply influenced by this concept, Daniel Defoe(1660-1731) showed us an island of the state of nature in his Robinson Crusoe. A print of man's foot on the sand, which evoked Robinson's fear, had become a symbol of the state of nature for Robinson's life on the island, and finally brought him a"state of war".展开更多
Natural radioactivity is very important for the assessment of the marine sand property and usability. By using gamma spectrometry, the concentration of the natural radionuclides 226Ra, 232Th and 40K have been measured...Natural radioactivity is very important for the assessment of the marine sand property and usability. By using gamma spectrometry, the concentration of the natural radionuclides 226Ra, 232Th and 40K have been measured in marine sand deposits from Liaodong Bay (LDB), North Yellow Sea (NYS), Zhoushan area (ZS), Taiwan Shoal (TS) and Pearl River Mouth (PR), offshore China, which are potential marine sand mining areas. The radiation activity equivalent (Raeq), indoor gamma absorbed dose rate (DR), annual effective dose (HR), alpha index (Ia), gamma index (Ig), external radiation hazard index (Hex), internal radiation hazard index (Hin), representative level index (RLI), excess lifetime cancer risk (ELCR) and annual gonadal dose equivalent (AGDE) associated with the natural radionuclides are calculated to assess the radiation hazard of the natural radioactivity in the marine sands offshore China. From the analysis, it is found that these marine sands are safe for the constructions. The Pearson correlation coefficient reveals that the 226Ra distribution in the marine sands offshore China is controlled by the variation of the 40K concentration. Principal component analysis (PCA) yields a two-component representation of the entire data from the marine sands, wherein 98.22% of the total variance is explained. Our results provide good baseline data to expand the database of radioactivity of building materials in China and all over the world.展开更多
Sand production is one of the main obstacles restricting gas extraction efficiency and safety from marine natural gas hydrate(NGH)reservoirs.Particle migration within the NGH reservoir dominates sand production behavi...Sand production is one of the main obstacles restricting gas extraction efficiency and safety from marine natural gas hydrate(NGH)reservoirs.Particle migration within the NGH reservoir dominates sand production behaviors,while their relationships were rarely reported,severely constrains quantitative evaluation of sand production risks.This paper reports the optical observations of solid particle migration and production from micrometer to mesoscopic scales conditioned to gravel packing during depressurization-induced NGH dissociation for the first time.Theoretical evolutionary modes of sand migration are established based on experimental observations,and its implications on field NGH are comprehensively discussed.Five particle migration regimes of local borehole failure,continuous collapse,wormhole expansion,extensive slow deformation,and pore-wall fluidization are proved to occur during depressurization.The types of particle migration regimes and their transmission modes during depressurization are predominantly determined by initial hydrate saturation.In contrast,the depressurization mainly dominates the transmission rate of the particle migration regimes.Furthermore,both the cumulative mass and the medium grain size of the produced sand decrease linearly with increasing initial methane hydrate(MH)saturation.Discontinuous gas bubble emission,expansion,and explosion during MH dissociation delay sand migration into the wellbore.At the same time,continuous water flow is a requirement for sand production during hydrate dissociation by depressurization.The experiments enlighten us that a constitutive model that can illustrate visible particle migration regimes and their transmission modes is urgently needed to bridge numerical simulation and field applications.Optimizing wellbore layout positions or special reservoir treatment shall be important for mitigating sand production tendency during NGH exploitation.展开更多
Natural radioactivity is a source of continuous exposure to human beings. The natural radioactivity due to the presence of 226Ra, 232Th and 40K in sand samples collected from Ad-Dahna was measured by means of HPGe. Th...Natural radioactivity is a source of continuous exposure to human beings. The natural radioactivity due to the presence of 226Ra, 232Th and 40K in sand samples collected from Ad-Dahna was measured by means of HPGe. The measured activity concentrations of radionuclides were compared with the worldwide reported data. Mean measured activity concentrations of 226Ra, 232Th and 40K varied between 16.2 - 30.6, 15.8 - 36.7 and 285.3 - 533.2 Bq·kg–1 respectively with a mean value of 23.4 ± 4.3 Bq·kg–1, 29.7 ± 5.9 Bq·kg–1 and 380 ± 65 Bq·kg–1 respectively. Mean values of radium equivalent activity, absorbed dose rate and external radiation hazard index were 106 ± 8 Bq·kg–1, 51.4 nGy·h–1 and 0.29 respectively. The annual effective radiation dose was calculated to be 0.32 mSv·y–1. The Raeq values of sand samples are lower than the limit of 370 Bq·kg–1, equivalent to a gamma dose of 1.5 mSv·yr–1.This study shows that the measured sand samples do not pose any significant source of radiation hazard and are safe for use in building materials.展开更多
Hydroquinone (HQ) is the most important hydroxy aromatic compound which is produced on a large scale. Understanding its fate in the environment is therefore of primary importance to prevent its migration in the soil a...Hydroquinone (HQ) is the most important hydroxy aromatic compound which is produced on a large scale. Understanding its fate in the environment is therefore of primary importance to prevent its migration in the soil and/or the contamination of the aquatic ecosystems. Here we present a column based method to investigate the physicochemical processes controlling the removal from the aqueous phase and the adsorption onto natural quartz sand (NQS), of organic pollutant such as HQ molecules. We will focus on the interactions that occur between the organic pollutant and the NQS substrate. Thus, column reactors filled with NQS were used to investigate the influence of physicochemical parameters such as the ionic strength, the pH, the flow rate, and the nature of the electrolyte cation, on the HQ adsorption from water onto NQS substrate. The data indicate that, when divalent instead of monovalent cations, are present in the effluent water injection phase, and/or when the ionic strength of the effluent increases, the adsorbed HQ amount decreases. Similar decrease of the adsorbed HQ amount was also observed, at constant ionic strength, by increasing either, the pH from 3 to 9, the flow rate Q from 1 to 3 ml·mn-1, or by decreasing the HQ initial concentration, C0 from 30 to 6 mg·L-1. Further, large amount of the organic pollutant (up to 93 wt% of HQ molecules) was removed from the effluent water phase by using NQS column. The overall data seem to indicate that the adsorption of HQ molecules on the NQS surface is mainly controlled by electrostatic interaction forces occurring between the organic molecule polar groups and the inorganic matrix silanol groups.展开更多
Geotechnical and geochemical assessment of natural sands being used as fine aggregates for construction purposes in Ahanta West and its Environs was carried out, as well as addressing the environmental problems associ...Geotechnical and geochemical assessment of natural sands being used as fine aggregates for construction purposes in Ahanta West and its Environs was carried out, as well as addressing the environmental problems associated with the exploitation of these sand through the sand winning activities. The results from geotechnical and geochemical tests were bench marked with British, American and Ottawa Standards for testing materials. Representative samples were taken from five different sand winning sites namely, Pompuni, Agona Banso, Fretsi, Tumentu stream and Fretsi river. The geotechnical tests carried out were specific gravity, grain size analysis, moisture content, silt content, permeability test using the constant head permeameter method. The photometer (Hydro Test HT 1000) was used to determine silica, sulphate and chloride concentrations in the sand samples. The oxides for the geochemical analysis w</span><span style="font-family:"">ere</span><span style="font-family:""> determined using the X-ray fluorescence (XRF) method. The results from the study areas showed that except for Fretsi, the specific gravity, grain size analysis, moisture content, silt content and permeability tests were within the acceptable range for natural sands. Sand samples from Pumponi and Agona Banso had the required Cu and Cc values of being well graded. Sulphate and chloride concentrations were within standards for all the samples;however, silica was low for all the samples. Fe<sub>2</sub>O<sub>3</sub>, Al<sub>2</sub>O<sub>3</sub>, MnO and Na<sub>2</sub>O did not meet the Ottawa sand standard. Natural sand is not recommended to be used for construction purpose</span><span style="font-family:"">s</span><span style="font-family:""> however, these sands may be treated or blended if it is to be used for construction purposes. There are serious environmental implications for the sand</span><span style="font-family:"">-</span><span style="font-family:"">winning activities in the study areas such as stripped overburden, creation of pits and ponds, increased total suspended solids in surface waters, and destruction of aquatic habitats which needs to be addressed.展开更多
基金supported jointly by one of the major projects of Basic and Applied Basic Research in Guangdong Province“Key Basic Theory Research for Natural Gas Hydrate Trial Production in Shenhu Pilot Test Area”(2020B0301030003)the project from Southern Marine Science&Engineering Guangdong Laboratory Guangzhou City“Research on New Closed Circulation Drilling Technology without Riser”(GML2019ZD0501)the special project for hydrate from China Geological Survey“Trial Production Implementation for Natural Gas Hydrate in Shenhu Pilot Test Area”(DD20190226)。
文摘To meet the requirements of marine natural gas hydrate exploitation,it is necessary to improve the penetration of completion sand control string in the large curvature borehole.In this study,large curvature test wells were selected to carry out the running test of sand control string with pre-packed screen.Meanwhile,the running simulation was performed by using the Landmark software.The results show that the sand control packer and screen can be run smoothly in the wellbore with a dogleg angle of more than 20°/30 m and keep the structure stable.Additionally,the comprehensive friction coefficient is 0.4,under which and the simulation shows that the sand control string for hydrate exploitation can be run smoothly.These findings have important guiding significance for running the completion sand control string in natural gas hydrate exploitation.
文摘Regression Analysis of Ashaka Clay-Bonded Sand has been successfully carried out. The study data were generated at the National Metallurgical Development Centre, Jos Sand Testing Laboratory. The result of the regression analysis showed that both dry compression strength and dry shear strength have a very strong relationship with clay content and moisture content. The correlation coefficient, coefficient of determination and the coefficient of multiple determination in each relationship was very high. The coefficient of multiple determination for the relationship between dry compression strength, clay content and moisture content was 0.91, while that of dry shear strength, clay and moisture content was 0.97. Two mathematical models have been developed for the estimation of dry compression strength and dry shear strength on the shop floor.
文摘Thomas Hobbes(1588-1679)put forward"state of nature",a term of political theory which had completely changed the Western political philosophy. Deeply influenced by this concept, Daniel Defoe(1660-1731) showed us an island of the state of nature in his Robinson Crusoe. A print of man's foot on the sand, which evoked Robinson's fear, had become a symbol of the state of nature for Robinson's life on the island, and finally brought him a"state of war".
文摘Natural radioactivity is very important for the assessment of the marine sand property and usability. By using gamma spectrometry, the concentration of the natural radionuclides 226Ra, 232Th and 40K have been measured in marine sand deposits from Liaodong Bay (LDB), North Yellow Sea (NYS), Zhoushan area (ZS), Taiwan Shoal (TS) and Pearl River Mouth (PR), offshore China, which are potential marine sand mining areas. The radiation activity equivalent (Raeq), indoor gamma absorbed dose rate (DR), annual effective dose (HR), alpha index (Ia), gamma index (Ig), external radiation hazard index (Hex), internal radiation hazard index (Hin), representative level index (RLI), excess lifetime cancer risk (ELCR) and annual gonadal dose equivalent (AGDE) associated with the natural radionuclides are calculated to assess the radiation hazard of the natural radioactivity in the marine sands offshore China. From the analysis, it is found that these marine sands are safe for the constructions. The Pearson correlation coefficient reveals that the 226Ra distribution in the marine sands offshore China is controlled by the variation of the 40K concentration. Principal component analysis (PCA) yields a two-component representation of the entire data from the marine sands, wherein 98.22% of the total variance is explained. Our results provide good baseline data to expand the database of radioactivity of building materials in China and all over the world.
基金supported by the Laoshan Laboratory(No.LSKJ LSKJ202203506)the Taishan Scholars Program,and the National Natural Science Foundation of China(Grant No.41976074).
文摘Sand production is one of the main obstacles restricting gas extraction efficiency and safety from marine natural gas hydrate(NGH)reservoirs.Particle migration within the NGH reservoir dominates sand production behaviors,while their relationships were rarely reported,severely constrains quantitative evaluation of sand production risks.This paper reports the optical observations of solid particle migration and production from micrometer to mesoscopic scales conditioned to gravel packing during depressurization-induced NGH dissociation for the first time.Theoretical evolutionary modes of sand migration are established based on experimental observations,and its implications on field NGH are comprehensively discussed.Five particle migration regimes of local borehole failure,continuous collapse,wormhole expansion,extensive slow deformation,and pore-wall fluidization are proved to occur during depressurization.The types of particle migration regimes and their transmission modes during depressurization are predominantly determined by initial hydrate saturation.In contrast,the depressurization mainly dominates the transmission rate of the particle migration regimes.Furthermore,both the cumulative mass and the medium grain size of the produced sand decrease linearly with increasing initial methane hydrate(MH)saturation.Discontinuous gas bubble emission,expansion,and explosion during MH dissociation delay sand migration into the wellbore.At the same time,continuous water flow is a requirement for sand production during hydrate dissociation by depressurization.The experiments enlighten us that a constitutive model that can illustrate visible particle migration regimes and their transmission modes is urgently needed to bridge numerical simulation and field applications.Optimizing wellbore layout positions or special reservoir treatment shall be important for mitigating sand production tendency during NGH exploitation.
文摘Natural radioactivity is a source of continuous exposure to human beings. The natural radioactivity due to the presence of 226Ra, 232Th and 40K in sand samples collected from Ad-Dahna was measured by means of HPGe. The measured activity concentrations of radionuclides were compared with the worldwide reported data. Mean measured activity concentrations of 226Ra, 232Th and 40K varied between 16.2 - 30.6, 15.8 - 36.7 and 285.3 - 533.2 Bq·kg–1 respectively with a mean value of 23.4 ± 4.3 Bq·kg–1, 29.7 ± 5.9 Bq·kg–1 and 380 ± 65 Bq·kg–1 respectively. Mean values of radium equivalent activity, absorbed dose rate and external radiation hazard index were 106 ± 8 Bq·kg–1, 51.4 nGy·h–1 and 0.29 respectively. The annual effective radiation dose was calculated to be 0.32 mSv·y–1. The Raeq values of sand samples are lower than the limit of 370 Bq·kg–1, equivalent to a gamma dose of 1.5 mSv·yr–1.This study shows that the measured sand samples do not pose any significant source of radiation hazard and are safe for use in building materials.
文摘Hydroquinone (HQ) is the most important hydroxy aromatic compound which is produced on a large scale. Understanding its fate in the environment is therefore of primary importance to prevent its migration in the soil and/or the contamination of the aquatic ecosystems. Here we present a column based method to investigate the physicochemical processes controlling the removal from the aqueous phase and the adsorption onto natural quartz sand (NQS), of organic pollutant such as HQ molecules. We will focus on the interactions that occur between the organic pollutant and the NQS substrate. Thus, column reactors filled with NQS were used to investigate the influence of physicochemical parameters such as the ionic strength, the pH, the flow rate, and the nature of the electrolyte cation, on the HQ adsorption from water onto NQS substrate. The data indicate that, when divalent instead of monovalent cations, are present in the effluent water injection phase, and/or when the ionic strength of the effluent increases, the adsorbed HQ amount decreases. Similar decrease of the adsorbed HQ amount was also observed, at constant ionic strength, by increasing either, the pH from 3 to 9, the flow rate Q from 1 to 3 ml·mn-1, or by decreasing the HQ initial concentration, C0 from 30 to 6 mg·L-1. Further, large amount of the organic pollutant (up to 93 wt% of HQ molecules) was removed from the effluent water phase by using NQS column. The overall data seem to indicate that the adsorption of HQ molecules on the NQS surface is mainly controlled by electrostatic interaction forces occurring between the organic molecule polar groups and the inorganic matrix silanol groups.
文摘Geotechnical and geochemical assessment of natural sands being used as fine aggregates for construction purposes in Ahanta West and its Environs was carried out, as well as addressing the environmental problems associated with the exploitation of these sand through the sand winning activities. The results from geotechnical and geochemical tests were bench marked with British, American and Ottawa Standards for testing materials. Representative samples were taken from five different sand winning sites namely, Pompuni, Agona Banso, Fretsi, Tumentu stream and Fretsi river. The geotechnical tests carried out were specific gravity, grain size analysis, moisture content, silt content, permeability test using the constant head permeameter method. The photometer (Hydro Test HT 1000) was used to determine silica, sulphate and chloride concentrations in the sand samples. The oxides for the geochemical analysis w</span><span style="font-family:"">ere</span><span style="font-family:""> determined using the X-ray fluorescence (XRF) method. The results from the study areas showed that except for Fretsi, the specific gravity, grain size analysis, moisture content, silt content and permeability tests were within the acceptable range for natural sands. Sand samples from Pumponi and Agona Banso had the required Cu and Cc values of being well graded. Sulphate and chloride concentrations were within standards for all the samples;however, silica was low for all the samples. Fe<sub>2</sub>O<sub>3</sub>, Al<sub>2</sub>O<sub>3</sub>, MnO and Na<sub>2</sub>O did not meet the Ottawa sand standard. Natural sand is not recommended to be used for construction purpose</span><span style="font-family:"">s</span><span style="font-family:""> however, these sands may be treated or blended if it is to be used for construction purposes. There are serious environmental implications for the sand</span><span style="font-family:"">-</span><span style="font-family:"">winning activities in the study areas such as stripped overburden, creation of pits and ponds, increased total suspended solids in surface waters, and destruction of aquatic habitats which needs to be addressed.