To identify the species in liquid surface using mass spectrometry,we must eliminate or reduce interferences during the vaporization or desorption of the species from the liquid surface.It is much more challenging to i...To identify the species in liquid surface using mass spectrometry,we must eliminate or reduce interferences during the vaporization or desorption of the species from the liquid surface.It is much more challenging to isolate the ionic,larger species from the liquid surface,because of the frangible structures and the higher solvation energies of those species.Here we demonstrate a new mass spectrometry in which the ionic species at the liquid surface can be desorbed with ultrasoft infrared picosecond laser pulses while the liquid surface is not breached.This laser desorption assisted mass spectrometry is not only a powerful tool to detect the fragile species but also promising to investigate vibrational energy transfer dynamics in the liquid surface.展开更多
AIM： To evaluate the reproducibility of a modified 13^C breath test-based measurement of solid phase gastric emptying （GE） within the frames of a simple-repeated measure study protocol. METHODS： Twelve healthy sub...AIM： To evaluate the reproducibility of a modified 13^C breath test-based measurement of solid phase gastric emptying （GE） within the frames of a simple-repeated measure study protocol. METHODS： Twelve healthy subjects （6 females and 6 males, mean age 24.9＋0.7 years） were recruited to undergo three identical GE examinations. In six subjects the first two examinations were performed 2 d apart, and the third session was carried out at a median interval of 19.5 d （range 18 - 20 d） from the second one. In another six subjects the first two measurements were taken 20 d apart （median, range： 17-23 d）, whereas the third session took place 2 d after the second one. Probes of expiratory air collected before and during six hours after intake of a solid meal （378 kcal） labelled with 75 μL （68 mg） 13^C-octanoic acid, were measured for 13^CO2 enrichment with the nondispersive isotopeselective infrared spectrometry NDIRS apparatus. RESULTS： Taking coefficients of variation for paired examinations into account, the short-term reproducibility of the GE measurement was slightly but not significantly better than the medium-term one： 7.7% and 11.2% for the lag phase （T-Lag）, 7.3% and 10.9% for the gastric half emptying time （T1/2）. The least differences in GE parameters detectable at P= 0.05 level in the 12 paired examinations were 9.6 and 15.6 min for T-Lag, 11.6 and 19.7 min for T1/2 by a two-day or two to three-week time gap, respectively CONCLUSION： The low-cost modification of the breath test involving a lower dose of 13^C-octanoic acid and NDIRS, renders good short- and medium-term reproducibility, as well as sensitivity of the measurement of gastric emptying of solids.展开更多
To rapidly determine the pollution extent of wastewater, the calibration models were established for deter-mination of Chemical Oxygen Demand and Biological Oxygen Demand in wastewater by partial least squares and nea...To rapidly determine the pollution extent of wastewater, the calibration models were established for deter-mination of Chemical Oxygen Demand and Biological Oxygen Demand in wastewater by partial least squares and near infrared spectrometry of 120 samples. Spectral data preprocessing and outliers’ diagnosis were also discussed. Correlation coefficients of the models were 0.9542 and 0.9652, and the root mean square error of prediction (RMSEP) were 25.24 mg?L-1 and 12.13 mg?L-1 in the predicted range of 28.40~528.0 mg?L-1 and 16.0~305.2 mg?L-1 for Chemical Oxygen Demand and Biological Oxygen Demand, respectively. By statistical significance test, the results of determination were compared with those of stan-dard methods with no significant difference at 0.05 level. The method has been applied to simultaneous de-termination of Chemical Oxygen Demand and Biological Oxygen Demand in wastewater with satisfactory results.展开更多
Methanol oxidation reaction （MOR） at Pt and Pt electrode surface deposited with various amounts of Ru （denoted as PtxRuy, nominal coverage y is 0.17, 0.27, and 0.44 ML） in 0.1 mol/L HClO4＋0.5 mol/L MeOH has been ...Methanol oxidation reaction （MOR） at Pt and Pt electrode surface deposited with various amounts of Ru （denoted as PtxRuy, nominal coverage y is 0.17, 0.27, and 0.44 ML） in 0.1 mol/L HClO4＋0.5 mol/L MeOH has been studied under potentiostatic conditions by in situ FTIR spectroscopy in attenuated-total-reflection con guration and di erential electro-chemical mass spectrometry under controlled flow conditions. Results reveal that （i） CO is the only methanol-related adsorbate observed by IR spectroscopy at all the Pt and PtRu electrodes examined at potentials from 0.3 V to 0.6 V （vs. RHE）; （ii） at Pt0.56Ru0.44, two IR bands, one from CO adsorbed at Ru islands and the other from COL at Pt substrate are detected, while at other electrodes, only a single band for COL adsorbed at Pt is observed; （iii） MOR activity decreases in the order of Pt0.73Ru0.27〉Pt0.56Ru0.44〉Pt0.83Ru0.17〉Pt; （iv） at 0.5 V, MOR at Pt0.73Ru0.27 reaches a current e ciency of 50% for CO2 production, the turn-over frequency from CH3OH to CO2 is ca. 0.1 molecule/（site sec）. Suggestions for further improving of PtRu catalysts for MOR are provided.展开更多
Coal mine fires,which can cause heavy casualties,environmental damages and a waste of coal resources,have become a worldwide problem.Aiming at overcoming the drawbacks,such as a low analysis efficiency,poor stability ...Coal mine fires,which can cause heavy casualties,environmental damages and a waste of coal resources,have become a worldwide problem.Aiming at overcoming the drawbacks,such as a low analysis efficiency,poor stability and large monitoring error,of the existing underground coal fire monitoring technology,a novel monitoring system based on non-dispersive infrared(NDIR)spectroscopy is developed.In this study,first,the measurement principle of NDIR sensor,the gas concentration calculation and its temperature compensation algorithms were expounded.Next,taking CO and CH_(4) as examples,the liner correlation coefficients of absorbance and the temperature correction factors of the two indicator gases were calculated,and then the errors of concentration measurement for CO,CO_(2),CH_(4) and C_(2)H_(4) were further analyzed.The results disclose that the designed NDIR sensors can satisfy the requirements of industrial standards for monitoring the indicator gases for coal fire hazards.For the established NDIR-based monitoring system,the NDIRbased spectrum analyzer and its auxiliary equipment boast intrinsically safe and explosion-proof performances and can achieve real-time and in-situ detection of indicator gases when installed close to the coal fire risk area underground.Furthermore,a field application of the NDIR-based monitoring system in a coal mine shows that the NDIR-based spectrum analyzer has a permissible difference from the chromatography in measuring the concentrations of various indicator gases.Besides,the advantages of high accuracy,quick analysis and excellent security of the NDIR-based monitoring system have promoted its application in many coal mines.展开更多
WnC0＇± （n= 1-6） clusters are investigated by using the density functional theory （DFT） at the B3LYP/LANL2DZ level. We find that the neutral, anionic and cationic ground state structures are similar within th...WnC0＇± （n= 1-6） clusters are investigated by using the density functional theory （DFT） at the B3LYP/LANL2DZ level. We find that the neutral, anionic and cationic ground state structures are similar within the same size, and constituted by substituting a C atom for one W atom in the structures of Wn＋1 clusters. The natural bond orbital （NBO） charge analyses indicate that the direction of electron transfer is from the W atom to the 2p orbital of the C atom. In addition, the calculated infrared spectra of the WnC0＇± （n= 2-6） clusters manifest that the vibrational frequencies of neutral, anionic and cationic clusters are similar in a range of 80 cm-1-864 cm-1. The high frequency, strong peak modes are found to be an almost stretched deformation of the carbide atom. Finally, the polarizabilities of WnC0＇± （n= 1-6） clusters are also discussed.展开更多
The authentication of milk requires the use of sophisticated and expensive analytical techniques. There is a huge need for reliable and cheap analytical technologies for use as fast and effective screening methods. Th...The authentication of milk requires the use of sophisticated and expensive analytical techniques. There is a huge need for reliable and cheap analytical technologies for use as fast and effective screening methods. This paper proposes the use of myristic acid in the authentication of cow, mare, camel and goat milk, using near infrared spectrometry. Comparison has been made with traditional gas chromatography methods, so that both methods can be used in the authentication of different types of dairy products.展开更多
To obtain excellent performance optical fiber couplers, the structural difference of SiO2 in couplers with different manufacturing techniques was investigated. With 740-FT-IR infrared spectrometric analyzer, the infra...To obtain excellent performance optical fiber couplers, the structural difference of SiO2 in couplers with different manufacturing techniques was investigated. With 740-FT-IR infrared spectrometric analyzer, the infrared absorption spectrum of SiO2 in couplers at different drawing velocities was measured, and two characteristic peaks in the wavenumber range of 6502000 cm-1 were observed. One characteristic peak is at about 943 cm-1, which is （attributed） to Si—O—Si bond asymmetric stretching vibration, the other is at about 773 cm-1, which is attributed to （Si—O—Si） bond symmetric stretching vibration. From the infrared spectrum, it is found that the intensity and wavenumber of the characteristic peaks are related to the manufacturing technique of couplers. The characteristic peak at （about） 943 cm-1 becomes steeper when increasing the drawing velocity. At the drawing velocity of 150 μm/s, the distance between the two characteristic peaks is maximum, and then the optical fiber coupler has excellent performance, indicating that the performance of the optical fiber coupler has a close relationship with the wavenumber of the two characteristic peaks.展开更多
We present the results obtained from extensive near-infrared （IR） spectro- scopic and photometric observations of the Be/X-ray binary A0535＋262/HDE 245770 at different phases of its - 111 d orbital period. This obs...We present the results obtained from extensive near-infrared （IR） spectro- scopic and photometric observations of the Be/X-ray binary A0535＋262/HDE 245770 at different phases of its - 111 d orbital period. This observation campaign is part of the monitoring program of selective Be/X-ray binary systems aimed at understanding X-ray and near-IR properties at different orbital phases, especially during the perias- tron passage of the neutron star. The near-IR observations presented here were carried out using the 1.2 m telescope at the Mt. Abu IR Observatory. Though the source was relatively faint for spectroscopic observations with the 1.2 m telescope, we monitored the source closely during the 2011 February-March giant X-ray outburst to primarily investigate whether any drastic changes in the near-IR JHK spectra took place at the periastron passage. Changes of such a striking nature were expected to be detectable in our spectra. Photometric observations of the Be star show a gradual and systematic fading in the JHK light curves since the onset of the X-ray outburst, which could suggest a mild evacuation/truncation of the circumstellar disk of the Be companion. Near-IR spectroscopy of the object shows that the JHK spectra are dominated by the emission lines of hydrogen Brackett and Paschen series and HeI lines at 1.0830, 1.7002 and 2.0585 μm. The presence of all the hydrogen emission lines in the JHK spectra, along with the absence of any significant change in the continuum of the Be companion during X-ray quiescent and X-ray outburst phases, suggests that the near- IR line emitting regions of the disk are not significantly affected during the X-ray outburst.展开更多
We present a stellar population synthesis study of a type II luminous infrared galaxy, IRAS F21013-0739. Optical images show clear characteristics of a merger remnant. The H-band absolute magnitude is MH = -25.1, whic...We present a stellar population synthesis study of a type II luminous infrared galaxy, IRAS F21013-0739. Optical images show clear characteristics of a merger remnant. The H-band absolute magnitude is MH = -25.1, which is -2 times as luminous as L＊ galaxies. Stellar populations are obtained through the stellar synthesis code STARLIGHT. We find that it experienced a recent starburst （SB） phase - 100 Myr ago. By reconstructing the ultraviolet-to-optical spectrum, and adopting Calzetti et al. and Leitherer et al.＇s extinction curves, we estimate the past infrared （IR） luminosities of the host galaxy and find it may have experienced an ultraluminous infrared galaxy phase which lasted for about 100 Myr. Its i-band absolute magnitude is Mi = -22.463, and its spectral type shows type 2 active galactic nucleus （AGN） characteristics. The mass of the supermassive black-hole is estimated to be MBH = 1.6 × 107 M⊙ （lower- limit）. The Eddington ratio Lbol/LEdd is 0.15, which is typical of Palomar-Green （PG） quasars. Both the nuclear SB and AGN contribute to the present IR luminosity budget, and the SB contributes -67%. On the diagram of IR color versus IR/opfical excess, it is located between IR quasars and PG quasars. These results indicate that IRAS F21013-0739 has probably evolved from a ULIRG, and it can possibly evolve into an AGN.展开更多
We made model fitting to the mid-to-far infrared spectral energy distributions （SEDs） for different categories of galaxies in the main extragalactic field of the Spitzer First Look Survey with the aid of spectroscop...We made model fitting to the mid-to-far infrared spectral energy distributions （SEDs） for different categories of galaxies in the main extragalactic field of the Spitzer First Look Survey with the aid of spectroscopic information from the Sloan Digital Sky Survey. We find that the mid-to-far infrared SEDs of HII galaxies, mixture type galaxies and LINERs can be well fitted by the one-parameter （α） dust model of Dale et al. plus the 13 Gyr dust-free elliptical galaxy model. The statistics of α values indicates that all these galaxies tend to be quiescent, although the HII galaxies are relatively more active than the LINERs. The midinfrared SEDs of absorption galaxies are well fitted simply by the 13 Gyr dust-free elliptical galaxy template, and the near-to-mid infrared SEDs of QSOs can be represented by AGN NGC 5506.展开更多
By checking DSS optical images and NVSS radio images, 782 Markarian galaxies were identified to be NVSS radio sources. A comparison of the radio luminosity at 1.4GHz and the far-infrared （FIR） luminosity for 468 “n...By checking DSS optical images and NVSS radio images, 782 Markarian galaxies were identified to be NVSS radio sources. A comparison of the radio luminosity at 1.4GHz and the far-infrared （FIR） luminosity for 468 “normal” galaxies shows a tight correlation. Most of the Seyfert galaxies and quasars follow the radio-FIR relation deduced from the “normal” galaxy sample, but with a somewhat larger scatter. A total 167 Markarian galaxies, comprising 100 “normal” galaxies, 66 Seyfert galaxies and one quasar, have either excess radio emission or much lower FIR spectral index α（25 μm, 60 μm）. These galaxies may be classified as “AGN-powered”. For “normal” galaxies, the average q value （defined as the log ratio between FIR and radio luminosities） is 2.3. There seems a trend for q to slightly decrease with increasing radio luminosity. This may imply that the ongoing active star formation in galaxies with higher radio luminosities is more efficient in heating the cosmic-ray electrons.展开更多
Sol-gel titania films were deposited on 316L stainless steel using titanium isopropoxide as a chemical precursor. Dip-coating was performed at withdrawal speeds of 6 mm/min, 30 mm/min, and 60 mm/min. Deposited gel fil...Sol-gel titania films were deposited on 316L stainless steel using titanium isopropoxide as a chemical precursor. Dip-coating was performed at withdrawal speeds of 6 mm/min, 30 mm/min, and 60 mm/min. Deposited gel films were heat treated in air at 80℃, 100℃, 300℃, and 400℃. The structural evolution of the coatings was evaluated by infrared reflection-absorption spectroscopy. The influence of the withdrawal speed and the heat treatment temperature on the structure of the films was studied by varying the reflectance incidence angle during the infrared experiments and by Glow Discharge Spectrometry. Free functional groups were detected. The results indicate the formation of bidendate bridging coordination of carboxylic acid to titanium. Titanium atoms can also be pentacoordinated according to the processing conditions of the films. We observed a tendency of increasing amounts of OH groups with decreasing reflectance incidence angle. The film hardness was measured via Knoop microindenation hardness test.展开更多
The infrared multiphoton dissociation(IRMPD)spectrum of the protonated heterodimer of Pro Phe H+,in the range of 2700-3700 cm^-1,has been obtained with a Fourier-transform ion cyclotron mass spectrometer combined with...The infrared multiphoton dissociation(IRMPD)spectrum of the protonated heterodimer of Pro Phe H+,in the range of 2700-3700 cm^-1,has been obtained with a Fourier-transform ion cyclotron mass spectrometer combined with an IR OPO laser.The experimental spectrum shows one peak at 3565 cm^-1 corresponding to the free carboxyl O-H stretching vibration,and two broad peaks centered at 2935 and 3195 cm^-1.Theoretical calculations were performed on the level of M062 X/6-311++G(d,p).Results show that the most stable isomer is characterized by a charge-solvated structure in which the proton is bound to the unit of proline.Its predicted spectrum is in good agreement with the experimental one,although the coexistence of salt-bridged structures cannot be entirely excluded.展开更多
基金supported by the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDB0450202).
文摘To identify the species in liquid surface using mass spectrometry,we must eliminate or reduce interferences during the vaporization or desorption of the species from the liquid surface.It is much more challenging to isolate the ionic,larger species from the liquid surface,because of the frangible structures and the higher solvation energies of those species.Here we demonstrate a new mass spectrometry in which the ionic species at the liquid surface can be desorbed with ultrasoft infrared picosecond laser pulses while the liquid surface is not breached.This laser desorption assisted mass spectrometry is not only a powerful tool to detect the fragile species but also promising to investigate vibrational energy transfer dynamics in the liquid surface.
基金Supported by a research grant(3 P05D 054 24)from the Ministry of Scientific Research and Information Technology(formerly:State Committee For Scientific Research)of the Republic of Poland-contract #0617/P05/2003/24
文摘AIM： To evaluate the reproducibility of a modified 13^C breath test-based measurement of solid phase gastric emptying （GE） within the frames of a simple-repeated measure study protocol. METHODS： Twelve healthy subjects （6 females and 6 males, mean age 24.9＋0.7 years） were recruited to undergo three identical GE examinations. In six subjects the first two examinations were performed 2 d apart, and the third session was carried out at a median interval of 19.5 d （range 18 - 20 d） from the second one. In another six subjects the first two measurements were taken 20 d apart （median, range： 17-23 d）, whereas the third session took place 2 d after the second one. Probes of expiratory air collected before and during six hours after intake of a solid meal （378 kcal） labelled with 75 μL （68 mg） 13^C-octanoic acid, were measured for 13^CO2 enrichment with the nondispersive isotopeselective infrared spectrometry NDIRS apparatus. RESULTS： Taking coefficients of variation for paired examinations into account, the short-term reproducibility of the GE measurement was slightly but not significantly better than the medium-term one： 7.7% and 11.2% for the lag phase （T-Lag）, 7.3% and 10.9% for the gastric half emptying time （T1/2）. The least differences in GE parameters detectable at P= 0.05 level in the 12 paired examinations were 9.6 and 15.6 min for T-Lag, 11.6 and 19.7 min for T1/2 by a two-day or two to three-week time gap, respectively CONCLUSION： The low-cost modification of the breath test involving a lower dose of 13^C-octanoic acid and NDIRS, renders good short- and medium-term reproducibility, as well as sensitivity of the measurement of gastric emptying of solids.
文摘To rapidly determine the pollution extent of wastewater, the calibration models were established for deter-mination of Chemical Oxygen Demand and Biological Oxygen Demand in wastewater by partial least squares and near infrared spectrometry of 120 samples. Spectral data preprocessing and outliers’ diagnosis were also discussed. Correlation coefficients of the models were 0.9542 and 0.9652, and the root mean square error of prediction (RMSEP) were 25.24 mg?L-1 and 12.13 mg?L-1 in the predicted range of 28.40~528.0 mg?L-1 and 16.0~305.2 mg?L-1 for Chemical Oxygen Demand and Biological Oxygen Demand, respectively. By statistical significance test, the results of determination were compared with those of stan-dard methods with no significant difference at 0.05 level. The method has been applied to simultaneous de-termination of Chemical Oxygen Demand and Biological Oxygen Demand in wastewater with satisfactory results.
文摘Methanol oxidation reaction （MOR） at Pt and Pt electrode surface deposited with various amounts of Ru （denoted as PtxRuy, nominal coverage y is 0.17, 0.27, and 0.44 ML） in 0.1 mol/L HClO4＋0.5 mol/L MeOH has been studied under potentiostatic conditions by in situ FTIR spectroscopy in attenuated-total-reflection con guration and di erential electro-chemical mass spectrometry under controlled flow conditions. Results reveal that （i） CO is the only methanol-related adsorbate observed by IR spectroscopy at all the Pt and PtRu electrodes examined at potentials from 0.3 V to 0.6 V （vs. RHE）; （ii） at Pt0.56Ru0.44, two IR bands, one from CO adsorbed at Ru islands and the other from COL at Pt substrate are detected, while at other electrodes, only a single band for COL adsorbed at Pt is observed; （iii） MOR activity decreases in the order of Pt0.73Ru0.27〉Pt0.56Ru0.44〉Pt0.83Ru0.17〉Pt; （iv） at 0.5 V, MOR at Pt0.73Ru0.27 reaches a current e ciency of 50% for CO2 production, the turn-over frequency from CH3OH to CO2 is ca. 0.1 molecule/（site sec）. Suggestions for further improving of PtRu catalysts for MOR are provided.
基金Project(2021MD703848) supported by the China Postdoctoral Science FoundationProjects(52174229, 52174230)supported by the National Natural Science Foundation of China+1 种基金Project(2021-KF-23-04) supported by the Natural Science Foundation of Liaoning Province,ChinaProject(2020CXNL10) supported by the Fundamental Research Funds for the Central Universities,China。
文摘Coal mine fires,which can cause heavy casualties,environmental damages and a waste of coal resources,have become a worldwide problem.Aiming at overcoming the drawbacks,such as a low analysis efficiency,poor stability and large monitoring error,of the existing underground coal fire monitoring technology,a novel monitoring system based on non-dispersive infrared(NDIR)spectroscopy is developed.In this study,first,the measurement principle of NDIR sensor,the gas concentration calculation and its temperature compensation algorithms were expounded.Next,taking CO and CH_(4) as examples,the liner correlation coefficients of absorbance and the temperature correction factors of the two indicator gases were calculated,and then the errors of concentration measurement for CO,CO_(2),CH_(4) and C_(2)H_(4) were further analyzed.The results disclose that the designed NDIR sensors can satisfy the requirements of industrial standards for monitoring the indicator gases for coal fire hazards.For the established NDIR-based monitoring system,the NDIRbased spectrum analyzer and its auxiliary equipment boast intrinsically safe and explosion-proof performances and can achieve real-time and in-situ detection of indicator gases when installed close to the coal fire risk area underground.Furthermore,a field application of the NDIR-based monitoring system in a coal mine shows that the NDIR-based spectrum analyzer has a permissible difference from the chromatography in measuring the concentrations of various indicator gases.Besides,the advantages of high accuracy,quick analysis and excellent security of the NDIR-based monitoring system have promoted its application in many coal mines.
基金supported by the National Natural Science Foundation of China (Grant No. 51072072)
文摘WnC0＇± （n= 1-6） clusters are investigated by using the density functional theory （DFT） at the B3LYP/LANL2DZ level. We find that the neutral, anionic and cationic ground state structures are similar within the same size, and constituted by substituting a C atom for one W atom in the structures of Wn＋1 clusters. The natural bond orbital （NBO） charge analyses indicate that the direction of electron transfer is from the W atom to the 2p orbital of the C atom. In addition, the calculated infrared spectra of the WnC0＇± （n= 2-6） clusters manifest that the vibrational frequencies of neutral, anionic and cationic clusters are similar in a range of 80 cm-1-864 cm-1. The high frequency, strong peak modes are found to be an almost stretched deformation of the carbide atom. Finally, the polarizabilities of WnC0＇± （n= 1-6） clusters are also discussed.
文摘The authentication of milk requires the use of sophisticated and expensive analytical techniques. There is a huge need for reliable and cheap analytical technologies for use as fast and effective screening methods. This paper proposes the use of myristic acid in the authentication of cow, mare, camel and goat milk, using near infrared spectrometry. Comparison has been made with traditional gas chromatography methods, so that both methods can be used in the authentication of different types of dairy products.
文摘To obtain excellent performance optical fiber couplers, the structural difference of SiO2 in couplers with different manufacturing techniques was investigated. With 740-FT-IR infrared spectrometric analyzer, the infrared absorption spectrum of SiO2 in couplers at different drawing velocities was measured, and two characteristic peaks in the wavenumber range of 6502000 cm-1 were observed. One characteristic peak is at about 943 cm-1, which is （attributed） to Si—O—Si bond asymmetric stretching vibration, the other is at about 773 cm-1, which is attributed to （Si—O—Si） bond symmetric stretching vibration. From the infrared spectrum, it is found that the intensity and wavenumber of the characteristic peaks are related to the manufacturing technique of couplers. The characteristic peak at （about） 943 cm-1 becomes steeper when increasing the drawing velocity. At the drawing velocity of 150 μm/s, the distance between the two characteristic peaks is maximum, and then the optical fiber coupler has excellent performance, indicating that the performance of the optical fiber coupler has a close relationship with the wavenumber of the two characteristic peaks.
基金funded by the Department of Space, Government of India
文摘We present the results obtained from extensive near-infrared （IR） spectro- scopic and photometric observations of the Be/X-ray binary A0535＋262/HDE 245770 at different phases of its - 111 d orbital period. This observation campaign is part of the monitoring program of selective Be/X-ray binary systems aimed at understanding X-ray and near-IR properties at different orbital phases, especially during the perias- tron passage of the neutron star. The near-IR observations presented here were carried out using the 1.2 m telescope at the Mt. Abu IR Observatory. Though the source was relatively faint for spectroscopic observations with the 1.2 m telescope, we monitored the source closely during the 2011 February-March giant X-ray outburst to primarily investigate whether any drastic changes in the near-IR JHK spectra took place at the periastron passage. Changes of such a striking nature were expected to be detectable in our spectra. Photometric observations of the Be star show a gradual and systematic fading in the JHK light curves since the onset of the X-ray outburst, which could suggest a mild evacuation/truncation of the circumstellar disk of the Be companion. Near-IR spectroscopy of the object shows that the JHK spectra are dominated by the emission lines of hydrogen Brackett and Paschen series and HeI lines at 1.0830, 1.7002 and 2.0585 μm. The presence of all the hydrogen emission lines in the JHK spectra, along with the absence of any significant change in the continuum of the Be companion during X-ray quiescent and X-ray outburst phases, suggests that the near- IR line emitting regions of the disk are not significantly affected during the X-ray outburst.
基金supported by the National Natural Science Foundation of China (Grant Nos. 10833006, 10773014, and 10978014)the Ministry of Science and Technology National Basic Science program (973 Program, Grant No. 2007CB815406)
文摘We present a stellar population synthesis study of a type II luminous infrared galaxy, IRAS F21013-0739. Optical images show clear characteristics of a merger remnant. The H-band absolute magnitude is MH = -25.1, which is -2 times as luminous as L＊ galaxies. Stellar populations are obtained through the stellar synthesis code STARLIGHT. We find that it experienced a recent starburst （SB） phase - 100 Myr ago. By reconstructing the ultraviolet-to-optical spectrum, and adopting Calzetti et al. and Leitherer et al.＇s extinction curves, we estimate the past infrared （IR） luminosities of the host galaxy and find it may have experienced an ultraluminous infrared galaxy phase which lasted for about 100 Myr. Its i-band absolute magnitude is Mi = -22.463, and its spectral type shows type 2 active galactic nucleus （AGN） characteristics. The mass of the supermassive black-hole is estimated to be MBH = 1.6 × 107 M⊙ （lower- limit）. The Eddington ratio Lbol/LEdd is 0.15, which is typical of Palomar-Green （PG） quasars. Both the nuclear SB and AGN contribute to the present IR luminosity budget, and the SB contributes -67%. On the diagram of IR color versus IR/opfical excess, it is located between IR quasars and PG quasars. These results indicate that IRAS F21013-0739 has probably evolved from a ULIRG, and it can possibly evolve into an AGN.
基金Supported by the National Natural Science Foundation of China.
文摘We made model fitting to the mid-to-far infrared spectral energy distributions （SEDs） for different categories of galaxies in the main extragalactic field of the Spitzer First Look Survey with the aid of spectroscopic information from the Sloan Digital Sky Survey. We find that the mid-to-far infrared SEDs of HII galaxies, mixture type galaxies and LINERs can be well fitted by the one-parameter （α） dust model of Dale et al. plus the 13 Gyr dust-free elliptical galaxy model. The statistics of α values indicates that all these galaxies tend to be quiescent, although the HII galaxies are relatively more active than the LINERs. The midinfrared SEDs of absorption galaxies are well fitted simply by the 13 Gyr dust-free elliptical galaxy template, and the near-to-mid infrared SEDs of QSOs can be represented by AGN NGC 5506.
文摘By checking DSS optical images and NVSS radio images, 782 Markarian galaxies were identified to be NVSS radio sources. A comparison of the radio luminosity at 1.4GHz and the far-infrared （FIR） luminosity for 468 “normal” galaxies shows a tight correlation. Most of the Seyfert galaxies and quasars follow the radio-FIR relation deduced from the “normal” galaxy sample, but with a somewhat larger scatter. A total 167 Markarian galaxies, comprising 100 “normal” galaxies, 66 Seyfert galaxies and one quasar, have either excess radio emission or much lower FIR spectral index α（25 μm, 60 μm）. These galaxies may be classified as “AGN-powered”. For “normal” galaxies, the average q value （defined as the log ratio between FIR and radio luminosities） is 2.3. There seems a trend for q to slightly decrease with increasing radio luminosity. This may imply that the ongoing active star formation in galaxies with higher radio luminosities is more efficient in heating the cosmic-ray electrons.
基金financial support from the Minas Gerais Research Agency(Fapemig),Brazilian Research Agency(CNPq),Brazilian Graduate Agency(CAPES),Minerals and Metallurgy Pole of Excellence of The Minas Gerais State,and The National Institute of Science and Technology on Mineral Resources,Water,and Biodiversity(Acqua).
文摘Sol-gel titania films were deposited on 316L stainless steel using titanium isopropoxide as a chemical precursor. Dip-coating was performed at withdrawal speeds of 6 mm/min, 30 mm/min, and 60 mm/min. Deposited gel films were heat treated in air at 80℃, 100℃, 300℃, and 400℃. The structural evolution of the coatings was evaluated by infrared reflection-absorption spectroscopy. The influence of the withdrawal speed and the heat treatment temperature on the structure of the films was studied by varying the reflectance incidence angle during the infrared experiments and by Glow Discharge Spectrometry. Free functional groups were detected. The results indicate the formation of bidendate bridging coordination of carboxylic acid to titanium. Titanium atoms can also be pentacoordinated according to the processing conditions of the films. We observed a tendency of increasing amounts of OH groups with decreasing reflectance incidence angle. The film hardness was measured via Knoop microindenation hardness test.
基金supported by the National Natural Science Foundation of China(No.21627810)the Fundamental Research Funds for the Central Universities,Nankai University(No.63191523)。
文摘The infrared multiphoton dissociation(IRMPD)spectrum of the protonated heterodimer of Pro Phe H+,in the range of 2700-3700 cm^-1,has been obtained with a Fourier-transform ion cyclotron mass spectrometer combined with an IR OPO laser.The experimental spectrum shows one peak at 3565 cm^-1 corresponding to the free carboxyl O-H stretching vibration,and two broad peaks centered at 2935 and 3195 cm^-1.Theoretical calculations were performed on the level of M062 X/6-311++G(d,p).Results show that the most stable isomer is characterized by a charge-solvated structure in which the proton is bound to the unit of proline.Its predicted spectrum is in good agreement with the experimental one,although the coexistence of salt-bridged structures cannot be entirely excluded.
