Based on the three laws of dialectics of nature-the law of unity of opposites, the law of mutual change of quality and the law of negation of negation, this paper analyzes the relationship between the three laws and a...Based on the three laws of dialectics of nature-the law of unity of opposites, the law of mutual change of quality and the law of negation of negation, this paper analyzes the relationship between the three laws and agricultural development, and proposes making good use of the three laws to promote the better development of agriculture and realize agricultural modernization.展开更多
The dihydrogen bonds B-H...H-X (X= the complexes of NH3BH3 with HF, HCl, F, Cl, Br, C, O, N) in the dimer (NH3BH3)2 and HBr, H2CO, H20, and CH3OH were theoretically studied. The results show that formation of the ...The dihydrogen bonds B-H...H-X (X= the complexes of NH3BH3 with HF, HCl, F, Cl, Br, C, O, N) in the dimer (NH3BH3)2 and HBr, H2CO, H20, and CH3OH were theoretically studied. The results show that formation of the dihydrogen bond leads to elongation and stretch frequency red shift of the BH and XH bonds, except that in the H2CO system, the CH bond blue shifts. For (NH3BH3)2 and the complexes of the halogenides, red shifts of the XH bonds are caused by the intermolecular hyperconjugation σ(BH)→σ^* (XH). For the system of H2CO, a blue shift of the CH bond is caused by a decrease of the intramolecular hyperconjugation n(O→σ^* (CH). In the other two systems, the red shift of OH bond is a secondary effect of the stronger traditional red-shifted H-bonds N-H... O. In all these systems, red shifts of the BH bonds are caused by two factors: negative repolarization and negative rehybridization of the BH bond, and decrease of occupancy on σ(BH) caused by the intermolecular hyperconjugation σ(BH)→σ^* (XH).展开更多
The aim of this paper is to investigate the central limit theorems for asymptotically negatively dependent random fields under lower moment conditions or the Lindeberg condition. Results obtained improve a central lim...The aim of this paper is to investigate the central limit theorems for asymptotically negatively dependent random fields under lower moment conditions or the Lindeberg condition. Results obtained improve a central limit theorem of Roussas[11]for negatively associated fields and the main results of Su and Chi [18]. and also include a central limit theorem for weakly negatively associated random variables similar to that of Burton et al.[20].展开更多
文摘Based on the three laws of dialectics of nature-the law of unity of opposites, the law of mutual change of quality and the law of negation of negation, this paper analyzes the relationship between the three laws and agricultural development, and proposes making good use of the three laws to promote the better development of agriculture and realize agricultural modernization.
基金ACKNOWLEDGMENT This work was supported Science Foundation of China by the National Natural (No.20873103).
文摘The dihydrogen bonds B-H...H-X (X= the complexes of NH3BH3 with HF, HCl, F, Cl, Br, C, O, N) in the dimer (NH3BH3)2 and HBr, H2CO, H20, and CH3OH were theoretically studied. The results show that formation of the dihydrogen bond leads to elongation and stretch frequency red shift of the BH and XH bonds, except that in the H2CO system, the CH bond blue shifts. For (NH3BH3)2 and the complexes of the halogenides, red shifts of the XH bonds are caused by the intermolecular hyperconjugation σ(BH)→σ^* (XH). For the system of H2CO, a blue shift of the CH bond is caused by a decrease of the intramolecular hyperconjugation n(O→σ^* (CH). In the other two systems, the red shift of OH bond is a secondary effect of the stronger traditional red-shifted H-bonds N-H... O. In all these systems, red shifts of the BH bonds are caused by two factors: negative repolarization and negative rehybridization of the BH bond, and decrease of occupancy on σ(BH) caused by the intermolecular hyperconjugation σ(BH)→σ^* (XH).
基金Research supported by National Natural Science Foundation of China (No. 19701011)
文摘The aim of this paper is to investigate the central limit theorems for asymptotically negatively dependent random fields under lower moment conditions or the Lindeberg condition. Results obtained improve a central limit theorem of Roussas[11]for negatively associated fields and the main results of Su and Chi [18]. and also include a central limit theorem for weakly negatively associated random variables similar to that of Burton et al.[20].