It is well known that in pyroxene structure, there are two metal sites, M1 and M2.Generally speaking, ferrous iron in each of these sites would normally be expected to give rise to a doublet. However, anomies have bee...It is well known that in pyroxene structure, there are two metal sites, M1 and M2.Generally speaking, ferrous iron in each of these sites would normally be expected to give rise to a doublet. However, anomies have been found in the relative areas of the peaks in the room temperature spectra of some clinopyroxene (CPX) when the above assigninent is folowed. Ac-cording to the calculation of Next Nearest Neighbor configurations of divalent cations in M1,we found that the four configurations of M1 can be divided into two groups. One group is 3Ca configuration that increases with the content of Ca (p. f. u); the other group is made up of three No-3Ca configurations that decrease with the content of Ca. The two groups contribute to the spectrum structure of M1, so in this study we fit two doublets for ferrous iron in M1.Though there were severa reports on Fe3+ in tetrahedral site previously, it wa not sure that Fe3+ occupies the T site is a universal fact in CPX, despite of the content of A1. We found that the Fe3+ in the T site fitted by Medauer spectroscopy is negatively correlated to the Si content in the T site and positively correlated to the Fe3 + in the T site estimated on the suppo-sition that Fe3+ and Al occupy the T site randomly. If it is true, it is important in the model-ing of ion exchange geobarometries and gepthermornetries.展开更多
Many real-world problems are dynamic, requiring optimization algorithms being able to continuously track changing optima （optimum） over time. This paper proposes an improved differential evolutionary algorithm using...Many real-world problems are dynamic, requiring optimization algorithms being able to continuously track changing optima （optimum） over time. This paper proposes an improved differential evolutionary algorithm using the notion of the near-neighbor effect to determine one individuals neighborhoods, for tracking multiple optima in the dynamic environment. A new mutation strategy using the near-neighbor effect is also presented. It creates individuals by utilizing the stored memory point in its neighborhood, and utilizing the differential vector produced by the ＇near- neighbor-superior＇ and ＇near-neighbor-inferior＇. Taking inspirations from the biological immune system, an immune system based scheme is presented for rapidly detecting and responding to the environmental changes. In addition, a difference- related multidirectional amplification scheme is presented to integrate valuable information from different dimensions for effectively and rapidly finding the promising optimum in the search space. Experiments on dynamic scenarios created by the typical dynamic test instance--moving peak problem, have demonstrated that the near-neighbor and immune system based differential evolution algorithm （NIDE） is effective in dealing with dynamic optimization functions.展开更多
Background: Light is an important environmental factor affecting the growth and survival of plants in forest communities. The competition for light resources and divergent responses to light may affect plant species c...Background: Light is an important environmental factor affecting the growth and survival of plants in forest communities. The competition for light resources and divergent responses to light may affect plant species coexistence in natural forests through niche partitioning and environmental filtering, respectively.Methods: In the present study, sequences of light-response-related functional genes were extracted from transcriptomic data of 99 tree species in a subtropical forest and average and nearest taxon phylogenetic diversity of adult(A_Apd’, A_NTpd’) and seedling neighbors(S_Apd’, S_NTpd’) around each focal seedling were calculated to evaluate effects of differentiation in light-response-related genes on community assembly processes.Results: The results showed that seedling survival was related to S_NTpd’, S_Apd’and A_Apd’of two chlorophyll ab-binding proteins involved in the assembly of photosystem Ⅱ and two genes responsive to light intensity,indicating seedlings surrounded by neighbors with distinct light responses tended to have high survival rates.Conclusions: Our results indicated that niche partitioning due to competition for light resources between plants may act as the key mechanism in determining seedling dynamics in subtropical forests.展开更多
Although single-atom catalysts(SACs)have attracted enormous attention for their applications in the electrochemical reduction of CO_(2)(CO_(2)RR)due to their extraordinary catalytic activity and well-defined active ce...Although single-atom catalysts(SACs)have attracted enormous attention for their applications in the electrochemical reduction of CO_(2)(CO_(2)RR)due to their extraordinary catalytic activity and well-defined active centers,neighboring effects and their influence on the electrochemical performance of SACs have not been well investigated.In this review,we present a summary of the neighboring effects on SACs for the CO_(2)RR process,where the surrounding atoms not only induce electronic modulation of the metal atom but also participate in the CO_(2)RR.Both theoretical and experimental studies have pointed out that the neighboring sites of the anchored metal center can provide second active/adsorption locations during the catalytic process,enhancing CO_(2)RR performance tremendously.This review supplies advanced insights into the significant roles and impacts of neighboring effects on the catalytic process,which also benefit the development of advanced SACs to achieve efficient electrocatalysis.展开更多
文摘It is well known that in pyroxene structure, there are two metal sites, M1 and M2.Generally speaking, ferrous iron in each of these sites would normally be expected to give rise to a doublet. However, anomies have been found in the relative areas of the peaks in the room temperature spectra of some clinopyroxene (CPX) when the above assigninent is folowed. Ac-cording to the calculation of Next Nearest Neighbor configurations of divalent cations in M1,we found that the four configurations of M1 can be divided into two groups. One group is 3Ca configuration that increases with the content of Ca (p. f. u); the other group is made up of three No-3Ca configurations that decrease with the content of Ca. The two groups contribute to the spectrum structure of M1, so in this study we fit two doublets for ferrous iron in M1.Though there were severa reports on Fe3+ in tetrahedral site previously, it wa not sure that Fe3+ occupies the T site is a universal fact in CPX, despite of the content of A1. We found that the Fe3+ in the T site fitted by Medauer spectroscopy is negatively correlated to the Si content in the T site and positively correlated to the Fe3 + in the T site estimated on the suppo-sition that Fe3+ and Al occupy the T site randomly. If it is true, it is important in the model-ing of ion exchange geobarometries and gepthermornetries.
基金partly supported by the Key Program of National Natural Science Foundation(NNSF) of China(Nos.70931001,70771021,70721001)the National Natural Science Foundation of China for Youth(Nos.61004121,70771021)+1 种基金the Science Fund for Creative Research Group of NNSF of China(No.60821063)the Ph.D.Programs Foundation of Ministry of Education of China(No.200801450008)
文摘Many real-world problems are dynamic, requiring optimization algorithms being able to continuously track changing optima （optimum） over time. This paper proposes an improved differential evolutionary algorithm using the notion of the near-neighbor effect to determine one individuals neighborhoods, for tracking multiple optima in the dynamic environment. A new mutation strategy using the near-neighbor effect is also presented. It creates individuals by utilizing the stored memory point in its neighborhood, and utilizing the differential vector produced by the ＇near- neighbor-superior＇ and ＇near-neighbor-inferior＇. Taking inspirations from the biological immune system, an immune system based scheme is presented for rapidly detecting and responding to the environmental changes. In addition, a difference- related multidirectional amplification scheme is presented to integrate valuable information from different dimensions for effectively and rapidly finding the promising optimum in the search space. Experiments on dynamic scenarios created by the typical dynamic test instance--moving peak problem, have demonstrated that the near-neighbor and immune system based differential evolution algorithm （NIDE） is effective in dealing with dynamic optimization functions.
基金funded by the Strategic Priority Research Program of Chinese Academy of Sciences(Grant No.XDB31000000)National Natural Science Foundation of China(No.32161123003)+1 种基金Beijing Natural Science Foundation(No.5202018)National Key Research Development Program of China(No.2022YFF0802300)。
文摘Background: Light is an important environmental factor affecting the growth and survival of plants in forest communities. The competition for light resources and divergent responses to light may affect plant species coexistence in natural forests through niche partitioning and environmental filtering, respectively.Methods: In the present study, sequences of light-response-related functional genes were extracted from transcriptomic data of 99 tree species in a subtropical forest and average and nearest taxon phylogenetic diversity of adult(A_Apd’, A_NTpd’) and seedling neighbors(S_Apd’, S_NTpd’) around each focal seedling were calculated to evaluate effects of differentiation in light-response-related genes on community assembly processes.Results: The results showed that seedling survival was related to S_NTpd’, S_Apd’and A_Apd’of two chlorophyll ab-binding proteins involved in the assembly of photosystem Ⅱ and two genes responsive to light intensity,indicating seedlings surrounded by neighbors with distinct light responses tended to have high survival rates.Conclusions: Our results indicated that niche partitioning due to competition for light resources between plants may act as the key mechanism in determining seedling dynamics in subtropical forests.
基金the support from the National Natural Science Foundation of China Grant Council of Hong Kong Joint Research Scheme(N_PolyU502/21)the funding for Projects of Strategic Importance of The Hong Kong Polytechnic University(Project Code:1-ZE2V)+2 种基金Shenzhen Fundamental Research Scheme-General Program(JCYJ20220531090807017)the Natural Science Foundation of Guangdong Province(2023A1515012219)Departmental General Research Fund(Project Code:ZVUL)from Department of Applied Biology and Chemical Technology of Hong Kong Polytechnic University.
文摘Although single-atom catalysts(SACs)have attracted enormous attention for their applications in the electrochemical reduction of CO_(2)(CO_(2)RR)due to their extraordinary catalytic activity and well-defined active centers,neighboring effects and their influence on the electrochemical performance of SACs have not been well investigated.In this review,we present a summary of the neighboring effects on SACs for the CO_(2)RR process,where the surrounding atoms not only induce electronic modulation of the metal atom but also participate in the CO_(2)RR.Both theoretical and experimental studies have pointed out that the neighboring sites of the anchored metal center can provide second active/adsorption locations during the catalytic process,enhancing CO_(2)RR performance tremendously.This review supplies advanced insights into the significant roles and impacts of neighboring effects on the catalytic process,which also benefit the development of advanced SACs to achieve efficient electrocatalysis.
