Drip irrigation and flood irrigation are major irrigation methods for maize crops in the Hetao Irrigation District,Inner Mongolia Autonomous Region,China.This research delves into the effects of these irrigation metho...Drip irrigation and flood irrigation are major irrigation methods for maize crops in the Hetao Irrigation District,Inner Mongolia Autonomous Region,China.This research delves into the effects of these irrigation methods on carbon dioxide(CO_(2))exchange and crop growth in this region.The experimental site was divided into drip and flood irrigation zones.The irrigation schedules of this study aligned with the local commonly used irrigation schedule.We employed a developed chamber system to measure the diurnal CO_(2)exchange of maize plants during various growth stages under both drip and flood irrigation methods.From May to September in 2020 and 2021,two sets of repeated experiments were conducted.In each experiment,a total of nine measurements of CO_(2)exchange were performed to obtain carbon exchange data at different growth stages of maize crop.During each CO_(2)exchange measurement event,CO_(2)flux data were collected every two hours over a day-long period to capture the diurnal variations in CO_(2)exchange.During each CO_(2)exchange measurement event,the biological parameters(aboveground biomass and crop growth rate)of maize and environmental parameters(including air humidity,air temperature,precipitation,soil water content,and photosynthetically active radiation)were measured.The results indicated a V-shaped trend in net ecosystem CO_(2)exchange in daytime,reducing slowly at night,while the net assimilation rate(net primary productivity)exhibited a contrasting trend.Notably,compared with flood irrigation,drip irrigation demonstrated significantly higher average daily soil CO_(2)emission and greater average daily CO_(2)absorption by maize plants.Consequently,within the maize ecosystem,drip irrigation appeared more conducive to absorbing atmospheric CO_(2).Furthermore,drip irrigation demonstrated a faster crop growth rate and increased aboveground biomass compared with flood irrigation.A strong linear relationship existed between leaf area index and light utilization efficiency,irrespective of the irrigation method.Notably,drip irrigation displayed superior light use efficiency compared with flood irrigation.The final yield results corroborated these findings,indicating that drip irrigation yielded higher harvest index and overall yield than flood irrigation.The results of this study provide a basis for the selection of optimal irrigation methods commonly used in the Hetao Irrigation District.This research also serves as a reference for future irrigation studies that consider measurements of both carbon emissions and yield simultaneously.展开更多
1.Challenges circular methane energy systems In recent decades,methane-based energy systems have rapidly gained traction across the globe because of the increasing availability of low-cost methane production capacity....1.Challenges circular methane energy systems In recent decades,methane-based energy systems have rapidly gained traction across the globe because of the increasing availability of low-cost methane production capacity.However,fossil methane production and combustion lead to large greenhouse gas emissions,contributing to climate change[1].展开更多
The unabated carbon dioxide(CO_(2))emission into the atmosphere has exacerbated global climate change,resulting in extreme weather events,biodiversity loss,and an intensified greenhouse effect.To address these challen...The unabated carbon dioxide(CO_(2))emission into the atmosphere has exacerbated global climate change,resulting in extreme weather events,biodiversity loss,and an intensified greenhouse effect.To address these challenges and work toward carbon(C)neutrality and reduced CO_(2)emissions,the capture and utilization of CO_(2)have become imperative in both scientific research and industry.One cutting-edge approach to achieving efficient catalytic performance involves integrating green bioconversion and chemical conversion.This innovative strategy offers several advantages,including environmental friendliness,high efficiency,and multi-selectivity.This study provides a comprehensive review of existing technical routes for carbon sequestration(CS)and introduces two novel CS pathways:the electrochemicalbiological hybrid and artificial photosynthesis systems.It also thoroughly examines the synthesis of valuable Cnproducts from the two CS systems employing different catalysts and biocatalysts.As both systems heavily rely on electron transfer,direct and mediated electron transfer has been discussed and summarized in detail.Additionally,this study explores the conditions suitable for different catalysts and assesses the strengths and weaknesses of biocatalysts.We also explored the biocompatibility of the electrode materials and developed novel materials.These materials were specifically engineered to combine with enzymes or microbial cells to solve the biocompatibility problem,while improving the electron transfer efficiency of both.Furthermore,this review summarizes the relevant systems developed in recent years for manufacturing different products,along with their respective production efficiencies,providing a solid database for development in this direction.The novel chemical-biological combination proposed herein holds great promise for the future conversion of CO_(2)into advanced organic compounds.Additionally,it offers exciting prospects for utilizing CO_(2)in synthesizing a wide range of industrial products.Ultimately,the present study provides a unique perspective for achieving the vital goals of“peak shaving”and C-neutrality,contributing significantly to our collective efforts to combat climate change and its associated challenges.展开更多
Climate researchers have observed that the carbon dioxide (CO2) concentration in the atmosphere have been growing significantly over the past century. CO2 from energy represents about 75% of the greenhouse gas (GHG...Climate researchers have observed that the carbon dioxide (CO2) concentration in the atmosphere have been growing significantly over the past century. CO2 from energy represents about 75% of the greenhouse gas (GHG) emissions for Annex B (Developed) countries, and over 60% of global emissions. Because of impermeable cap rocks hydrocarbon reservoirs are able to sequester CO〉 In addition, due to high-demand for oil worldwide, injection of CO2 is a useful way to enhance oil production. Hence, applying an efficient method to co-optimize CO2 storage and oil production is vital. Lack of suitable optimization techniques in the past led most multi-objective optimization problems to be tackled in the same way as a single objective optimization issue. However, there are some basic differences between the multi and single objective optimization methods. In this study, by using a non- dominated sorting genetic algorithm (NSGA-II) for an oil reservoir, some appropriate scenarios are proposed based on simultaneous gas storage and enhanced oil recovery optimization. The advantages of this method allow us to amend production scenarios after implementing the optimization process, by regarding the variation of economic parameters such as oil price and CO2 tax. This leads to reduced risks and time duration of making new decisions based on upcoming situations.展开更多
The use of sequestered carbon dioxide(CO) as the heat exchange fluid in enhanced geothermal system(EGS) has significant potential to increase their productivity, contribute further to reducing carbon emissions and inc...The use of sequestered carbon dioxide(CO) as the heat exchange fluid in enhanced geothermal system(EGS) has significant potential to increase their productivity, contribute further to reducing carbon emissions and increase the economic viability of geothermal power generation. Coupled COsequestration and geothermal energy production from hot dry rock(HDR) EGS were first proposed 15 years ago but have yet to be practically implemented. This paper reviews some of the issues in assessing these systems with particular focus on the power generation and COsequestration capacity. The Habanero geothermal field in the Cooper Basin of South Australia is assessed for its potential COstorage capacity if supercritical COis used as the working fluid for heat extraction. The analysis suggests that the major COsequestration mechanisms are the storage in the fracture-stimulation damaged zone followed by diffusion into the pores within the rock matrix. The assessment indicates that 5% of working fluid loss commonly suggested as the storage capacity might be an over-estimate of the long-term COsequestration capacity of EGS in which supercritical COis used as the circulation fluid.展开更多
AIM: To evaluate the effects of using CO2 as negative contrast agent in decreasing the overlapping on the pancreaticobiliary system from intestinal fluids.METHODS:We evaluated the magnetic resonance cholangiopancreato...AIM: To evaluate the effects of using CO2 as negative contrast agent in decreasing the overlapping on the pancreaticobiliary system from intestinal fluids.METHODS:We evaluated the magnetic resonance cholangiopancreatography(MRCP) images in 117 patients divided into two groups(group 1,without taking gas producing crystals to produce CO2,n=64;group 2,with CO2,n=53)in a 1.5T unit using MRCP sequence.Anatomic locations of intestinal fluids distribution,overlapping with common bile duct(CBD)and pancreatic duct(PD),were evaluated.RESULTS:In the group with CO2,the decrease in distribution of intestinal fluids was significant in the gastric antrum(P=0.001)and duodenal bulb(P<0.001),but not in the gastric fundus and body and in the second portion of the duodenum(P=1.000,P=0.171,and P=0.584 respectively).In the group with CO2,the decrease in overlapping with CBD was significant(P< 0.001),but the decrease in overlapping with PD was not (P=0.106).CONCLUSION:MRCP with carbon dioxide as negative contrast agent would decrease intestinal fluids in the gastric antrum and duodenal bulb,thereby decreasing overlapping with the CBD.展开更多
Interannual variations of the air-sea CO2 exchange from 1965 to 2000 in the Pacific Ocean are studied with a Pacific Ocean model. Two numerical experiments are performed, including the control run that is forced by cl...Interannual variations of the air-sea CO2 exchange from 1965 to 2000 in the Pacific Ocean are studied with a Pacific Ocean model. Two numerical experiments are performed, including the control run that is forced by climatological monthly mean physical data and the climate-change run that is forced by interannually varying monthly mean physical data. Climatological monthly winds are used in both runs to calculate the coefficient of air-sea CO2 exchange. The analysis through the differences between the two runs shows that in the tropical Pacific the variation of export production induced by interannual variations of the physical fields is negatively correlated with that of the air-sea CO2 flux, while there is no correlation or a weak positive correlation in the subtropical North and South Pacific. It indicates that the variation of the physical fields can modulate the variation of the air-sea CO2 flux in converse ways in the tropical Pacific by changing the direct transport and biochemical process. Under the interannually varying monthly mean forcing, the simulated EOF 1 of the air-sea CO2 flux is basically consistent with that of sea surface temperature (SST) in the tropical Pacific, but contrary in the two subtropical Pacific Ocean. The correlation coefficient between the regionally integrated air-sea CO2 flux and area-mean SST shows that when the air-sea CO2 flux lags SST by about 5 months, the positive coefficient in the three regions is largest, indicating that in the tropical Pacific or on the longer time scale in the three regions, physical processes control the fiux-SST relationship.展开更多
Acorn production in oak(Quercus spp.)shows considerable inter-annual variation,known as masting,which provides a natural defence against seed predators but a highly-variable supply of acorns for uses such as in commer...Acorn production in oak(Quercus spp.)shows considerable inter-annual variation,known as masting,which provides a natural defence against seed predators but a highly-variable supply of acorns for uses such as in commercial tree planting each year.Anthropogenic emissions of greenhouse gases have been very widely reported to influence plant growth and seed or fruit size and quantity via the‘fertilisation effect’that leads to enhanced photosynthesis.To examine if acorn production in mature woodland communities will be affected by further increase in CO_(2),the contents of litter traps from a Free Air Carbon Enrichment(FACE)experiment in deciduous woodland in central England were analysed for numbers of flowers and acorns of pedunculate oak(Quercus robur L.)at different stages of development and their predation levels under ambient and elevated CO_(2) concentrations.Inter-annual variation in acorn numbers was considerable and cyclical between 2015 and 2021,with the greatest numbers of mature acorns in 2015,2017 and 2020 but almost none in 2018.The numbers of flowers,enlarged cups,immature acorns,empty acorn cups,and galls in the litter traps also varied amongst years;comparatively high numbers of enlarged cups were recorded in 2018,suggesting Q.robur at this site is a fruit maturation masting species(i.e.,the extent of abortion of pollinated flowers during acorn development affects mature acorn numbers greatly).Raising the atmospheric CO_(2) concentration by 150μL L^(−1),from early 2017,increased the numbers of immature acorns,and all acorn evidence(empty cups+immature acorns+mature acorns)detected in the litter traps compared to ambient controls by 2021,but did not consistently affect the numbers of flowers,enlarged cups,empty cups,or mature acorns.The number of flowers in the elevated CO_(2) plots’litter traps was greater in 2018 than 2017,one year after CO_(2) enrichment began,whereas numbers declined in ambient plots.Enrichment with CO_(2) also increased the number of oak knopper galls(Andricus quercuscalicis Burgsdorf).We conclude that elevated CO_(2) increased the occurrence of acorns developing from flowers,but the putative benefit to mature acorn numbers may have been hidden by excessive pre-and/or post-dispersal predation.There was no evidence that elevated CO_(2) altered masting behaviour.展开更多
Understanding the response of the Earth system to varying concentrations of carbon dioxide(CO_(2))is critical for projecting possible future climate change and for providing insight into mitigation and adaptation stra...Understanding the response of the Earth system to varying concentrations of carbon dioxide(CO_(2))is critical for projecting possible future climate change and for providing insight into mitigation and adaptation strategies in the near future.In this study,we generate a dataset by conducting an experiment involving carbon dioxide removal(CDR)—a potential way to suppress global warming—using the Chinese Academy of Sciences Earth System Model version 2.0(CASESM2.0).A preliminary evaluation is provided.The model is integrated from 200–340 years as a 1%yr^(−1) CO_(2) concentration increase experiment,and then to~478 years as a carbon dioxide removal experiment until CO_(2) returns to its original value.Finally,another 80 years is integrated in which CO_(2) is kept constant.Changes in the 2-m temperature,precipitation,sea surface temperature,ocean temperature,Atlantic meridional overturning circulation(AMOC),and sea surface height are all analyzed.In the ramp-up period,the global mean 2-m temperature and precipitation both increase while the AMOC weakens.Values of all the above variables change in the opposite direction in the ramp-down period,with a delayed peak relative to the CO_(2) peak.After CO_(2) returns to its original value,the global mean 2-m temperature is still~1 K higher than in the original state,and precipitation is~0.07 mm d^(–1) higher.At the end of the simulation,there is a~0.5°C increase in ocean temperature and a 1 Sv weakening of the AMOC.Our model simulation produces similar results to those of comparable experiments previously reported in the literature.展开更多
Methane(CH_(4))and carbon dioxide(CO_(2))are primary components of coal seam gas(CSG).Understanding their adsorption-desorption hysteresis characteristics,along with the fundamental mechanism,is crucial for CSG exploi...Methane(CH_(4))and carbon dioxide(CO_(2))are primary components of coal seam gas(CSG).Understanding their adsorption-desorption hysteresis characteristics,along with the fundamental mechanism,is crucial for CSG exploitation and related hazards mitigation.This research focused on the representative Bulli coal seam in the Sydney Basin,Australia.Through the purpose-built indirect gravimetric high-pressure isothermal adsorption-desorption hysteresis experiment,a novel Langmuir-based desorption model,incorporating hysteresis effect and residual gas,was proposed.Quantitative characterization of the adsorption-desorption hysteresis degrees of CO_(2)and CH_(4)i n coal particles of various sizes and inΦ50mm 100 mm intact coal samples were achieved using the improved hysteresis index(IHI).The experimental findings validated that the proposed desorption model accurately describes the desorption behavior of CO_(2)and CH_(4)in coal(R^(2)>0.99).Based on the adsorption-desorption properties of inkbottle-shaped micropores and pore deformation caused by gas adsorption-induced coal expansion,the occurrence mechanism of adsorption–desorption hysteresis and the fundamental reasons for the presence of residual gas were elucidated.Furthermore,the study explored the impact of CO_(2)and CH_(4)adsorption-desorption hysteresis effects on coal and gas outbursts,suggesting that coal seams rich in CO_(2)do not have a higher propensity for outbursts than those rich in CH_(4).展开更多
Despite the extensive application of advanced oxidation processes(AOPs)in water treatment,the efficiency of AOPs in eliminating various emerging contaminants such as halogenated antibiotics is constrained by a number ...Despite the extensive application of advanced oxidation processes(AOPs)in water treatment,the efficiency of AOPs in eliminating various emerging contaminants such as halogenated antibiotics is constrained by a number of factors.Halogen moieties exhibit strong resistance to oxidative radicals,affecting the dehalogenation and detoxification efficiencies.To address these limitations of AOPs,advanced reduction processes(ARPs)have been proposed.Herein,a novel nucleophilic reductant—namely,the carbon dioxide radical anion(CO_(2)^(·-))—is introduced for the simultaneous degradation,dehalogenation,and detoxification of florfenicol(FF),a typical halogenated antibiotic.The results demonstrate that FF is completely eliminated by CO_(2)^(·-),with approximately 100%of Cland 46%of Freleased after 120 min of treatment.Simultaneous detoxification is observed,which exhibits a linear response to the release of free inorganic halogen ions(R^(2)=0.97,p<0.01).The formation of halogen-free products is the primary reason for the superior detoxification performance of this method,in comparison with conventional hydroxyl-radical-based AOPs.Products identification and density functional theory(DFT)calculations reveal the underlying dehalogenation mechanism,in which the chlorine moiety of FF is more susceptible than other moieties to nucleophilic attack by CO_(2)^(·-).Moreover,CO_(2)^(·-)-based ARPs exhibit superior dehalogenation efficiencies(>75%)in degrading a series of halogenated antibiotics,including chloramphenicol(CAP),thiamphenicol(THA),diclofenac(DLF),triclosan(TCS),and ciprofloxacin(CIP).The system shows high tolerance to the pH of the solution and the presence of natural water constituents,and demonstrates an excellent degradation performance in actual groundwater,indicating the strong application potential of CO_(2)^(·-)-based ARPs in real life.Overall,this study elucidates the feasibility of CO_(2)^(·-)for the simultaneous degradation,dehalogenation,and detoxification of halogenated antibiotics and provides a promising method for their regulation during water or wastewater treatment.展开更多
Natural magnetite formed by the isomorphism substitutions of transition metals,including Fe,Ti,Co,etc.,was activated by mechanical grinding followed by H2 reduction.The temperature-programmed reduction of hydrogen(H2-...Natural magnetite formed by the isomorphism substitutions of transition metals,including Fe,Ti,Co,etc.,was activated by mechanical grinding followed by H2 reduction.The temperature-programmed reduction of hydrogen(H2-TPR)and temperature-programmed surface reaction of carbon dioxide(CO2-TPSR)were carried out to investigate the processes of oxygen loss and CO2 reduction.The samples were characterized by X-ray diffraction(XRD),field emission scanning electron microscopy(FE-SEM),and energy-dispersive X-ray spectroscopy(EDS).The results showed that the stability of spinel phases and oxygen-deficient degree significantly increased after natural magnetite was mechanically milled and reduced in H2 atmosphere.Meanwhile,the activity and selectivity of CO2 reduction into carbon were enhanced.The deposited carbon on the activated natural magnetite was confirmed as amorphous.The amount of carbon after CO2 reduction at 300°C for 90 min over the activated natural magnetite was 2.87wt%higher than that over the natural magnetite.展开更多
The efficient pyrolysis and conversion of organic matter in organic-rich shale,as well as the effective recovery of pyrolysis shale oil and gas,play a vital role in alleviating energy pressure.The state of carbon diox...The efficient pyrolysis and conversion of organic matter in organic-rich shale,as well as the effective recovery of pyrolysis shale oil and gas,play a vital role in alleviating energy pressure.The state of carbon dioxide(CO_(2))in the pyrolysis environment of shale reservoirs is the supercritical state.Its unique supercritical fluid properties not only effectively heat organic matter,displace pyrolysis products and change shale pore structure,but also achieve carbon storage to a certain extent.Shale samples were made into powder and three sizes of cores,and nitrogen(N_(2))and supercritical carbon dioxide(ScCO_(2))pyrolysis experiments were performed at different final pyrolysis temperatures.The properties and mineral characteristics of the pyrolysis products were studied based on gas chromatography analysis,Xray diffraction tests,and mass spectrometry analysis.Besides,the pore structure characteristics at different regions of cores before and after pyrolysis were analyzed using N_(2) adsorption tests to clarify the impact of fracturing degree on the pyrolysis effect.The results indicate that the optimal pyrolysis temperature of Longkou shale is about 430℃.Compared with N_(2),the oil yield of ScCO_(2) pyrolysis is higher.The pyrolysis oil obtained by ScCO_(2) extraction has more intermediate fractions and higher relative molecular weight.The ScCO_(2) can effectively improve the pore diameter of shale and its effect is better than that of N_(2).The micropores are produced in shale after pyrolysis,and the macropores only are generated in ScCO_(2) pyrolysis environments with temperatures greater than 430℃.The pore structure has different development characteristics at different pyrolysis temperatures,which are mainly affected by the pressure holding of volatile matter and products blocking.Compared to the surface of the core,the pore development effect inside the core is better.With the decrease in core size,the pore diameter,specific surface area,and pore volume of cores all increase after pyrolysis.展开更多
The process based on supercritical fluid extraction for reprocessing of the spent nuclear fuel has some remarkable advantages over the plutonium-uranium extraction(PUREX) process.Especially,it can minimize the generat...The process based on supercritical fluid extraction for reprocessing of the spent nuclear fuel has some remarkable advantages over the plutonium-uranium extraction(PUREX) process.Especially,it can minimize the generation of secondary waste.Dynamic reactive extraction of neodymium oxide(Nd2O3) in supercritical carbon dioxide(SC-CO2) containing tri-n-butyl phosphate-nitric acid(TBP-HNO3) complex was investigated.Temperature showed a positive effect on the extraction efficiency,while pressure showed a negative effect when the unsaturated TBP-HNO3 complex was employed for the dynamic reactive extraction of Nd2O3 in SC-CO2.Both temperature and pressure effects indicated that the kinetic process of the reactive extraction was controlled by the chemical reaction.A kinetic model was proposed to describe the extraction process.展开更多
The phase change of CO_(2) has a significant bearing on the siting, injection, and monitoring of storage. The phase state of CO_(2) is closely related to pressure. In the process of seismic exploration, the informatio...The phase change of CO_(2) has a significant bearing on the siting, injection, and monitoring of storage. The phase state of CO_(2) is closely related to pressure. In the process of seismic exploration, the information of formation pressure can be response in the seismic data. Therefore, it is possible to monitor the formation pressure using time-lapse seismic method. Apart from formation pressure, the information of porosity and CO_(2) saturation can be reflected in the seismic data. Here, based on the actual situation of the work area, a rockphysical model is proposed to address the feasibility of time-lapse seismic monitoring during CO_(2) storage in the anisotropic formation. The model takes into account the formation pressure, variety minerals composition, fracture, fluid inhomogeneous distribution, and anisotropy caused by horizontal layering of rock layers(or oriented alignment of minerals). From the proposed rockphysical model and the well-logging, cores and geological data at the target layer, the variation of P-wave and S-wave velocity with formation pressure after CO_(2) injection is calculated. And so are the effects of porosity and CO_(2) saturation. Finally, from anisotropic exact reflection coefficient equation, the reflection coefficients under different formation pressures are calculated. It is proved that the reflection coefficient varies with pressure. Compared with CO_(2) saturation, the pressure has a greater effect on the reflection coefficient. Through the convolution model, the seismic record is calculated. The seismic record shows the difference with different formation pressure. At present, in the marine CO_(2) sequestration monitoring domain, there is no study involving the effect of formation pressure changes on seismic records in seafloor anisotropic formation. This study can provide a basis for the inversion of reservoir parameters in anisotropic seafloor CO_(2) reservoirs.展开更多
As a common precursor for supercritical CO_(2)(scCO_(2))deposition techniques,solubility data of organometallic complexes in scCO_(2)is crucial for the preparation of nanocomposites.Recently,metal acetylacetonates hav...As a common precursor for supercritical CO_(2)(scCO_(2))deposition techniques,solubility data of organometallic complexes in scCO_(2)is crucial for the preparation of nanocomposites.Recently,metal acetylacetonates have shown great potential for the preparation of single-atom catalytic materials.In this study,the solubilities of iron(Ⅲ)acetylacetonate(Fe(acac)3)and nickel(Ⅱ)acetylacetonate(Ni(acac)2)were measured at the temperature from 313.15 to 333.15 K and in the pressure range of 9.5–25.2 MPa to accumulate new solubility data.Solubility was measured using a static weight loss method.The semi-empirical models proposed by Chrastil and Sung et al.were used to correlate the solubility data of Fe(acac)3 and Ni(acac)2.The equations obtained can be used to predict the solubility of the same system in the experimental range.展开更多
Responses of atmospheric carbon dioxide(CO_(2))density to geomagnetic secular variation are investigated using the Whole Atmosphere Community Climate Model-eXtended(WACCM-X).Our ensemble simulations show that CO_(2) v...Responses of atmospheric carbon dioxide(CO_(2))density to geomagnetic secular variation are investigated using the Whole Atmosphere Community Climate Model-eXtended(WACCM-X).Our ensemble simulations show that CO_(2) volume mixing ratios(VMRs)increase at high latitudes and decrease at mid and low latitudes by several ppmv in response to a 50%weakening of the geomagnetic field.Statistically significant changes in CO_(2) are mainly found above~90 km altitude and primarily redetermine the energy budget at~100-110 km.Our analysis of transformed Eulerian mean(TEM)circulation found that CO_(2) change is caused by enhanced upwelling at high latitudes and downwelling at mid and low latitudes as a result of increased Joule heating.We further analyzed the atmospheric CO_(2) response to realistic geomagnetic weakening between 1978 and 2013,and found increasing(decreasing)CO_(2) VMRs at high latitudes(mid and low latitudes)accordingly.For the first time,our simulation results demonstrate that the impact of geomagnetic variation on atmospheric CO_(2) distribution is noticeable on a time scale of decades.展开更多
In recent years, there has been global interest in meeting targets relating to energy affordability and security while taking into account greenhouse gas emissions. This has heightened major interest in potential inve...In recent years, there has been global interest in meeting targets relating to energy affordability and security while taking into account greenhouse gas emissions. This has heightened major interest in potential investigations into the use of supercritical carbon dioxide (sCO2) power cycles. Climate change mitigation is the ultimate driver for this increased interest;other relevant issues include the potential for high cycle efficiency and a circular economy. In this study, a 25 MWe recompression closed Brayton cycle (RCBC) has been assessed, and sCO2 has been proposed as the working fluid for the power plant. The methodology used in this research work comprises thermodynamic and techno-economic analysis for the prospective commercialization of this sCO2 power cycle. An evaluated estimation of capital expenditure, operational expenditure, and cost of electricity has been considered in this study. The ASPEN Plus simulation results have been compared with theoretical and mathematical calculations to assess the performance of the compressors, turbine, and heat exchangers. The results thus reveal that the cycle efficiency for this prospective sCO2 recompression closed Brayton cycle increases (39% - 53.6%) as the temperature progressively increases from 550˚C to 900˚C. Data from the Aspen simulation model was used to aid the cost function calculations to estimate the total capital investment cost of the plant. Also, the techno-economic results have shown less cost for purchasing equipment due to fewer components being required for the cycle configuration as compared to the conventional steam power plant.展开更多
The environmental impact of aerosols is currently a hot issue that has received worldwide attention. Lacking simultaneous observations of aerosols and carbon flux, the understanding of the aerosol radiative effect of ...The environmental impact of aerosols is currently a hot issue that has received worldwide attention. Lacking simultaneous observations of aerosols and carbon flux, the understanding of the aerosol radiative effect of urban agglomeration on the net ecosystem carbon exchange(NEE) is restricted. In 2009-2010, an observation of the aerosol optical property and CO_(2) flux was carried out at the Dongguan Meteorological Bureau Station(DMBS) using a sun photometer and eddy covariance systems. The different components of photosynthetically active radiation(PAR),including global PAR(GPAR), direct PAR(DPAR), and scattered PAR(FPAR), were calculated using the Santa Barbara DISORT Atmospheric Radiative Transfer(SBDART) model. The effects of PAR on the NEE between land-atmosphere systems were investigated. The results demonstrated that during the study period the aerosol optical depth(AOD)reduced the DPAR by 519.28±232.89 μmol photons · m^(-2)s^(-1), but increased the FPAR by 324.93±169.85μmol photons ·m^(-2)s^(-1),ultimately leading to 194.34±92.62 μmol photons · m^(-2)s^(-1);decrease in the GPAR. All the PARs(including GPAR,DPAR, and FPAR) resulted in increases in the NEE(improved carbon absorption), but the FPAR has the strongest effect with the light use efficiency(LUE) being 1.12 times the values for the DPAR. The absorption of DPAR by the vegetation exhibited photo-inhibition in the radiation intensity > 600 photons · m^(-2)s^(-1);in contrast, the absorptions of FPAR did not exhibit apparent photo-inhibition. Compared with the FPAR caused by aerosols, the DPAR was not the primary factor affecting the NEE. On the contrary, the increase in AOD significantly increased the FPAR, enhancing the LUE of vegetation ecosystems and finally promoting the photosynthetic CO_(2) absorption.展开更多
This paper aims at using of an approach integrating the fuzzy logic strategy for hypoxemic hypoxia tissue blood carbon dioxide human optimal control problem. To test the efficiency of this strategy, the authors propos...This paper aims at using of an approach integrating the fuzzy logic strategy for hypoxemic hypoxia tissue blood carbon dioxide human optimal control problem. To test the efficiency of this strategy, the authors propose a numerical comparison with the direct method by taking the values of determinant parameters of cardiovascular-respiratory system for a 30 years old woman in jogging as her regular physical activity. The results are in good agreement with experimental data.展开更多
基金supported by the Shandong Province Natural Science Foundation Youth Branch(ZR2023QC157)the National Natural Science Foundation of China(51979233)+1 种基金the Key Research and Development Project of Shaanxi Province(2022KW-47,2022NY-220)the Heze University Doctoral Research Fund(XY21BS24,XY22BS17).
文摘Drip irrigation and flood irrigation are major irrigation methods for maize crops in the Hetao Irrigation District,Inner Mongolia Autonomous Region,China.This research delves into the effects of these irrigation methods on carbon dioxide(CO_(2))exchange and crop growth in this region.The experimental site was divided into drip and flood irrigation zones.The irrigation schedules of this study aligned with the local commonly used irrigation schedule.We employed a developed chamber system to measure the diurnal CO_(2)exchange of maize plants during various growth stages under both drip and flood irrigation methods.From May to September in 2020 and 2021,two sets of repeated experiments were conducted.In each experiment,a total of nine measurements of CO_(2)exchange were performed to obtain carbon exchange data at different growth stages of maize crop.During each CO_(2)exchange measurement event,CO_(2)flux data were collected every two hours over a day-long period to capture the diurnal variations in CO_(2)exchange.During each CO_(2)exchange measurement event,the biological parameters(aboveground biomass and crop growth rate)of maize and environmental parameters(including air humidity,air temperature,precipitation,soil water content,and photosynthetically active radiation)were measured.The results indicated a V-shaped trend in net ecosystem CO_(2)exchange in daytime,reducing slowly at night,while the net assimilation rate(net primary productivity)exhibited a contrasting trend.Notably,compared with flood irrigation,drip irrigation demonstrated significantly higher average daily soil CO_(2)emission and greater average daily CO_(2)absorption by maize plants.Consequently,within the maize ecosystem,drip irrigation appeared more conducive to absorbing atmospheric CO_(2).Furthermore,drip irrigation demonstrated a faster crop growth rate and increased aboveground biomass compared with flood irrigation.A strong linear relationship existed between leaf area index and light utilization efficiency,irrespective of the irrigation method.Notably,drip irrigation displayed superior light use efficiency compared with flood irrigation.The final yield results corroborated these findings,indicating that drip irrigation yielded higher harvest index and overall yield than flood irrigation.The results of this study provide a basis for the selection of optimal irrigation methods commonly used in the Hetao Irrigation District.This research also serves as a reference for future irrigation studies that consider measurements of both carbon emissions and yield simultaneously.
基金funding from the European Research Council (ERC)under grant agreement no.834134 (WATUSO)VLAIO for Moonshot funding (ARCLATH,No.HBC.2019.0110 and ARCLATH2,No.HBC.2021.0254)+3 种基金supported by the Flemish Government as an international research infrastructure (I001321N)infrastructure support by Department EWI via the Hermes Fund (AH.2016.134)the Hercules Foundation (AKUL/13/21)FWO Vlaanderen for an FWO-SB fellowship。
文摘1.Challenges circular methane energy systems In recent decades,methane-based energy systems have rapidly gained traction across the globe because of the increasing availability of low-cost methane production capacity.However,fossil methane production and combustion lead to large greenhouse gas emissions,contributing to climate change[1].
基金supported by the National Key R&D Program of China(2018YFA0901700)the National Natural Science Foundation of China(31970038,22278241)+1 种基金a grant from the Institute Guo Qiang,Tsinghua University(2021GQG1016)the Department of Chemical Engineering-i BHE Joint Cooperation Fund。
文摘The unabated carbon dioxide(CO_(2))emission into the atmosphere has exacerbated global climate change,resulting in extreme weather events,biodiversity loss,and an intensified greenhouse effect.To address these challenges and work toward carbon(C)neutrality and reduced CO_(2)emissions,the capture and utilization of CO_(2)have become imperative in both scientific research and industry.One cutting-edge approach to achieving efficient catalytic performance involves integrating green bioconversion and chemical conversion.This innovative strategy offers several advantages,including environmental friendliness,high efficiency,and multi-selectivity.This study provides a comprehensive review of existing technical routes for carbon sequestration(CS)and introduces two novel CS pathways:the electrochemicalbiological hybrid and artificial photosynthesis systems.It also thoroughly examines the synthesis of valuable Cnproducts from the two CS systems employing different catalysts and biocatalysts.As both systems heavily rely on electron transfer,direct and mediated electron transfer has been discussed and summarized in detail.Additionally,this study explores the conditions suitable for different catalysts and assesses the strengths and weaknesses of biocatalysts.We also explored the biocompatibility of the electrode materials and developed novel materials.These materials were specifically engineered to combine with enzymes or microbial cells to solve the biocompatibility problem,while improving the electron transfer efficiency of both.Furthermore,this review summarizes the relevant systems developed in recent years for manufacturing different products,along with their respective production efficiencies,providing a solid database for development in this direction.The novel chemical-biological combination proposed herein holds great promise for the future conversion of CO_(2)into advanced organic compounds.Additionally,it offers exciting prospects for utilizing CO_(2)in synthesizing a wide range of industrial products.Ultimately,the present study provides a unique perspective for achieving the vital goals of“peak shaving”and C-neutrality,contributing significantly to our collective efforts to combat climate change and its associated challenges.
文摘Climate researchers have observed that the carbon dioxide (CO2) concentration in the atmosphere have been growing significantly over the past century. CO2 from energy represents about 75% of the greenhouse gas (GHG) emissions for Annex B (Developed) countries, and over 60% of global emissions. Because of impermeable cap rocks hydrocarbon reservoirs are able to sequester CO〉 In addition, due to high-demand for oil worldwide, injection of CO2 is a useful way to enhance oil production. Hence, applying an efficient method to co-optimize CO2 storage and oil production is vital. Lack of suitable optimization techniques in the past led most multi-objective optimization problems to be tackled in the same way as a single objective optimization issue. However, there are some basic differences between the multi and single objective optimization methods. In this study, by using a non- dominated sorting genetic algorithm (NSGA-II) for an oil reservoir, some appropriate scenarios are proposed based on simultaneous gas storage and enhanced oil recovery optimization. The advantages of this method allow us to amend production scenarios after implementing the optimization process, by regarding the variation of economic parameters such as oil price and CO2 tax. This leads to reduced risks and time duration of making new decisions based on upcoming situations.
基金funded by Australian Research Council Discovery Project(Grant No.DP110104766)financial support from the China Australia Geological Storage of CO_2 Project(CAGS)Australia-China Young Researchers Exchange Program 2012
文摘The use of sequestered carbon dioxide(CO) as the heat exchange fluid in enhanced geothermal system(EGS) has significant potential to increase their productivity, contribute further to reducing carbon emissions and increase the economic viability of geothermal power generation. Coupled COsequestration and geothermal energy production from hot dry rock(HDR) EGS were first proposed 15 years ago but have yet to be practically implemented. This paper reviews some of the issues in assessing these systems with particular focus on the power generation and COsequestration capacity. The Habanero geothermal field in the Cooper Basin of South Australia is assessed for its potential COstorage capacity if supercritical COis used as the working fluid for heat extraction. The analysis suggests that the major COsequestration mechanisms are the storage in the fracture-stimulation damaged zone followed by diffusion into the pores within the rock matrix. The assessment indicates that 5% of working fluid loss commonly suggested as the storage capacity might be an over-estimate of the long-term COsequestration capacity of EGS in which supercritical COis used as the circulation fluid.
文摘AIM: To evaluate the effects of using CO2 as negative contrast agent in decreasing the overlapping on the pancreaticobiliary system from intestinal fluids.METHODS:We evaluated the magnetic resonance cholangiopancreatography(MRCP) images in 117 patients divided into two groups(group 1,without taking gas producing crystals to produce CO2,n=64;group 2,with CO2,n=53)in a 1.5T unit using MRCP sequence.Anatomic locations of intestinal fluids distribution,overlapping with common bile duct(CBD)and pancreatic duct(PD),were evaluated.RESULTS:In the group with CO2,the decrease in distribution of intestinal fluids was significant in the gastric antrum(P=0.001)and duodenal bulb(P<0.001),but not in the gastric fundus and body and in the second portion of the duodenum(P=1.000,P=0.171,and P=0.584 respectively).In the group with CO2,the decrease in overlapping with CBD was significant(P< 0.001),but the decrease in overlapping with PD was not (P=0.106).CONCLUSION:MRCP with carbon dioxide as negative contrast agent would decrease intestinal fluids in the gastric antrum and duodenal bulb,thereby decreasing overlapping with the CBD.
基金The Research and Development Special Fund for Public Welfare Industry (meteorology) of the China Meteorological Adminstration under contract No.2008416022the Ocean Public Welfare Scientific Research Project of State Oceanic Administration of China under contract No.200905012-4+1 种基金the National Natural Science Foundation of China under contract Nos 40730106,41075091 and 41105087the National Basic Research Program (973 Program) of China under contract No. 2010CB951802
文摘Interannual variations of the air-sea CO2 exchange from 1965 to 2000 in the Pacific Ocean are studied with a Pacific Ocean model. Two numerical experiments are performed, including the control run that is forced by climatological monthly mean physical data and the climate-change run that is forced by interannually varying monthly mean physical data. Climatological monthly winds are used in both runs to calculate the coefficient of air-sea CO2 exchange. The analysis through the differences between the two runs shows that in the tropical Pacific the variation of export production induced by interannual variations of the physical fields is negatively correlated with that of the air-sea CO2 flux, while there is no correlation or a weak positive correlation in the subtropical North and South Pacific. It indicates that the variation of the physical fields can modulate the variation of the air-sea CO2 flux in converse ways in the tropical Pacific by changing the direct transport and biochemical process. Under the interannually varying monthly mean forcing, the simulated EOF 1 of the air-sea CO2 flux is basically consistent with that of sea surface temperature (SST) in the tropical Pacific, but contrary in the two subtropical Pacific Ocean. The correlation coefficient between the regionally integrated air-sea CO2 flux and area-mean SST shows that when the air-sea CO2 flux lags SST by about 5 months, the positive coefficient in the three regions is largest, indicating that in the tropical Pacific or on the longer time scale in the three regions, physical processes control the fiux-SST relationship.
基金supported by Future Trees Trust,The Patsy Wood Trust,Scottish Forestry Trust,Aitchinson Tait Trust,and Action Oak for fundingsupport from the UK Natural Environment Research Council (NE/S015833/1 (QUINTUS))+1 种基金support from the JABBS Trust,Norbury Park Estate,The John Horseman Trust,Ecological Continuity Trust,and the University of BirminghamAccess to BIFoR Core Data was funded by Royal Society University Research Fellowship URFR1191326
文摘Acorn production in oak(Quercus spp.)shows considerable inter-annual variation,known as masting,which provides a natural defence against seed predators but a highly-variable supply of acorns for uses such as in commercial tree planting each year.Anthropogenic emissions of greenhouse gases have been very widely reported to influence plant growth and seed or fruit size and quantity via the‘fertilisation effect’that leads to enhanced photosynthesis.To examine if acorn production in mature woodland communities will be affected by further increase in CO_(2),the contents of litter traps from a Free Air Carbon Enrichment(FACE)experiment in deciduous woodland in central England were analysed for numbers of flowers and acorns of pedunculate oak(Quercus robur L.)at different stages of development and their predation levels under ambient and elevated CO_(2) concentrations.Inter-annual variation in acorn numbers was considerable and cyclical between 2015 and 2021,with the greatest numbers of mature acorns in 2015,2017 and 2020 but almost none in 2018.The numbers of flowers,enlarged cups,immature acorns,empty acorn cups,and galls in the litter traps also varied amongst years;comparatively high numbers of enlarged cups were recorded in 2018,suggesting Q.robur at this site is a fruit maturation masting species(i.e.,the extent of abortion of pollinated flowers during acorn development affects mature acorn numbers greatly).Raising the atmospheric CO_(2) concentration by 150μL L^(−1),from early 2017,increased the numbers of immature acorns,and all acorn evidence(empty cups+immature acorns+mature acorns)detected in the litter traps compared to ambient controls by 2021,but did not consistently affect the numbers of flowers,enlarged cups,empty cups,or mature acorns.The number of flowers in the elevated CO_(2) plots’litter traps was greater in 2018 than 2017,one year after CO_(2) enrichment began,whereas numbers declined in ambient plots.Enrichment with CO_(2) also increased the number of oak knopper galls(Andricus quercuscalicis Burgsdorf).We conclude that elevated CO_(2) increased the occurrence of acorns developing from flowers,but the putative benefit to mature acorn numbers may have been hidden by excessive pre-and/or post-dispersal predation.There was no evidence that elevated CO_(2) altered masting behaviour.
基金jointly supported by the National Key Research and Development Program of China (Grant No. 2022YFC3105000)the Youth Innovation Promotion Association of CAS (2022074)+3 种基金the National Natural Science Foundation of China (Grant Nos. 42005123, 42275173 and 41706028)the National Key Research and Development Program of China(2022YFE0106500)the 7th Youth Talent Support Project of Ningxia Hui Autonomous Region Association for Science and TechnologyNational Key Scientific and Technological Infrastructure project ‘‘Earth System Science Numerical Simulator Facility’’(EarthLab) for supporting the simulations in this study
文摘Understanding the response of the Earth system to varying concentrations of carbon dioxide(CO_(2))is critical for projecting possible future climate change and for providing insight into mitigation and adaptation strategies in the near future.In this study,we generate a dataset by conducting an experiment involving carbon dioxide removal(CDR)—a potential way to suppress global warming—using the Chinese Academy of Sciences Earth System Model version 2.0(CASESM2.0).A preliminary evaluation is provided.The model is integrated from 200–340 years as a 1%yr^(−1) CO_(2) concentration increase experiment,and then to~478 years as a carbon dioxide removal experiment until CO_(2) returns to its original value.Finally,another 80 years is integrated in which CO_(2) is kept constant.Changes in the 2-m temperature,precipitation,sea surface temperature,ocean temperature,Atlantic meridional overturning circulation(AMOC),and sea surface height are all analyzed.In the ramp-up period,the global mean 2-m temperature and precipitation both increase while the AMOC weakens.Values of all the above variables change in the opposite direction in the ramp-down period,with a delayed peak relative to the CO_(2) peak.After CO_(2) returns to its original value,the global mean 2-m temperature is still~1 K higher than in the original state,and precipitation is~0.07 mm d^(–1) higher.At the end of the simulation,there is a~0.5°C increase in ocean temperature and a 1 Sv weakening of the AMOC.Our model simulation produces similar results to those of comparable experiments previously reported in the literature.
基金provided by the China Scholarship Council(No.202006430006)and the University of Wollongongsupported by the ACARP Projects(Nos.C28006 and C35015)support from the Coal Services Health and Safety Trust(No.20661)。
文摘Methane(CH_(4))and carbon dioxide(CO_(2))are primary components of coal seam gas(CSG).Understanding their adsorption-desorption hysteresis characteristics,along with the fundamental mechanism,is crucial for CSG exploitation and related hazards mitigation.This research focused on the representative Bulli coal seam in the Sydney Basin,Australia.Through the purpose-built indirect gravimetric high-pressure isothermal adsorption-desorption hysteresis experiment,a novel Langmuir-based desorption model,incorporating hysteresis effect and residual gas,was proposed.Quantitative characterization of the adsorption-desorption hysteresis degrees of CO_(2)and CH_(4)i n coal particles of various sizes and inΦ50mm 100 mm intact coal samples were achieved using the improved hysteresis index(IHI).The experimental findings validated that the proposed desorption model accurately describes the desorption behavior of CO_(2)and CH_(4)in coal(R^(2)>0.99).Based on the adsorption-desorption properties of inkbottle-shaped micropores and pore deformation caused by gas adsorption-induced coal expansion,the occurrence mechanism of adsorption–desorption hysteresis and the fundamental reasons for the presence of residual gas were elucidated.Furthermore,the study explored the impact of CO_(2)and CH_(4)adsorption-desorption hysteresis effects on coal and gas outbursts,suggesting that coal seams rich in CO_(2)do not have a higher propensity for outbursts than those rich in CH_(4).
基金financially supported by the National Natural Science Foundation of China(22176059,21777042,and 22076045)the authors would also like to acknowledge support from the Science and Technology Commission of Shanghai Municipality’s Yangfan Special Project(23YF1408400)the Fundamental Research Funds for the Central Universities.
文摘Despite the extensive application of advanced oxidation processes(AOPs)in water treatment,the efficiency of AOPs in eliminating various emerging contaminants such as halogenated antibiotics is constrained by a number of factors.Halogen moieties exhibit strong resistance to oxidative radicals,affecting the dehalogenation and detoxification efficiencies.To address these limitations of AOPs,advanced reduction processes(ARPs)have been proposed.Herein,a novel nucleophilic reductant—namely,the carbon dioxide radical anion(CO_(2)^(·-))—is introduced for the simultaneous degradation,dehalogenation,and detoxification of florfenicol(FF),a typical halogenated antibiotic.The results demonstrate that FF is completely eliminated by CO_(2)^(·-),with approximately 100%of Cland 46%of Freleased after 120 min of treatment.Simultaneous detoxification is observed,which exhibits a linear response to the release of free inorganic halogen ions(R^(2)=0.97,p<0.01).The formation of halogen-free products is the primary reason for the superior detoxification performance of this method,in comparison with conventional hydroxyl-radical-based AOPs.Products identification and density functional theory(DFT)calculations reveal the underlying dehalogenation mechanism,in which the chlorine moiety of FF is more susceptible than other moieties to nucleophilic attack by CO_(2)^(·-).Moreover,CO_(2)^(·-)-based ARPs exhibit superior dehalogenation efficiencies(>75%)in degrading a series of halogenated antibiotics,including chloramphenicol(CAP),thiamphenicol(THA),diclofenac(DLF),triclosan(TCS),and ciprofloxacin(CIP).The system shows high tolerance to the pH of the solution and the presence of natural water constituents,and demonstrates an excellent degradation performance in actual groundwater,indicating the strong application potential of CO_(2)^(·-)-based ARPs in real life.Overall,this study elucidates the feasibility of CO_(2)^(·-)for the simultaneous degradation,dehalogenation,and detoxification of halogenated antibiotics and provides a promising method for their regulation during water or wastewater treatment.
基金This work was supported by the National Key Research and Development Program of China(No.2016YFB 0600904).The authors gratefully acknowledge the support of the Analytical and Test Center of Sichuan University.
文摘Natural magnetite formed by the isomorphism substitutions of transition metals,including Fe,Ti,Co,etc.,was activated by mechanical grinding followed by H2 reduction.The temperature-programmed reduction of hydrogen(H2-TPR)and temperature-programmed surface reaction of carbon dioxide(CO2-TPSR)were carried out to investigate the processes of oxygen loss and CO2 reduction.The samples were characterized by X-ray diffraction(XRD),field emission scanning electron microscopy(FE-SEM),and energy-dispersive X-ray spectroscopy(EDS).The results showed that the stability of spinel phases and oxygen-deficient degree significantly increased after natural magnetite was mechanically milled and reduced in H2 atmosphere.Meanwhile,the activity and selectivity of CO2 reduction into carbon were enhanced.The deposited carbon on the activated natural magnetite was confirmed as amorphous.The amount of carbon after CO2 reduction at 300°C for 90 min over the activated natural magnetite was 2.87wt%higher than that over the natural magnetite.
基金supported by the National Natural Science Foundation of China (Nos.U22B6004,51974341)State Key Laboratory of Deep Oil and Gas (No.SKLDOG2024-ZYTS-14)the Fundamental Research Funds for the Central Universities (No.20CX06070A)。
文摘The efficient pyrolysis and conversion of organic matter in organic-rich shale,as well as the effective recovery of pyrolysis shale oil and gas,play a vital role in alleviating energy pressure.The state of carbon dioxide(CO_(2))in the pyrolysis environment of shale reservoirs is the supercritical state.Its unique supercritical fluid properties not only effectively heat organic matter,displace pyrolysis products and change shale pore structure,but also achieve carbon storage to a certain extent.Shale samples were made into powder and three sizes of cores,and nitrogen(N_(2))and supercritical carbon dioxide(ScCO_(2))pyrolysis experiments were performed at different final pyrolysis temperatures.The properties and mineral characteristics of the pyrolysis products were studied based on gas chromatography analysis,Xray diffraction tests,and mass spectrometry analysis.Besides,the pore structure characteristics at different regions of cores before and after pyrolysis were analyzed using N_(2) adsorption tests to clarify the impact of fracturing degree on the pyrolysis effect.The results indicate that the optimal pyrolysis temperature of Longkou shale is about 430℃.Compared with N_(2),the oil yield of ScCO_(2) pyrolysis is higher.The pyrolysis oil obtained by ScCO_(2) extraction has more intermediate fractions and higher relative molecular weight.The ScCO_(2) can effectively improve the pore diameter of shale and its effect is better than that of N_(2).The micropores are produced in shale after pyrolysis,and the macropores only are generated in ScCO_(2) pyrolysis environments with temperatures greater than 430℃.The pore structure has different development characteristics at different pyrolysis temperatures,which are mainly affected by the pressure holding of volatile matter and products blocking.Compared to the surface of the core,the pore development effect inside the core is better.With the decrease in core size,the pore diameter,specific surface area,and pore volume of cores all increase after pyrolysis.
基金Supported by the National Natural Science Foundation of China (20506014).
文摘The process based on supercritical fluid extraction for reprocessing of the spent nuclear fuel has some remarkable advantages over the plutonium-uranium extraction(PUREX) process.Especially,it can minimize the generation of secondary waste.Dynamic reactive extraction of neodymium oxide(Nd2O3) in supercritical carbon dioxide(SC-CO2) containing tri-n-butyl phosphate-nitric acid(TBP-HNO3) complex was investigated.Temperature showed a positive effect on the extraction efficiency,while pressure showed a negative effect when the unsaturated TBP-HNO3 complex was employed for the dynamic reactive extraction of Nd2O3 in SC-CO2.Both temperature and pressure effects indicated that the kinetic process of the reactive extraction was controlled by the chemical reaction.A kinetic model was proposed to describe the extraction process.
文摘The phase change of CO_(2) has a significant bearing on the siting, injection, and monitoring of storage. The phase state of CO_(2) is closely related to pressure. In the process of seismic exploration, the information of formation pressure can be response in the seismic data. Therefore, it is possible to monitor the formation pressure using time-lapse seismic method. Apart from formation pressure, the information of porosity and CO_(2) saturation can be reflected in the seismic data. Here, based on the actual situation of the work area, a rockphysical model is proposed to address the feasibility of time-lapse seismic monitoring during CO_(2) storage in the anisotropic formation. The model takes into account the formation pressure, variety minerals composition, fracture, fluid inhomogeneous distribution, and anisotropy caused by horizontal layering of rock layers(or oriented alignment of minerals). From the proposed rockphysical model and the well-logging, cores and geological data at the target layer, the variation of P-wave and S-wave velocity with formation pressure after CO_(2) injection is calculated. And so are the effects of porosity and CO_(2) saturation. Finally, from anisotropic exact reflection coefficient equation, the reflection coefficients under different formation pressures are calculated. It is proved that the reflection coefficient varies with pressure. Compared with CO_(2) saturation, the pressure has a greater effect on the reflection coefficient. Through the convolution model, the seismic record is calculated. The seismic record shows the difference with different formation pressure. At present, in the marine CO_(2) sequestration monitoring domain, there is no study involving the effect of formation pressure changes on seismic records in seafloor anisotropic formation. This study can provide a basis for the inversion of reservoir parameters in anisotropic seafloor CO_(2) reservoirs.
基金financial support from the National Key Research and Development Program of China(2020YFA0710202)the National Natural Science Foundation of China(21978043,U1662130)+1 种基金Inner Mongolia University of Technology Scientific Research Initial Funding(DC2300001240)Talent Introduction Support Project of Inner Mongolia(DC2300001426).
文摘As a common precursor for supercritical CO_(2)(scCO_(2))deposition techniques,solubility data of organometallic complexes in scCO_(2)is crucial for the preparation of nanocomposites.Recently,metal acetylacetonates have shown great potential for the preparation of single-atom catalytic materials.In this study,the solubilities of iron(Ⅲ)acetylacetonate(Fe(acac)3)and nickel(Ⅱ)acetylacetonate(Ni(acac)2)were measured at the temperature from 313.15 to 333.15 K and in the pressure range of 9.5–25.2 MPa to accumulate new solubility data.Solubility was measured using a static weight loss method.The semi-empirical models proposed by Chrastil and Sung et al.were used to correlate the solubility data of Fe(acac)3 and Ni(acac)2.The equations obtained can be used to predict the solubility of the same system in the experimental range.
基金This work was supported by the B-type Strategic Priority Program of the Chinese Academy of Sciences(Grant No.XDB41000000)the National Natural Science Foundation of China(41621004,41427901)+2 种基金the Open Research Project of Large Research Infrastructures—“Study on the interaction between low/mid-latitude atmosphere and ionosphere based on the Chinese Meridian Project”the Key Research Program of the IGGCAS with Grant No.IGGCAS-201904XZ thanks the UCAS Joint PhD Training Program.The National Center for Atmospheric Research is a major facility sponsored by the National Science Foundation under Cooperative Agreement No.1852977.
文摘Responses of atmospheric carbon dioxide(CO_(2))density to geomagnetic secular variation are investigated using the Whole Atmosphere Community Climate Model-eXtended(WACCM-X).Our ensemble simulations show that CO_(2) volume mixing ratios(VMRs)increase at high latitudes and decrease at mid and low latitudes by several ppmv in response to a 50%weakening of the geomagnetic field.Statistically significant changes in CO_(2) are mainly found above~90 km altitude and primarily redetermine the energy budget at~100-110 km.Our analysis of transformed Eulerian mean(TEM)circulation found that CO_(2) change is caused by enhanced upwelling at high latitudes and downwelling at mid and low latitudes as a result of increased Joule heating.We further analyzed the atmospheric CO_(2) response to realistic geomagnetic weakening between 1978 and 2013,and found increasing(decreasing)CO_(2) VMRs at high latitudes(mid and low latitudes)accordingly.For the first time,our simulation results demonstrate that the impact of geomagnetic variation on atmospheric CO_(2) distribution is noticeable on a time scale of decades.
文摘In recent years, there has been global interest in meeting targets relating to energy affordability and security while taking into account greenhouse gas emissions. This has heightened major interest in potential investigations into the use of supercritical carbon dioxide (sCO2) power cycles. Climate change mitigation is the ultimate driver for this increased interest;other relevant issues include the potential for high cycle efficiency and a circular economy. In this study, a 25 MWe recompression closed Brayton cycle (RCBC) has been assessed, and sCO2 has been proposed as the working fluid for the power plant. The methodology used in this research work comprises thermodynamic and techno-economic analysis for the prospective commercialization of this sCO2 power cycle. An evaluated estimation of capital expenditure, operational expenditure, and cost of electricity has been considered in this study. The ASPEN Plus simulation results have been compared with theoretical and mathematical calculations to assess the performance of the compressors, turbine, and heat exchangers. The results thus reveal that the cycle efficiency for this prospective sCO2 recompression closed Brayton cycle increases (39% - 53.6%) as the temperature progressively increases from 550˚C to 900˚C. Data from the Aspen simulation model was used to aid the cost function calculations to estimate the total capital investment cost of the plant. Also, the techno-economic results have shown less cost for purchasing equipment due to fewer components being required for the cycle configuration as compared to the conventional steam power plant.
基金National Key R&D Program of China(2019YFC0214605)Key-Area R&D Program of Guangdong Province (2020B1111360003)+4 种基金Provincial Natural Science Foundation of Guangdong (2021A1515011494)Science and Technology Innovation Team Plan of Guangdong Meteorological Bureau (GRMCTD202003)Open Project of the Key Laboratory for Aerosol-Cloud-Precipitation of China Meteorological Administration,Nanjing University of Information Science and Technology (KDW 1803)Scientific and Technological Innovation Team Project of Guangzhou Joint Research Center of Atmospheric Sciences,China Meteorological Administration (201704)Science and Technology Research Project of Guangdong Meteorological Bureau (GRMC2018M01)。
文摘The environmental impact of aerosols is currently a hot issue that has received worldwide attention. Lacking simultaneous observations of aerosols and carbon flux, the understanding of the aerosol radiative effect of urban agglomeration on the net ecosystem carbon exchange(NEE) is restricted. In 2009-2010, an observation of the aerosol optical property and CO_(2) flux was carried out at the Dongguan Meteorological Bureau Station(DMBS) using a sun photometer and eddy covariance systems. The different components of photosynthetically active radiation(PAR),including global PAR(GPAR), direct PAR(DPAR), and scattered PAR(FPAR), were calculated using the Santa Barbara DISORT Atmospheric Radiative Transfer(SBDART) model. The effects of PAR on the NEE between land-atmosphere systems were investigated. The results demonstrated that during the study period the aerosol optical depth(AOD)reduced the DPAR by 519.28±232.89 μmol photons · m^(-2)s^(-1), but increased the FPAR by 324.93±169.85μmol photons ·m^(-2)s^(-1),ultimately leading to 194.34±92.62 μmol photons · m^(-2)s^(-1);decrease in the GPAR. All the PARs(including GPAR,DPAR, and FPAR) resulted in increases in the NEE(improved carbon absorption), but the FPAR has the strongest effect with the light use efficiency(LUE) being 1.12 times the values for the DPAR. The absorption of DPAR by the vegetation exhibited photo-inhibition in the radiation intensity > 600 photons · m^(-2)s^(-1);in contrast, the absorptions of FPAR did not exhibit apparent photo-inhibition. Compared with the FPAR caused by aerosols, the DPAR was not the primary factor affecting the NEE. On the contrary, the increase in AOD significantly increased the FPAR, enhancing the LUE of vegetation ecosystems and finally promoting the photosynthetic CO_(2) absorption.
文摘This paper aims at using of an approach integrating the fuzzy logic strategy for hypoxemic hypoxia tissue blood carbon dioxide human optimal control problem. To test the efficiency of this strategy, the authors propose a numerical comparison with the direct method by taking the values of determinant parameters of cardiovascular-respiratory system for a 30 years old woman in jogging as her regular physical activity. The results are in good agreement with experimental data.