Experimental and quantum chemical studies of carboxylates as corrosion inhibitors for AM50 alloy in pH neutral NaCl solution

Sodium salts of mono-and di-carboxylic acids(glycolic,fumaric and benzoic acid)were studied as corrosion inhibitors for AM50 alloy in pH neutral aqueous NaCl environment.Hydrogen evolution,electrochemical and surface characterization techniques were employed to reveal their corrosion inhibition mechanism,whilst the molecular features of inhibitors were investigated by quantum chemical calculation.All inhibitors reduced anodic dissolution of AM50 and their efficiency generally increased with time and concentration from 5 mM to 100 mM.The inhibition mechanism can be described as physisorption of inhibitive molecules on the surface of the intrinsic oxide layer followed by chemisorption with Mg^(2+)and Al^(3+),and the difference in inhibition action among these inhibitors was explained on the molecular scale.

Electrochemical Oxidation of Ammonia on Ir Anode in Potential Fixed Electrochemical Sensor

Ir catalyst possesses a good electrocatalytic activity and selectivity for the oxidation of NH3 and/or NH4OH at Ir anode in the potential fixed electrochemical sensor with the neutral solution. Owing to the same electrochemical behavior of NH3 and NH4OH in a NaClO4 solution, NH4OH can be used instead of NH3 for the experimental convenience. It was found that the potential of the oxidation peak of NH4OH at the Ir/GC electrode in NaClO4 solutions is at about 0.85 V, and the current density of the oxidation peak of NH4OH is linearly proportional to the concentration of NHaOH. The electrocatalytic oxidation of NH4OH is diffusion-controlled. Especially, Ir has no electrocatalytic activity for the CO oxidation, illustrating that CO does not interfere in the measurement of NH4OH and the potential fixed electrochemical NH3 sensor with the neutral solution, and the anodic Ir catalyst possesses a good selectivity. Therefore, Ir may have practical application in the potential fixed electrochemical NH3 sensor with the neutral solution.

Stress corrosion cracking behavior of PH13-8Mo stainless steel in Cl^- solutions

The stress corrosion cracking（ SCC） behavior of PH13-8Mo precipitation hardening stainless steel（ PHSS） in neutral NaCl solutions was investigated through slow-strain-rate tensile（ SSRT） test at various applied potentials. Fracture morphology,elongation ratio,and percentage reduction of area were measured to evaluate the SCC susceptibility. A critical concentration of 1. 0 mol / L neutral NaCl existed for SCC of PH13-8Mo steel. Significant SCC emerged when the applied potential was more negative than -0. 15 VSCE,and the SCC behavior was controlled by an anodic dissolution（ AD） process.When the applied potential was lower than -0. 55 VSCE,an obvious hydrogen-fracture morphology was observed,which indicated that the SCC behavior was controlled by hydrogen-induced cracking（ HIC）.Between -0. 15 and -0. 35 VSCE,the applied potential exceeded the equilibrium hydrogen evolution potential in neutral NaCl solutions and the crack tips were of electrochemical origin in the anodic region; thus,the SCC process was dominated by the AD mechanism.

Weighted Pseudo Almost Periodic Solutions of N-th Order Neutral Differential Equations with Piecewise Constant Arguments

In this work, we present some existence theorems of weighted pseudo almost periodic solutions for N-th order neutral differential equations with piecewise constant argument by means of weighted pseudo almost periodic solutions of relevant difference equations.

UNIQUE EXISTENCE OF PERIODIC SOLUTIONS OF NEUTRAL VOLTERRA INTEGRODIFFERENTIAL EQUATIONS

This paper deals with the uniqueness and existence of periodic solutions of neutral Volterraintegrodifferential equations (1) and (2). Some new unique existence criteria are obtained.

THE NECESSARY AND SUFFICIENT CONDITIONS FOR THE EXISTENCE 0F PERIODIC SOLUTIONS OF A TYPE OF NEUTRAL FUNCTIONAL DIFFERENTIAL EQUATIONS

In this paper, using Fourier series, we study the problem of the existence of periodic solutionsof a type of periodic neutral differential difference system. Some necessary and sufficient conditionsfor the existence of periodic solutions of a type of neutral functional equation system are obtained,and at the same time, we present a method with formula shows how to find the periodicsolutions.

STABILITY AND ALMOST PERIODIC SOLUTIONS OF NEUTRAL FUNCTIONAL DIFFERENTIAL EQUATIONS WITH INFINITE DELAY

For the operator D(t), we prove the inherence theorem, Theorem 2. Basing on it, we study the stability with respect to the hull for neutral functional differential equations with infinite delay. We prove that if periodic Eq.(1) possesses the solution ξ(t) that is uniformly asymptotically stable with respect to then Eq.(1) has an mω-periodic solution p(t), for some integer m≥1. Furthermore, we prove that if the almost periodic Eq.(1) possesses the solution ξ(t) that is stable under disturbance from H+ (ξ,D,f), then Eq.(1) has an almost periodic solution.

TYPES AND CRITERIA OF NONOSCILLATORY SOLUTIONS FOR A CLASS OF SECOND ORDER NEUTRAL FUNCTIONAL DIFFERENTIAL EQUATIONS WITH NONPOSITIVE COEFFICIENTS

In this paper we discuss the types and criteria of nonoscillatory solutions for the fol-lowing second order neutral functional differential equation with nonpositive coefficients

Waste heat recovery and denitrification of flue gases from gas-fired boilers

A waste heat recovery and denitrification system was developed for improving energy conservation and emissions control especially for control of PM2.5 particles and haze. The system uses enhanced heat and mass transfer techniques in a packed heat exchange tower with self-rotation and zero-pressure spraying, low temperature NO oxidation by ozone, and neutralization with an alkali solution. Operating data in a test project gave NOx in the exhaust flue gas of less than 30 mg/Nm3 with an ozone addition rate of 8 kg/h and spray water p H of 7.5–8, an average heat recovery of 3 MW, and an average heat supply of 7.2 MW.